Carbon Nanotubes Content Research Articles

Wear resistance of extruder parts in the production of polymer nanomodified products

Extrusion equipment is widely used in the production of polymer materials. One of the urgent questions that arises when studying the processes of obtaining polymer products by the extrusion method is the question of studying abrasive wear, which may depend on the efficiency of the equipment, the duration and reliability of its work. In the context of abrasive wear, the process that needs attention is the extrusion of polymer materials with carbon nanotubes. The purpose of this work is to develop a numerical method for determining the evolution of abrasive wear of the equipment of the extruder working area in the process of processing nanomodified polymer granules and determining the life cycle of this equipment with in order to increase the parameters of their durability. The specific objectives of the study include: 1) Determination of the influence of the content of CNTs in PVC on the rate of wear of the steel surface of the extruder; 2) Analysis of the dependence between friction and the content of CNTs in the polymer composite; 3) Establishing optimal extrusion conditions to minimize abrasive wear of the steel surface; 4) Comparison of simulation results with experimental data to check the reliability of the model. The work is aimed at understanding the processes that occur during the extrusion of nanocomposites and their impact on the wear resistance of equipment materials, which can contribute to the improvement of technological processes and ensure longer and more efficient operation of extruders in production conditions. It has been established that the processes of extrusion processing of polymer nanoreinforced composites can be effectively studied by developing and implementing numerical models that take into account the interaction of all physical and mechanical parameters of a representative volume of the contact zone of the equipment with the polymer and the nanotube with the adhesive layer. In this work, a model for determining the physical and mechanical properties of the interface layer between the CNT and the polymer array is constructed and implemented. The technique for determining the properties of the nanotube-polymer interface is integrated into the APROKS system for analyzing the stress-strain state of nanomodified polymer materials. Based on a multilayer isoparametric FE, a series of numerical experiments were carried out to simulate the process of abrasive wear of the material of equipment elements in the extruder working area. The possibility of a detailed study of the processes of nonlinear contact interaction of nanotubes with an interface layer with equipment elements of the extruder working area based on multilayer FE has been confirmed. Diagrams were obtained that determine the service life of equipment in the working area of the extruder depending on the volume concentration of carbon nanotubes in the polymer at different levels of operating pressure in the “nanotube – polymer – equipment” contact system. It is advisable to use the proposed methodology in the development of information support systems for the life cycle of operation of equipment in the working area of extruders intended for the production of nanomodified polymer products.

Influence of carbon nanotubes on printing quality and mechanical properties of 3D printed cementitious materials

This paper presents the impact of incorporating carbon nanotubes (CNTs) into the 3D printing of cementitious materials, along with the effective dispersion of CNTs. Compared to the control mix, adding CNTs with superplasticizer significantly enhanced the printing quality by reducing the error in height of two-layers from 38% to 30% and an 81% enhancement in the buildability. Moreover, rheology properties revealed shear-thinning behaviour with lower viscosity, resulting in improved flowability. The progressive increase in CNT concentrations up to 0.2% yielded a noteworthy improvement in the mechanical properties. At 28 days, the incorporation of 0.2% CNTs resulted in a significant increase in the flexural strength, compressive strength, and Young's modulus by 99%, 72%, and 43%, respectively, compared to the mix containing silica fume. Microstructural investigation of the CNT-cement matrix revealed nanoscale crack bridges formed by CNTs, reinforcing the cementitious material and improving its mechanical properties.

Connectivity patterns in lead-free piezocomposites: A critical analysis for 0-3 and 1-3 configurations

