Waste Slag Research Articles

Utilizing Sewage Sludge Slag, a By-Product of the Circulating Fluidized Bed Combustion Process, to Efficiently Remove Copper from Aquatic Environment

Currently, one of the greatest threats to the aquatic environment is industrial wastewater containing heavy metals and other toxic substances. Hence, it seems necessary to search for ecological and cheap technologies for removing metals from wastewater. In this research, slag was used as waste obtained in the circulating fluidized bed combustion technology (CFBC), which is considered to be a modern, clean, and very effective method of incineration of municipal sewage sludge. The physicochemical properties of the waste material were characterized using selected analytical techniques. Next, the processes of adsorption of Cu(II) ions on slag in aqueous solutions were investigated. The results showed a high metal removal efficiency of 98.8% at pH 1.8 and slag dosage 5 g/L. Numerous studies have demonstrated that high process efficiency at a level of at least 90% is attainable. Based on the Langmuir equation, the maximum adsorption capacity was calculated to be 70.3 mg/g. Kinetic analysis revealed that the process fits better into the pseudo-second-order reaction model and the Freundlich isotherm. The intraparticle diffusion model was considered as a rate-controlling step for Cu(II) adsorption. In summary, the slag waste produced in the CFBC technology seems to be a highly effective adsorbent for potential use in adsorption processes to remove heavy metals from the aquatic environment. This solution is in line with the current European ‘zero waste’ strategy and the assumptions of a sustainable development economy.

Investigation of the water resistance of non-sintered wrap-shell lightweight aggregates with high content solid waste and its application in water permeable bricks

Non-sintered solid waste lightweight aggregates can be used as building materials. However, its active hydration performance has brought challenges to its application. In this study, non-sintered waterproof solid waste wrap-shell lightweight aggregates (W-SWSLAs) were prepared from dredged sediments, steel slag, and other solid waste materials, and activator and waterproof agent were also added. The shell phase of W-SWSLAs was treated with inorganic aluminum salt waterproof agent (IWA) and silicone waterproof agent (SWA), respectively, to investigate the effects of different kinds and dosages of waterproof agents on the properties of the bearing capacity of single grain and water resistance. The performance of W-SWSLAs was assessed from the environmental, physicochemical and mechanical perspectives, respectively. In addition, its application in water permeable bricks was also studied. The results showed that when the addition amount of SWA was 0.08%, it could reach a good balance between the water resistance and mechanical performance of W-SWSLAs. The leaching values of pollutants were well below the limit value set out in the legislation. The water absorption rate, cylinder compression strength and softening coefficient of W-SWSLAs were 8.73%, 20.35 MPa, and 0.84, respectively. The permeability coefficient of water permeable bricks prepared from W-SWSLAs (W-SWSLAPB) was 0.022 cm/s, and the strength loss rate was 10.4% after 25 freeze–thaw cycles, which all met the current Chinese National Standards. The production of W-SWSLAs, whose solid waste content is 95.17 wt%, provides an eco-friendlier approach to converting hazardous and industrial solid waste into high value-added materials.

Composite Cements Using Ground Granulated Blast Furnace Slag, Fly Ash, and Geothermal Silica with Alkali Activation

In recent decades, alkali activated and blended cements have attracted great interest worldwide due to their advantages of low energy cost, high strength, and good durability. This study evaluated the effects of replacing 50% of Portland cement with a mixture of three waste materials: ground granulated blast furnace slag (GGBFS), fly ash (FA), and geothermal waste (GS), with and without external alkaline activation, and activated with different alkali agents: 4 and 7% Na2O equivalent of sodium hydroxide, sodium silicate (water glass), and sodium sulfate. After 90 days of curing, samples were characterized using compressive strength tests, scanning electron microscopy, X-ray diffraction, and thermogravimetric analyses. The results showed that sodium hydroxide caused an alkali–silica reaction and reduced the strength, while sodium silicate and sodium sulfate improved the strength and hydration products formation. Moreover, the addition of fly ash decreased the compressive strength but increased the workability, while the addition of slag and geothermal waste increased strength and densified the matrix with the formation of additional hydration products. The blended cements without activation also showed better performance than pure cement and a more compact matrix of hydration products. The study demonstrated the feasibility of using waste materials to produce blended cements with low energy costs and high durability.

