Washing Effluents Research Articles

Efficient PFAS removal from contaminated soils through combined washing and adsorption in soil effluents

This study investigates soil washing as a viable strategy to remove poly- and perfluoroalkyl substances (PFAS) from contaminated soils using various washing agents including water, methanol, ethanol, and cyclodextrin ((2-Hydroxypropyl)-β-cyclodextrin HPCD)). Water was less effective (removing only 30 % of PFAS), especially for long-chain hydrophobic PFAS. Methanol (50 % v/v) or HPCD (10 mg g–1 soil) achieved > 95 % PFAS removal regardless of PFAS type, soil size fraction (0–400 µm or 400–800 µm), or experimental setups (batch or column, at liquid/solid (L/S) = 1). Column optimization studies revealed improved efficiency at L/S = 10 with diluted washing solutions, where HPCD exhibited rapid PFAS mobilization even at lower concentrations (1 mg mL–1). We then applied a first-order decay model to effectively predict PFAS breakthrough curves and mobilization within soil columns. Subsequent treatment of wash effluents by activated carbon and biochar effectively reduced PFAS concentrations below detection limits. The performance of both soil washing and subsequent adsorption was found to depend strongly on the specific characteristics of PFAS compounds. These findings highlight the significant potential of methanol and HPCD in soil washing and the effectiveness of integrated soil washing and adsorption for optimizing PFAS removal.

Insight into the electrochemical process of EDTA-assisted soil washing effluent under alternating current

EDTA has been widely utilized as a chelating agent in soil heavy metal remediation, due to its strong coordination capability. Electrochemical deposition is a promising avenue to treat soil washing effluent. However, the impact of advanced electrochemical techniques on EDTA remains incompletely understood. Herein, we present a pioneering approach, utilizing a dual-chamber electrolytic cell and alternating current (AC) power supply. This approach achieves concurrent removal of M-EDTA while efficiently recovering heavy metal and recycling EDTA. Results demonstrate AC displays superior heavy metal removal capability for Cu, Pb, and Cd compare to direct current (DC), with EDTA decomposition mainly occurring in the anolyte. Substituting DC with AC and employing the dual-chamber electrolytic cell significantly enhances EDTA recovery efficiency from 47% to an impressive 96.8%. XPS and Raman spectra reveal an enhanced oxidative surface of the graphite anode under AC, which diminishes the decomposition of EDTA. Long-term experiments validate that this strategy boosts EDTA cyclability to 20 cycles with an outstanding 84% recovery efficiency and negligible electrode corrosion, surpassing the 8 cycles under the traditional strategy. This study innovatively combines cell design and electrochemical techniques, remarkably improving the reusability of EDTA and anode, offering valuable insights for chelate-related applications.

Effective chromium mitigation using phosphorous doped bio carbon electrode via capacitive deionisation

ABSTRACT Capacitive deionisation (CDI) is an emerging eco-economic water reclamation technology that can remove inorganic salts and heavy metals. Biomass-derived carbon electrodes have attracted the scientific communities in recent years due to their economic feasibility and sustainability. However, electrochemical performance needs to be improved to achieve durability and reusability. Hence, the present study develops rice straw-derived phosphorous-doped (P-doped) carbon as an electrode for mitigating Cr(VI) ions. Phosphorus doping of biocarbon electrodes enhances their electrochemical properties, including increased electrical conductivity, improved charge storage capacity, and enhanced ion adsorption capabilities. Here, Phosphoric acid plays a dual role of activation and doping that enhances the physico-electrochemical properties. The synthesised material was found to be P-doped carbon with better pore distribution, which was confirmed through FESEM-EDX analysis. Further, the physicochemical properties of the electrode material are enriched with carbon and possess an enhanced surface area of 753 m2/g. The cyclic voltammetry shows the specific capacitance of 67 F/g for the Cr(VI) ions, which was found to be 15 times more than the non-doped carbon. CDI studies were performed with optimisation of operational parameters and found that mitigation of Cr(VI) ions was efficient at pH 2 for the applied voltage of 2V. The electrode’s performance with real-time chrome wash effluent confirms its potentiality and has better scope upon optimisation. The experimental data fits well with pseudo first-order kinetics, which ensures the nature of electrosorption is physisorption.

