Tunnel Magnetoresistance Ratio Research Articles

Magnetic-ferroelectric synergic control of multilevel conducting states in van der Waals multiferroic tunnel junctions towards in-memory computing.

van der Waals (vdW) multiferroic tunnel junctions (MFTJs) based on two-dimensional materials have gained significant interest due to their potential applications in next-generation data storage and in-memory computing devices. In this study, we construct vdW MFTJs by employing monolayer Mn2Se3 as the spin-filter tunnel barrier, TiTe2 as the electrodes and In2S3 as the tunnel barrier to investigate the spin transport properties based on first-principles quantum transport calculations. It is highlighted that apparent tunneling magnetoresistance (TMR) and tunneling electroresistance (TER) effects with a maximum TMR ratio of 6237% and TER ratio of 1771% can be realized by using bilayer In2S3 as the tunnel barrier under finite bias. Furthermore, the physical origin of the distinguished TMR and TER effects is unraveled from the k||-resolved transmission spectra and spin-dependent projected local density of states analysis. Interestingly, four distinguishable conductance states reveal the implementation of four-state nonvolatile data storage using one MFTJ unit. More importantly, in-memory logic computing and multilevel data storage can be achieved at the same time by magnetic switching and electrical control, respectively. These results shed light on vdW MFTJs in the applications of in-memory computing as well as multilevel data storage devices.

A Device Model for Achieving Sizable and Tunable Tunneling Magnetoresistance Using Two‐Dimensional Materials InX (X = O, Se) without Hetero‐Interface

AbstractThe two‐dimensional (2D) materials InX (X = O, Se), experimentally available thus far, can become a ferromagnetic half metal under hole doping, though the charge neutral states of them are nonmagnetic semiconductors. Based on such an electronic characteristic, a theoretical model of magnetic tunnel junction (MTJ) is proposed composed only of one of the 2D InX. In doing so, the two semi‐infinite pieces of 2D InX in the half‐metallic state is assumed as the opposite electrodes which are separated by a strip of the same material but in its nonmagnetic state. Owing to the 2D nature of InX, the half metal electrodes of the InX device induced by hole doping can be achieved by using split gating technique. The numerical simulations identify a proper hole doping concentration, at which 100% tunneling magnetoresistance (TMR) ratios can be realized, accompanying an appreciable conductance of majority spin electron under parallel magnetization configuration. Under a finite bias voltage, the TMR ratio remains high. Therefore, the proposed device model is an ideal candidate for future spintronics applications. It enables electrical control of TMR and circumvents the detriment of hetero‐interface disorder inevitable in conventional MTJs.

A novel time-domain in-memory computing unit using STT-MRAM

Advancements in technologies like Big Data, IoT, and AI have revealed a bottleneck in traditional von-Neumann architecture, resulting in high energy consumption and limited memory bandwidth. In-memory computing (IMC) presents a promising solution by enabling computations directly within the memory, enhancing energy-efficient computing. The existing time-domain (TD)-based IMC computations either require multiple cycles for computation through a successive read/write approach or contribute to the complexity of the peripheral circuit by adopting a cumulative delay approach. In this paper, we present a novel array architecture that utilizes spin transfer torque magnetic random access memory (STT-MRAM) bit-cells, mitigating source degeneration issue. By leveraging this advanced technology and employing a TD computing scheme, we have successfully implemented various arithmetic operations, alongside a comprehensive set of Boolean logic operations. Our design demonstrates improved area and energy efficiency compared to other existing TD computing schemes. Furthermore, despite the higher delay, our parameter-driven optimization approach efficiently minimizes it. To validate our proposal, we performed simulations using the 45 nm CMOS process and the Verilog-A based magnetic tunnel junction (MTJ) compact model. Through meticulous Monte-Carlo simulations, considering CMOS variations, the results demonstrate enhanced computational accuracy with increasing Tunnel Magnetoresistance (TMR) ratio, showcasing the potential of our architecture in advancing the field of computing.

