Double Structure Research Articles

Mechanism underlying V-type structure formation in maize starch through glycerol–ethanol thermal substitution method

V-type starches have been widely used in food science, agriculture, and biomedical science, but their mechanism of formation in nonaqueous solvents remains unclear. This study performed glycerol–ethanol thermal substitution to prepare V-type starch at atmospheric pressure. Scanning electron microscopy and confocal laser scanning microscopy revealed that breakage of starch particles began in the hilum region and rapidly spread to the periphery with the temperature increased from 100 °C to 130 °C. The Maltese crosses of the starch disappeared and starch particles had the form of doughnut-shaped rings when the glycerol temperature was 140 °C. Glycerol temperature was not found to significantly affect the chain length of amylopectin, meaning that glycerol molecules may stabilize the conformation of amylose through hydrogen bonding, promoting the amylose to form a V-type spiral structure. Additionally, A-type crystallinity and double helix structure proportion of the samples significantly decreased from 30.81 % and 42.21 % to 5.70 % and 16.47 % as the temperature of glycerol was increased to 140 °C, whereas the V-type crystallinity and single helix structure proportion of the samples remarkably increased from 13.26 % and 1.05 % to 37.97 % and 25.09 %, respectively. This study provided a facile and versatile approach to effectively regulate the formation of V-type starch.

Double-crosslinked polyvinyl alcohol/starch bioplastic with superior water-resistance and flame retardancy

The high water solubility and flammability of polyvinyl alcohol (PVA) limits its further widespread use in areas such as bioplastic and green packaging. In this study, double-crosslinked polyvinyl alcohol/starch bioplastics (named PDA) were fabricated using PVA, dialdehyde starch (DAS), and phytic acid (PA), resulting in a material with superior water resistance, flame retardancy, and excellent degradability. PA not only plays the role of catalyst for the chemical crosslinking but also as the physical crosslinker to form the intermolecular hydrogen bonds with PVA and DAS. This chemically and physically double cross-linked network structure results in PDA bioplastics with excellent toughness and water resistance. Specifically, the optimal formulation with 15 % PA content, designated as PDA15, exhibited a high toughness of 35.5 MJ/m3 and demonstrated prolonged shape retention in the boiling water. Additionally, PA also serves as a flame-retardant and antibacterial agent; the PDA15 achieved a high limit oxygen index (LOI) value of 40.0 % and passed the UL-94 V-0 rating without melt dripping, along with better degradability compared to pure PVA film. These outstanding performances make the PDA bioplastics highly promising for various applications, particularly in disposable plastics and laminated flexible packaging materials.

Characterization of A-site doped PrBaCo2O5+δ perovskites as cathode materials for IT-SOFCs

Creating highly efficient and durable cathodes persists as a formidable task in the realm of intermediate temperature solid oxide fuel cells (IT-SOFCs). Hence, we present a double perovskite oxide, Pr0.6Sr0.4BaCo2O5+δ (PS0.4BC), and its electrocatalytic activity is thoroughly investigated. The XRD test is carried out and a notable transformation in the phase structure is observed upon the introduction of Sr2+ ions into the PBC matrix. That is, the phase structure of the material changes from double perovskite structure to single perovskite structure. Through the TG and TEC test that the introduction of Sr2+ ions into the lattice can create additional sites for oxygen vacancy formation and reduce TEC values. Further verify that Sr doping can enhance the concentration of oxygen vacancies of the material. The PS0.4BC cathode material exhibits remarkably low polarization resistance, achieving an impressive value of 0.027 Ω cm2 at an operating temperature of 800 °C. Oxygen partial pressure test shows that as the oxygen partial pressure decreases, there is a notable increase in impedance, particularly evident in the low frequency region of the Nyquist plots. This indicates that the oxygen content has obvious effects on the low-frequency processes. When the oxygen partial pressure exceeds 0.05 atm, the oxygen adsorption-dissociation and diffusion process is the rate-limiting step in the ORR. However, when the oxygen partial pressure is less than 0.05 atm, the formation of lattice oxygen through the combination of oxygen ions and oxygen vacancies processes is the rate-limiting step. Compared PBC cathode material, the more pronounced changes in the high frequency arc of the PS0.4BC cathode at the same oxygen content. It shows that Sr doping significantly changes the high frequency process. After doping, the oxygen vacancy concentration increases, which facilitates the occurrence of the charge transfer process at high frequency.