Microplastic occurrence during the pre-treatment of polypropylene in a simulated washing process for mechanical recycling

AbstractIn this study, the micro-plastic emission during polypropylene washing was investigated. Washing post-consumer waste before the re-granulation step is an important process to remove contaminants on the waste material which can interfere with downstream processing and product quality. To simulate a pre-treatment step during mechanical recycling, an industrial washing machine with two different temperatures (30 °C and 60 °C) and residence times (5 min and 15 min) was used. The whole washing effluent was filtered, gravimetrically quantified and with DSC measurements qualitatively identified. Results suggest a release of micro-plastics during washing whereby the residence time has about a two-fold higher impact on possible emissions than temperature. Graphical abstract

Comparative Analysis of Gas-Turbine Engine Diagnostics through Compressor Wash Wastewater Parameter Monitoring for Geregu Gas-Turbine Power Plant

This paper focuses on finding a lasting solution to the reason why offline compressor washing of unit 13 at Geregu Power plc in Ajaokuta does not restore power output lost due to fouling back to the rated output, as is the case for the other two (2) units in the plant and for several reported cases published in the literature. Monitoring of parameters closely related to the power output was carried out to find out the root causes for the low output recovery after offline compressor wash and came up with a successful diagnosis by interrelating GT13 wash effluent test results of parameters like conductivity, turbidity, and heavy metal concentration with parameters of two (2) other turbines in the plant. Using statistical tools like the mean and Pearson correlation coefficient for the four-year period, the mean comparative result indicates that the conductivity of GT13 was higher than that of GT11 and GT12 by 50% and 79%, respectively. The turbidity of GT13 was 570% and 700% higher than that of GT11 and GT12. The Pearson correlation coefficients of GT13 effluent conductivity, turbidity, and silica content relative to the power output recovery after wash were (-89.2%), (-64.4%), and (-77.3%), respectively, and the covariance of each of the three parameters relative to one another was high. Effluent Ph as a factor was discarded based on its 0% linear correlation coefficient with the output. The conclusion reached is that the co-linear relationship between conductivity, silica content, and effluent turbidity is responsible for GT13's low output recovery after the wash.

Thermosensitive polymer-assisted extraction and purification of fungal laccase from citrus pulp wash effluent.

This study explores the use of liquid-liquid extraction with thermosensitive polymers for producing laccase (Lac) from Pleurotus sajor-caju. This process leverages liquid waste from the citrus industry, specifically pulp wash. The research delves into extractive fermentation and thermoseparation, both processes being facilitated by a polymer exhibiting a lower critical solution temperature transition. Key factors considered include the choice of polymer, its concentration, pH, separation temperature, and the behavior of the polymer-rich phase post-extractive fermentation concerning the lower critical solution temperature. Notably, under conditions of 45% by weight of Pluronic L-61 and pH 5.0 at 25 °C, the Lac resulted in an enhancement in the purification factor of 28.4-fold, compared with the Lac obtained directly from the fermentation process on the eighth day. There was an 83.6% recovery of the Lac enzyme in the bottom phase of the system. Additionally, the unique properties of Pluronic L-61, which can induce phase separation and also allow for thermoseparation, led to a secondary fraction (aqueous solution) of Lac with purification factor of 2.1 ± 0.1-fold (at 32 ± 0.9 °C and 30 ± 0.3 min without stirring) from the polymeric phase (top phase). Fourier-transform infrared analysis validated the separation data, particularly highlighting the α-helix content in the amide I region (1600-1700 cm-1 ). In summary, the insights from this study pave the way for broader industrial applications of these techniques, underscoring benefits like streamlined process integration, heightened selectivity, and superior separation efficacy. © 2023 Society of Chemical Industry.

Determination and implementation of an onsite management system for motor-vehicle wash effluents: A field-scale commercial application toward sector sustainability

The global upsurge of vehicle wash enterprises is allied to the production of large wastewater volumes. This effluent contains organic and inorganic compounds which can cause environmental pollution. Upscaling the laboratory-scale systems for motor-vehicle wash wastewater (MVWW) treatment to field-scale commercial application is essential for enabling the circular economy framework, meeting the United Nations' 2030 Agenda. In this study, 98 research publications on MVWW treatment technologies were scrutinized for bibliometric-meta analysis. After, a practical treatment option was identified and designed for implementation in a Ugandan motor-vehicle wash station and a comprehensive economic evaluation was performed. A continental outlook on MVWW quality showed that its major pollutants include oil-greasy compounds, surfactants, and suspended solids. Results showed that a hybrid system consisting of coagulation/flocculation/sedimentation and sand/gravel filtration was identified as the most practical treatment method for implementation in motor-vehicle washing stations. The final effluent of the field-scale integrated treatment system contained turbidity = 2 ± 0.0 NTU, chemical oxygen demand (COD) = 18.9 ± 0.6 mg/L, surfactants = 3.2 ± 0.3 mg/L, supporting onsite recyclability in motor-vehicle washing activities. The integrated system demonstrated a profitability scenario with a benefit-cost ratio (B/C) > 1 and a payback period of 2.7 years. Implementing the hybrid system for onsite MVWW treatment could fulfil targets of sustainable development goals related to; water conservation, water recycling and reuse, and environmental protection.

