Double Structure Research Articles

Emulsion Structural Remodeling in Milk and Its Gelling Products: A Review.

The fat covered by fat globule membrane is scattered in a water phase rich in lactose and milky protein, forming the original emulsion structure of milk. In order to develop low-fat milk products with good performance or dairy products with nutritional reinforcement, the original emulsion structure of milk can be restructured. According to the type of lipid and emulsion structure in milk, the remolded emulsion structure can be divided into three types: restructured single emulsion structure, mixed emulsion structure, and double emulsion structure. The restructured single emulsion structure refers to the introduction of another kind of lipid to skim milk, and the mixed emulsion structure refers to adding another type of oil or oil-in-water (O/W) emulsion to milk containing certain levels of milk fat, whose final emulsion structure is still O/W emulsion. In contrast, the double emulsion structure of milk is a more complicated structural remodeling method, which is usually performed by introducing W/O emulsion into skim milk (W2) to obtain milk containing (water-in-oil-in-water) W1/O/W2 emulsion structure in order to encapsulate more diverse nutrients. Causal statistical analysis was used in this review, based on previous studies on remodeling the emulsion structures in milk and its gelling products. In addition, some common processing technologies (including heat treatment, high-pressure treatment, homogenization, ultrasonic treatment, micro-fluidization, freezing and membrane emulsification) may also have a certain impact on the microstructure and properties of milk and its gelling products with four different emulsion structures. These processing technologies can change the size of the dispersed phase of milk, the composition and structure of the interfacial layer, and the composition and morphology of the aqueous phase substance, so as to regulate the shelf-life, stability, and sensory properties of the final milk products. This research on the restructuring of the emulsion structure of milk is not only a cutting-edge topic in the field of food science, but also a powerful driving force in promoting the transformation and upgrading of the dairy industry to achieve high-quality and multi-functional dairy products, in order to meet the diversified needs of consumers for health and taste.

From Double-Stranded Helicates to Abiotic Double Helical Supramolecular Assemblies.

The folding of oligomeric strands is the method that nature has selected to generate ordered assemblies presenting spectacular functions. In the purpose to mimic these biomacro-molecules and extend their properties and functions, chemists make important efforts to prepare artificial secondary, tertiary, and even quarternary structures based on folded abiotic backbones. A large variety of oligomers and polymers, encoded with chemical informations, were designed, synthesized and characterized, and the establishment of non-covalent interactions lead to complex and functional supramolecular architectures resulting from a spontaneous self-assembly process. The association of comple-mentary molecular strands into double helical structures is a common structural pattern of nucleic acids and proteins, so the synthesis of bio-inspired double helices has emerged as an important subject. In recent years, a number of synthetic oligo-mers have been reported to form stable double helices and it was shown that the equilibrium between single and double helices can be controlled via different stimuli like the modification of the solvent or the temperature. This kind of structure presents highly interesting functions, such as molecular recognition within the cavity of double helices, and some other potential applications will emerge in the future.

MARKETING FACTORS OF COMPETITIVENESS MEDITERRANEAN MARKET OF TOURIST SERVICES

The article analyzes the system of marketing factors of the competitiveness of the Mediterranean leisure industry since the promotion of tourist services today becomes impossible without the use of modern technologies. It is noted that the digitalization of marketing communications allows for the formation of unique competitive advantages of the Mediterranean tourism industry through the use of an integrated approach to the most effective combination of classical marketing provisions and the potential of modern technologies in the competitive environment of the tourism industry. Classical marketing techniques and digital technologies offer enormous potential for maximizing tourism revenues, increasing tourism demand, improving the quality of supply and facilitating communication. The influence of marketing elements on the competitiveness of the tourism industry of the Mediterranean countries is evaluated. It has been proven that this influence is uneven and differs according to the destination and the stage of creation and provision and implementation of the tour service. This influence is observed most in the sphere of pricing in Spain and least - in the sphere of tourism product promotion in such European countries as Albania and African countries - Morocco, Algeria and Tunisia. Directions for the analysis of the competitiveness of destinations in the Mediterranean region are proposed, which can be carried out according to different criteria and through different perspectives, such as: customer expectations, tourist satisfaction and service value, tourist and destination motivations, branding, destination attractiveness, destination sustainability and destination value. It is emphasized that, in contrast to classical marketing, modified tourism marketing was formed as a mix that includes seven elements: tourism product, tourism product pricing, distribution of tourism services, tourism promotion, human potential, service provision process and customer service, and which to varying degrees provide competitive advantages of the countries of the Mediterranean basin. It is shown that the competitiveness of the Mediterranean tourism industry has a double structure. Its first element is the process of positioning tourist products on the market of leisure services, the second is the efficiency of the operational activities of tour operators. It has been confirmed that the drivers of the main changes in the market of tourist services of the Mediterranean that have occurred recently are the intensive introduction of information technologies in marketing activities, where the main trends in the development of the leisure industry have become the globalization of the tourist business and the dominance of Internet technologies in the system of promoting tourist services.

