Weak Polarization Research Articles

Research on interfacial fusion characteristics of rejuvenator-aged asphalt system: Wettability, permeability and molecular simulation

The research aims to illuminate the interfacial fusion mechanism of rejuvenator-aged asphalt to guide the development of high-performance rejuvenators and foster the high-value utilization of waste asphalt pavement materials. In the research, the contact angle between rejuvenator and aged asphalt was measured to assess its interface wettability, and the permeability and contributing factors in aged asphalt were profiled based on the permeation test and permeation degree parameter. Concurrently, the molecular dynamics simulations of the fusion behavior between rejuvenator and aged asphalt were conducted to comprehend the fusion mechanism deeply. Results reveal that thermal oxygen and photo-oxygen aging enhanced the asphalt mixture’s hydrophobicity with similar effects, and they also had comparable impacts on the wettability of rejuvenator-aged asphalt interface. A more considerable asphalt aging eventuated a more challenging for the rejuvenator to wet the asphalt surface naturally. Waste vegetable oil rejuvenators tended to have a superior wetting effect on the aged asphalt surface compared to mineral oil rejuvenators. Higher permeation temperatures and permeation durations facilitated the rejuvenator’s fusion with aged asphalt, and the permeability varied across different rejuvenators, hinging on the rejuvenator’s permeation performance and composition. The rejuvenator’s permeation process into light aged asphalt or aged matrix asphalt was prone to occur. The aging effect of asphalt negatively impacted the fusion process of the layered system. Compared to oleic acid, aromatic hydrocarbons exhibited superior permeation ability and better fusion effect with aged asphalt. Rejuvenator composition materials yielding high permeation and fusion effects should display the following characteristics: lower viscosity, weak molecular polarity, small molecular weight, linear molecular structure, or end phenyl ring structure.

Macroporous polymeric resin for the purification of flavonoids from medicinal plants: A review.

The purification of flavonoids using the macroporous polymer resin method has gained attention in recent years due to its simplicity, precision, cost-effectiveness, and the ability to separate flavonoids from other constituents. Several studies have been conducted to investigate the efficiency and effectiveness of macroporous polymer resin in purifying flavonoids from various plant sources. This review aims to evaluate the existing literature on macroporous polymer resin purification of flavonoids and provide a comprehensive analysis of the current research trends and advancements in this field. It also highlights the importance of optimizing the adsorption parameters and conditions such as resin type, resin concentration, pH, and temperature for efficient purification of flavonoids using macroporous polymer resin. The key findings of this review reveal that macroporous resins with weak polarity, large surface areas, and pore diameters have a stronger adsorption capacity for flavonoids compared to polar resins. Furthermore, ultrasonic-solvent assisted extraction often combines with macroporous resin for effective the extraction and purification of flavonoids.

Surface phonon activation for broadband high emissivity via textured structure on TiO2 coating

In the pursuit of developing broadband high emissivity coatings for metallic radiation thermal protection, conventional approaches often involve complex photonic structures or the incorporation of transition metals and rare earth additives, which pose significant technological challenges and environmental concerns. Here, we present a straightforward and eco-friendly surface structuring strategy for creating a high emissivity TiO2 coating on titanium, eliminating the need for environmentally hazardous additives. By controlling surface micropore diameter to ∼6 um through soft-sparking discharge, we successfully engineered a textured surface that effectively mitigates the intrinsic emissivity dip of planar TiO2 at wavelengths with weak polarization extinction (3–8 µm) and strong polarization resonance (>12 µm). Finite-difference time-domain (FDTD) simulations highlighted the crucial role of micropores in confining the incident electric field, maximizing the absorption potential of surface phonon polaritons. This improvement yields an impressive emissivity of 0.83 across the thermal infrared spectrum. The coating also demonstrated robust resistance to oxidation and retained its high emissivity at elevated temperatures, presenting a promising solution for sustainability in spacecraft and electronic applications.

Revisiting the phase transition of PbF2 in solution

The β → α phase transition of PbF2 driven by hydroxide ions was studied in aqueous solution, and by characterizing the crystal phase and morphology during the transformation process. The phase transformation of PbF2 is essentially a process of dissolving and re-precipitating. The phase transition from β-PbF2 to α-PbF2 in aqueous solvent was conducted by adjusting the pH value of the solution. β-PbF2 was stable when immersed in aqueous solutions with pH varying from 1 to 5, and β-PbF2 transformed into α-PbF2 when the pH of the aqueous solution varied from 6 to 9. β-PbF2 cannot transform to α-PbF2 in a non-aqueous solvent (weak polarity solvents) due to poor solubility of β-PbF2. Pure crystalline phase PbF2 (α and β) was synthesized in aqueous solutions by controlling the concentration of hydroxide ions and in a non-aqueous solvent (weak polarity solvent) by controlling the molar concentration ratio of fluoride to lead ions.

