Air Vapor Research Articles

Thermal mineralization of Perfluorooctanoic acid (PFOA): The synergistic role of oxygen and water vapor inhibiting products of incomplete destruction (PID) formation

The thermal decomposition of PFOA was studied in an α-alumina reactor between 400 and 1000 °C under two separate conditions: 1) in a bath gas of air and water vapor (H2O(g)) and 2) in a bath gas of helium, nitrous oxide (N2O) and H2O(g). PFOA decomposition studies undertaken under these conditions, both experimental and modeling analysis, provided insightful information on the conditions leading to the formation of products of incomplete destruction (PIDs).The combination of O2 from air or O from N2O decomposition, combined with H2O(g), resulted in complete mineralization of PFOA at temperatures above 950 °C into HF and CO2. An elementary mass balance of F and C atoms concluded that, at 1000 °C, 105 ± 10 % of F atoms present in PFOA are converted into HF, while 100 ± 5 % of C atoms into CO2. Both H2O(g) and oxygen together are necessary for complete mineralization.

Oxidation mechanism of the Si-X (X=HfO2, Yb2O3 or HfO2+Yb2O3) composite systems in air and water vapor at 1300 ℃

The formation rate of SiO2 during oxidation of Si bond layer is a key issue to determine the lifetime of environmental barrier coatings. The oxidation kinetics and mechanism of Si and Si-X (X=HfO2, Yb2O3 or HfO2+Yb2O3) composite systems were investigated systematically. The thickness of the SiO2 layer was greatly reduced by the dynamic formation of silicates (HfSiO4, Yb2SiO5 and Yb2Si2O7) in air and water vapor, benefiting for long-term servicing. However, the addition of HfO2 promoted the oxidation of Si with an increased total SiO2 thickness, while that of Yb2O3 not. These results provide a guidance for the design of next generation bond layers.

Diagnosing electrostatic problems and hazards in industrial processes: Case studies

AbstractStatic electricity is a phenomenon commonly encountered yet often misunderstood and underestimated in terms of its hazard potential; it continues to challenge the safety and reliability of industrial processes, particularly those involving flammable substances. This paper delves into the critical issue of electrostatic hazards in industrial settings by presenting two flash fire/explosion case studies, one involving biphenyl dust and the other gasoline vapor; both linked to electrostatic discharges. The first case study examines an explosion in a flaker and pack‐out hopper during biphenyl flake manufacturing. The investigation reveals the role of electrostatic charges in the incident and how well‐intentioned equipment changes created warning signs of increased risk that were missed. The second case study discusses a gasoline vapor flash fire, highlighting the common yet overlooked hazard of static electricity during the transfer of flammable liquids. It underscores how common activities involving people can generate sufficient electrostatic charge to ignite flammable vapor–air mixtures in industry. The outcomes of these studies highlight the importance of acting on early warning signs of static electricity and the crucial role of data‐driven diagnostic techniques in addressing and controlling those hazards. By dissecting the intricacies of electrostatic phenomena, safety professionals can formulate actionable strategies to adapt plant operations and prevent hazards from static electricity. The paper advocates for a proactive approach to identifying and mitigating electrostatic risks in industrial settings beginning with process hazard analyses that incorporate static electricity hazards analysis and continues through employee training to ensure that early warning signs are identified, understood, and acted upon. It stresses the need for comprehensive safety measures, including proper grounding and bonding, use of static dissipative materials, and regular maintenance of safety equipment, to prevent incidents. Through these case studies, the paper contributes to understanding of electrostatic hazards in industrial processes and highlights the importance of integrating electrostatic safety measures into routine industrial operations.

