Potential for selective oxidation of aniline in soil washing effluent by active chlorine and testing its practicality

Abstract

Recovery of surfactants in the soil washing effluent (SWE) can significantly reduce the cost of the soil washing (SW) technology. This paper consists of two parts experiments. The first part constructed a selective oxidation system of active chlorine by electrochemical technology to treat SWE. Three factors, current density, NaCl concentration and TW 80 to aniline concentration ratio (T/A), were set up for a total of nine sets of experiments after orthogonal design. The results of ANOVA analysis and visual analysis showed that the NaCl concentration greatly affected the aniline removal efficiency (ARE) and the TW 80 retention efficiency (TW 80 RE), and the effects were in opposite directions. The biotoxicity of the SWE decreased as the experiment progressed, and at the end of the experiment, 30%–45% of TW 80 was still present in each set. And the oxidation group quenching experiments determined that the degradation of aniline was mainly contributed by active chlorine. Because active chlorine slowed the loss rate of TW 80, the electrochemical treatment of SWE + soil in-situ sequential batch recirculation washing method was designed, and 50% of aniline in the soil was washed out after 125h. At the end of the experiment, the less biotoxic SWE was collected where no aniline and TW 80 were present, and only small organic acids were present after the GC-MS test. The method has a great potential to be applied as it shows good results in the treatment of soil pollution incidents.