In the quest for eco-friendly alternatives within materials science, the development of sustainable and non-toxic piezoelectric composites is of utmost importance. This study undertakes a computational exploration to elucidate the influence of phase connectivity on the engineering performance of lead-free piezocomposites. Employing a combination of analytical and numerical methodologies, we critically evaluated various figures of merit across different microstructural configurations, juxtaposing these findings with traditional lead zirconate titanate (PZT)-based materials. Our analysis considers 0-3 and 1-3 connectivity patterns, incorporating active phases in the form of spherical particles and cylindrical fibers. We also examine the impact of carbon nanotubes (CNTs) in enhancing the polymeric matrix, which introduces the potential for network percolation and further mechanical and electrical property optimization. The study yields pivotal insights into the phase connectivity of lead-free piezocomposites, with direct implications for their application in sensing, actuating, and energy harvesting domains. We ascertain that the electromechanical performance of these composites is contingent upon the connectivity pattern and the proportion of active phase. Notably, the KNNS-BNZH & Polyethylene composite demonstrates exceptional potential in 1-3 configurations, while the BTO & PVDF composite distinguishes itself with superior dielectric and piezoelectric responses across varying volume fractions. The strategic infusion of CNTs into the PDMS matrix emerges as a significant enhancer of electromechanical attributes, albeit with performance improvements that are specific to the type of coefficient and CNT concentration. This investigation underscores the nuanced interplay between composite design and microstructural attributes, reinforcing the critical role these factors play in the advancement of effective and eco-conscious piezoelectric materials.

Three-layered PBAT/CNTs composite foams prepared by supercritical CO2 foaming for electromagnetic interference shielding

Plastic pollution and electromagnetic radiation cause serious environmental problems. Herein, biodegradable poly(butylene adipate-co-terephthalate) (PBAT) and carbon nanotubes (CNTs) composite foams with three-layered structure for electromagnetic interference (EMI) shielding application were prepared by an environmentally friendly supercritical CO2 foaming method. For the CNTs content of 4.9 vol%, the EMI shielding efficiency (SE) of three-layered composite was 23.4 dB, which was improved by 125 % compared with that of single-layered composite with a CNTs content of 4.7 vol% owing to high conductivity in skin layer and multiple reflection between interfaces. The CNTs content in core has little effect on the EMI SE when the CNTs content in skin was 16 wt%. After foaming, SE values slightly decreased due to a decreased volume content of CNTs. However, considering the decreased density of foam, the specific EMI SE was improved by 26.2% after foaming when the CNTs content was 16 wt% in skin and 0 in core. This work provided a facile and green method for preparing lightweight EMI shielding materials.

Post-creep residual tensile properties of multi-walled carbon nanotube/epoxy nanocomposites

Epoxy resin as a thermoset polymer is vulnerable to creep loading even at room temperature due to its viscoelastic nature. This study investigated the effect of reinforcing epoxy resin with different functionalized multi-walled carbon nanotubes (MWCNT) contents on the creep response and post-creep residual tensile properties of nanocomposites. The creep tests were performed on the nanocomposite specimens containing different filler contents and the neat epoxy specimen at 40°C under a constant load level of 200 N. It was found that the nanocomposites containing 0.3 wt% MWCNTs experienced 29.6%, 69.1%, and 74.1% decreases in the elastic strain, creep strain, and steady-state creep strain rate, respectively, compared to the neat epoxy. Furthermore, the tensile strength and stiffness of the neat epoxy and nanocomposite specimens were evaluated before and after a partial creep test (at a load level of 200 N for 150 min) by conducting tensile tests. The nanocomposites containing 0.3 wt% MWCNTs demonstrated considerable improvements of 35.9%, 41.2%, 27.9%, and 28.1% in strength, residual strength, stiffness, and residual stiffness, respectively, compared to the neat epoxy. Furthermore, scanning electron microscopy assessment was utilized to investigate the fracture surfaces of the nanocomposite specimens.

Bimodal coaxial fiber sensor for simultaneous strain and temperature sensing for composite manufacturing process

Coaxial structured fibers have gained significant attention in sensor applications due to their design flexibility and ability for multifunctionality. However, the complex and thicker structure of a sensor can lead to stress concentration and signal interference when utilized for strain monitoring in composite manufacturing processes. To address this issue, we propose a bimodal coaxial fiber sensor capable of simultaneous temperature and strain measurement during composite cure and strain monitoring, while preserving the mechanical properties of the fabricated composites. To achieve bimodal sensing, we employ a multi-shell structure consisting of a multi-conductive layer with varying concentrations of multiwalled carbon nanotubes and a PEDOT:PSS layer, applied to a creep-enhanced ultra-high molecular weight polyethylene core fiber using a simple dip-coating method. The bimodal coaxial fiber sensor exhibits a high gauge factor (>4.1), stable cyclic tensile response (>1000 cycles), and linear response to stepwise temperature cycles. Moreover, the sensor demonstrates high sensing accuracy (<3% error) in cure strain monitoring and maintains the fracture toughness of the composite (<1% discrepancy) wherein it is embedded. These results confirm the significant potential of the bimodal coaxial fiber sensor for various applications in the composite industry and other fields.