Tropospheric ozone pollution increases the sensitivity of plant production to vapor pressure deficit across diverse ecosystems in the Northern Hemisphere

Tropospheric ozone (O3) pollution often accompanies droughts and heatwaves, which could collectively reduce plant productivity. Previous research suggested that O3 pollution can alter plant responses to drought by interfering with stomatal closure while drought can reduce stomatal conductance and provide protection against O3 stress. However, the interactions between O3 pollution and drought stress remain poorly understood at ecosystem scales with diverse plant functional types. To address this research gap, we used 10-year (2012−2021) satellite near-infrared reflectance of vegetation (NIRv) observations, reanalysis data of vapor pressure deficit (VPD), soil moisture (SM), and air temperature (Ta), along with O3 measurements and reanalysis data across the Northern Hemisphere to statistically disentangle the interconnections between NIRv, VPD, SM, and Ta under varying O3 levels. We found that high O3 concentrations significantly exacerbate the sensitivity of NIRv to VPD while have no notable impacts on the sensitivity of NIRv to Ta or SM for all plant functional types, indicating an enhanced combined impact of VPD and O3 on plants. Specifically, the sensitivity of NIRv to VPD increased by >75 % when O3 anomalies increased from the lowest 10 to the highest 10 percentiles across diverse plant functional types. This is likely because long-term exposure to high O3 concentrations can inhibit stomatal closure and photosynthetic enzyme activities, resulting in reduced water use efficiency and photosynthetic efficiency. This study highlights the need to consider O3 in understanding plant responses to climate factors and that O3 can alter plant responses to VPD independently of Ta and SM.

Comparative analysis of water-use strategies in three subtropical mangrove species: a study of sap flow and gas exchange monitoring.

Water-use strategies play a crucial role in the adaptive capabilities of mangroves to the saline intertidal conditions, yet the intricacies of daily water-use patterns in mangrove species, which are pivotal for maintaining water balance, remain poorly understood. In this comprehensive study, we aimed to clarify the water use strategies of three co-occurring mangrove species, Avicennia marina, Aegiceras corniculatum and Kandelia obovata, through stem sap flow monitoring, leaf gas exchange and stem diameter change measurements. Our findings revealed that the daily sap flow density of Avicennia and Aegiceras reached the peak about 1 h earlier than that of Kandelia. When transpiration was strong, Kandelia and Aegiceras used stem storage to meet water demand, while Avicennia synchronized stem water storage. These three mangrove species adopted cross-peak water used and unique stem water storage to regulate their water balance. In Kandelia, the daily sap flow in per sapwood area was significantly lower, while water-use efficiency was significantly higher than those of Avicennia and Aegiceras, indicating that Kandelia adopted a more conservative and efficient water-use strategy. Sap flow in Avicennia was the most sensitive to environmental changes, while Kandelia limited water dissipation by tightly controlling stomata. Meteorological factors (photosynthetically active radiation, vapor pressure deficit and air temperature) were the main driving factors of sap flow. The increase of soil temperature can promote the water use of mangrove species, while the increase of salinity resulted in more conservative water use. Our results highlight the diversity of daily water-use strategies among the three co-occurring mangrove species, pinpointing Kandelia as the most adaptive at navigating the changing conditions of intertidal habitats in the future climate. In conclusion, our findings provide a mesoscale perspective on water-use characteristics of mangroves and also provides theoretical basis for mangroves afforestation and ecological restoration.

The ratio of transpiration to evapotranspiration and water use efficiency in an irrigated oasis agroecosystem: Different temporal-scale effects

Agroecosystems play an important role in carbon sequestration and water consumption of global terrestrial ecosystems. However, the magnitude, pattern, and regulation of the ratio of transpiration to evapotranspiration (T/ET), and also water use efficiency at ecosystem (WUEe) and canopy (WUEc) scales, remain unclear in agroecosystems in arid areas. In this study, a six-year synchronous observation of water-carbon fluxes and sap flow by the eddy covariance and sap flow techniques was conducted in an irrigated vineyard in northwest China. We found that T/ET, WUEe, and WUEc changed dynamically at the daily (1.0–98.6%, 0.3–4.9 g C kg–1 H2O, 0.4–5.9 g C kg–1 H2O) and monthly (26.0–71.0%, 0.8–1.8 g C kg–1 H2O, 2.3–3.2 g C kg–1 H2O) scales. At the annual scale, the range was relatively narrow, with mean values of 61.7% ± 3.7%, 1.5 ± 0.1 g C kg–1 H2O, and 2.4 ± 0.3 g C kg–1 H2O, respectively (mean ± standard deviation). Biological and environmental factors regulated their dynamics on different temporal scales. Specifically, leaf area index (LAI) and canopy conductance (gc) mainly determined the seasonal variation of T/ET, WUEe, and WUEc at the daily and monthly scales. However, at the annual scale, vapor pressure deficit (VPD) and air temperature (Ta) became the main influencing factors. These results highlight the complexity of water-carbon coupling in agroecosystems and the necessity of considering specific factors at different temporal scales when modeling and managing agricultural water resources. In addition, there is still great water-saving potential from the perspective of WUE in the cultivation of vines in Northwest China.