Effect of different washing methods on denim fabric properties and their effluent’s environmental impact

Nowadays, denim is in trend. To achieve visually appealing results, various washing processes are applied to denim. For washing denim, a variety of methods are available, and they all produce distinct kinds of waste. These methods have various environmental effects. This study aims to examine the environmental impact of various denim washing effluents. Here, six different washes desizing, enzyme, stone, bleach, acid, and random wash are performed. In order to compare how washing affects both the environment and the fabric, effluent tests are carried out. Since enzymes are unique by nature, enzyme wash demonstrated the greatest GSM. They don't affect the fibre composition; they just break down the color that is on the surface of the cellulose. Shrinkage is the cause of the general rise in GSM. However, the thickness, pilling, and elongation % of the cloth were unaffected by the washing. Due to the alkaline nature of the washing procedure, which results in minimal harm to the cloth, the enzyme and desize wash exhibit high strength. The fabric's rigidity decreases when stone, bleach, and acid wash damage it, which raises the angle at which the crease recovers. Due to the use of enzyme and desize wash produces effluent with a reduced TDS. In these procedures, the indigo hue on the denim surface is diminished, which causes the fading to occur. This process results in less polluted water that is simpler for wastewater treatment plants to process.

Exploration of the performance of iron-based superhydrophilic meshes for oil-water separation

This study investigates the oil-water separation capability of iron-based superhydrophilic meshes. It also intends to provide an optimistic view of their potential for industrial application. Oil-water separation performance of the 150 mesh, 300 mesh, and 400 mesh is primarily examined by analyzing the efficiency and speediness of separation as well as the limit of oil intrusion using petroleum based oils. The superhydrophilic meshes are further applied for oil-water separation of locomotive wash effluent. The superhydrophilic meshes showed good oil-water separation behavior. The 300 mesh is observed to have superior separation performance. It is also tested to have good reusability and resistance in harsh conditions. The separation effectiveness of 94.7%, reduced turbidity of 21.8 NTU, and chemical oxygen demand of around 70 ppm, along with reasonable flux and intrusion pressure values of 73.28 Lm−2min−1 and 0.848 kPa, respectively, are noticed for the separation study conducted for locomotive wash effluent using the designated superhydrophilic mesh. This study hence as well demonstrates a prospective future of superhydrophilic mesh for practical utility.

Bibliometric evaluation of nanoadsorbents for wastewater treatment and way forward in nanotechnology for clean water sustainability

Water is a necessity of life that needs to be treated, protected, and conserved. Bibliometric analysis as an indispensable roadmap in science and technology was conducted on nanoadsorbent research for wastewater treatment. Data sourced from the Scopus®database from 1997 to 2020 were employed in this study. The analysis of the co-authorship of authors, organizations, and countries, co-citation of authors, citation of documents and sources, and co-occurrence of author keywords were performed using VOS viewer® software. A total of 4873 research papers was published on nanoadsorbent for wastewater treatment which grew gradually over the years. This translated to scientific publications of 689 (14.14%), 894 (18.35%), and 1022 (20.97%) papers in 2018, 2019, and 2020 respectively. China was the leading country (1924 papers) with the University of Chinese Academy of Sciences accounting for 28 publications as the top-ranked organization while Wang Y. published the highest number of research articles (127). These results revealed the importance of cross-national and international cooperation in this field with Environmental Science (2497 papers) ranked as the top-subject category. The co-citation of authors, citation of documents and sources showed that Wang Y., Gao L. (2007), and “Environmental Science and Technology” journal with citations of 3492, 2508, and 13651, respectively, were ranked highest. The most used keyword was "Wastewater treatment” with 593 occurrences. Research hotspots in the nanoadsorbents for wastewater treatment were summed up as application of nanoadsorbent to decontaminate different carcinogenic, mutagenic, and toxic compounds discharged from various processes. Future research lies in the implementation of nanoadsorbent for wastewater treatment from hospital effluents, household washing effluents, endocrine descriptive chemicals, and other emerging contaminants. Conclusively, this work suggests some important ways forward in nanotechnology and nanoadsorbents to ensuring clean water sustainability for developing and developed countries.