Design of waveguide with double layer diffractive optical elements for augmented reality displays

We investigated a diffraction optical waveguide structure with a double layer coupling configuration. This double layer-coupled diffraction optical waveguide structure modulates light information through wavefront modulation for propagation within the optical waveguide and then reproduces the light information through further wavefront modulation, thus achieving optical information transmission. Analysis indicates that the theoretical maximum field of view can reach 90° × 90°. With an actual field of view set to 53° × 53°, an entrance pupil size of 3.2 × 3.2 mm², an eye relief of 10 mm, and 50 pupil expansion, the system’s total energy transmission efficiency is 37%, with field of view uniformity at 91% and uniformity within the eye movement range reaching 97%.

Electric Double Layer and Structure of the Li-ion Battery Separator/Liquid Electrolyte Interface Detected with the Atomic Force Microscope

Electric Double Layer and Structure of the Li-ion Battery Separator/Liquid Electrolyte Interface Detected with the Atomic Force Microscope

Using of Machine Learning Capabilities to Predict Double Phosphate Structures for Biomedical Applications

In the rapidly developing field of biomedical research, the search for new materials with improved properties is crucial to moving the entire field forward. Double phosphates have generated significant interest in a wide range of applications, ranging from drug delivery systems to catalysts for biomedical reactions, and the fields of biomedicine and tissue engineering are no exception. In this article, we propose a method for finding new double phosphate materials based on machine learning, screening and applying data from structural databases, and we use this methodology combined with chemical knowledge to propose several promising materials for bone engineering. For the selected candidates, we develop a solid-phase synthesis procedure and apply physical characteristics to confirm the results. In addition, the role of microstructure, i.e. The porosity of frameworks based on these materials is discussed from a biomedical point of view, and several synthetic ways to adjust this parameter are proposed and investigated.

Zr4+ and Al3+ coordinated cross-linked conductive collagen fibers/solvent-free polyurethane foam with ultra-low reflective electromagnetic shielding properties

In recent years, electromagnetic shielding materials with low reflectance have developed rapidly. However, high material cost, poor bonding fastness, weak mechanical properties and other problems seriously limit its effect in practical use. In this work, flexible conductive collagen fibers (CLF-Zr4+/Al3+-CNTs) were prepared using chromium tanned waste leather as ingredient, carbon nanotubes (CNTs) as conductive filler and transition metal ions as coordination crosslinking agents, and their molecular dynamics were investigated by quantum chemical simulation software. On this basis, a flexible conductive foam with the double layer and double core-clad structure containing carbon nanotubes was constructed using the solvent-free polyurethane (SFPU) chemical foaming technology, and their electromagnetic shielding properties and reflectance were studied. The experiment results showed that when the ratio of CLF-Zr4+/Al3+-CNTs to SFPU polyol is 1:9 and the impregnation times of CNTs are 2, the loading capacity of CNTs in conductive foam is 0.14 mg/cm3, the electrical conductivity is 57.8 S/m, and the thermal conductivity is 0.061 W/(m·K). Meanwhile, when the thickness is 3 cm, the electromagnetic shielding performance is 42.09 dB, and the reflection efficiency is 0.66 %, the lowest reflection efficiency reaches 0.16 % in the experiment. The mechanism of electromagnetic shielding in conductive foams with the double layer and double core-clad structure has been further explored. The experiment results proved that the flexible conductive foam has excellent mechanical properties, stability, heat insulation and flame retardant properties, and has excellent electromagnetic shielding and low reflection characteristics due to its abundant holes, functional group, interface and hierarchical structure.