Response mechanism of ecosystem gross primary productivity to cloud and aerosol changes in a Chinese winter-wheat cropland.

Changes in clouds and aerosols may alter the quantity of solar radiance and its diffuse components, as well as air temperature (Ta) and vapor pressure deficit (VPD), thereby affecting canopy photosynthesis. Our aim was to determine how ecosystem gross primary productivity (GPP) responds to the cloudiness and aerosol depth changes, as indicated by diffuse light fraction (fDIF). The environmental factors that caused these responses were examined using 2 years of eddy covariance data from a winter-wheat cropland in northern China. The GPP decreased significantly along with the fDIF in a nonlinear pattern, with a determination coefficient of 0.91. Changes in fDIF altered total photosynthetic active radiation (PAR), diffuse PAR, Ta and VPD. The variations in GPP with fDIF in both fDIF change Phase I (fDIF < 0.65) and Phase II (fDIF > 0.65) resulted from the combined effects of multiple environmental factors. Because the driving factors were closely correlated, a path analysis was used to distinguish their respective contribution to the GPP response to fDIF by integrating path coefficients. In Phases I and II, the decreased responses of GPP to fDIF were mainly caused by total PAR and diffuse PAR, respectively, which contributed approximately 49% and 37% to GPP variations, respectively. Our research has certain implications for the necessity to consider fDIF and to incorporate diffuse light into photosynthetic models.

Thermodynamic equilibrium modeling of biomass gasification: Effects of operating conditions on gasifier performance

Biomass has remarkable potential to reduce harmful emissions and ensure stable and sustainable energy production. In this paper, various parameters such as operating temperature, type of gasifying agent, air–fuel ratio and steam-fuel ratio are investigated on the qualitative characteristics of the syngas obtained from biomass gasification. The qualitative indicators considered were the percentage of combustible components under the energy aspect and the percentage of undesirable components under the environmental aspect. The composition of the syngas was determined for a temperature range of 500–1000 °C as an equilibrium composition using the Gibbs free energy minimisation method. The results showed that increasing the gasification temperature above 900 °C had a positive effect on the energy and environmental properties of the syngas. Air and water vapour were selected as possible gasifying agents. The results showed that water vapour was significantly more favourable than air as a gasifying agent in terms of syngas quality. In the best case, the H2 yield for gasification with air is 35 %vol, while this value reaches 65 %vol for gasification with steam. In addition to the type, the ratio of the gasifying agent to the amount of fuel was also analysed. The analysis showed that it was more favourable to carry out the gasification process at lower air-to-fuel and steam-to-fuel ratios, which is consistent with the work of other authors.

Numerical Study of Air–Vapor–Particle Flow in Gas Cyclone

AbstractThis paper presents a numerical study of the complex multiphase flow of air, vapor, and particles in an innovative gas cyclone called CAP cyclone. The air–vapor flow is modeled as a mixture by the Reynolds‐averaged Navier‐Stokes equations with the mixture species transport and the Eulerian wall film model using FLUENT. Particle flow is modeled by the Lagrangian particle tracking method and the condensational growth of particle droplets is modeled via a user‐defined function. The model is validated by reaching good agreement with experimental results. Flow field analysis shows that the added vapor does not change the major vortex characteristics in the cyclone, but the vapor distribution is not uniform. The vapor concentration is much higher in the upper part than in the lower part of the cyclone, leading to insufficient condensational growth in the lower part. A secondary vapor injection is proposed to improve the vapor concentration in the lower part, which is shown to be effective in improving the collection efficiency. The model and the results are helpful to the understanding and optimization of the CAP cyclone technology, and also the vapor and particle droplet flow in turbulent flows.