The role of diabatic heating/cooling in outer rainbands in the secondary eyewall formation and evolution in a numerically simulated tropical cyclone

In this study, the role of diabatic heating/cooling in outer rainbands (ORBs) in the formation and evolution of the secondary eyewall of a numerically simulated tropical cyclone (TC) is investigated. This is done through a series of sensitivity experiments under idealized conditions using a high-resolution cloud-resolving atmospheric model. The results show that artificially increasing diabatic heating in rainbands enhances convective activities in ORBs and leads to an earlier secondary eyewall formation (SEF), and later the faster weakening and earlier dissipation of the primary eyewall. Reducing diabatic heating in ORBs weakens the rainbands and delays the SEF but prolongs the duration of the double eyewall structure if the SEF occurs. Reducing diabatic cooling in ORBs enhances convective activity in rainbands but has little effect on convection in the primary eyewall prior to the SEF. However, it results in a widened eyewall structure and a stronger TC after the eyewall replacement. Increasing diabatic cooling in ORBs largely suppresses convection in rainbands and prohibits the SEF. These results demonstrate that diabatic heating/cooling in ORBs plays important roles in the SEF and evolution. Since diabatic heating/cooling in rainbands is sensitive to the near-core environmental relative humidity, our results demonstrate the critical importance of large-scale environmental moist condition to the formation and evolution of secondary eyewall in TCs. In addition, it is also found that when the area-averaged diabatic heating rate in ORBs becomes similar in magnitude to that in the primary eyewall, the secondary eyewall forms. Plain language summaryPrevious studies have demonstrated the importance of diabatic heating/cooling in outer rainbands to the structure and intensity changes of tropical cyclones (TCs) with a single eyewall. It is unclear whether and how diabatic heating/cooling in outer rainbands may affect the formation and evolution of the secondary eyewall in TCs. These issues have been addressed based on a series of sensitivity experiments under idealized conditions using a high-resolution atmospheric model. Results show that diabatic heating in outer rainbands is favorable for the secondary eyewall formation (SEF). Increasing diabatic heating in outer eyewall can lead to faster weakening and thus earlier dissipation of the primary eyewall. Diabatic cooling in outer rainbands suppresses convection in outer rainbands and prohibits the SEF. Since diabatic heating/cooling in outer rainbands is sensitive to the near-core environmental relative humidity, our results demonstrate the importance of the large-scale environmental moist condition to the SEF of TCs. We also found that when the area-averaged diabatic heating rate in outer rainbands becomes similar in magnitude to that in the primary eyewall, the secondary eyewall would form, which can be considered as a measure of the SEF in TCs. Key points1.Increasing diabatic heating in outer rainbands leads to earlier SEF, and faster weakening and earlier dissipation of the primary eyewall.2.Increasing diabatic cooling in outer rainbands suppresses convective activity in outer rainbands and is unfavorable for the SEF.3.When the area-averaged diabatic heating rate in outer rainbands and the eyewall become similar in magnitude, the secondary eyewall forms.

Proton conductivity of Ca-doped Ba2R1-xCaxNbO6-δ (R = La, Nd, Sm, Gd, Dy, Y, and Yb) ceramics with double perovskite structure

The influence of Ca substitution for R (R = La, Nd, Sm, Gd, Dy, Y, and Yb) on the electrical conductivity of double perovskite-structured Ba2R1-xCaxNbO6-δ (x = 0 and 0.2) ceramics was characterized in this study. Crystal structure analysis of Ba2R0.8Ca0.2NbO6-δ showed three types of lattices, monoclinic (R= La and Nd), tetragonal (R= Sm, Gd, and Dy) and cubic (R= Y and Yb), resulting the reduction of structural distortion for monoclinic structure by the Ca substitution for R. The significant differences in the electrical conductivity between the Ba2LaNbO6 and Ba2La0.8Ca0.2NbO6-δ ceramics may be related to the decrease in the structural distortion, as suggested by the changes in HT-XRPD patterns. Ba2La0.8Ca0.2NbO6 ceramic exhibited the highest electrical conductivity of 2.21 × 10−3 S/cm at 800 ℃ measured under a wet 1 % H2/Ar atmosphere. EMF measurements using a hydrogen concentration cell with water vapor and a water vapor concentration cell revealed that the predominant charge carriers in the Ba2R1-xCaxNbO6-δ ceramics were protons in the temperature range of 600–800 ℃.