Cementitious composites modified by nanocarbon fillers with cooperation effect possessing excellent self-sensing properties

Abstract The safety and durability of concrete structures are prone to damage and result in significant harm to human society. Hence, monitoring and estimating the states of concrete structures is of great significance to protecting human safety. Graphene nanoplatelets (GNPs) and carbon nanotubes (CNTs) are promising candidates to endow cementitious composites with piezoresistivity for the health monitoring of concrete structures. Therefore, the aim of this article is to explore the effect of the hybrid GNPs and CNTs on behavior of cementitious composites with cooperation effects. The cementitious composites containing the hybrid GNPs and CNTs with simplified manufacturing methods are developed first. And then, the mechanical behaviors, electrical conductivities, and piezoresistive performances of the composites are investigated systematically. Finally, the modification mechanisms are also discussed. The results proved that the electrical resistivity of the composites with the hybrid GNPs and CNT concentration of 5.0 wt% is reduced by three orders of magnitudes, and the FCR and sensitivities are reached at 36.0% and 1.1% MPa−1/177.9, respectively. Its compressive strength/elastic modulus is achieved at 73.3 MPa/16.9 GPa. Therefore, the hybrid GNPs and CNTs modified cementitious composite present great potential application in monitoring and evaluating service states of civil infrastructures.

Influence of PLA/HDPE Ratio and CNT content on the morphology, electrical, and EMI shielding of CNT-filled PLA/HDPE blends

The influence of polylactic acid/high-density polyethylene (PLA/HDPE) volume ratio on the microstructure, electrical resistivity, and electromagnetic interference (EMI) shielding effectiveness (SE) of 1.0 vol% carbon nanotube (CNT) filled PLA/HDPE composites were investigated. Also, the effect of CNT content on the electrical resistivity and EMI SE of 90/10, 50/50, and 10/90 PLA/HDPE blends were studied. The CNT/PLA composite showed superior electrical and EMI SE performance compared with the CNT/HDPE composite. In the PLA/HDPE blends, the nanotubes were selectively localized in the HDPE domain. The EMI SE and electrical conductivity increased with the decrease of HDPE volume fraction in the blend. The 90/10 PLA/HDPE blend exhibited electrical percolation at 0.25 vol% CNT compared to 1.0 vol% for the 10/90 PLA/HDPE blend. At 7.0 vol% CNT and higher, the EMI SE of the 50/50 PLA/HDPE blend showed marginally higher SE than the 90/10 PLA/HDPE blend. The EMI SE was found to be a function of the composite’s electrical resistivity and microstructure.

Synergistic Effect of Carbon Nanotubes, Zinc, and Copper Oxides on Rheological Properties of Fracturing Fluid: A Comparative Study

Nanomaterials play a beneficial role in enhancing the rheological behavior of fracturing (frac) fluid by reacting with intermolecular structures. The inclusion of these materials into the fluid improves its stability, increases the viscosity of polymers, and enhances its resistance to high temperature and pressure. In this investigation, multi-walled carbon nanotubes (CNTs), nano-zinc oxides (N-ZnO), and nano-copper oxides (N-CuO) have been utilized to ameliorate the rheological properties of water-based fracturing fluid. Different concentrations of these aforementioned nanomaterials were prepared to determine their effects on the rheological behavior of the fluid. The results revealed that the size of nanoparticles ranged from 10 to 500 nm, 300 nm, and 295 nm for CNTs, N-ZnO, and N-CuO, respectively. Moreover, employing CNTs exhibited a resistance of 550 cp at 25 °C and reached 360 cp at 50 °C with a CNT concentration of 0.5 g/L. In contrast, N-CuO and N-ZnO showed a resistance of 206 cp at 25 °C and significantly decreased to 17 cp and 16 cp with higher concentrations of 10 g/L and 1 g/L, respectively. Based on these findings, this study recommends utilizing CNTs to enhance fracking fluid’s chemical and physical properties, which need to be highly viscous and stable under reservoir conditions.