Synergistic and competitive adsorption of NOx and SO2 using a microwave-assisted approach with industrial waste materials fly ash and carbide slag as sorbents

A novel catalytic adsorption approach for microwave-assisted synergistic utilization of coal fly ash (FA) and carbide slag (CS) as adsorbents and Na2O/Na2O2 as a catalyst was proposed as an efficient and low-cost De-SO2 and De-NOx technology. The highest SO2 and NOx adsorption capabilities under these circumstances were 0.55 and 0.06 mg/g under 2% Na2O/FA-CS adsorbent at 150 °C respectively. The experimental results shows that the loaded Na2O2 as adsorbent in the Na2O2/FA-CS was strongly oxidized and decomposed into reactive oxygen (O∗), in which the conversion behavior of NOx (ads) and SOx (ads) contributed to the catalytic activation and adsorption performance. In the synergistic adsorption process, both NOx (ads) and SOx (ads) were present on the adsorption interface of the X% Na2O/FA-CS adsorbent, which also facilitated the production of unstable nitrogen and sulfur compounds. In the competitive adsorption process, NOx and SOx readily occupied the active adsorption spots of CaO used as an adsorbent in FA-CS while also contaminating the active catalytic spots of the coexisting Na2+/Na1+ ions, thus reducing the activity and efficiency of the adsorbent.Environmental implications: Coal fly ash is the main solid waste discharged from coal-fired power stations. The large amount of coal fly ash occupies land resources, while solid fine particles and heavy metals pollute the surrounding air. In addition, calcium carbide slag is a kind of industrial waste slag mainly comprising calcium hydroxide. Calcium carbide slag exhibits the characteristics of high humidity and alkalinity, leading to stockpiling and land pollution. To achieve resource utilization and high-value utilization, synergistic microwave-assisted utilization of industrial waste materials coal fly ash and carbide slag was assessed for high-efficiency desulfurization and denitrification.

Defect-enriched ilmenite-type catalyst derived from titanium dioxide slag for peroxymonosulfate activation in efficient tetracycline removal

The removal of antibiotics from wastewater is crucial, and the activating of PMS is an effective method for this purpose. To design a suitable catalyst, a defect-enriched ilmenite-type catalyst (D-FeTiO3/C) was constructed using titanium dioxide slag as a precursor for peroxymonosulfate (PMS) activation to remove tetracycline (TC). The obtained D-FeTiO3/C catalyst showed excellent activation ability towards PMS, achieving a TC degradation efficiency over 90% within 120 min. The introduction of oxygen vacancies by ball milling significantly improved the activation ability. The effects of operational conditions on TC removal were systematically investigated in the D-FeTiO3/C/PMS system. The primary active species in the D-FeTiO3/C/PMS system were non-free radicals of singlet oxygen, although free radical species also contributed to TC degradation. Degradation pathways for TC were proposed, and most of the intermediates were non-toxic by-products. This study developed a promising method to recycle solid slag wastes and effectively treat antibiotics in water environments.

Synthesis of Cenospheres from Ash and Their Application

The possibility of improving the strength properties of concrete materials based on ash/slag waste from thermal power plants of Almaty (Kazakhstan) by adjusting their chemical composition is considered. An X-ray phase analysis, scanning electron microscopic (SEM) analysis, infrared analysis (IR), and elemental determination analysis (EDAX) of ash and slag wastes were carried out, and additives to correct their chemical composition were selected. The analysis of the conducted studies shows that the addition of polypropylene fiber leads to an increase in the compressive crack resistance compared to the composition of the mixture in which ash is present. The highest compressive strength in which cenospheres increase in strength characteristics is observed on samples modified with 7% cenospheres. It was found that the strength of the concrete with the addition of cenospheres increased by more than two times in comparison with a sample without additives.

Utilization of copper slag waste in alkali-activated metakaolin pervious concrete

This study aims to evaluate the feasibility for preparing alkali-activated metakaolin (AAM) pervious concrete incorporating copper slag (CS) waste. The effects of replacement of metakaolin with CS on the total void ratio, water permeability, mechanical properties, and abrasive resistance of the pervious concretes were investigated. Hydration heat evaluation, SEM, and XRD were conducted to reveal the components interaction. The results showed that the total void ratio and water permeability of the pervious concretes increased with adding CS, since the binder thickness for coating aggregate correspondingly reduced due to the higher density for CS than metakaolin. Although the reactivity of CS was lower than that of metakaolin, the pervious concrete with 30% CS still obtained the comparable compressive and flexural strengths to the concrete without CS. It is mainly attibuted to the strength compensation caused by the CS micro-aggregate effect and a denser microstructure. Adding CS in the concretes obtained a satisfactory abrasive resistance owing to the high paste strength and low wear loss. This study extends the knowledge of using CS in AAM pervious concrete and broadens the CS application scenarios, which is beneficial for consuming CS waste and reducing carbon emissions and costs of pervious concrete preparation.