HNTs Improve Flame Retardant and Thermal Insulation of the PVA/CA Composite Aerogel.

Porous materials are widely used in construction, batteries, electrical appliances, and other fields. In order to meet the demand for flame-retardant and thermal insulation properties of organic porous materials, in this work, poly(vinyl alcohol)/calcium alginate/halloysite nanotube (PVA/CA/HNTs) aerogels with a hierarchical pore structure at micrometer-nanometer scales were prepared through freeze-drying using PVA as the substrate. The cross-linking reactions of PVA with H3BO3 and sodium alginate (SA) with CaCl2 constructed a double cross-linking network structure within the aerogel. And the HNTs were incorporated as reinforcing agents. The experimental results showed that the PVA/CA/HNTs aerogels had excellent flame-retardant and thermal insulation properties, and the heat release rate (HRR) and total heat release (THR) were effectively reduced compared to the PVA/CA aerogel. In addition, PVA/CA/HNTs aerogels had a high limiting oxygen index (LOI 60%) and low thermal conductivity (0.040 W/m·K). While their surface was subjected to a flame (800-1000 °C) for 25 min, the temperatures of the back surface were still lower than 80 °C. The low thermal conductivity of HNTs with hollow nanotube-like structures and the excellent flame-retardant properties of CA contributed to this phenomenon. The presence of HNTs and CA facilitated the formation of a dense carbon layer during combustion, enhancing the flame retardancy for PVA. In addition, the interpenetrating cross-linking network and the unique nanopores of HNTs collectively established a hierarchical pore structure within the gel, effectively impeding substance and heat exchange between the substrate and external environment. As the flame-retardant and thermal insulating material, PVA/CA/HNTs aerogels have a promising development prospect and potential in the fields of construction, transportation, electronics, and electrical appliances.

Early Planet Formation in Embedded Disks. XI. A High-resolution View Toward the BHR 71 Class 0 Protostellar Wide Binary

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of the binary Class 0 protostellar system BHR 71 IRS1 and IRS2 as part of the Early Planet Formation in Embedded Disks (eDisk) ALMA Large Program. We describe the 12CO (J = 2–1), 13CO (J = 2–1), C18O (J = 2–1), H2CO (J = 32,1–22,0), and SiO (J = 5–4) molecular lines along with the 1.3 mm continuum at high spatial resolution (∼0.″08 or ∼5 au). Dust continuum emission is detected toward BHR 71 IRS1 and IRS2, with a central compact component and extended continuum emission. The compact components are smooth and show no sign of substructures such as spirals, rings, or gaps. However, there is a brightness asymmetry along the minor axis of the presumed disk in IRS1, possibly indicative of an inclined geometrically and optically thick disk-like component. Using a position–velocity diagram analysis of the C18O line, clear Keplerian motions were not detected toward either source. If Keplerian rotationally supported disks are present, they are likely deeply embedded in their envelope. However, we can set upper limits of the central protostellar mass of 0.46 M ⊙ and 0.26 M ⊙ for BHR 71 IRS1 and BHR 71 IRS2, respectively. Outflows traced by 12CO and SiO are detected in both sources. The outflows can be divided into two components, a wide-angle outflow and a jet. In IRS1, the jet exhibits a double helical structure, reflecting the removal of angular momentum from the system. In IRS2, the jet is very collimated and shows a chain of knots, suggesting episodic accretion events.

Design and in vitro/in vivo evaluation of chitosan-polyvinyl alcohol copolymer material cross-linked by dynamic borate ester covalent for pregabalin film-forming delivery system

This research introduced a novel polymer synthesized by combining chitosan and modified polyvinyl alcohol, cross-linked with boric acid using dynamic covalent bonds. The polymer was developed to formulate a pregabalin Film-forming system (FFS) for treating postherpetic neuralgia via topical application, showcasing notable skin adhesion and drug delivery properites. The chitosan-boric acid-modified polyvinyl alcohol polymer was analyzed using NMR, FTIR. The exceptional features of the optimized FFS were evaluated through rheometer, Differential scanning calorimetry (Tg = 45.98 °C), contact angle (θ = 78.62°). The elongation (60.05 ± 3.67 %), cohesion (56.94 ± 4.65 MPa) and skin adhesion (58.12 ± 2.99 kPa) of chitosan-boric acid-modified polyvinyl alcohol were found to be 5.2, 6.8, and 8.3 times higher than those of the pure chitosan film, attributed to the double network structure formed by the cross-linked reversible dynamic covalent bond. The optimized pregabalin FFS exhibited increased in vitro (86.25 ± 1.87 μg/g) and in vivo (100.42 ± 7.44 μg/g) skin retention amounts compared to in vivo oral administration (28.43 ± 4.61 μg/g). In summary, the utilization of borate ester dynamic covalent bonds in developing chitosan-based film-forming polymer proved beneficial in improving skin adhesion and topical therapeutic effectiveness, thereby mitigating the risk of systemic side effects associated with oral administration.