Effect of carbon nanotubes content on compressive properties and deformation behaviors of aluminum matrix composite foams

The incorporation of nano carbon reinforcement is a useful strategy to broaden the engineering applications of metal foams. In this work, carbon nanotubes (CNTs) reinforced aluminum (Al) matrix composite foams (CNTs/Al composite foams) with different CNTs content are prepared by combining ball-milling technique with powder metallurgy method. The result shows that the appropriate content of CNTs can reduce the pore size, improve the circularity, and enhance the compressive properties. Especially, the 1.0 wt% CNTs/Al composite foams possess the optimal compressive properties of yield stress (7.90 MPa), plateau stress (8.75 MPa) and energy absorption capacity (5.19 MJ/m3), which have an enhancement of 23.24%, 98.41% and 84.70%, respectively. Composite foams undergo shear deformation throughout the quasi-static compression process, and the failure mode performs as the brittle mode combined with ductile mode. Meanwhile, the incorporation of CNTs can contribute to the inhomogeneous distribution of the Si phase, provide more nucleation sites, and significantly refine the pore size. It is confirmed that the CNTs in composite foams contribute the grain refinement and the formation of micro stacking faults, making the mechanical properties of CNTs/Al composite foams outperform the counterpart of Al-Si foams. Moreover, due to the weak interfacial reaction, the low content of aluminum carbide is formed, which can promote the load transfer between CNTs and Al. The present finding provides a theoretical and practical design strategy to the future preparation of CNTs/Al composite foams.

Effects of PVA fibers and multi-walled carbon nanotubes reinforcement on uniaxial compression fatigue properties of Engineered geopolymer composites

As a new type of green and environmentally friendly cementing material, engineered geopolymer composites (EGC) have broad application prospects. In this study, uniaxial compression fatigue tests were conducted to investigate the fatigue properties of geopolymer material. A total of 137 samples were tested to investigate the effects of carbon nanotubes content, polyvinyl alcohol (PVA) fibers volume content, and maximum stress level on the fatigue life and deformation of geopolymers. The results showed that the fatigue life of geopolymers obeys Weibull distribution, and PVA fibers and multi-walled carbon nanotubes (MWCNTs) achieved multiscale enhancement of the fatigue life by up to 16.34 times. The total strain accumulation, residual strain, and fatigue stiffness of the geopolymers under fatigue loading exhibited a three-stage evolution rule, with stability within the secondary creep branch. In the process of EGC production, the innovative adoption of optimized MWCNTs surface modification and dispersion strategies improved the uniformity of MWCNTs distribution in the matrix. Scanning electron microscopy (SEM) confirmed the hybridization of MWCNTs and PVA fibers at the microscopic level, which can achieve multi-scale enhancement of geopolymers. This study successfully optimized the content of MWCNTs and PVA fibers, further expanding the application range of composite materials.

Tunable electrospun scaffolds of polyacrylonitrile loaded with carbon nanotubes: from synthesis to biological applications.

