Electrochromic (EC) devices have been gaining attention for display, electronic paper, and smart windows because of the low-power consumption, low-voltage drive, and memory effect of the colored state holding sharp contrast. They could be useful for the intended usage, which organic light emitting diode and liquid crystal display do not cover.The minimum components of EC devices are (i) redox-active EC material for a transparent electrode of interest, (ii) supporting electrolyte, (iii) medium (solvent), and (iv) charge-compensating (charge-balancing) redox material for another electrode. The medium (solvent) is required for electrolytes, which provide electric conductivity to the device. However, it is difficult to solve the problems of solvent evaporation and leakage of the electrolyte solution from the device. Recently, ionic liquids (ILs) are the focus of extensive investigations for electrochemical devices due to their non-volatility, moderate viscosity, and chemical stability. ILs can play roles of both solvent and supporting electrolytes. We have been focused on ILs as a designable liquid material with the above useful properties and developed electrochromic redox-active ionic liquids (RAILs).In RAILs, either or both constituent ions are redox-active. RAILs are a new class of ILs, which are non-volatile, electro-conductive, and viscous liquid materials. In addition, RAILs consist of concentrated redox-active ions, resulting in large redox density. In the case of RAILs with electrochromic ions, which are electrochromic RAILs (EC-RAILs), the concentrated electrochromic species give a large light absorption resulting in a very thin device thickness. The non-volatility and chemical stability provide the long-term durability of the EC devices. EC-RAILs play the roles of (i)-(iv) required in EC devices. In this study, we developed EC-RAILs, the coloration process by the voltage control, and their application to the EC devices without using solvents and supporting electrolytes. Because of the concentrated redox species and absence of the supporting electrolyte, the resistance of the EC cells could be dominant for the coloration kinetics.In this study, we have analyzed the electrode kinetics of the EC device composed of pure EC-RAILs.
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