A spurious-free SAW filter employing a novel transducer structure on bulk LiNbO3 substrates

In order to cope with the ubiquitous wireless connections and the rapid transmission of data in communication systems, surface acoustic wave filters are required to have high performance. With a large electromechanical coupling coefficient (K2), conventional bulk 64°YX-LiNbO3 substrates are attractive for low-cost mass production of surface acoustic wave (SAW) resonators. However, the influence of the transverse modes restricts their practical application. In this work, a novel and simple tilted transducer is fabricated, and successfully achieved spurious-free passband SAW filters based on 64°YX-LN piezoelectric substrates. In this work, the transverse modes suppression method is theoretically studied and designed, and the effectiveness of the energy concentrated structure is verified. The optimal tilt IDT angle for eliminating the influence of transverse modes in Al/64 °YX-LN structure is about 6°. Subsequently, based on the above research, three types of tilted resonators were designed and fabricated, which not only verified the reliability of the aforementioned results but also enhanced the performance of the devices, compensating for the deficiency caused by the reduction of the Q factor due to the tilted structure. Finally, based on the double busbar tilted structure, a SAW filter was designed, which has a large 3 dB fractional bandwidth (FBW) and a spurious-free passband. The SAW filter designed in this work has low cost and excellent performance, and can be mass produced. In the field of low-cost RF devices, this work contributes to maintaining the competitive advantage of SAW technology.

Unraveling the Bivalent and Rapid Interactions Between a Multivalent RNA Recognition Motif and RNA: A Kinetic Approach.

The kinetics of the interaction between Musashi-1 (MSI1) and RNA have been characterized using surface plasmon resonance biosensor analysis. Truncated variants of human MSI1 encompassing the two homologous RNA recognition motifs (RRM1 and RRM2) in tandem (aa 1-200), and the two RRMs in isolation (aa 1-103 and aa 104-200, respectively) were produced. The proteins were injected over sensor surfaces with immobilized RNA, varying in sequence and length, and with one or two RRM binding motifs. The interactions of the individual RRMs with all RNA variants were well described by a 1:1 interaction model. The interaction between the MSI1 variant encompassing both RRM motifs was bivalent and rapid for all RNA variants. Due to difficulties in fitting this complex data using standard procedures, we devised a new method to quantify the interactions. It revealed that two RRMs in tandem resulted in a significantly longer residence time than a single RRM. It also showed that RNA with double UAG binding motifs and potential hairpin structures forms less stable bivalent complexes with MSI1 than the single UAG motif containing linear RNA. Substituting the UAG binding motif with a CAG sequence resulted in a reduction of the affinity of the individual RRMs, but for MSI1, this reduction was strongly enhanced, demonstrating the importance of bivalency for specificity. This study has provided new insights into the interaction between MSI1 and RNA and an understanding of how individual domains contribute to the overall interaction. It provides an explanation for why many RNA-binding proteins contain dual RRMs.

Capped Polyoxometalate-Based Metal-Organic Complex with Mixed-Valence CuI/CuII for Synergistic Catalytic Synthesis of p-Benzoquinone.

