Titanium Zinc Oxide Research Articles

Room temperature atomic layer deposition of zinc titanium oxide using sequential adsorption of dimethyl zinc and tetrakis(dimethylamino)titanium

Complex oxide films of TiO2 and ZnO are deposited by RT atomic layer deposition (ALD) with a sequential adsorption process. In this ALD, a Zn precursor of dimethyl zinc (DMZ) and a Ti precursor of tetrakis(dimethylamino)titanium (TDMAT) are used. In the sequential adsorption step, the DMZ saturation on the surface is followed by partial adsorption of TDMAT. It is assumed that the TDMAT molecule is adsorbed on the DMZ uncovered area. The mixed layer of DMZ and TDMAT is formed in the adsorption step, followed by being oxidized with the plasma-excited humidified Ar. All the ALD processes are performed at RT without any sample heating in the ALD chamber. The growth per cycle of the balanced Zn and Ti oxide deposition is recorded at 0.086 nm/cycle. The mixing ratio of Zn and Ti is controlled by the TDMAT exposure in the adsorption step. In this study, the reaction model and the related rate equations to calculate the mixing concentration ratio are proposed based on the in situ observation of the surface reaction by IR absorption spectroscopy.

Synthesis and characterization of zinc-titanium oxide nanoparticles blended methylcellulose derived from Albizia tree as an antibacterial natural polymer composite

This paper seeks to synthesize antibacterial green polymeric composites utilizing extracted cellulose, a natural polymer sourced from biomass. The cellulose was obtained from local agricultural waste. Subsequently, the polymeric composites were synthesized, incorporating blends of nano zinc oxide and nano titanium dioxide in varying proportions. All synthesized samples undergo comprehensive characterization and examination through a range of tests encompassing structural and thermal testes. Furthermore, the antibacterial activity of the samples was assessed using the disc diffusion method, enabling the identification of the most effective formulations. The ultimate selection of the optimal composite was based on the collective outcomes of all tests, facilitating its potential utilization across diverse applications. In conclusion, the Albizia tree demonstrates a notable potential for efficient cellulose extraction, making it a viable candidate for such purposes. The cellulose extracted from Albizia tree holds the capability to yield methylcellulose. The bacterial activity assessment of Nano materials highlighted a distinct efficacy in the case of the 75% Nano TiO2 and 25% Nano ZnO mixture. However, it is worth noting that an excessive increment in Nano ZnO content exhibited adverse effects. Thorough thermal analyses verified the thermal stability of methylcellulose.

Construction of bismuth oxide iodide (BiOI)/zinc titanium oxide (Zn2TiO4) p-n heterojunction nanofibers with abundant oxygen vacancies for improving photocatalytic carbon dioxide reduction

The conversion of carbon dioxide (CO2) into value-added syngas represents an effective approach for addressing both environmental issues and carbon neutrality issue. However, the slow charge dynamics and low CO2 affinity severely limit the photocatalytic CO2 reduction reaction. In this study, bismuth oxide iodide (BiOI)/zinc titanium oxide (Zn2TiO4) composite nanofibers were successfully prepared by immobilizing BiOI nanosheets on Zn2TiO4 electrospun nanofibers through a solvothermal reaction method. The results of photocatalytic research indicate that the BiOI/Zn2TiO4 composite nanofibers exhibit improved photocatalytic activity in CO2 reduction compared to pristine BiOI nanosheets and Zn2TiO4 nanofibers. The highest carbon monoxide (CO) release rate of BiOI/Zn2TiO4 nanofibers could reach 9.10 µmol‧g−1‧h−1, which is 18.6 times and 6.6 times higher than that of pristine BiOI nanosheets and Zn2TiO4 nanofibers, respectively. The enhanced photocatalytic activity can be credited to the formed BiOI/Zn2TiO4 p-n heterojunction, which can boost electron separation, reduce charge recombination at the interface, and promote the reaction process. The presence of oxygen vacancies in BiOI/Zn2TiO4 nanofibers can not only provide active site to facilitate the adsorption and activation of CO2 molecules, but also adjust the energy band structure of the catalyst to accelerate carriers transfer. After four cycles of testing, the CO release rate of BiOI/Zn2TiO4 nanofibers remains nearly constant, demonstrating its excellent stability. This work develops a feasible strategy to improve the efficiency of photoreduction of CO2 through energy band engineering and surface defect technology.

The removal enhancement of organic contaminations and optimization of the photocatalytic efficiency by Box-Behnken design using ZnO-TiO2/porous graphene aerogel.