Investigation of adsorption equilibrium in the system of ammonium ions and a calcined sorbent from ash and slag waste of thermal power plants

A calcined sorbent from ash and slag waste of thermal power plants was used for water purification from ammonium ions. Experiments were carried out under static conditions at a temperature of 25±2 °С. The concentration of ammonium ions in the solution was measured by the spectrophotometric method according to the established graduation characteristic tested for convergence and correctness. The sorption process was studied at a sorbent dose of 1.0 g per 50 cm3 of the model solution taking the specific pore volume of the sorbent into account. For a solution with an ammonium ion content of 20 mg/dm3, the following modifications were carried out: the frequency of magnetic stirrer rotation was varied from 50 to 500 rpm; the pH of the solution – from 4 to 9; and the time to equilibrium – from 10 to 210 min. The time to equilibrium was 180 min. The effect of initial concentration of ammonium ions (2.0; 5.0; 20; 50 and 100 mg/dm3) in the solution on the adsorption process was studied under optimal sorption parameters. The adsorption equilibrium in the “ammonium ions–calcined sorbent” system was studied for the initial concentration of ammonium ions from 5 to 300 mg/dm3. Experimental data were processed using Langmuir and Freundlich adsorption isotherms. The maximum value of adsorption comprised 1.1251 mg/g. The experimental data were found to agree with the Langmuir theory. To describe the adsorption kinetics, the parameters of pseudo-first and pseudo-second order equations were determined. The highest convergence between the experimental and calculated data was achieved by the pseudo-first order model.

Effects of microorganisms on the migration and transformation of typical heavy metal (loid)s in mercury-thallium mining waste slag during the combined application of fish manure and natural minerals

Mercury-thallium mining waste slag has the characteristics of extremely acidic, low fertility and highly toxic polymetallic composite pollution, making it difficult to be treated. We use nitrogen- and phosphorus-rich natural organic matter (fish manure) and calcium- and phosphorus-rich natural minerals (carbonate and phosphate tailings) individually or in combination to amend the slag, analyze their effects on the migration and transformation of potentially toxic elements (Tl and As) in the waste slag. We set up sterile and non-sterile treatments specifically to further investigate the direct or indirect effect of microorganisms attached to added organic matter on Tl and As. The results showed that addition of fish manure and natural minerals to the non-sterile treatments promoted the release of As and Tl, resulting in an increase in As and Tl concentrations in the tailing lixiviums from 0.57 to 2.38–6.37 μg/L and from 69.92 to 107.51–157.21 μg/L, respectively. Sterile treatments promoted the release of As (from 0.28 to 49.88–104.18 μg/L) and inhibited the release of Tl (from 94.53 to 27.60–34.50 μg/L). Use of fish manure and natural minerals alone or in combination significantly reduced the biotoxicity of the mining waste slag, in which the combination was more efficient. XRD analysis showed that microorganisms in the medium promoted the dissolution of jarosite and other minerals, which indicated that the release and migration of As and Tl in Hg–Tl mining waste slag were closely related to microbial activities. Furthermore, metagenomic sequencing revealed that microorganisms such as Prevotella, Bacteroides, Geobacter, and Azospira, which were abundant in the non-sterile treatments, had remarkable resistance to a variety of highly toxic heavy metals and could affect the dissolution of minerals and the release and migration of heavy metals through redox reactions. Our results may aid in the rapid soilless ecological restoration of related large multi-metal waste slag dumps.

Full utilization of coal-fired power plant ash and slag waste components

Ash and slag waste are a major source of raw materials for various industries. In this work, we studied the possibility of the fractionation of coal-fired power plant ash and slag waste. The fractionation was carried out by the flotation to separate the aluminosilicate and carbon concentrate. The magnetic separation was used for isolation of iron oxide. The composition of the ash and slag as well as the fractions obtained was studied. Moreover, the morphology of the concentrate was investigated.