The design and synthesis of efficient and environmentally friendly heterogeneous catalysts for the oxidation of phenols to benzoquinones are of great significance. Considering the highly catalytic activity of mixed-valence metals and polyoxometalates (POMs), a three-dimensional polyoxometalate-based metal-organic complex with mixed-valence CuI/CuII, [Cu2ICu2II(pyca)4(OH)3(PMo12O40Cu2II)(H2O)4]·3.5H2O (1, Hpyca = 2-pyrazinecarboxylic acid) has been successfully synthesized under solvothermal conditions. Surprisingly, complex 1 not only combines the desired mixed-valent CuI/CuII and POM sites but also contains a rare double Cu-capped POM structure. Due to the ternary synergistic effect of CuI, CuII, and POM, complex 1 exhibits excellent catalytic activity in the oxidation reaction of 2,3,6-trimethylphenol to the corresponding p-benzoquinone. The conversion and selectivity can reach 98 and 99% within 5 min, respectively, and the turnover frequency (TOF) value is as high as 8167 h-1, which is superior to most catalysts.

Resonant tunneling properties of laser dressed hyperbolic Pöschl-Teller double barrier potential

We examine the resonant tunneling properties of the laser-dressed hyperbolic Pöschl-Teller double quantum barrier structure. We use the non-equilibrium Green's function method to investigate structure parameters and electric field bias on the transmission properties of the system. The transmission probabilities and resonance energy levels are significantly influenced by the well widths and barrier heights. The barrier height increases, resonance energy levels shift toward higher values, and the resonance peak width narrows, leading to sharper and more selective tunneling behavior. Our results show that increasing the electric field bias leads to a decrease in the transmission probability at the first resonance peak, but this effect is not as strong for the subsequent peaks. Moreover, we find that changes in the laser field's parameter and structure parameters allow for fine control over the electronic spectra, allowing for modifications like red or blue shifts based on particular needs. The significance of comprehending the interaction among structural factors, external fields, and transmission qualities in quantum barrier structures is highlighted by our research, providing valuable information for the development and enhancement of electronic and optoelectronic systems with customized functionality. Our findings show the laser field has a considerable impact on resonant tunneling properties, opening the door to new device applications.

Investigation of the nonlinear dynamics of thin sandwich shells composed of functionally graded materials with double curvature in thermal environments

Double curvature structures play a crucial role as load-bearing components across various engineering fields. Functionally graded materials, blending metals and ceramics, boast superior material characteristics, fueling their expanding applications. This study pioneers the non-linear dynamic analysis of sandwich shells that feature functional gradient compositions in thermal settings. We assume that both the upper and lower shells of these double curvature structures are crafted from functionally graded materials, with a ceramic core. This variation in material exhibits a ceramic layer on the inner surface and a metallic layer on the outer surface, showing properties that vary along the shell thickness in a power-law gradient. Non-linear dynamic equations are derived using third-order shear theory, encompassing geometric non-linearity and shear deformation. Employing the Galerkin method, we discretize the equations of motion into a non-linear dynamic system with five degrees of freedom, and subsequently give an analytical expression for the nonlinear naturalfrequency by means of multiscale analysis. Our discussion examines the impacts of structural parameters, porosity volume fraction, volume fraction index, and temperature differences on the non-linear/linear frequency ratio of doubly curved sandwich shells. Calculations reveal a sharp rise followed by a rapid decline in the non-linear/linear frequency ratio with increasing structural aspect ratio b/a. Conversely, it decreases with increasing thickness-to-length and radius-to-length ratios, with temperature differences initially reducing and later increasing it. These findings offer practical insights for designing functional gradient double curvature sandwich shells.

Performance and failure modes of thermal barrier coatings deposited by EB-PVD on blades under real service conditions in gas turbine

Thermal barrier coatings (TBCs) with a double columnar crystal structure of CoCrAlY/YSZ, prepared using electron beam physical vapor deposition (EB-PVD), were applied to turbine blades and tested in real gas turbine conditions. This study investigates their failure mechanisms under both actual operating conditions and simulated external loads, using three-point bending tests. The performance of full-sized, TBC-coated blades was analyzed through finite element modeling, while the thermomechanical and mechanical properties of the coatings after service were measured to support the simulation and provide insights into the failure processes. A new degradation mode, characterized by penetration cracking, was observed in the EB-PVD coatings. This behavior is linked to the columnar grain structure of YSZ and CoCrAlY, lower operational temperatures, and the reduced thickness of the YSZ layer. Surface cracks in the YSZ coating primarily occurred in regions with large curvature, where stress concentrations are higher. This study offers new insights into the failure modes of TBCs under real gas turbine operating conditions.