Tunable Multistate Ferroelectricity of Unit-Cell-Thick BaTiO3 Revived by a Ferroelectric SnS Monolayer via Interfacial Sliding.

Stabilization of multiple polarization states at the atomic scale is pivotal for realizing high-density memory devices beyond prevailing bistable ferroelectric architectures. Here, we show that two-dimensional ferroelectric SnS or GeSe is able to revive and stabilize the ferroelectric order of three-dimensional ferroelectric BaTiO3, even when the latter is thinned to one unit cell in thickness. The underlying mechanism for overcoming the conventional detrimental critical thickness effect is attributed to facile interfacial inversion symmetry breaking by robust in-plane polarization of SnS or GeSe. Furthermore, when invoking interlayer sliding, we can stabilize multiple polarization states and achieve efficient interstate switching in the heterostructures, accompanied by dynamical ferroelectric skyrmionic excitations. When invoking sliding and twisting, the moiré domains exhibit nontrivial polar vortexes, which can be laterally displaced via different sliding schemes. These findings provide an intuitive avenue for simultaneously overcoming the standing critical thickness issue in bulk ferroelectrics and weak polarization issue in sliding ferroelectricity.

Ultralow-loss polarization-insensitive silicon nitride-assisted double-etched silicon edge coupler with polarization splitting.

High-performance silicon-based edge couplers for interfacing with standard single-mode fibers encounter significant challenges due to limitations imposed by the minimum fabrication width. Here, we propose a silicon nitride-assisted double-etched O-band silicon edge coupler with a minimum width of 180 nm. Notably, the polarization splitting function naturally integrates into this edge coupler. Through simulation, the proposed edge coupler, without a cantilever, demonstrates a minimum coupling loss of 0.53/0.82 dB with an average extinction ratio of 42/18 dB for TE/TM polarization. Additionally, this edge coupler exhibits weak polarization dependence with an average difference of only 0.24 dB in the O band. Leveraging a segmented taper shape design, the 0.5-dB bandwidth of coupling loss extends to approximately 100 nm for both TE and TM polarizations, despite the inclusion of two evanescent coupling parts.

Efficient Second‐Harmonic Generation with Weak Polarization Sensitivity in Gallium Nitride Metasurfaces via Bound States in the Continuum

AbstractBound states in the continuum (BICs) are widely exploited in all‐dielectric metasurfaces to significantly enhance the Q‐factor and second harmonic generation (SHG). However, a higher SHG conversion efficiency is overshadowed by the narrow transparency window of all‐dielectric materials and strict requirement of polarization‐matching. Herein, an augmented SHG assisted is demonstrated by symmetry‐protected quasi‐BICs from z‐cut wurtzite GaN metasurfaces, whose wide transparent range suppresses self‐absorption of second harmonic. Strong resonances emerge under both X‐ and Y‐polarized excitations, where the multipole characters of each eigenmode are quantitatively identified via decomposition simulations. The local field enhancement enabled by the extreme energy confinement of quasi‐BICs contributes to an efficient SHG, recording a conversion efficiency up to 2 × 10−7 at moderately low input peak intensity (≈1 GW cm−2), orders of magnitude larger than bulk GaN. With proper design, the overlapping X‐ and Y‐polarized resonances can support SHG from excitation with arbitrary polarizations. The alleviation of polarization‐matching remarkably enhances the SHG power by 66.2% under unpolarized illumination condition. The results of intense SHG reveal GaN as a promising candidate for high‐performance nanoscale nonlinear photonic devices. The weak polarization sensitivity of the designed structure will chart a novel course for the advancement of next‐generation efficient all‐dielectric metasurfaces.