Solar arrays create novel environments that uniquely alter plant responses

Societal Impact StatementGlobally, the combustion of fossil fuels represents the vast majority of greenhouse gas emissions, and as such, a transition to renewable forms of energy provides the greatest potential for mitigating climate warming. Although solar photovoltaic energy generation is a leading climate solution, these energy facilities have a significant spatial footprint. Naturally, concerns regarding the coexistence of solar development in agriculturally productive and pristine native ecosystems remain. This study offers insight for how plants respond to novel environmental conditions within a solar array and contextualizes results to inform future array siting, design, and management to realize a sustainable solar energy future.Summary Photovoltaic (PV) solar arrays impose dynamic shading regimes and redistribute precipitation to the ecosystems beneath, leading to spatial and temporal heterogeneity in plant growth environments. Although PV are known to alter ecosystem‐level processes in managed and native landscapes, the control of PV‐induced microenvironments on plant ecophysiological responses are largely unexplored. A more robust and mechanistic understanding of how PV microenvironments control plant response will inform management of existing solar arrays and provide insight for future arrays designed to enhance ecosystem services. Here, we evaluated carbon (photosynthetic parameters) and water relations (daily patterns of leaf water potential (ψL) and stomatal conductance (gsw)) in a C3 perennial grass (Bromus inermis) across PV microsites within a 1.6 ha (1.2 MW) array in semiarid Colorado, USA. Light‐saturated photosynthetic rate was surprisingly consistent spatially, not differing between plants growing in near full sun (between PV rows) versus those growing in shadier microsites beneath panels (~28% of full sunlight). Additionally, plants located in microsites receiving only direct sunlight in the morning, when air temperature and vapor pressure deficits (VPD) were low, had greater ψL and gsw than plants receiving direct sunlight primarily in the hotter drier afternoon. Thus, while soil moisture is a primary control of plant productivity in most water‐limited grasslands, we found that VPD was a better predictor of daily patterns of leaf‐level photosynthetic and water relations responses that control aboveground biomass production in a PV array. These findings provide new mechanistic insight for evaluating vegetation management strategies in semiarid PV arrays.

Determination of Ambient Air Vaporizers’ Performance Based on a Study on Heat Transfer in Longitudinal Finned Tubes

Ambient air vaporizers (AVVs) are the most commonly used type of heat exchanger for cryogenic regasification stations. The transfer of heat from the environment for heating the liquefied gas and its vaporization is a cost-free and efficient method. Designing ambient air vaporizers for regasification or fueling stations requires accepting the size and related thermal power of the AVV considering the operating conditions and the type of liquefied gases to be vaporized. The nominal capacity of the ambient air vaporizer depends on its design, the frosting of longitudinal finned tubes, and the airflow through the vaporizer structure. This paper presents the results of experimental studies and computational fluid dynamics (CFD) analysis on determining the heat output of AVV longitudinal finned tubes depending on their design. This experiment was conducted in order to establish a numerical model. The relation between the longitudinal finned tubes thermal power and the air flow velocity is demonstrated and the beneficial effect of forced convection is proved. The obtained results are used for verification calculations of ambient air vaporizers’ performance depending on the size of the AVV, the profile cross-section, and the airflow velocity for different liquefied gases. Under conditions of forced convection, profiles with 12 equal-height fins were discovered to be the most efficient for higher airflow velocity providing up to 7% higher heat rate than profiles with 8 equal-height fins. However, at low air velocity, profiles with 8 equal-length fins showed a comparable heat output to profiles with 12 equal-length fins. Profiles with 8 and 12 unequal high fins differ in average heat output by about 28%. The profile with 12 unequal high fins turned out to be the least effective when 2D airflow was considered in this analysis.