Multilevel resistance states in van der Waals multiferroic tunnel junctions above room temperature

Multiferroic tunnel junctions (MFTJs) comprised of magnetic electrodes and a ferroelectric tunnel barrier have been emerging as promising candidates for nonvolatile memory applications. The recently discovered above room-temperature van der Waals (vdW) ferromagnet Fe3GaTe2 and ferroelectric α-In2Se3 provides possibilities for constructing room-temperature vdW MFTJs. In this work, by using first-principles calculations, we investigate the spin-dependent transport in vdW MFTJs with structure of Fe3GaTe2/bilayer α-In2Se3/Fe3GaTe2. We predict a giant tunneling magnetoresistance (TMR) high up to 10 000% by switching the magnetic alignments of Fe3GaTe2 and tunneling electroresistance (TER) exceeding 300% by controlling the ferroelectric configurations of bilayer α-In2Se3 in the proposed MFTJs. Furthermore, by introducing interface asymmetry and inserting monolayer of h-BN on one interface, the TMR and TER ratios of the MFTJs can be substantially enhanced. In consequence, the multi-level resistance states can be achieved by applying magnetic and electric field in asymmetric MFTJs. Our results highlight full vdW MFTJs for their potential applications in spintronic devices, particularly in the field of multilevel nonvolatile memories.

Reconfigured Self-Referenced MRAM Cell Supporting 2.527-fJ/bit Reading and In Situ Multiplication

The development of nonvolatile memories (NVM) based normally-off, instantly-on applications is hindered by high energy consumption for data readout. In particular, magnetic random access memory (MRAM) is a promising candidate for embedded non-volatile memory for its high cell density, high endurance and compatibility with the CMOS process. However, considering the low tunneling magnetoresistance ratio (TMR) of standard 1T1MTJ bit-cell, the state-of-art voltage sensing amplifiers (VSA) and current sensing amplifiers (CSA) need the direct current path to build considerable voltage or current difference. This paper demonstrates a reconfigured latch-based 4T2MTJ bit-cell achieving 2.527-fJ/bit ultra-low-power data readout at 0.4-V read voltage. Simulated results show that 2-ns latency can be realized with a traditional VSA and parasitic capacitance. The proposed 4T2MTJ bit-cell can perform in-situation (in-situ) multiplication between stored data and input with negligible extra energy consumption.

Tunnel-magneto resistance of double-barrier tunnel junctions in the presence of spin-orbit coupling within spin-filter barriers

The tunnel magneto-resistance ratio is investigated for double-barrier tunnel junctions with spin-filter (magnetic insulators) barriers. The transmission probability is calculated in the tight-binding model by the non-equilibrium Green's function formalism considering spin-orbit coupling within barriers. The formation of resonant states inside a non-magnetic spacer gives rise to an enhancement in tunnel magneto-resistance ratio. Double spin-filter tunnel junctions have also shown a higher tunnel magneto-resistance ratio compared to that in double-barrier magnetic tunnel junctions. These findings will be valuable to improve the performance of spintronics devices.

Nano-crystal domains in Co-based fcc(111) epitaxial magnetic junctions and their impact on tunnel magnetoresistance