Optical Spectropolarimetric Variability Properties in Blazars PKS 0637–75 and PKS 1510–089

Spectropolarimetry is a powerful tool to investigate the central regions of active galactic nuclei (AGNs) as polarization signatures are key to probing magnetic field structure, evolution, and the physics of particle acceleration in jets. Optical linear polarization of blazars is typically greater than a few percent, indicating the emission is dominated by nonthermal synchrotron radiation, while polarization less than a few percent is common for other type 1 AGNs. We present a spectropolarimetric study of PKS 0637–75 and PKS 1510–089 to determine how the head-on orientation of a jet and dominant emission processes influence polarimetric variations in the broad lines and continuum. Observations were obtained biweekly from the Robert Stobie Spectrograph on the Southern African Large Telescope. Variability in the continuum polarization is detected for both PKS 0637–75 and PKS 1510–089, with a total average level of 2.5% ± 0.1% and 7.5% ± 0.1%, respectively. There is no clear polarization in the broad Balmer emission lines and weak polarization in Mg ii as the average level across all observations is 0.2% ± 0.1% for Hβ, 0.2% ± 0.3% for Hγ, and 0.6% ± 0.2% for Mg ii. We find that polarization measurements confirm the conclusions drawn from spectral energy distribution modeling of the disk–jet contributions to the emission as optical polarization and time variability for PKS 0637–75 are shown to be dominated by accretion disk emission while those of PKS 1510–089 are due to both disk and jet emission, with greater jet contribution during flaring states.

Interaction mechanisms between fibers and bubbles during foam forming

It is critical to understand the interaction mechanism of fiber-bubble before the foam-forming technique is used to disperse the long fiber and tailor the material microporous structure. Herein, the adhesion behavior of ionic and nonionic surfactants with different concentrations on five fibers was investigated, and the effect of electrostatic force and adhesion driving force on the interaction between fibers and bubbles was analyzed. In addition, the fiber dispersion mechanisms and the response mechanism of the fiber orientation and tensile strength of foam-formed paper on the interaction strength between fiber and bubble were clarified. The results show that the adhesion ability between hydrophobic fibers with weak surface polarity and cationic and amphoteric surfactants is more obvious. Though electrostatic repulsion weakens the interaction strength of fibers with anionic surfactants, the adhesion ability can exist when the adhesion driving force is larger than 6.6 mN/m. Furthermore, the bridge effect between ethoxylated surfactant headgroups with the acylamino on the aramid fiber surface also propels the adhesion behavior of bubble-fiber. The fiber dispersion mechanisms were proposed based on the adhesion effect of the fiber-bubble, electrostatic elimination, and high-viscosity (≥95 mPa∙s) properties of the “foam-fiber” slurry. Eventually, under the gradually decreased interaction strength between fibers and bubbles, the fiber orientation in the Z direction of foam-formed NBSKP fiber paper turned from −20°-20° to −60°-40°, and the tensile strength decreased from 693 KPa to 537 KPa. This work has implications for improving the long fiber dispersion and regulating the structure of foam-formed fiber composites.

Full‐Color Electrochromics with Donor‐Gradient Architectures for Chameleon‐Like Adaptive Camouflage

AbstractMulticolor electrochromics have emerged as a promising solution for achieving active color modulation akin to chameleon‐like adaptive camouflage. However, the development of electrochromics with full‐color tunability still remains challenging, given the weak molecular polarity of inherent active materials and the difficulty in forming polarizer orbitals under varying applied voltages. Employing molecular polarity adjustments, a novel electrochromic polymer is successfully developed with a donor‐gradient design of molecular architecture, enabling comprehensive full‐color tunability. The polymer demonstrates outstanding overall electrochromic performance, including fast switching (around 1.4 s), high coloration efficiency (395.1 cm2 C−1@550 nm) and excellent reversibility (over 92% retention after 5000 cycles). Leveraging the full‐color tunability and rapid response, the electrochromic polymer is further integrated with sensing and control modules to create an environmental adaptive camouflage prototype system capable of seamlessly blending colors with dynamic background environments. This work is expected to provide a straightforward approach for developing full‐color electrochromics for electrochromic camouflage applications.