Potential use of extracellular polymeric substances (EPS) of Bacillus subtilis for biosorption of mercury produced from soil-washing effluent

Extracellular polymeric substances (EPS) can be used as an effective biosorbent for removing heavy metals from soil washing effluent. In this research, Bacillus subtilis was used as an EPS-producing bacteria with a yield of bound EPS of 0.6 mg/g biomass with protein and polysaccharide content of 199 mg/g EPS and 8.8 mg/g EPS, respectively. The maximum biosorption capacities for mercury in artificial wastewater using bound EPS and dead biomass of Bacillus subtilis as biosorbents were 9.32 mg/g and 6.04 mg/g, respectively, at a biosorbent dose of 0.1 g/100 mL. Biosorption using Bacillus subtilis fitted the Langmuir isotherm, while biosorption using bound EPS fitted the Freundlich isotherm. The biosorption process followed a pseudo-second-order kinetic model for both biosorbents. Bound EPS was also feasible to treat soil washing effluent with a biosorption capacity of 2.21 mg/g of mercury. The use of bound EPS could effectively remove mercury from wastewater.

Insight into the application of magnetic molecularly imprinted polymers in soil-washing effluent: Selective removal of 4,4′-dibromodiphenyl ether, high adaptivity of material and efficient recovery of eluent

Soil washing techniques can effectively remove soil polybrominated diphenyl ethers (PBDEs), but further removal of PBDEs from washing effluent is disrupted by environmental factors and coexisting organic matter. Hence, this work prepared novel magnetic molecularly imprinted polymers (MMIPs) to selectively remove PBDEs in soil washing effluent and recycling surfactants, with Fe3O4 nanoparticles as the magnetic core, methacrylic acid (MAA) as the functional monomer, and ethylene glycol dimethacrylate (EGDMA) as the cross-linker. Later, the prepared MMIPs were applied to adsorb 4,4′-dibromodiphenyl ether (BDE-15) in Triton X-100 soil-washing effluent and characterized by scanning electron microscopy (SEM), infrared spectrometry (FT-IR), nitrogen adsorption and desorption experiments. According to our observations, BDE-15 equilibrium adsorptions on dummy-template magnetic molecularly imprinted adsorbent (D-MMIP, 4-bromo-4′-hydroxyl biphenyl as template) and part-template magnetic molecularly imprinted adsorbent (P-MMIP, toluene as template) were reached within 40 min, and their equilibrium adsorption capacities were 164.54 μmol/g and 145.55 μmol/g, respectively, with imprinted factor α > 2.03, selectivity factor β > 2.14, and selectivity S > 18.05. MMIPs exhibited good adaptability to pH, temperature, and cosolvent. Our Triton X-100 recovery rate reached as high as 99.9%, and MMIPs maintained a more than 95% adsorption capacity after being recycled five times. Our results offer a novel approach to selectively remove PBDEs in soil-washing effluent, with efficient recovery of surfactants and adsorbents in soil-washing effluent.

Tween 80 assisted washing ciprofloxacin-contaminated soil, and recycled it using active chlorines

Active chlorines (ACs) can selectively oxidize contaminants with benzene rings to recycle surfactants, which greatly facilitates the resource cycle. This paper firstly utilized Tween 80 to assist in ex-situ washing the ciprofloxacin (CI) contaminated soil, including the solubilization experiment, shake washing and soil column washing, all of which showed that 2 g/L of Tween 80 (TW 80) was the most effective in removing CI. Then electrochemically treated the collected soil washing effluent (SWE) at 10 V with an electrolyte of 20 mM NaCl + 10 mM Na2SO4; Pre-experiments screened the range of electrode spacing, pH and temperature, based on which an orthogonal design Table L9 (34) was designed. Visual analysis and ANOVA were performed on the ciprofloxacin removal efficiency and Tween 80 retention efficiency during the orthogonal experiments in 9 groups, and the results showed that CI was usually degraded within 30 min, and 50% of TW 80 was still present at the end of the experiment, and there was no significant effect of all three factors. LC-MS demonstrated that CI was mainly degraded synergistically by ·OH and ACs, and ·OH effectively reduced the biotoxicity of the SWE, so the mixed electrolyte may be more suitable for the electrochemical recycling system of ACs. This paper conducted the washing remediation study of CI-contaminated soil for the first time, and applied the theory of selective oxidation by ACs on benzene ring to treat the SWE, which provides a new treatment idea for antibiotic-contaminated soil.

