Abstract
This chapter introduces luminescence responsive chemical sensing of anions by rare earth metal-organic framework (MOF) hybrid materials. Compared to cation analytes, reports on luminescent sensing of anions via rare earth MOF hybrid materials are not abundant, except for Cr(VI) oxysalts. There are two typical kinds of anions, the complicated oxysalt group of ions and simple halogen ions or pseudohalogen ions. Herein four sections discuss: (1) rare earth MOF hybrid materials for luminescence responsive chemical sensing of fluoride ions (F−); (2) rare earth MOF hybrid materials for luminescence responsive chemical sensing of other simple anions (S2−, HS−, and SCN−); (3) rare earth MOF hybrid materials for luminescence responsive chemical sensing of main group element oxysalt anions; (4) rare earth MOF hybrid materials for luminescence responsive chemical sensing of transition metal oxysalts anions.
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