In this study, zinc oxide-titanium dioxide/graphene aerogel (ZnO-TiO2/GA) was successfully synthesized through a simple and cost-effective hydrothermal self-assembly process. Besides, the surface response model and the experimental design according to the Box-Behnken model were selected to determine the optimal removal efficiency for crystal violet (CV) dye and para-nitrophenol (p-NP) phenolic compound. According to the obtained results, the highest degradation efficiency for CV dye of 99.6% was obtained under the following conditions: pH 6.7, CV concentration of 23.0 mg/L, and catalyst dose of 0.30 g/L. For p-NP, the degradation efficiency reached 99.1% under the following conditions: H2O2 volume of 1.25 mL, pH 6.8, and catalyst dose of 0.35 g/L. Therewithal, kinetic models of adsorption-photodegradation, thermodynamic adsorption, and free radical scavenging experiments were also investigated to propose the specific mechanisms involving the removal of CV dye and p-NP. According to the aforementioned results, the study provided a resulting ternary nanocomposite with great removal performance for water pollutants via the synergetic effects of adsorption and photodegradation processes.

Atomic Layer Deposition of Chlorine Containing Titanium–Zinc Oxide Nanofilms Using the Supercycle Approach

Atomic layer deposition (ALD) is a useful tool for producing ultrathin films and coatings of complex composition with high thickness control for a wide range of applications. In this study, the growth of zinc–titanium oxide nanofilms was investigated. Diethyl zinc, titanium tetrachloride, and water were used as precursors. The supercycle approach was used, and wide ZnO/TiO2 (ZTO) ALD cycles were prepared: 5/1, 3/1, 2/1, 1/1, 1/2, 1/3, 1/5, 1/10, 1/20. Spectral ellipsometry, X-ray reflectometry, X-ray diffraction, scanning electron microscopy, SEM-EDX, and contact angle measurements were used to characterize the thickness, morphology, and composition of the films. The results show that the thicknesses of the coatings differ considerably from those calculated using the rule of mixtures. At high ZnO/TiO2 ratios, the thickness is much lower than expected and with increasing titanium oxide content the thickness increases significantly. The surface of the ZTO samples contains a significant amount of chlorine in the form of zinc chloride and an excessive amount of titanium. The evaluation of the antibacterial properties showed significant activity of the ZTO–1/1 sample against antibiotic-resistant strains and no negative effect on the morphology and adhesion of human mesenchymal stem cells. These results suggest that by tuning the surface composition of ALD-derived ZTO samples, it may be possible to obtain a multi-functional material for use in medical applications.

Piezo/Triboelectric Nanogenerator from Lithium-Modified Zinc Titanium Oxide Nanofibers to Monitor Contact in Sports

The need for technological innovation in competitive sports is crucial for self-monitoring and smart decision making. In this work, we demonstrate how intelligent sports and smart decision making can be achieved in cricket and boxing using lithium-modified zinc titanium oxide (LZTO) nanofibers based on piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs). Zinc titanium oxide (ZTO) nanofibers synthesized using electrospinning followed by a calcination technique are modified with lithium to increase the output of the nanogenerator. An optimized PENG is fabricated using 25 wt % loading of LZTO (d33 = 214 pm/V) in a poly(vinylidene fluoride) (PVDF) matrix as a double-layered structure and yields an open-circuit voltage (Voc) of 35 V and a short-circuit current (Isc) of 1.6 μA by manual tapping. To fabricate the TENG, Kapton and LZTO are used as negative and positive tribolayers, while Cu and adhesive polymer tape are used as the electrode and spacer, respectively. Furthermore, a hybrid nanogenerator (HNG) is fabricated by combining the PENG and TENG to produce a rectified voltage, current, and power density of up to 75 V, 3.2 μA, and 240 μW/cm2, respectively. These HNGs are integrated with a punching bag and demonstrated to differentiate among the six types of punches in boxing. Furthermore, PENGs are used in cricket to monitor the number of balls middled on the bat during practice and the contact of the ball with the bat and stumps for smart decision making. All kinds of lab-scale testing are done for these applications, which pave a way for exploring the frontiers in nanogenerator applications in sports as maintenance-free and self-powered sensing technology.

Catalytic behavior of a ZnO/TiO2 composite in the synthesis of polycarbonate diol.