Double cross-linked biomass aerogels with enhanced mechanical strength and flame retardancy for construction thermal insulation

Biomass aerogels are expected to be a popular material in construction field due to their sustainability, eco-friendliness and excellent thermal insulation properties. In this paper, high modulus biomass aerogels based on the principle of double cross-linking of physics and chemistry were synthesized by freeze-drying technique using gelatin, sodium carboxymethyl cellulose, glutaraldehyde, phytic acid and diatomite as raw materials. The presence of a double cross-linked network structure endowed the prepared aerogels with a low thermal conductivity (0.021–0.029 W·m−1·k−1). The density of only 0.0865 g·cm−3 biomass aerogel exhibited an extrastrong compression modulus of 31.5 MPa, which was superior to common biomass aerogels. Biomass intumescent flame retardant system composed of sodium carboxymethyl cellulose (carbon source), gelatin (gas source) and phytic acid (acid source) was used in combination with diatomite to enhance flame retardancy (limit oxygen index value up to 36.5 %, UL-94 V-0 rating and total smoke production reduced from 0.31 m2 to 0.18 m2) and thermal stability (the residue up to 48.91 %). Remarkably, the modified aerogel showed incredible hydrophobicity (hydrophobic angle of 137°). In summary, the results indicated this study proposed a novel green idea for the preparation of construction thermal insulation materials with a combination of high modulus, flame retardancy and hydrophobicity.

Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and catalytic activities

Two new heteronuclear Cd(II)/Co(III) compounds, {[Cd(1-meim)3Cd0.5(1-meim)Co(μ-CN)4(CN)2]}n (1) and {[Cd(1-etim)3Cd0.5(1-etim)2Co(μ-CN)3(CN)3]⋅H2O}n (2) (1-meim: 1-methylimidazole, 1-etim = 1-ethylimidazole), have been synthesized and characterized using elemental analysis, FT-IR and Raman spectroscopy, single-crystal X-ray diffraction techniques. The single crystal X-ray study shows that the compound 1 exhibited a 1D double chain structure and is further linked into 3D supramolecular architectures through CH⋅⋅⋅N and π⋅⋅⋅π interactions. Whereas the compound 2 displayed 2D network which is extended into a 3D supramolecular framework by OH⋅⋅⋅N hydrogen bonds and CH∙∙∙π interactions. In 1 and 2, each Co(III) ion is coordinated by six carbon atoms from cyanide ligands, thus showing an octahedral coordination geometry. Cd1 and Cd2 ions exhibited two different geometries, distorted trigonal bipyramidal and octahedral. Furthermore, phase purities, catalytic and thermal properties were investigated.

Investigation of the double layer structure of 1-butyl-3-methylimidazolium thiocyanate at the air-water interface using sum-frequency generation vibrational spectroscopy.

The interfacial structure and adsorption behavior of 1-butyl-3-methylimidazolium thiocyanate ionic liquids (ILs) aqueous solutions were investigated using sum-frequency generation vibrational spectroscopy (SFG-VS) and surface tension measurements. Polarization-dependent measurements revealed a dramatic increase in the SFG signal for both CH and CN stretching modes with increasing ILs concentration, reaching a maximum at a mole fraction of 0.01. This concentration dependence was accompanied by a dramatic drop in surface tension. Upon further increasing the concentration, surface tension varied slightly and reached a constant value, while the SFG signal decreased significantly. Quantitative polarization analysis showed that as the bulk concentration increased, the apparent molecular orientation of the SCN- transition dipole at the interface changed from 51° to 46°, and the tilt angle of CH3 group of the butyl chain attached to the imidazole cationic ring changed from 18° to 32°. The decrease in the SFG signal can be explained by the formation of a double layer adsorption structure at the air/water interface. It was also demonstrated that the anions were adsorbed at the interface simultaneously with the cationic group, rather than by successive adsorption as proposed in a previous study. Using the Shereshefsky model, the thermodynamic Gibbs free energy of adsorption deduced from surface tension data was compared with SFG results.