Evaluating the microcystin-LR-degrading potential of bacteria growing in extreme and polluted environments

Inhabitants of extreme and polluted environments are attractive as candidates for environmental bioremediation. Bacteria growing in oil refinery effluents, tannery dumpsite soils, car wash effluents, salt pans and hot springs were screened for microcystin-LR biodegradation potentials. Using a colorimetric BIOLOG MT2 assay; Arthrobacter sp. B105, Arthrobacter junii, Plantibacter sp. PDD-56b-14, Acinetobacter sp. DUT-2, Salinivibrio sp. YH4, Bacillus sp., Bacillus thuringiensis and Lysinibacillus boronitolerans could grow in the presence of microcystin-LR at 1, 10 and 100 µg L−1. Most bacteria grew optimally at 10 µg L−1 microcystin-LR under alkaline pH (8 and 9). The ability of these bacteria to use MC-LR as a growth substrate depicts their ability to metabolize the toxin, which is equivalent to its degradation. Through PCR screening, these bacteria were shown to lack the mlr genes implying possible use of a unique microcystin-LR degradation pathway. The study highlights the wide environmental and taxonomic distribution of microcystin-LR degraders.

Surfactant recovery and efficient separation of PAHs from surfactant solutions by low-cost waste activated sludge and two-stage design optimization.

The treatment and surfactant recovery of soil washing/flushing effluent containing high levels of surfactants and organic pollutants are critical for the surfactant-assisted remediation of soils and waste management due to their complexity and high-potential risks. Combination of waste activated sludge material (WASM) and a kinetic-based two-stage system design was introduced in this study as a novel strategy for the separation of phenanthrene and pyrene from Tween 80 solutions. The results showed that WASM can effectively sorb phenanthrene and pyrene with high affinities (Kd) of 2325.5 L·kg-1 and 9911.2 L·kg-1, respectively. This allowed a high-level recovery of Tween 80 of 90.47 ± 1.86%, with selectivity of up to 69.7. In addition, a two-stage design was constructed, and the results showed an improved reaction time (approximately 5% of equilibrium time in conventional single-stage process) and increased the separation levels of phenanthrene or pyrene from Tween 80 solutions. For instance, the minimal total operating time for the sorption of 99% pyrene from 1.0g·L-1 Tween 80 was only 23.0min in the two-stage process compared to that of 480min with a 71.9% removal level in the single-stage system. Results indicated that the combination of low-cost waste WASH and two-stage design was a high-efficiency and time-saving way to recover surfactants from soil washing effluents.

Removal of Sulfide Ions from Kraft Washing Effluents by Photocatalysis with N and Fe Codoped Carbon Dots.

N and Fe codoped carbon dots (N,Fe-CDs) were fabricated from citric acid, L-glutamic acid and ferric chloride via a hydrothermal method for the photocatalytic removal of S2- from kraft washing effluents (KWE). The N,Fe-CDs were fluorescent nanoparticles (average size of 3.18 nm) and catalyzed the oxidation of S2- following a first-order kinetic model with an activation energy of 33.77 kJ/mol. The N,Fe-CDs tolerated elevated temperatures as high as 80 °C without catalyst deactivation. The N,Fe-CDs catalysts were reusable for at least four cycles, preserving over 90% of the activity. In the treatment of KWE from the kraft pulping of eucalyptus, the concentration of S2- was decreased by the N,Fe-CDs from 1.19 to 0.41 mmol/L in 6 h. Consequently, near complete remediation was obtained in 24 h. In addition, half of the chemical oxygen demand was removed after treatment with 500 mg/L of the N,Fe-CDs. In addition, the present photocatalyst was safe within a concentration of 200 mg/L, as indicated by the acetylcholinesterase inhibition test. Our findings may help develop a cleaner production process for kraft brownstock washing.

Sustainable decontamination of heavy metal in wastewater and soil with novel rectangular wave asymmetrical alternative current electrochemistry.