Effect of TiO2 on the occurrence and distribution of chromium in stainless‐steel slag glass ceramics

AbstractStainless steel slag waste can be used to prepare value‐added glass ceramics, which can fix potentially toxic Cr from the slag within the crystalline phase. The occurrence and distribution of Cr during the preparation of glass ceramics has a great influence on the final Cr fixation effect. In this study, the effects of the TiO2 content on the occurrence and distribution of Cr during the nucleation and crystallization steps and on the final properties of the glass ceramics were systematically studied. In the nucleation stage, with increasing TiO2 content, the Cr distributed in the spinel containing chromium nuclei first increases and then decreases. In the crystallization stage, Diopside crystal phase nucleates and grows with spinel containing chromium nanocrystals as heterogeneous nuclei. X‐ray photoelectron spectroscopy analysis showed that the chromium distributed in the diopside crystals first increased and then slightly decreased as the TiO2 content increased. The optimal TiO2 content is 3.4 wt.%, which resulted in 97 wt.% of the total Cr being fixed in the diopside crystalline phase (with a very low Cr leaching concentration of 0.009 mg/L), and a high compressive strength of the final glass ceramic of 267.4 MPa, and a Vickers hardness of 1211.8 HV. The research results provide theoretical and technical support for strengthening Cr fixation to enable harmless and high‐value utilization of stainless steel slag for fabricating glass ceramics.

"INDUSTRIAL WASTE UTILIZATION IN THE PRODUCTION OF BUILDING MATERIALS ON ECOSTROINII-PV LLP EXAMPLE "

"The results of the work of EcostroyNII-PV LLP on the processing of technogenic waste of energy and metallurgy of the Republic of Kazakhstan, Pavlodar region are presented. The use of waste in the manufacture of construction products is one of the most effective solutions to environmental problems in the region. The proposed technology for the production of construction products using ash and slag waste provides for innovative compositions of raw materials mixtures and provides an increase in operational characteristics and an increase in labor productivity in construction. The applied technology, in comparison with existing analogues, provides for the use of local waste (ash and slag waste from the burning of Ekibastuz coal, bauxite sludge of the Pavlodar aluminum plant, steelmaking slag). They differ in chemical and granulometric composition, as well as binding properties from other analogues and prototypes. In the production of construction products, a concrete mixture has been introduced and patented, including, %: slag-Portland cement – 14.32–17.00; sand – 18.74–25.52, crushed stone – 46.50-49.71, alumina sludge obtained during processing of Kazakhstan bauxite – 5–7; self–disintegrating slag of steelmaking production – 5–7; ash and slag waste of thermal power plants from burning Ekibastuz coals – 5–7. According to the test results, the average tensile strength of building products (paving slabs, curbstones, hollow bricks) is 3.2 – 3.8 MPa (strength class 2.5). "

Water gas shift reaction mechanism with copper slag as heat carrier and catalyst

Researchers in related fields are concentrating on the use of metallurgical slag waste heat to deliver stable heat for the pyrolysis or gasification of carbon–based materials. The key technology to achieve the clean utilization of coal is coal gasification. An important challenge for the technology is how to increase the amount of H2 in the mixture while decreasing the energy consumption of the gasification process. The typical temperature of copper slag, a typical iron–rich metallurgical slag, is 1300 °C. Relevant studies have demonstrated that copper slag can increase H2 production and support the water gas shift (WGS) reaction in addition to providing stable heat for coal gasification. The largest contribution of copper slag to the catalytic effect of the WGS reaction is demonstrated by the density functional theory (DFT) calculations, which reveal that the presence of copper slag lowers the energy barrier of H2O molecules dissociation from 6.57 eV to 4.61 eV. Additionally, the reduction in the CO2 formation process on the copper slag surface from 4.92 eV to 3.94 eV encouraged CO2 formation. This explains how the WGS reaction, which is catalyzed by copper slag acting as a heat carrier during the pulverized coal–vapor gasification process, works.

Simultaneous immobilization of multiple heavy metals in polluted soils amended with mechanical activation waste slag