Double perovskite CaSrMSbO6(M = La, Gd, Y): Bi3+ phosphors for multifunctional application

Bi3+-doping luminescent materials have recently evoked considerable interest in versatile applications. In this work, we have developed a series of Bi3+-activated CaSrMSbO6(M = La, Gd, Y) phosphors with double perovskite structures, exhibiting blue emission from 350 nm to 500 nm. The emission spectral position and intensity of Bi3+ ions can be tuned by changing excitation wavelength and doping concentrations. The relationship between the local crystal field environment and the luminescence properties is comprehensively analyzed. Importantly, optical temperature properties of CaSrLaSbO6: Bi3+ were investigated and were found to reach a maximum relative sensitivity of 4.57 % K−1 at 298 K. Furthermore, the anti-counterfeiting ink was prepared using CaSrLaSbO6: Bi3+ phosphors, and it showed tunable emission under different light stimulation. These results indicate that CaSrLaSbO6: Bi3+ phosphors have application potential in optical temperature sensing and anti-counterfeiting.

Effects of sintering temperature on the microstructure and mechanical properties of double-hard-phase TiB2–TiC cermets

The mechanical properties and microstructure of double-hard-phase TiB2–25-wt.%-TiC–20-wt.%-CoNi cermets prepared at different temperatures were investigated by performing scanning electron microscopy, X-ray diffraction, and transmission electron microscopy. The results showed that the transverse rupture strength, indentation fracture toughness, hardness, and relative density of the cermets reached the maximum values of 1654 MPa, 11.06 MPa m1/2, 90.1 HRA, and 99.42 %, respectively, when the sintering temperature was 1462 °C. Solid- and liquid-phase sintering occurred at temperatures below and above 1354.5 °C, respectively. The cermets were composed of TiB2, TiC, TiB, and CoNi phases when sintered at 1440 °C and below, but the TiB phase disappeared when sintered at 1462 °C and above. Both TiB2 core–(Ti, Co, Ni)B rim and TiC core–(Ti, Co, Ni)C rim structures appeared in cermets sintered at 1440 °C and above. In addition, a few TiC core–(Ti, W)C inner–(Ti, W, Co, Ni)C outer double rim structures were formed. A coherent interface was found between the (Ti, Co, Ni)B rim and TiB2 core. A thin CoNi amorphous metallic layer existed at the interface between the (Ti, Co, Ni)C rim and TiC core. In addition, amorphous CoNi was observed in the interfacial region between the CoNi binder and (Ti, Co, Ni)C rim phase and inside the CoNi binder phase. These multi-interface and core–rim structures resulted in excellent strength and toughness of the cermets.

A qualitative analysis on the double porous thermoelastic bodies with microtemperature

This study examines a mixed initial-boundary value problem in thermoelastic materials with a double porosity structure, taking into account the effects of microtemperature. The existence of a solution is established by converting the problem into a Cauchy-type problem. Given the complexity of the equations, unknowns, and conditions, we apply contraction semigroup theory within a specific Hilbert space. We prove the existence of a solution using the Lax-Milgram theorem. Additionally, the uniqueness of the solution is demonstrated based on the Lumer-Phillips corollary, which corresponds to the Hille-Yosida theorem. In the final section, we show the continuous dependence of the solution on the mixed initial-boundary value problem for double porous thermoelasticity with microtemperature.

