Electrical properties of hafnium oxide (HfO 2) gate dielectric with various metal nitride gate electrodes, i.e., tantalum nitride (TaN), molybdenum nitride (MoN), and tungsten nitride (WN), were studied over a range of HfO 2 thicknesses, e.g., 2.5–10 nm, and post-metal annealing (PMA) temperatures, e.g., 600 °C to 800 °C. The work function of the nitride gate electrode was dependent on the material and the post-metal annealing (PMA) temperature. The scanning transmission electron microscopy technique is used to observe the effect of PMA on the interfacial gate dielectric thickness. After high-temperature annealing, the metal nitride gates were suitable for NMOS. At the same PMA temperature, the oxide-trapped charges increased and the interface state densities decreased with the increase of the HfO 2 thickness for TaN and WN gate electrodes. However, for MoN gate electrode the interface state density is almost independent of film thickness. Therefore, dielectric properties of the HfO 2 high- k film depend not only on the metal nitride gate electrode material but also the post-metal annealing condition as well as the film thickness. During constant voltage stress of the MOS capacitors, an increase in the time-dependent gate leakage current is also observed.
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