Nano-crystal domain structures formed in a MgO barrier and their effects on tunnel magnetoresistance (TMR) in epitaxial fcc-Co90Fe10 (CoFe)(111)/MgO(111)/CoFe(111) magnetic tunnel junctions (MTJs) have been systematically studied using scanning transmission electron microscopy and first-principles calculations. These domains are widely distributed in the (111)-textured MgO layer, being different from conventional bcc-CoFe/MgO(001)-based MTJs. The (111)-texture is formed by extension of {111} planes through several adjacent MgO domains. Three types of orientation relationships (ORs) between CoFe and MgO are identified, including cube-on-cube type (Type-1), twin-like type (Type-2), and unexpected type (Type-3). Crystallographic analysis indicated that Type-2 OR is a variant of Type-1 OR, triggered by different stacking orders of MgO(111) planes, while Type-3 OR is formed by a 30° in-plane rotation of MgO lattice relative to Type-1 OR. Due to the large in-plane lattice mismatch (19.6%) between Co(111) and MgO(111) in Type-1 and Type-2 ORs, Type-3 OR (mismatch 3.4%) can be stabilized. First-principles calculations uncovered that the theoretical TMR ratio of the MgO(111) MTJ with Type-3 OR is ∼2 orders of magnitude smaller than that with Type-1 and Type-2 ORs. The small contribution of Type-3 OR to the transport reasonably interprets why the experimental TMR ratio (∼37%) is much lower than the theoretical value (∼2100%) in the Co/MgO/Co(111) MTJ. This study has revealed the nano-crystal domain formation unique to the fcc-CoFe/MgO(111) MTJs, indicating that controlling the nano-crystal domains (e.g., lattice optimization by atomic doping) can be a guiding principle to develop MgO(111)-based epitaxial MTJs and related heterostructure devices.

The Influence of Capping Layers on Tunneling Magnetoresistance and Microstructure in CoFeB/MgO/CoFeB Magnetic Tunnel Junctions upon Annealing.

This study investigates the effects of annealing on the tunnel magnetoresistance (TMR) ratio in CoFeB/MgO/CoFeB-based magnetic tunnel junctions (MTJs) with different capping layers and correlates them with microstructural changes. It is found that the capping layer plays an important role in determining the maximum TMR ratio and the corresponding annealing temperature (Tann). For a Pt capping layer, the TMR reaches ~95% at a Tann of 350 °C, then decreases upon a further increase in Tann. A microstructural analysis reveals that the low TMR is due to severe intermixing in the Pt/CoFeB layers. On the other hand, when introducing a Ta capping layer with suppressed diffusion into the CoFeB layer, the TMR continues to increase with Tann up to 400 °C, reaching ~250%. Our findings indicate that the proper selection of a capping layer can increase the annealing temperature of MTJs so that it becomes compatible with the complementary metal-oxide-semiconductor backend process.

Effect of spin-orbit coupling within the spin-filter layer on the tunnel magneto-resistance in spin-filter magnetic tunnel junctions

The tunnel magneto-resistance ratio is investigated for spin-filter magnetic tunnel junctions in the presence of spin–orbit coupling within a spin-filter layer. The non-equilibrium Green’s function formalism is utilized to calculate the transmission function in the linear-response limit. The results show that a larger tunnel magneto-resistance is achieved for spin-filter magnetic tunnel junctions compared to that for conventional magnetic tunnel junctions due to the existence of a spin-filter layer. Therefore, the current findings can be introduced new routes to improve the field of spintronics.

Enhanced sensitivity and thermal tolerance in tunnel magnetoresistance sensor using Ta-doped CoFeSiB soft magnetic layer

We developed a tunnel magnetoresistance (TMR) sensor consisting of a CoFeB/MgO/CoFeB magnetic tunnel junction (MTJ) and a CoFeSiB amorphous soft magnetic layer. This multilayer structure is promising for a high-sensitivity sensor because a giant TMR ratio of the MTJ and a small anisotropy field Hk of the free layer can be obtained simultaneously. However, the soft magnetic properties of the CoFeSiB layer disappear when it is annealed at above the crystallization temperature (around 300 °C), which determines the thermal tolerance of the TMR sensor and limits improvements to the sensor's sensitivity and applications. In this study, we doped the CoFeSiB layer with various amounts of Ta to raise its crystallization temperature. TMR sensors using the Ta-doped CoFeSiB layers showed thermal tolerance to annealing temperatures above 425 °C, whereas the sensor with the undoped CoFeSiB layer was tolerant to annealing temperatures up to 325 °C. As well, the Ta doping effectively reduced Hk of the CoFeSiB layer, which resulted in a sensitivity of 50%/Oe, over three times higher than the sensor with the undoped CoFeSiB layer. These results pave the way toward next-generation TMR sensors having higher sensitivity and wider applicability.