Cross-linking Arenga pinnata starch and chitosan by citric acid: Structure and properties

In order to improve the processing and digestibility of the Arenga pinnata (Wurmb.) Merr. starch (APS), low concentration citric acid (CA) and chitosan (CS) were used for dual modification. The purpose of this study was to prepare APS and CS complexes with CA, the complexes (CA-CS-APS) physicochemical properties were investigated. The short-range ordered structure (DO), double helix structure (DO) and relative crystallinity (RC) were decreased; CA-CS resulted in the surface roughness of APS, but the particle integrity was preserved; the particle size of CA-CS-APS was increased. Compared with APS, the peak viscosity of CA-CS-APS was decreased from 2534 cP to 27 cP; CA-CS reduced the swelling power of APS, CA3%-CS-APS decreased from 19.00 g/g to 8.17 g/g. The gelatinization enthalpy was decreased after CA-CS modification from 3.25 J/g to 0.55 J/g. CA-CS-APS exhibits higher storage modulus and loss modulus (2067 Pa and 80 Pa). CA-CS significantly improved the anti-digestibility of APS, and the resistant starch (RS) content was increased from 32 % to 39 %. This study provided a simple and effective way to prepare modified starch, which had the potential as food additives or used as a base material for film preparation.

Enhanced Stability Under Positive Bias Temperature Stress in Oxide Thin Film Transistors with Double Gate Structure By Improving Bottom Channel Interface

In this paper, we discuss the causes of reliability degradation in oxide TFTs with a double gate structure and propose methods for improvement. Reducing IGZO deposition power significantly improves PBTS (Positive Bias Temperature Stability) reliability in double gate structures. This improvement is attributed to reduction of excess oxygen defects accumulated at the bottom channel interface, as inferred from the difference in PBTS results for the top single gate and double gate structures

Environmentally stable, Adhesive, Self-healing, Stretchable and Transparent Gelatin based Eutectogels for Self-Powered Humidity Sensors

Intrinsic environmental and stability limitations of hydrogels have inhibited their practical applications as a flexible wearable device due to water evaporation or freezing in complex environments such as low temperatures and arid environments. In this work, a multifunctional gelatin based ionic conductive eutectogel with double network structure is designed via ternary deep eutectic solvent (DES) (acrylic acid (AA), choline chloride (ChCl) and ethylene glycol (EG)). In this system, the introduction of ethylene glycol (EG) can be used to dissolve gelatin. The resulting DESG eutectogel exhibited excellent adhesion, mechanical robustness, anti-freeze, anti-drying, and self-healing. Interestingly, the DESG gels showed high humidity sensitivity in a wide humidity detection range (11 %–83 %), which can be assembled as a self-powdered humidity sensor to monitor human mouth and nose breathing. This work is expected to bring new prospect to construct high performance humidity sensors using gelatin based humidity-responsive materials for a wide range of potential applications in respiratory diagnostics, sleep monitoring, electronic skin and wearable electronics.

Development and Performance Evaluation of a New Conformance Control Agent Gel.

How to effectively plug the multi-scale fractured water channeling has always been the key to achieving efficient water flooding of fractured low-permeability oil reservoirs. In this paper, a new type of supramolecular-polymer composite gel is developed, which is suitable for plugging multi-scale fractured water channeling. The supramolecular-polymer composite gel is composed of a polymer (such as polyacrylamide), cross-linking agent (such as polyethyleneimine), supramolecular gel factor (such as cyclodextrin) and polarity regulator (such as ethyl alcohol). The mass fraction of polyacrylamide, polyethyleneimine, cyclodextrin and ethyl alcohol are 0.15%, 0.2%, 1% and 0.2%, respectively. At the initial state, the viscosity of the composite gelant system is less than 20 mPa·s. It has good injection performance in micro-scale fractures and can enter the deep part of a fractured reservoir. At 40 °C, the composite gelant system can form a gel with a double network structure after gelation. One of the networks is formed by the covalent interaction between polyacrylamide and polyethyleneimine, the other network is formed by the self-assembly of cyclodextrins under the action of the ethyl alcohol. The comprehensive performance of the composite gel is greatly improved. The strength of the composite gel is >5 × 104 mPa·s, and it has good plugging strength in large-scale fractures. The composite gel can be used as a conformance control agent for fractured low-permeability oilfields.

A protocol for detecting the cytoplasm-exposed mitochondrial DNA

Mitochondria, being semi-autonomous organelles, possess a double membrane structure and harbor their own DNA, known as mtDNA. In situations of stress, mtDNA is released from the mitochondrial membrane and enters the cytoplasm. The mtDNA released into the cytoplasm plays a dual role in promoting both the initiation and escalation of intracellular reactive oxygen species (ROS), the activation of inflammatory pathways, and the death of cells. Consequently, the identification of intracytoplasmic mtDNA fragments holds immense significance in the realm of scientific investigation. In this paper, we delineate the experimental methodologies presently employed for quantifying intracytoplasmic mtDNA fragments.