Heavy metal soil contamination has become an increasingly serious problem in industrial development. However, industrial byproducts used for remediation are one aspect of green remediation that can contribute to sustainable practices in waste recycling. In this study, electrolytic manganese slags (EMS) were mechanically activated and modified into a passivator (M-EMS), and the heavy metal adsorption performance of M-EMS, heavy metal passivation ability in soil, dissolved organic matter (DOM) change and its effect on the microbial community structure of soil were investigated. The findings revealed that the maximum adsorption capacities of As(V), Cd2+, Cu2+ and Pb2+ were 76.32 mg/g, 301.41 mg/g, 306.83 mg/g and 826.81 mg/g, respectively, indicating that M-EMS demonstrated remarkable removal performance for different heavy metals. The Langmuir model fits Cd2+, Cu2+ and Pb2+ better than the Freundlich model, and monolayer adsorption is the main process. Surface complexation played a major role in the As(V) adsorption's on the surface of metal oxides in M-EMS.The passivation effect was ranked as Pb > Cr > As>Ni > Cd > Cu, with the highest passivation rate of 97.59 % for Pb, followed by Cr (94.76 %), then As (71.99 %), Ni (65.17 %), Cd (61.44 %), and the worst one was Cu (25.17 %). In conclusion, the passivator has the effect of passivation for each heavy metal. The addition of passivating agent can enhance the diversity of microorganisms. Then it can change the dominant flora and induce the passivation of heavy metals through microorganisms. XRD, FTIR, XPS and the microbial community structure of soil indicated that M-EMS can stabilize heavy metals in contaminated soils through four main mechanisms: ion exchange, electrostatic adsorption, complex precipitation and the microbially induced stabilization. The results of this study may provide new insights into the ecological remediation of multiple heavy-metal-contaminated soils and water bodies and research on the strategy of waste reduction and harmlessness by using EMS-based composites in combination with heavy metals in soil.

Influence of Waste Filler on the Mechanical Properties and Microstructure of Epoxy Mortar

This paper presents experimental investigations on epoxy mortar produced using industrial wastes. In some recent studies, coal bottom ash and polyethylene terephthalate (PET) waste have been chosen as a filler to replace sand, and fly ash and silica fume have been chosen as micro fillers for epoxy mortar production; enhanced results in terms of compressive and tensile strengths and durability have been achieved. However, these approaches failed to boost the strength and durability compared to the epoxy steel slag, epoxy sand, epoxy marble dust, and epoxy polyvinyl chloride (PVC) waste. This present research work has investigated the influence of waste filler on the mechanical properties and microstructure of epoxy mortar, produced by using sand and industrial wastes, i.e., steel slag, marble dust, and polyvinyl chloride waste. Based on the composition ratio, the prepared samples of epoxy resin mortar containing 25% epoxy binder (epoxy resin plus epoxy hardener) and 75% filler (1:3) were compared to the cement mortar. However, each specimen of epoxy resin mortar was prepared by mixing with different fillers. The properties such as compressive strength, tensile strength, and microstructural changes were measured using different characterization techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared radiation spectroscopy (FTIR), and scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDX). From the obtained results, it was found that the strength of the specimens increases when blended with steel slag and marble dust, which is attributed to their peak densities and enhanced particle interactions. The XRD, SEM, FTIR, and SEM-EDX analyses showed the formation of calcium, magnesium, and other phases in the microstructure of epoxy resin-based mortars. This resulted in lower water absorption and porosity, as well as improvements in both compressive and tensile strengths. This research can help in understanding the important role of different industrial wastes as feasible fillers in epoxy resin-based composites.

Sustainably produced concrete using weathered Linz-Donawitz slag as a fine aggregate Substitute: A comprehensive study with Artificial intelligence approach

Continuous consumption of natural resources such as river sand and coarse aggregates due to increased industrialization and urbanization has impeded the movement towards green concrete in construction, i.e., utilizing waste materials in its production, steel slag waste being one of them. Accumulation of Linz-Donawitz slag (LD slag) has become cumbersome in India, posing a problem of landfills and environmental degradation, i.e., abating soil and water quality due to the leaching of toxic metals. Fewer experimental studies have examined whether weathered fine LD Slag can substitute for fine aggregates in concrete. Additionally, the research has yet to compare the behavior of concrete comprising weathered fine LD slag in Normal Strength Concrete (NSC) and High Strength Concrete (HSC) containing Metakaolin. The current study aims to establish an optimum replacement quantity for fine aggregates with fine LD slag. The slag replaced fine aggregates by volume at 25, 50, 75 and 100%. The findings that examined the effects of using LD slag on the mechanical behaviour, durability and microstructure of concrete are presented in this study. Furthermore, taking a total of 180 experimental data points, the compressive strength of concrete was predicted using artificial intelligence (AI) methods such as Artificial Neural Networks (ANNs), Decision Trees (DT) and Random Forests (RF). Coefficient of determination R2, Mean Absolute Error (MAE) and Root Mean Square Error (RMSE) were computed to assess the performance of generated models. Besides, a sensitivity analysis technique was employed to determine the most influential parameter among cement, Metakaolin, Fine Aggregate, Coarse Aggregate, LD slag, Superplasticizer, water content and testing age on the compressive strength results. Experimental investigation showed that adding LD slag up to 50% for NSC and 25% for HSC was optimal and showed better results for tested properties than conventional concrete mixes. Among proposed AI techniques, the DT technique was the best-performing model with an R2 value of 0.973 and the least for MAE (3.534 MPa) and RMSE (4.409 MPa). Sensitivity analysis performed on the DT model showed that testing age was the most critical parameter for the prediction of compressive strength.