Effect of volute structure on the performance of double suction centrifugal pump

Abstract This study aims to investigate the impact of the double volute structure on the internal flow dynamics and hydraulic performance of a double-suction pump. To achieve this, a double-suction centrifugal pump was selected as the research subject, and three-dimensional turbulence numerical simulations were conducted under various working conditions using the Reynolds average method (RANS) and RNG k-ε turbulence model. The results of the simulation are compared with the experimental data, which demonstrates the validity of the numerical simulation. This study analyzes the impact of the splitter on the flow field within the volute and impeller, as well as its effect on the radial force of the impeller. The results indicate that the water flow has a significant impact on the head of the splitter, resulting in a noticeable high-pressure zone on the pressure side of the blade in close proximity to the starting end of the splitter; Under off-design conditions, a significant recirculation zone exists between the end of the splitter and the pump outlet, and it increases as the deviation from the designed condition increases; In the case of a small flow rate, the flow inhomogeneity near the starting end of the splitter is serious, and there are large zones of low speed on the outside of the splitter; The double volute structure can make the inlet velocity of the volute more evenly distributed along the circumferential direction, and can be effectively utilized to reduce the radial force exerted on the impeller, thereby improving its performance.

Unidirectional steel wire reinforced metal matrix syntactic foams

Abstract A double composite structure has been successfully produced using vacuum infiltration. In this structure, the matrix was unalloyed aluminium filled with Lightweight Expanded Clay Aggregate Particles to create metal matrix syntactic foam, and stainless steel wires were placed inside this matrix as unidirectional reinforcement. The wires created a shape-locking bond with the matrix owing to their wave-like form, which helped to prevent reinforcement pullout. Based on the acquired tensile data, the tensile strength of the specimens calculated with the theoretical maximum area of reinforcement wires is Rm, theoretical = 1063 ± 192 MPa, while the tensile strength of the individual wires is Rm, wires = 882 ± 2, which leads to the conclusion that the matrix distributed some of the stress.

III-nitride MQW-based optoelectronic sensors for multifunctional environmental monitoring

This work presents an integrated multi-quantum well (MQW) optoelectronic sensor leveraging III-nitride materials for multifunctionality on a monolithic chip. Fabricated using standard microfabrication techniques, the sensor adopts identical InGaN/GaN MQWs, enabling simultaneous emission and detection. The sensor features a double concentric circle structure, supporting both on-chip and off-chip detection mechanisms, capable of detecting environmental parameters like rotational speed, proximity, and sucrose concentration. It exhibits stable photocurrent response to rotational speed up to 8000 rpm, a 3 cm vertical detection range, and a linear response with 3.9 nA/% sensitivity to changes in sucrose concentration, demonstrating potential for diverse applications including industrial and biomedical fields.

Synthesis of Sr2(Co1.1;Mo0.9)O6-δ double perovskite and its electrochemical performance in the oxygen reduction reaction

Mixed ionic-electronic conductors composed of Sr2(Co;Mo)O6-δ double perovskites have been identified as potential candidates for symmetric Solid Oxide Fuel Cells, but their performance and stability under cathodic conditions remain unclear. Typically, a Co:Mo ratio of 1:1 leads to the formation of SrMoO4 as a by-product when the material is treated in air. In this study, we show that employing a glycine-nitrate combustion process with a high fuel ratio, along with an excess of cobalt, leads to a single-phase material with a double perovskite crystal structure (I4/m space group) after air calcination at high temperatures. Detailed Co and Mo speciation studies conducted using XPS and XANES spectroscopies are also presented to support these findings. Our electrochemical impedance spectroscopy study shows that this material exhibits excellent electrocatalytic response for the oxygen reduction reaction, with oxygen ion diffusion through the cathode being the rate-limiting process. Furthermore, the material shows strong chemical compatibility with (La;Sr)(Ga;Mg)O3-δ electrolytes at temperatures up to 1000 °C. For comparison purposes, we also present the properties of single perovskite cathodes with the composition Sr(Co0.95;Mo0.05)O3-δ.