Biomimetic enhanced polarization orientation method for underwater scenes

Underwater polarization information can provide reliable autonomous heading feedback for underwater scenes in the presence of satellite denial and multi-source interference. A biologically inspired highly robust polarization orientation strategy is proposed to address the degradation caused by weak polarization and noisy patterns in underwater environments with poor illumination, turbidity, and cloud recession. This approach initially develops a biomimetic algorithm that enhances weak polarization information, based on the increased perception mechanism of the visual neural pathway of syrphid fly under weak light conditions. After overcoming restricting polarization transmission, it is further optimized with a non-local sparse coding denoising part that takes into account the similarity in the detailed structure of the polarized image's effective zenith region. Relying on the stable ∞ symmetric distribution of the angle of polarization, the ±π/2 feature point distribution is traversed and assigned, and polarization information is quantitatively assigned, compensated, and regulated along the solar meridian region, excluding invalid polarized pixels. The experiments demonstrate that the methodology effectively reconstructs the symmetry of the partially damaged angle of polarization distribution, eliminates external interference, autonomously solves the fitted heading correction problem, and improves the environmental adaptability of the bionic polarization compass. The data from underwater experiments indicate the orientation accuracy: the error in weakly polarized patterns is within 2°, and the accuracy in noisy patterns can be increased by over 50%.

Utilizing Cost-Effective Determination Techniques to Authenticate Cosmetics

(1) Background: The adulteration of cosmetics has become increasingly common, which seriously harms ordinary consumers. The counterfeit cosmetics pointed out in this study mainly refer to imitating genuine products in terms of ingredients and packaging. Ordinary consumers cannot distinguish their authenticity solely based on appearance and daily use. If there is a convenient and low-cost detection method that can expose this phenomenon of adulteration, it will be able to expose adulteration and protect the interests of consumers quickly and conveniently. (2) Methods: MALDI-TOF, GC-MS, and mid-IR were used to develop low-cost and fast methods for identifying the authenticity of cosmetics. Five types of liquid and five types of emulsion cosmetics purchased from container and wholesale markets were analyzed using the three instruments mentioned above, and their spectra and acquired data were carefully compared to determine their authenticity. MALDI-TOF and GC-MS directly tested cosmetic samples, and mid-IR spectroscopy tested the ink on the outer packaging of cosmetics. (3) Results: The data procured by MALDI-TOF can provide a representation of its product attributes; two liquid samples and one paste sample demonstrated inconsistent test outcomes with the corresponding reference samples, suggesting contamination. The results of GC-MS can illustrate the substance count within cosmetic samples; the comparison outcomes of the total ion chromatogram indicate that one paste sample was a counterfeit. The results attained from mid-IR were consonant with those acquired from the MALDI-TOF analysis and GC-MS. (4) Conclusions: These three newly developed techniques can all be effectively utilized for the task of detecting cosmetic adulteration and quality control in the manufacturing process. With regard to user-friendliness and rapidity, both MALDI-TOF and mid-IR outperform GC-MS, demonstrating consistently superior levels of detection. Conversely, GC-MS has unique advantages in identifying emulsion cosmetics containing a high amount of weak polarity and volatile substances. Consequently, these corresponding methods could serve as efficient and cost-effective ways to detect authenticity issues in real-world cosmetic products.

Dendritic copper oxide catalyst engineering weak-polarity Cu-O bond for high-efficiency nitrate electroreduction

Nitrate reduction reaction (NO3RR) is deemed a promising pathway for both ammonia synthesis and water purification. Developing a high-efficiency catalyst with excellent NH3 selectivity and catalytic stability is desirable but remains challenging. In this work, a dendritic copper oxide catalyst (Cu-B2) has been developed to efficiently catalyze NO3RR for ammonia production, the Cu-B2 exhibits excellent catalytic performance, achieving an NH3 Faradaic efficiency as high as 94 % and an NH3 yield of 16.9 mg h−1 cm−2 with a current density of 192.3 mA cm−2 at − 0.6 V (vs. RHE, reversible hydrogen electrode). During NO3RR testing, the Cu-B2 catalysts are reduced in situ to form highly active Cu0/Cu+ sites, while retaining its dendritic morphology. Compared with other catalysts, the Cu-O bond in Cu-B2 catalyst has weaker polarity, resulting in Cu0/Cu+ sites in lower oxidation states. In situ attenuated total reflection surface enhanced infrared absorption spectroscopy (ATR-SEIRAS) studies reveal the Cu-B2 catalyst exhibits a potential-independent capability for *NO3- adsorption and high conversion efficiency of NO2- intermediate into ammonia, DFT calculations reveal that Cu-B2 exhibts higher NO3- adsorption energy and lower NO3- adsorption energy barrier than Cu-B1, thus endowing it with a remarkably improved catalytic activity and durability.