Growing cells in a biomimetic environment is critical for tissue engineering as well as for studying the cell biology underlying disease mechanisms. To this aim a range of 3D matrices have been developed, from hydrogels to decellularized matrices. They need to mimic the extracellular matrix to ensure the optimal growth and function of cells. Electrospinning has gained in popularity due to its capacity to individually tune chemistry and mechanical properties and as such influence cell attachment, differentiation or maturation. Polyacrylonitrile (PAN) derived electrospun fibres scaffolds have shown exciting potential due to reports of mechanical tunability and biocompatibility. Building on previous work we fabricate here a range of PAN fibre scaffolds with different concentrations of carbon nanotubes. We characterize them in-depth in respect to their structure, surface chemistry and mechanical properties, using scanning electron microscopy, image processing, ultramicrotomic transmission electron microscopy, x-ray nanotomography, infrared spectroscopy, atomic force microscopy and nanoindentation. Together the data demonstrate this approach to enable finetuning the mechanical properties, while keeping the structure and chemistry unaltered and hence offering ideal properties for comparative studies of the cellular mechanobiology. Finally, we confirm the biocompatibility of the scaffolds using primary rat cardiomyocytes, vascular smooth muscle (A7r5) and myoblast (C2C12) cell lines.

Evolution of surface oxide chemistry and its effect on the electrochemical degradation behaviour of AlCoFeCuNi high entropy alloy coating incorporated with multiwalled carbon nanotubes

AlCoFeCuNi high entropy alloy (HEA) coatings containing different volume fractions of carbon nanotubes (CNTs) were electrodeposited over mild steel substrate. Phase constitution, morphological evolution, electrochemical corrosion properties and surface oxide chemistry of the coatings were investigated as a function of their CNT content and correlated. With initial incorporation of the CNTs, the surface morphology of the composite coatings became progressively finer and compact till an optimum CNT volume fraction. Higher volume fractions of CNTs led to their agglomeration which yielded rougher and defective coating morphology. Corrosion rate of the HEA coating was highly sensitive to the CNT content and at an optimum CNT volume fraction HEA-CNT composite coatings (HEA_CNT-3 coating produced from electrolyte with 10 mg/L of CNT) with lowest corrosion rate was obtained (polarization resistance: Rp = 1178.85 Ω-cm2) while the highest corrosion rate was observed for the pristine HEA coating (Rp = 225.84 Ω-cm2). The coating with highest CNT volume fraction (HEA_CNT-6 coating produced from electrolyte with 35 mg/L of CNT) exhibited the polarization resistance value of 281.80 Ω-cm2. Contact angle measurement revealed that with increase in CNT content, coating hydrophobicity increased monotonically. Analysis of the surface oxide layer of the exposed samples exhibited increase in the relative content of Co3O4, CuO, NiO, AlO(OH) oxides with the presence of CNTs. This work shows that an optimum volume fraction of CNT which produces relatively compact morphology and facilitates evolution of stabler surface oxides leads to significant enhancement in the corrosion resistance of AlCoFeCuNi HEA-CNT composite coating.

Development of Sugarcane Bagasse Ash Blended Cementitious Composites Reinforced with Carbon Nanotubes and Polypropylene Fibers

Cement-based composites, as primary construction materials, have undergone significant advancements over the years, yet researchers still face challenges in terms of their durability and impact on the environment. The goal of this research is to develop environmentally friendly cementitious composites blended with sugarcane bagasse ash (SCBA) and reinforce them with multi-walled carbon nanotubes and polypropylene (PP) fibers. Because of the high cost associated with carbon nanotubes (CNTs) and PP fibers, as well as CO2 emission, which affect the economic and environmental aspects of this field, an agricultural waste such as SCBA was introduced in the current study that is both economically and environmentally viable. For this purpose, five mixes were designed by varying the CNTs content whilst keeping the PP fibers and SCBA contents constant at 1.5% and 15% by weight of the binder (ordinary Portland cement + SCBA), respectively. The developed blends were tested for various mechanical and durability properties, i.e., compressive strength, flexural strength, impact strength, water absorption, and ultrasonic pulse velocity. Moreover, the microstructures of the newly developed low-carbon SCBA-based composites reinforced with PP fibers and CNTs were studied through scanning electron microscopy and energy dispersive spectroscopy. The results showed that the developed blends incorporating 15% SCBA, 1.5% PP fibers, and 0.08% CNTs, by weight of the binder, demonstrated the compressive, flexural, and impact strengths as 15.30 MPa, 0.98 MPa, and 0.11 MPa, respectively. The investigated blends proved to be cost-effective and environmentally beneficial, rendering them suitable for utilization in general construction and maintenance works.