A new concept of removal and recovery of heavy metals and simultaneous regeneration and reuse of ethylenediamine-tetraacetic acid (EDTA) in soil washing effluent containing metal-EDTA complexes is proposed, which is used to remediate heavy metal contaminated soil. To achieve this goal, soil washing approach coupled with rectangular wave asymmetrical alternative current electrochemistry (RW-ACE) equipped with amidoxime-functionalized electrodes (Ami-CF) is employed. With high hydrophilicity and strong binding affinity, Ami-CF could specifically compete for heavy metals over EDTA under electric field. RW-ACE system is found successfully to achieve the non-destructive decomplexation of heavy metal-EDTA, and then regenerate EDTA for highly recycling, which saves as high as 98.9 % EDTA consumption compared with conventional washing method. Moreover, more than 90% of heavy metals are recovered and deposited on the electrode with a majority of them existed as zero-valence state as evidenced by XPS. The RW-ACE method is universal for various heavy metals such as Cu2+, Zn2+, Cd2+, and Pb2+ in an authentic contaminated soil, and the loss of soil nutrient is very limited. Along with long-term assessment and operation cost estimation, the RW-ACE method is a sustainable remediation approach for the heavy metal polluted wastewater and soils, and easily scaled up for field practice.

Cost-effective remedial to microfiber pollution from wash effluent in Kolkata and Ranaghat

The microfibers generated from Polyester and Nylon based materials during washing cause serious environmental pollution by both contaminating the aquatic environment and the livelihood of the underwater creatures as well. This study aims at investigating the microfiber-pollution in wash effluents collected from different regions of Kolkata which is believed to be one of the microfiber-polluted cities in the South-east Asia in recent times. In this work, packed bed microfiltration (PBMF) was adopted in an economic and eco-friendly manner to arrest adequate amounts of microfibers and non-biodegradable matters present in the water samples collected from different regions of Kolkata and its surrounding areas. Moreover, effective parameters such as packed bed height to diameter ratio (H/D), mess size of the adopted filtration unit were varied from 0.71 to 2.85 and 60 to 100, respectively to understand the efficacy of the approach and to justify the potential of such alternative in order to alleviate the concern as well. The present study reveals that the microfiltration efficiency of the proposed PBMF unit was achieved maximum 93.5% for sample A and 92.2% for sample D respectively to reduce the microfiber count from 7614 to 543 in an hour operation at a flow rate of 60 L h−1. Besides, the cost of such system was found to be promising as much as 5 US$ on a yearly basis.

A pH-responsive phosphoprotein washing fluid for the removal of phenanthrene from contaminated peat moss in the cold region

Oil pollution is one of the major environmental concerns in the petroleum industry. In this study, a cheap food-grade sodium caseinate (NaCas) was used as a pH-responsive washing fluid in the remediation of phenanthrene (PHE) affected peat moss. The effects of environmental factors on the removal of PHE were systematically investigated. The results showed that increasing NaCas concentration and washing temperature improved the PHE mobilization, while high salinity and humic acid dosage displayed a negative effect. The factorial analysis revealed that three individual factors and two interactions exhibited significant effects on the washing performance. Due to the pH-responsive property of NaCas, the turbidity, total organic carbon (TOC), and chemical oxygen demand (COD) of the washing effluent were remarkably reduced by simply adjusting the solution acidity, improving the practical application of such a washing method. Significantly, the toxicity modeling proved that NaCas can reduce the binding energy between PHE and superoxide dismutase (SOD) of the selected marine organism, and thus relieve the toxicity of PHE to the organisms. Given these advantages, NaCas-assisted washing can be a viable option for the remediation of contaminated peat moss.

Potential for selective oxidation of aniline in soil washing effluent by active chlorine and testing its practicality

Recovery of surfactants in the soil washing effluent (SWE) can significantly reduce the cost of the soil washing (SW) technology. This paper consists of two parts experiments. The first part constructed a selective oxidation system of active chlorine by electrochemical technology to treat SWE. Three factors, current density, NaCl concentration and TW 80 to aniline concentration ratio (T/A), were set up for a total of nine sets of experiments after orthogonal design. The results of ANOVA analysis and visual analysis showed that the NaCl concentration greatly affected the aniline removal efficiency (ARE) and the TW 80 retention efficiency (TW 80 RE), and the effects were in opposite directions. The biotoxicity of the SWE decreased as the experiment progressed, and at the end of the experiment, 30%–45% of TW 80 was still present in each set. And the oxidation group quenching experiments determined that the degradation of aniline was mainly contributed by active chlorine. Because active chlorine slowed the loss rate of TW 80, the electrochemical treatment of SWE + soil in-situ sequential batch recirculation washing method was designed, and 50% of aniline in the soil was washed out after 125h. At the end of the experiment, the less biotoxic SWE was collected where no aniline and TW 80 were present, and only small organic acids were present after the GC-MS test. The method has a great potential to be applied as it shows good results in the treatment of soil pollution incidents.