ZnO/TiO2 catalysts with different ZnO contents have been prepared through equal volume impregnation method, characterized by XRD, SEM, Py-IR, ICP, XPS, NH3-TPD and N2 adsorption/desorption, and evaluated in the synthesis of polycarbonate diol (PCDL) through transesterification. The results showed that titanium zinc oxide formed in these catalysts, and the content of acidic sites varied with the ZnO content, and ZnO/TiO2 (10%) has the highest acid amount. The ZnO/TiO2 (20%) with medium acidic sites showed the highest catalytic activity. The synthesis process of polycarbonate glycol was also optimized. Under the optimal reaction conditions, the yield of PCDL was 72.5%, and the M n reached 4829 g mol-1 with a PDI of 1.6.

Synthesis of Zinc-Titanium Oxide Nanocomposites by Plasma Jet and Its Application to Photocatalyst

In order to synthesize the zinc-titanium (Zn-Ti) oxide nanocomposites using an atmospheric soft plasma jet, in this study mixtures of Zn and Ti precursors such as zinc nitrate and titanium butoxide were first prepared with different molar ratios; the mixed precursors then stirred at 700 rpm for two hours with atmospheric plasma, while maintaining a temperature of 25 °C. All the synthesized Zn-Ti oxide nanocomposites were post-heat-treated at 600 °C for six hours in an electrical furnace. The morphology, particle shape and size, crystal structure, oxidation state, and composition ratio were analyzed using FE-SEM, XRD, SEM-EDS, and Raman spectroscopy. BET was measured to calculate the specific surface area of the Zn-Ti oxide nanocomposites. Photocatalytic activity tests were performed for an application study, with 10 mL of 10 ppm methylene blue dye. UV-visible spectroscopy was performed on five different samples in order to analyze the changes of photocatalytic reactions. When the composition ratio of Zn/Ti was 2/1, maximum photocatalytic efficiency was obtained. We also carried out a theoretical kinetic study.

Structural and Optical Properties of ZnO-TiO<sub>2 </sub>Nanocomposite Synthesized with Various Molar Ratios by Hydrothermal Technique

Zinc oxide-titanium dioxide (ZnO-TiO2) have been successfully synthesized by hydrothermal method. ZnO-TiO2 nanocomposite were prepared at different molar ratio 100:0, 100:0, 30:70, 50:50 and 70:30. The objective of this research is to determine the effect of molar ratios on the structural and optical properties of ZnO-TiO2 nanocomposite. The samples were analyzed using X-ray diffraction (XRD) analysis, Field-emission scanning electron microscopy (FESEM) and UV-Vis spectroscopy. Based on the XRD results, it is revealed that ZnO-TiO2 nanocomposite consists of hexagonal wurtzite structure of ZnO and mixed of anatase/ rutile phase of TiO2. FESEM images showed ZnO in rod-like structure while TiO2 is formed in nanoparticle. ZnO-TiO2 composite is formed combination of rod-like and nanoparticles. UV-Vis spectra showed that all samples exhibited good absorption towards UV region. The calculated energy band gaps of ZnO-TiO2 composite are 2.92 eV which is slightly smaller compared to bulk ZnO and TiO2. The tuning energy band gaps of ZnO-TiO2 composite samples is a good indicator for use in catalytic activities.

Structural, Optical, Antibacterial and Anticancer Properties of ZnO-TiO2-GO-Chitosan Nanocomposites Prepared by Coprecipitation Method

The zinc oxide-titanium dioxide-graphene oxide-chitosan (ZTGCO) nanocomposites were synthesized via the chemical precipitation method. The synthesized nanocomposites were characterized by XRD, FTIR, DRS, FESEM, EDAX and PL. The XRD patterns of ZTGCO nanocomposites showed Wurtzite hexagonal structure. The FT-IR spectra represent the various stretching vibrational bands of ZnO, TiO2, GO and chitosan. The FESEM images revealed that the ZTGCO nanocomposites were in the cauliflower structure. The EDS spectrum showed elemental compositions of ZTGCO with oxygen vacancies. The antibacterial potential of the ZTGCO nanocomposites achieved against S. aureus and E. coli results showed the ZTGCO had more antibacterial activity than the standard antibiotic amoxicillin. The anticancer activity of the ZTGCO nanocomposites was studied in human liver cancer cells (A549) and the IC50 concentration value was observed at 48.67 μg/mL.