Design of behavior prediction model of molybdenum disulfide magnetic tunnel junctions using deep networks

Magnetic tunnel junctions (MTJ) are widely used in spintronics development owing to their high scalability and minimal power consumption. However, analyzing the electrical and magnetic behaviors of MTJ in real-time applications is challenging. In this study, an MTJ based on molybdenum disulfide (MoS2) is designed, and a novel deep Elman neural behavior prediction model is developed to analyze its behavior. MoS2 acts as a tunnel barrier in the proposed model, whereas iron oxide (Fe3O4) acts as a ferromagnetic electrode. The interface between Fe3O4 and MoS2 in the MTJ improves the spin polarization and tunnel magnetoresistance ratio. Herein, the performance parameters of the MTJ are used as inputs for the developed prediction model, which analyzes the magnetic and electrical properties of the MTJ using prediction parameters. The spin currents in the parallel and antiparallel configurations are also determined. The designed model is implemented using MATLAB and validated by comparing simulation and experimental results. Moreover, a maximum resistivity of 91 Ω is attained at a temperature of 300 K for the proposed model. At 120 K, under a positive bias, the proposed model achieves a TMR ratio of 0.936. Under negative bias, the maximum TMR ratio attained by the proposed model is 0.817.

First-Principles Studies on Spin-Dependent Transport of Magnetic Junctions with Half-Metallic Heusler Compounds

Two types of magnetoresistance (MR), i.e., tunnel magnetoresistance (TMR) and current perpendicular to plane giant magnetoresistance (CPP-GMR), are theoretically discussed for systems with half-metallic (HFM) Co-based full Heusler compounds. In TMR, the non-collinear spin structure at the Co2MnSi(CMS)/MgO(001) interface that results from thermal spin fluctuations significantly reduced the TMR ratio at room temperature (RT). Enhancement of the exchange stiffness of CMS/MgO was essential to suppress the reduction in TMR at RT. Furthermore, it is proposed that inserting of a B2-CoFe layer between CMS and MgO is a promising way to enhance the interface exchange stiffness constant. In CPP-GMR, the interface spin asymmetry γ in the Valet-Fert model was essential to enhance GMR at RT, because the temperature dependence of γ in experiments was much larger than that of the bulk spin asymmetry β. I showed that the experimental CPP-GMR ratio increases with the decrease in the theoretical resistance-area product RPA, which is roughly consistent with the RP dependence of γ. This means that matching of the conductive channel between HMF and a non-magnetic metallic spacer is a key parameter to enhance γ. These findings will be very important for room temperature spintronics devices applied in future artificial intelligence hardware.

Enhancing spin-transfer torque in magnetic tunnel junction devices: Exploring the influence of capping layer materials and thickness on device characteristics

We have developed and optimized two categories of spin-ransfer torque magnetic tunnel junctions (STT-MTJs) that exhibit a high tunnel magnetoresistance ratio, low critical current, high outputpower in the micro-watt range, and auto-oscillation behavior. These characteristics demonstrate the potential of STT-MTJs for low-power, high-speed, and reliable spintronic applications, including magnetic memory, logic, and signal processing. The only distinguishing factor between the two categories, denoted as A-MTJs and B-MTJs, is the composition of their free layers, two CoFeB/0.21 Ta/6 CoFeSiB for A-MTJs and two CoFeB/0.21 Ta/7 NiFe for B-MTJs. Our study reveals that B-MTJs exhibit lower critical currents for auto-oscillation than A-MTJs. We found that both stacks have comparable saturation magnetization and anisotropy field, suggesting that the difference in auto-oscillation behavior is due to the higher damping of A-MTJs compared to B-MTJs. To verify this hypothesis, we employed the all-optical time-resolved magneto-optical Kerr effect technique, which confirmed that STT-MTJs with lower damping exhibited auto-oscillation at lower critical current values. Additionally, our study aimed to optimize the STT-MTJ performance by investigating the impact of the capping layer on the device’s response to electronic and optical stimuli.

