This paper presents a highly efficient ternary flash ADC, designed using the innovative gate-overlap tunnel FET (GOTFET) at the 45 nm technology node. The proposed GOTFETs have on-state currents Ion more than double, while the off-state currents Ioff remaining at least an order of magnitude lower than the corresponding values of the standard 45 nm CMOS technology with the same width. Replacing MOSFETs with the proposed GOTFETs significantly reduces the static power consumption and improves performance. However, the higher Ion increases the dynamic power as well. To minimize the dynamic power, we propose a novel complementary GOTFET (CGOT) based comparator design. In addition to the inherent advantages of the GOTFET technology, the proposed design further reduces the dynamic power, such that the final power delay product (PDP) is merely 6.3% of the PDP in conventional CMOS comparator design. In addition to the novelty related to the innovative GOTFET devices, there are at least two-fold circuit-level novelty reported in this work. Firstly, we propose a novel CGOT based comparator circuit design, which, in addition to the advantages of GOTFET, further reduces the dynamic power such that the PDP is less than 1/3rd of the original PDP of the conventional comparator designed with GOTFETs. Secondly, the proposed CGOT based ADC requires only 48 transistors to encode the comparator outputs into the 2-bit ternary output, which is 30% lower than the 70 transistors necessary for the 2-bit CMOS based ternary flash ADC designs reported earlier in the literature. We propose an efficient 2-bit ternary flash ADC with a resolution of 50 mV and input quantized to 9 levels. Subsequently, we benchmark the performance of the proposed CGOT ternary flash ADC with the same ADC circuit implemented using the standard 45 nm CMOS technology library, all corresponding devices having the same width. We demonstrate that in addition to the superior performance than the corresponding CMOS ADC, the proposed CGOT ADC design consumes significantly lower power. The overall PDP of the proposed CGOT ADC is merely 6.3% of the PDP in corresponding CMOS design.