Influence of B2O3 on the thermophysical properties of molten blast furnace slag

The thermophysical characteristics of blast furnace molten slags have crucial implications for their smelting process and the subsequent utilization of resources. To efficiently recover molten slag waste heat resources, the thermodynamic properties and viscous flow characteristics of molten blast furnace slag systems with various B2O3 contents were investigated. The stability of the slag at high temperatures was evaluated by calculating its heat capacity and critical heat release. The structural evolution of the melt under varying B2O3 contents was comprehensively studied using Raman spectroscopy and Nuclear Magnetic Resonance. From the perspective of viscous flow characteristics, the impact of B2O3 resulted in a reduction in viscosity of the slag, while the electrical conductivity of the slag increased. Concerning the thermodynamic properties, the break temperature decreased from 1377 °C to 1280 °C with an increase in B2O3 content in the range of 0 to 6 wt.%, while heat capacity and critical heat release of the slag both increased. The introduction of B2O3 facilitated smoother the blast furnace smelting conditions while enhancing the superiority of the granulated product and the efficiency of heat recovery. Adding B2O3 to the molten slag disrupted part of chain structure (Si-O-Si) to create a more flowable cyclic borosilicate structure (Si-O-B).

Numerical and experimental studies of the plasma-thermal processing of ash and slag waste

Numerical and experimental studies of the plasma-thermal processing of ash and slag waste

Mitochondrial Lipid Peroxidation and Microsomal Drug-metabolizing Enzyme Activity of Rat Hepatotoxicity under Heavy Metals from Slag Waste Exposure

Heavy metals from slag waste (HMSWs) have attracted much attention because of their serious toxicity to the environment and human organs, especially hepatotoxicity. The aim of this study was to explore the effects of different HMSWs exposure on mitochondrial lipid peroxidation, microsomal drug metabolizing enzyme activities as well as their relationship in the rat liver injury. Based on toxicogenomic analysis, heavy metals including iron, copper, cobalt, nickel and manganese, might interfere with pathophysiological processes such as oxidative stress, cell death, and energy metabolism regulation in vivo, and participate in the regulation of HIF-1 signaling pathway, peroxisomes, drug metabolism-cytochrome P450, ferroptosis, and other signaling pathways. HMSWs exposure caused weight loss, and significantly increased lactate dehydrogenase (LDH), malondialdehyde (MDA), alanine transaminase (ALT), and aspartate transaminase (AST) in different groups of rat liver, suggesting the presence of mitochondrial lipid peroxidation damage. In addition, the ratios of AST/ALT and ALT/LDH were down-regulated, especially the ALT/LDH ratios were less than 1, indicating that hepatic ischemic injury occurred in the process of liver injury. The superoxide dismutase (SOD) and mitochondrial membrane potential (MMP) activities in rats also showed significant decreases, indicating the occurrence of hepatic oxidative/antioxidant dysfunction imbalance. Further decision tree analysis of live biochemical abnormalities suggested that AST > 58.78 U/gprot and MDA > 173.2 nmol/mgprot could be used for hepatotoxicity warning. Liver microsomal cytochrome P4501A2 (CYP1A2) and 3A1 (CYP3A1) enzymes were also involved in the hepatotoxic process of heavy metals. These results suggest that lipid peroxidation damage and metabolic damage in liver mitochondria and peroxisomes, may be one of the key events in heavy metal-induced liver injury.

Strength assessment of concrete with copper slag as fine aggregates

Concrete is an excellent material for creating a wide range of load-bearing solid structures. Concrete is the second-most consumed resource in the world as a result of the ongoing depletion of natural resources and certain environmental issues. River sand is constantly being reduced, which affects the groundwater table because it is primarily used as a fine aggregate in concrete. Because of these factors, looking for alternative concrete materials is essential. Copper production leaves behind a sizable am looking for alternative concrete materials is an essential problem, Alternative sources for this waste material are required by environmental protection agencies and governments. As a result, an effort is made to partially replace fine aggregate in the construction industry with copper slag. The current paper examines the laboratory testing of various concrete mixes (Mix20, Mix40, and Mix60) containing copper slag waste as a partial replacement for fine aggregate (0% to 100%). The fresh properties and mechanical properties of the concrete mixes were assessed.