A 6T-3M SOT-MRAM for in-memory computing with reconfigurable arithmetic operations

Traditional von Neumann architecture bottlenecks such as the “memory wall” limit artificial intelligence (AI) development, and in-memory computing (IMC) as a new computing architecture can solve the above problems. Spin-orbit-torque-magnetic random access memory (SOT-MRAM) has very good advantages in IMC architecture because of its good compatibility with CMOS, high tunneling magnetoresistance (TMR) ratio, and high energy efficiency. In this paper, we propose a 6T-3M-based MRAM-IMC architecture with reconfigurable memory mode and logical operation mode. The functionality of the proposed architecture is validated using the 28 nm process design kit and the SOT-MTJ model.

Design of Ultracompact Content Addressable Memory Exploiting 1T-1MTJ Cell

Content addressable memories (CAMs) are a promising category of computing-in-memory (CiM) elements that can perform highly parallel and efficient search operations for routers, pattern matching, and other data-intensive applications. Various magnetic tunnel junction (MTJ) based content addressable memory (CAM) designs have been proposed to realize zero standby power and high performance search. However, due to the relatively small tunnel magneto-resistance (TMR) ratio, MTJ based CAMs require extra transistors and differential MTJ branches to distinguish between the parallel and anti-parallel resistance states, resulting in significant area and energy overhead. In this paper, we propose a device-circuit co-design approach for an ultra-compact CAM design by only exploiting an 1T-1MTJ structure in each cell. We propose a 2-step search scheme to enable the parallel in-memory search operation across the proposed CAM array, and demonstrate the sufficient sensing margin of the array in a successful search operation. Evaluation results suggest that our proposed 1T-1MTJ based CAM design improves 179X/301X area efficiency compared with the state-of-the-art 15T-4MTJ/20T-6MTJ CAM design. Application benchmarking on hyperdimensional computing (HDC) inference shows a 54.6X/12.8X speedup compared with GPU/20T-6MTJ CAM based approaches.

Giant intrinsic magnetoresistance in spin-filtered tunnel junctions with ferrimagnetic electrode

In recent years, magnetic tunnel junctions (MTJs) have attracted strong research interest due to their potential use in nonvolatile memory technologies, such as magnetoresistive random access memory and magnetic logic applications. Half-metallic materials have been proposed as ideal electrode materials for MTJs to achieve large tunnel magnetoresistance (TMR) effects. Here, we design and investigate a spin-filter MTJ (sf-MTJ) consisting of a ferrimagnetic inverse Heusler alloy, ${\mathrm{Mn}}_{2}\mathrm{CoSi}$ as the electrode and CaS as the insulating tunnel barrier using ab initio quantum transport calculations. Our results demonstrate a high zero-bias voltage TMR ratio that initially oscillated before decreasing as the bias voltage increased. Despite the oscillatory TMR under bias voltage, the spin injection remains high and stable, highlighting the potential of sf-MTJs formed by ${\mathrm{Mn}}_{2}\mathrm{CoSi}$ electrodes for practical applications.

631% room temperature tunnel magnetoresistance with large oscillation effect in CoFe/MgO/CoFe(001) junctions

We demonstrate tunnel magnetoresistance (TMR) ratios of up to 631% at room temperature (RT) using CoFe/MgO/CoFe(001) epitaxial magnetic tunnel junctions (MTJs). The TMR ratio increased up to 1143% at 10 K. The large TMR ratios resulted from fine-tuning of atomic-scale structures of the MTJs, such as crystallographic orientations and MgO interface oxidation by interface insertion of ultrathin CoFe and Mg layers, which are expected to enhance the well-known Δ1 coherent tunneling transport. Interestingly, the TMR oscillation effect, which is not covered by the standard coherent tunneling theory, also became significant. A 0.32-nm period TMR oscillation with increasing MgO thickness dominates the transport in a wide range of MgO thicknesses; the peak-to-valley difference of the TMR oscillation exceeds 140% at RT, which is attributed to the appearance of large oscillatory components in the resistance area product.