Reduction of Torque Ripple and Axial Force in a Fully Pitched Axial Flux Switched Reluctance Motor Using a Double Stator Structure

Reduction of Torque Ripple and Axial Force in a Fully Pitched Axial Flux Switched Reluctance Motor Using a Double Stator Structure

A Highly Sensitive, Low Creep Hydrogel Sensor for Plant Growth Monitoring

Ion−conducting hydrogels show significant potential in plant growth monitoring. Nevertheless, traditional ionic hydrogel sensors experience substantial internal creep and inadequate sensitivity, hindering precise plant growth monitoring. In this study, we developed a flexible hydrogel sensor composed of polyvinyl alcohol and acrylamide. The hydrogel sensor exhibits low creep and high sensitivity. Polyvinyl alcohol, acrylamide, and glycerol are crosslinked to create a robust interpenetrating double network structure. The strong interactions, such as van der Waals forces, between the networks minimize hydrogel creep under external stress, reducing the drift ratio by 50% and the drift rate by more than 60%. Additionally, sodium chloride and AgNWs enrich the hydrogel with conductive ions and pathways, enhancing the sensor’s conductivity and demonstrating excellent response time (0.4 s) and recovery time (0.3 s). When used as a sensor for plant growth monitoring, the sensor exhibits sensitivity to small strains and stability for long−term monitoring. This sensor establishes a foundation for developing plant health monitoring systems utilizing renewable biomass materials.

Low-velocity impact resistance behaviors of bionic hybrid-helicoidal composite laminates

The exoskeleton of the Homarus americanus lobster feature a hybrid-helicoidal structure of chitin-protein fibers, with distinct helicoidal configurations in the exocuticle and endocuticle, exhibiting strong impact resistance. Taking inspiration from this biological structure, combined with single-helicoidal and double-helicoidal structures, various helicoidal configurations of composite laminates were designed. Both linear and nonlinear helicoidal angles, including sinusoidal and exponential configurations, were considered. The interlaminar and intralaminar damage mode were adopted to simulate material damage initiation and evolution. The effect of helicoidal angles, position, thickness and angle variations of endocuticle on low-velocity impact resistance was analyzed, revealing the damage mechanisms of bio-inspired laminates. The results show that bio-inspired hybrid helicoidal structures with special features could significantly enhance the impact resistance of composites, with laminates featuring sinusoidal-exponential double helicoidal structures showing superior performance. Sinusoidal configurations, being less prone to penetration, are more suitable for the exocuticle. The introduction of double-helicoidal configurations could enhance the toughness and strength of the structure. This studying deepened an understanding of failure mechanisms of bio-inspired helicoidal composite laminates under low-velocity impact and provide a design strategies for developing high-performance, impact-resistant composite materials.

Carboxymethyl cellulose-coated iron-doped hollow silica carriers with erythrocyte-like structure for improved foliar adhesion and responsive pesticide delivery

The development of nanopestcide carriers with high foliage adhesion remains a challenging task. Erythrocytes are double concave disc structure with thinner center and thicker rim and erythrocyte-like carriers would present enhanced foliar affinity. In this study, we fabricated novel rough-surfaced erythrocyte-like carriers for pesticide delivery. Firstly, erythrocyte-like silica (ES) nanoparticles were prepared by sol-gel method. Subsequently, the ES nanoparticles were further hydrothermal treated to obtain rough-surfaced iron-doped hollow ES (Fe-EHS) nanocarriers. The Fe-EHS nanocarriers could increase contact area and form a topological effect between the pesticide carriers and the micro/nanostructures on plant foliage, effectively enhancing the retention and rain fastness on foliage. Fe-EHS nanocarriers presented a loading capacity of 38.1 % for imidacloprid (IMI). After loading IMI, carboxymethyl cellulose (CMC) was encapsulated to generate nanopesticide delivery system (IMI@Fe-EHS-CMC). The obtained IMI@Fe-EHS-CMC exhibited good foliar adhesion, biosafety, and excellent UV shielding. Additionally, the IMI@Fe-EHS-CMC system possessed pH/cellulase responsive release behavior and could be bidirectionally transported through vascular bundles in tobacco plants. Furthermore, the IMI@Fe-EHS-CMC system showed potent insecticidal activity. This work offers valuable insights for enhancing the effective utilization of pesticides.