Effect of TiC nanoparticles on microstructure and corrosion resistance of laser cladding Al-CNTs composite coatings on AZ31 alloy

ABSTRACT Al-CNTs composite coatings were successfully prepared on AZ31 alloy using laser cladding (LC). The effect of TiC nanoparticles on microstructure and corrosion resistance of the LC Al-CNTs and Al-TiC-CNTs composite coatings were investigated. The LC composite coatings were composed of α-Mg solid solution phase and β-Al12Mg17, Mg2Al3, Mg32(Al,Zn)49 and TiC compound phases. A sound metallurgical bonding interface was produced between the LC composite coatings and AZ31 alloy. The surface microhardness and corrosion resistance of the LC composite coatings, which were gradually decreased with increasing the content of carbon nanotubes (CNTs) and TiC nanoparticles, were significantly enhanced compared to those of the AZ31 alloy. The LC Al-CNTs (99 wt% Al + 1 wt% CNTs) composite coating exhibits excellent surface microhardness and corrosion resistance. The mean surface microhardness, self-corrosion potential and self-corrosion current were 266.4 HV, −1.233 V and 2.55 × 10−5 A, which were 426.2%, 78.9% and 16.5% of the AZ31 alloy, respectively.

Carbon nanotubes enhancement of tribological and nanomechanical properties of PVDF-BN nanocomposites

There have been continuous efforts to further promote various properties of polymeric materials to meet various industrial demands, especially in the area of thermal, electrical, mechanical and wear properties. This study developed polyvinylidene fluoride (PVDF)-boron nitride (BN) nanocomposites and significantly enhanced their wear and nanomechanical properties by incorporating very low content of carbon nanotubes (CNT). The nanocomposites were developed via simple technique of solution mixing and hot compression. Scanning electron microscope showed that the nanocomposites achieved uniform microstructure with no significant agglomeration of the nanoparticles in the PVDF matrix. The wear rate of PVDF-10wt%BN-0.1wt%CNT was reduced from 5.68 × 10–4 and 5 × 10–3 mm3/Nm for pure PVDF to 1.6 × 10–6 and 8 × 10–6 mm3/Nm at applied loads of 10 N and 20 N, respectively. Also, an increase in hardness and elastic modulus of 225% and 219% for PVDF-10wt%BN-0.1wt%CNT was obtained relative to the pure PVDF at 100-mN applied load. While the nanocomposite showed about 75% and 103% increments compared to PVDF-10wt%BN at 100 mN. This study revealed that the addition of small amount of CNT could further improve the wear and mechanical properties of PVDF-BN as well as any other polymer-ceramic binary systems various advanced engineering applications.

Chloride penetration resistance of ultra-high performance concrete with various multi-walled carbon nanotubes

Ultra-high performance concrete (UHPC) with outstanding chloride penetration resistance (CPR) exhibits excellent prospects for extending the service life of structures in the marine environment. This study investigates the effects of various types and contents of multi-walled carbon nanotube (MWCNT) on the CPR of UHPC, including pristine MWCNT with different sizes, MWCNT with surface modification, and MWCNT with special structures. The results show that 0.25% thick-short pristine MWCNT, 0.5% short hydroxyl functionalized MWCNT, and 0.25% helical MWCNT show more significant enhancement effect, improving the CPR by 74.14%, 72.91%, and 77.17%, respectively. The correlation analysis results suggest a negative linear correlation between the CPR and pore volume of the composites. The C-S-H gels and small capillary pores with a diameter below 50 nm are the significant factors determining the CPR of the composites. This illustrates that the CPR enhancement effects of various types of MWCNT change with the refinement of pore structure of UHPC. The enhancing mechanisms can be attributed to the nano-core effects of MWCNT, reducing the CH crystal size and primary cracks, inhibiting the growth and propagation of microcracks, refining the pore structure, optimizing the compactness of the cement paste matrix and interfacial transition zone, thus reducing the channels for chloride ion diffusion, while increasing the constrictivity and tortuosity of the channels.