Development of Indium Titanium Zinc Oxide Thin Films Used as Sensing Layer in Gas Sensor Applications

InTiZnO gas sensors with different oxygen ratios were fabricated by RF sputtering at room temperature. The sensing responses for five different gases, including ethanol, isopropanol (IPA), acetone (ACE), CO, and SO2, were reported. The InTiZnO gas sensor with the MSM (metal–semiconductor–metal) structure generated a higher sensing response when the O2/Ar ratio was increased to 10%. It also revealed high selectivity among these gases and good repeatability. Moreover, the UV light-activated InTiZnO gas sensors were also studied, which could reduce the operating temperature from 300 °C to 150 °C and did not seem to damage the sensing film, demonstrating long-term stability. The high response and selectivity revealed that InTiZnO thin films possess high potential to be applied in gas sensing technology.

Comparison between crystal structure and dielectric properties Nd(Mg1/2Ti1/2)O3 (NMT) and Nd(Zn1/2Ti1/2)O3 (NZT)

The dielectric properties of Neodymium zinc titanium oxide (NZT) and Neodymium magnesium titanium oxide (NMT) were investigated. The single-phase ceramic was synthesized at various temperatures below 1650[Formula: see text]C.The result shows that the value of temperature of resonant frequency [Formula: see text] for NMT is higher than NZT.Our findings also indicate that the rare earth materials produce high property dielectric materials, despite the fact some elements produce lower negative value of temperature of resonant frequency [Formula: see text]. By doping a compound such as CaTiO3which has a very positive temperature of resonant frequency ([Formula: see text] ppm/[Formula: see text]C) and a very high relative permittivity [Formula: see text], it is possible to tune NZT and MNT to achieve an excellent dielectric material. This work is under consideration. The results of this scientific research could be very important for modern advance applications in microelectronic miniaturization.

Comparison of self-cleaning and transmittance properties between ZnO and ZnO@TiO2 core–shell nanoparticle array coating films

Zinc oxide (ZnO) nanoparticles (NPs) were synthesized on a fluorine-doped tin oxide (FTO) substrate by sol–gel coating and hydrothermal method to produce a film with self-cleaning and transmittance properties. To improve hydrophilic and photocatalytic activity of the film, zinc oxide titanium dioxide (ZnO@TiO2) core–shell NPs were synthesized using two different amounts of TiO2. The ZnO@TiO2 array film showed better stability and transmittance than the ZnO array film. The hydrophilicity of the ZnO@TiO2 array film was better, because its contact angle was smaller than that of ZnO array film. The wettability also increased with increasing TiO2 concentration. In addition, the ZnO@TiO2 core–shell NP array FTO film exhibited excellent photocatalytic activity in comparison with the ZnO array film. This study demonstrates that the ZnO@TiO2 core–shell NPs array FTO film is more useful due to its self-cleaning and transmittance properties.

Fabrication of Solution Combustion Based Transparent Semiconducting Titanium and Zinc Co-Doped Indium Oxide (ITiZO) Films

In this work, solution combustion processed titanium, zinc co-doped indium oxide high transparent semiconducting thin films were demonstrated at annealing temperatures of 300, 350 °C. In the process, low-temperature combustion at 123 °C was verified through thermogravimetric analysis; acetylacetone, 2-methoxyethanol served as fuel and solvent respectively in the redox reaction. Indium titanium zinc oxide (ITiZO) films were developed on glass substrates by spin coating followed by annealing at different temperatures. ITiZO films, powder exhibited high crystallinity exactly matching with indium oxide peaks without forming secondary phases. But, the presence of In, Ti, Zn, and O is clearly visible on film through energy dispersive spectroscopy. Films had transparency more than 85% in the visible range with optical band gap ranging 3.8-3.9 eV. These ITiZO films with smooth and low roughness ranging 0.46-0.5 nm, can have a potential application as an active layer in transparent thin film transistors and optoelectronic devices.

Nano gold coated hierarchically porous zinc titanium oxide sol–gel based thin film: fabrication and photoelectrochemical activity

In this work, for the first time homogeneously distributed near periodic macroporous (HDPM) with nested mesoporous (hierarchically porous) semicrystalline zinc titanium oxide (ZTO) thin film on pure silica glass and fluorine doped tin oxide coated glass substrates was deposited by sol–gel dip coating technique from an optimized precursor solution of zinc nitrate hexahydrate and titanium isopropoxide with acetylacetone in low boiling solvents. The HDPM film formation was carried out by simple breath figure method where the pore formation occurred from the generated water droplets via molecular condensation onto the as-deposited cold solution film surface owing to solvent evaporation. Zinc to titanium ratio in precursor solution, room relative humidity and other critical parameters were tailored towards optimization of the periodic macropores formation. Gold nanoparticles (NPs) were further deposited onto the ZTO thin films by solution technique. Crystallinity, surface morphology and microstructure of the thin films were critically analyzed by X-ray diffraction, atomic force, scanning, and transmission electron microscopic studies. The photoelectrochemical (PEC) performance of the films was examined under visible light irradiation. A significant improvement in PEC activity was observed in nano Au coated hierarchically porous thin film. This facile fabrication process could be applied in different mixed metal oxide thin films for improving the PEC activity of the materials.