Ab-initio predictions of mechanical, electronic, magnetic, and transport properties of bulk and heterostructure of a novel Fe-Cr based full Heusler chalcogenide

According to electronic structure calculations based on density functional theory, we predicted and studied the structural, mechanical, electronic, magnetic, and transport properties of a new full Heusler chalcogenide called Fe2CrTe in both its bulk and heterostructure forms. This system exhibits ferromagnetic and half-metallic (HM)-like behavior, with very high (about 95%) spin polarization at the Fermi level in its cubic phase. Interestingly, under tetragonal distortion, a clear minimum (with almost the same energy as the cubic phase) was found at a c/a value of ∼1.26, but it exhibits ferrimagnetic and fully metallic characteristics. The compound was found to be dynamically stable against lattice vibration in both phases. The elastic properties indicate that the compound is mechanically stable in both phases according to the stability criteria for the cubic and tetragonal phases. The elastic parameters demonstrate the mechanically anisotropic and ductile nature of the alloy system. Due to the HM-like behavior of the cubic phase and considering practical aspects, we probed the effect of strain and the substrate on various physical properties of the alloy. The transmission profile was calculated for the Fe2CrTe/MgO/Fe2CrTe heterojunction to investigate its possible use as a magnetic tunneling junction material in both the cubic and tetragonal phases. A large tunneling magnetoresistance ratio of ≈103 % was determined for the tetragonal phase and it was one order of magnitude larger than that for the cubic phase.

Double-Ended Superposition Anti-Noise Resistance Monitoring Write Termination Scheme for Reliable Write Operation in STT-MRAM

Although resistance monitoring write termination (RM-WT) scheme for STT-MRAM can reduce the write energy, the degradation of read margin due to low tunnel magnetoresistance ratio (TMR) and intrusion of noise with process variation still seriously deteriorates the stability of the WT operation. In this paper, a double-ended superposition anti-noise write termination (DSA-WT) scheme is proposed and implemented, in which the voltage changes on both BL and SL can be superimposed to boost sensing margin (SM). Schmitt trigger (ST) is adopted to take the place of the inverter (INV) in the traditional WT scheme, which is demonstrated to be helpful for stability improvement. Based on 65-nm CMOS technology, the proposed DSA-WT scheme shows 15% ~33% sensing margin boosting under various PVT conditions and 1000 times lower read bit-error-rate (BER) compared with the other WT schemes. The write done (WD) delay and the energy-delay-product (EDP) achieve 49.6% and 47.2% improvements compared to the state-of-art self-referenced single-ended RM-WT scheme (SS-RM-WT), respectively.

Tunnel magnetoresistance exceeding 100% in magnetic tunnel junctions using Mn-based tetragonal alloy electrodes with perpendicular magnetic anisotropy

We studied MgO barrier magnetic tunnel junctions (MTJs) comprising perpendicularly magnetized MnGa and FeCoB electrodes. In those perpendicular (p-) MTJs, we utilized thin metastable bcc CoMn alloys as an interlayer between MnGa and MgO to enhance the tunnel magnetoresistance (TMR) effect. Moreover, we investigated the effect of a thin Mg interlayer between MnGa and CoMn. Owing to the interlayer engineering, we achieved a TMR ratio over 100%, the highest value observed for p-MTJs with a tetragonal MnGa electrode. Our study contributes to the further development of spintronic devices using p-MTJs with various Mn-based tetragonal alloy electrodes.