Influence of Incorporating MWCNTs on Some Physical Characteristics of Blend Nanocomposites

Nanocomposite membranes made of chitosan (Cs) concentrations, and polyvinyl alcohol (PVA) with a fixed ratio of (60:40), then incorporated with different concentrations of multi-walled carbon nanotubes (MWCNTs) (1, 1.5, 2, 2.5, and 3%) were created using the solution cast method. The membranes were identified using UV-vis spectroscopy, Fourier transform infrared (FTIR), and X-ray diffraction (XRD). The results demonstrated that the samples were sufficiently stable, and the interactions between nanoparticles and polymers were generally negligible. XRD patterns showed a crystalline phase of PVA, an amorphous phase of chitosan, and a more crystalline phase as MWCNTs were introduced. In particular, at high percentages of MWCNTs, the dominant phase (002), connected to MWCNTs, was shifted to a higher value. The UV-vis spectroscopy of the sample showed only one absorption peak at about 230 nm and no other peaks. This may be due to transparency in PVA and Cs. The band gap energy decreased when higher percentages of MWCNTs were added to the mixture.

Removal of organochlorine pesticides by nanofiltration membranes modified with NH2-MWCNTs

Excessive use of pesticides and therefore the spread of pesticides in the environment with destructive effects on human and animal health is a very great problem in the world. In this study, the removal of three samples of organochlorine pesticides including aldrin, lindane, and endosulfan was investigated using nanofiltration membranes modified with NH2-MWCNTs. The properties of the prepared membranes were investigated by scanning electron microscopy (SEM), contact angle, water content, porosity, and mechanical strength. The performance of the membranes was evaluated by analysis of the rejection and flux of pesticide solutions at different pH. The addition of NH2-MWCNTs to the polymer matrix significantly improved the hydrophilic properties of the membranes and reduced the contact angle. Membrane flux was also improved by increasing the concentration of carbon nanotubes to 0.2 wt%. The highest flux at pH 10 is related to lindane pesticide. The modified membrane with 0.5 wt% functionalized carbon nanotubes showed a 98% rejection for endosulfan at neutral pH compared to the pure membrane. In the pH range experiment, lindane rejection was lower than of other pesticides. The steric hindrance due to the structure and molecular size of pesticides and interaction with membrane surface was very important in membrane efficiency. The M3 membrane with 0.3 wt% NH2-MWCNTs revealed high antifouling performance.

PAM/CNTs-Au microcrack sensor with high sensitivity and wide detection range for multi-scale human motion detection

As the quintessential material for flexible sensors, conductive hydrogels face an inherent sensitivity-sensing range paradox and electrical-mechanical balance, which significantly curtail its applicability in multiscale motion detection. Inspired by the spider slit sensor, PAM/CNTs-Au hydrogel microcrack sensor is obtained by depositing conductive gold film on the surface of PAM/CNTs hydrogel using magnetron sputtering. By modulating the cross-linking density of conductive hydrogels and the content of carbon nanotubes (CNTs), it is possible to tailor the mechanical properties and adhesion of PAM/CNTs-Au hydrogel crack-based sensors. This self-adhering flexible sensor aids in minimizing detection errors arising from mechanical mismatch between flexible sensors and human tissues. Moreover, the exceptional electrical conductivity of CNTs, coupled with their unique one-dimensional structure, facilitates the formation of an interconnected conductive network "bridge" within the hydrogel. The harmonization of electrical and mechanical attributes in the PAM/CNTs flexible substrate is achieved by finely tuning the crosslinking density of the PAM hydrogel and the content of carbon CNTs. Simultaneously, the high-conductivity "islands" formed by the Au conductive layer during stretching ensures elevated sensitivity (gauge factor (GF) = 54.89) over an extensive detection range (>1200%). The distinctive "island-bridge" configuration of the PAM/CNTs-Au hydrogel microcrack sensor effectively suppresses crack propagation, thereby markedly augmenting the sensor's stability. Successful monitoring of physiological and motion signals across various scales attests to the potential of the PAM/CNTs-Au hydrogel microcrack sensor in wearable biosensor.