Hydrothermal synthesis of mesoporous TiO2–ZnO nanocomposite for photocatalytic degradation of methylene blue under UV and visible light

Mesoporous ZnO–TiO2 was synthesized successfully by a one-step hydrothermal procedure using titanium sulfate and Zinc nitrate hexahydrate as precursors, and Pluronic P123 as a template. The prepared ZnO–TiO2 materials were heat treated at 400, 600, 800 and 1000 °C to remove the template and increase the degree of crystallization. Field emission scanning electron microscopy, wide angle X-ray diffraction, Fourier transformed infrared spectroscopy, transmission electron microscopy and N2 adsorption–desorption experiments were used to characterize the synthesized powders. Comparison photocatalytic investigations for the prepared materials and commercially available P25 were carried out under identical UV and visible light to understand the effect of the achieved phases and surface area on photocatalytic rate constant and percentage degradation. Results show that the sample which was heat treated at 800 °C (S-800) presents a very high performance under visible light and around 60% of the methylene blue (MB) solution can be degraded by this catalyst in spite of its low surface area. The high efficiency of this sample under visible light can be related to its high degree of crystallinity, formation of anatase and titanium–zinc oxide phases and interfacial coupling between ZnO and TiO2 nanoparticles.

Amorphous Indium Titanium Zinc Oxide Thin Film Transistor and Impact of Gate Dielectrics on Its Photo-Electrical Properties

Bottom-gate thin film transistors (TFTs) with indium titanium zinc oxide (InTiZnO) active layer were prepared by radio-frequency (RF) sputtering system at room temperature. Alumina was introduced as the gate dielectric material to acquire better electrical properties by improving the quality of interface between dielectric and channel layer. At zero gate bias and under 290-nm light illumination, the TFTs exhibited a photoresponsivity of 2.3 A/W. The photo-to-dark current ratio was almost up to 105 and the UV-to-visible rejection ratio was 1817. These results revealed that InTiZnO, as a novel UV-sensitive material, had potential for practical optoelectronic applications with high performance.

Effect of concentration and exposure time of ZnO-TiO2 nanocomposite on photosynthetic pigment contents, ROS production ability, and bioaccumulation of freshwater algae (Desmodesmus multivariabilis)

AbstractIn this study, the toxic effect of zinc oxide-titanium dioxide nanocomposite (ZnO-TiO2)NCM on the reactive oxygen species (ROS) production ability, bioaccumulation, and photosynthetic pigme...

Influence of oxygen on the performance of indium titanium zinc oxide UV sensors fabricated via RF sputtering

The authors report the sputtering-based syntheses of five amorphous indium titanium zinc oxide (InTiZnO) UV sensing devices with Ni/Au electrodes. To investigate their UV photodetection performance, the devices were subjected to current-voltage (I-V) characteristic measurements in the dark and under visible light and UV illumination. The oxygen flow ratio played a critical role in the sensing performance of the devices. That is, incorporation of oxygen during RF sputtering may influence the number of oxygen-related defects in the films. All devices exhibited transmittances of over 80% in the visible light region. With an applied bias of 10V and 290nm illumination, sample B exhibited a photo-to-dark current ratio of over 104, a UV-to-visible rejection ratio of over 103, and a photoresponsivity of 0.17A/W.

Oxygen Partial Pressure Impact on Characteristics of Indium Titanium Zinc Oxide Thin Film Transistor Fabricated via RF Sputtering.

Indium titanium zinc oxide (InTiZnO) as the channel layer in thin film transistor (TFT) grown by RF sputtering system is proposed in this work. Optical and electrical properties were investigated. By changing the oxygen flow ratio, we can suppress excess and undesirable oxygen-related defects to some extent, making it possible to fabricate the optimized device. XPS patterns for O 1s of InTiZnO thin films indicated that the amount of oxygen vacancy was apparently declined with the increasing oxygen flow ratio. The fabricated TFTs showed a threshold voltage of −0.9 V, mobility of 0.884 cm2/Vs, on-off ratio of 5.5 × 105, and subthreshold swing of 0.41 V/dec.