Polarized QED cascades over pulsar polar caps

ABSTRACT The formation of e± plasmas within pulsar magnetospheres through quantum electrodynamics (QED) cascades in vacuum gaps is widely acknowledged. This paper aims to investigate the effect of photon polarization during the QED cascade occurring over the polar cap of a pulsar. We employ a Monte Carlo-based QED algorithm that accurately accounts for both spin and polarization effects during photon emission and pair production in both single-particle and particle-in-cell (PIC) simulations. Our findings reveal distinctive properties in the photon polarization of curvature radiation (CR) and synchrotron radiation (SR). CR photons exhibit high linear polarization parallel to the plane of the curved magnetic field lines, whereas SR photons, on average, demonstrate weak polarization. As the QED cascade progresses, SR photons gradually dominate over CR photons, thus reducing the average degree of photon polarization. Additionally, our study highlights an intriguing observation: the polarization of CR photons enhances e± pair production by approximately 5 per cent, in contrast to the inhibition observed in laser–plasma interactions. Our self-consistent QED-PIC simulations in the corotating frame reproduce the essential results obtained from single-particle simulations.

High-performance flexible triboelectric nanogenerator based on micropatterned allicin-grafted cellulose film

Developing high-performance cellulose-based flexible triboelectric nanogenerators (TENGs) remains challenging due to the weak surface polarity of cellulose. In this work, allicin-grafted cellulose nanofiber films (Alc-CNF) containing square micropatterns on the surface are fabricated, and their successful application for bio-based TENGs with enhanced triboelectric output performance is demonstrated. Allicin was chemically grafted onto the CNFs through the utilization of 'thio-ene' click chemistry. Square micropatterns with different gaps (40, 50, 60 μm) between patterns were created on the CNF film using lithography, then casting Alc-CNF suspension and drying in cleanroom conditions. The Alc-CNF TENG, having a 50 μm gap between the patterns, showed an output power of 87 μW (387 mW/m2), 260 times larger than the pure CNF TENG and 35 times larger than the no-patterned Alc-CNF TENG. The performance is related to the higher surface polarity, electron-donating tendency, and surface roughness of the Alc-CNF film.

How to enhance the polarization intensity of two-dimensional sliding ferroelectricity for hexagonal boron- or nitrogen-based binary compounds?

In recent years, two-dimensional (2D) sliding ferroelectric (SFE) materials have received widespread attention due to their unique ferroelectric mechanism, which exists in van der Waals bilayer and multilayer systems. However, compared to traditional ferroelectric materials, their relatively weak polarization intensity and low energy barrier limit their practical applications. Here, using the first-principles calculations, we focus on hexagonal layered structures formed by group III–V elements and propose a design principle that utilizes bilayer materials composed of elements with significant differences in atomic electronegativity to address this issue. The results show that materials composed of two atoms with significant electronegativity differences can effectively increase the polarization intensity and possess moderate energy barriers. Furthermore, the polarization intensity can be effectively modulated by adjusting interlayer distance. The research findings have important significance for the exploration of other 2D SFE materials with high polarization intensity.

Study on corrosion characteristics of reinforcing bars in concrete under industrial SO2 environment

Sulfur dioxide (SO2) is the primary pollutant in industrial atmospheres, leading to significant damage to industrial buildings. The corrosion caused by SO2 in concrete, including neutralization and solid phase volume expansion, poses particular concerns. However, there is a lack of research on the electrochemical behaviour and corrosion mechanisms of reinforcing bars embedded in concrete. This study conducted indoor simulations of reinforced concrete specimens exposed to industrial SO2 corrosion utilizing an SO2 testing chamber. The corrosion behavior of the reinforcing bars was monitored through half-cell potential, weak polarization, and electrochemical impedance spectroscopy (EIS). Additionally, the corrosion mechanisms of the reinforcing bars under SO2 exposure were investigated using scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), and Raman spectra. The results demonstrated a consistent correlation between variations in corrosion potential (Ecorr) and corrosion current density (icorr) of steel rebars in different types of concrete. The corrosion rates of the reinforcing steel in C1 (w/b=0.57), C2 (w/b=0.47), and C3 (w/b=0.37) concrete exceeds 0.1 μA/cm2 after 42, 72, and 90 days of SO2 corrosion, respectively. At this time, the ratio of the depth of neutralization to the thickness of the protective layer is 0.51–0.65. The rust exhibits a layered structure with a presence of S elements adsorbed and deposited on the surface of the rust layer. Moreover, the research has identified the accumulation of S elements within corrosion pits, which can be attributed to localized acidification reactions. The rust products identified include iron hydroxide (FeOOH), and iron oxide (Fe2O3), rozenite (FeSO4·4 H2O). The formation of FeSO4·4 H2O in corrosion pits suggests that significant localized corrosion on the surface of reinforcing bars in concrete under the impact of SO2.

Advances in heavy alkaline earth chemistry provide insight into complexation of weakly polarizing Ra2+, Ba2+, and Sr2+ cations.

Numerous technologies-with catalytic, therapeutic, and diagnostic applications-would benefit from improved chelation strategies for heavy alkaline earth elements: Ra2+, Ba2+, and Sr2+. Unfortunately, chelating these metals is challenging because of their large size and weak polarizing power. We found 18-crown-6-tetracarboxylic acid (H4COCO) bound Ra2+, Ba2+, and Sr2+ to form M(HxCOCO)x-2. Upon isolating radioactive 223Ra from its parent radionuclides (227Ac and 227Th), 223Ra2+ reacted with the fully deprotonated COCO4- chelator to generate Ra(COCO)2-(aq) (log KRa(COCO)2- = 5.97 ± 0.01), a rare example of a molecular radium complex. Comparative analyses with Sr2+ and Ba2+ congeners informed on what attributes engendered success in heavy alkaline earth complexation. Chelators with high negative charge [-4 for Ra(COCO)2-(aq)] and many donor atoms [≥11 in Ra(COCO)2-(aq)] provided a framework for stable complex formation. These conditions achieved steric saturation and overcame the weak polarization powers associated with these large dicationic metals.

Theoretical Study on ORR/OER Bifunctional Catalytic Activity of Axial Functionalized Iron Polyphthalocyanine.

Designing efficient ORR/OER bifunctional electrocatalysts is very significant for reducing energy consumption and environmental protection. Hence, we studied the ORR/OER bifunctional catalytic activity of iron polyphthalocyanine (FePPc) coordinated by a series of axial ligands which has different electronegative coordination atom (FePPc-L) (L = -CN, -SH, -SCH3, -SC2H5, -I, -Br, -NH2, -Cl, -OCH3, -OH, and -F) in alkaline medium by DFT calculations. Among all FePPc-L, FePPc-CN, FePPc-SH, FePPc-SCH3, and FePPc-SC2H5 exhibit excellent ORR/OER bifunctional catalytic activities. Their ORR/OER overpotential is 0.256 V/0.234 V, 0.278 V/0.256 V, 0.280 V/0.329 V, and 0.290 V/0.316 V, respectively, which are much lower than that of the FePPc (0.483 V/0.834 V). The analysis of the electronic structure of the above catalysts shows that the electronegativity of the coordination atoms in the axial ligand is small, resulting in less distribution of dz2, dyz, and dxz orbitals near Ef, weak orbital polarization, small charge and magnetic moment of the central Fe atom, and weak adsorption strength for *OH. All these prove that the introduction of axial ligands with appropriate electronegativity coordinating atoms can adjust the adsorption of catalyst to intermediates and modify the ORR/OER bifunctional catalytic activities. This is an effective strategy for designing efficient ORR/OER bifunctional electrocatalysts.

Structure Investigation of Mesogenic Homo- and Copolymers Based on Chiral and Achiral Acrylates

The X-ray diffraction method was used to study the structure of mesogenic homo- and copolymers based on chiral and achiral acrylates (disubstituted biphenyl and phenylbenzoate) under the orienting influence of magnetic and (in some cases) electric fields. The analysis of diffraction patterns was carried out in terms of the Hosemann model of a paracrystal using structural modeling and diffraction calculations on models. It was established that chiral and achiral homopolymers form smectic bilayer polar structures, but the structure of the achiral homopolymer possesses weak polarization due to small value of total dipole moment of C=O groups in the side chains. The copolymers (as the chiral homopolymer) form smectic bilayer polar helicoidal structures. The distribution of chiral and achiral components in the layers of the common bilayer depends on their ratios in the copolymer. In turn, this distribution affects both the step of helicoidal structure and the nature of structural-phase transformations in the copolymers. A comparative evaluation of the orientational effects of magnetic and electric fields on the structure of the chiral homopolymer and the copolymers has been carried out. The analysis of the temperature dependences of diffraction and structural parameters of the investigated polymers allowed us to explain some features of their behaviour within seemingly similar (by the type of X-ray patterns) smectic phases.