Spatiotemporal Evolution of Gas in Transmission Fluid under Acoustic Cavitation Conditions

The presence of gas in transmission fluid can disrupt the flow continuity, induce cavitation, and affect the transmission characteristics of the system. In this work, a gas void fraction model of gas–liquid two-phase flow in a transmission tube is established by taking ISO 4113 test oil, air, and vapor to accurately predict the occurrence, development, and end process of the cavitation zone as well as the transient change in gas void fraction. This model is based on the conservative homogeneous flow model, considering the temperature change caused by transmission fluid compression, and cavitation effects including air cavitation, vapor cavitation, and pseudo-cavitation. In this model, the pressure term is connected by the state equation of the gas–liquid mixture and can be applied to the closed hydrodynamic equations. The results show that in the pseudo-cavitation zone, the air void fraction decreases rapidly with pressure increasing, while in the transition zone from pseudo-cavitation to air cavitation, the air void fraction grows extremely faster and then increases slowly with decreasing pressure. However, in the vapor cavitation zone, the vapor void fraction rises slowly, grows rapidly, and then decreases, which is consistent with the explanation that rarefaction waves induce cavitation and compression waves reduce cavitation.

Comparing the Two Methods of Ion Chromatography and Titration in Evaluating the Concentration of Sulfuric Acid Mist and Vapor in the General Air of the Electrolysis Unit of the Copper Production Industry

Comparing the Two Methods of Ion Chromatography and Titration in Evaluating the Concentration of Sulfuric Acid Mist and Vapor in the General Air of the Electrolysis Unit of the Copper Production Industry

Influence of water vapor concentration on photoacoustic spectroscopy‐based characteristic gas analysis of transformer faults

AbstractThe water vapor in the ambient air affects the accuracy of the photoacoustic (PA) dissolved gas analysis system for transformer health monitoring. A laser PA system was evaluated by dry and humidified standard gases to study the influence of water vapor concentration on PA gas detection. Theoretical analysis was conducted on the effect of gas molecule relaxation on PA signal detection. A high‐frequency resonant PA cell and a low‐frequency nonresonant PA cell were used to detect acetylene (C2H2) and carbon monoxide (CO), respectively. The experimental results show that the PA signal of humidified CO is about 12 times higher than PA signal of dry gas for the resonant PA detection system, respectively. In addition, as the frequency is increased from 30 to 980 Hz, the PA signals of humidified and dry CO attenuate by 1.5 and 6.9 times, respectively.

Hybrid passive cooling and heating system for Mediterranean greenhouses. Microclimate and sweet pepper crop response

The microclimate of low-tech, unheated greenhouses in Mediterranean areas, associated with the local outdoor climate, is often outside the optimal range for most horticultural crops during both the warm and cold growing season. The use of a new hybrid system of passive cooling (evaporative screens) and heating (water-filled sleeves), in combination with an internal movable shading/thermal screen, was evaluated on a representative summer transplanted sweet pepper crop grown in perlite growing bags. The experiment was carried out in two identical greenhouses at the IFAPA La Mojonera research center in Almeria (SE Spain): one greenhouse with the hybrid passive system of cooling and heating, in combination with a shading/thermal screen, and another (reference greenhouse) using common local greenhouse climate management practices. Evaporative screens, in combination with a movable shading screen, improved the greenhouse climate, in particular the air vapour pressure deficit, and increased the leaf area index in the early stages of the crop, which, in turn, increased the early production of leaf and shoot dry matter and marketable fruit, compared to the reference greenhouse crop. In addition, the combined use of water-filled sleeves and thermal screen during the cold growth period increased greenhouse air temperatures, especially at night, and substrate temperatures. Overall, by improving the greenhouse microclimate during the warm and cold growth periods, the hybrid passive cooling/heating system, in combination with the shading/thermal screen, increased the marketable yield of a summer transplanted sweet pepper crop by 25 %, reduced the irrigation water supply by 8 %, and improved the irrigation water use efficiency by 20 % (including the potential water used to humidify the evaporative screens).

COMPARISON OF ANTIBACTERIAL AND SOME PHYSICAL PROPERTIES OF KNITTED FABRICS PRODUCED FROM BAMBOO, COTTON AND VISCOSE FIBER

Cotton, bamboo, and viscose fibers were examined in this study for their suitability in textile production. Bamboo, being a regenerated cellulosic fiber, has gained popularity in the industry due to its ecological properties. Fabrics made from bamboo exhibit comfort, wrinkle resistance, and thermal regulation. Additionally, they possess natural antibacterial, hypoallergenic, and biodegradable properties, along with high moisture absorption, shine, softness, and UV protection. The study compared knitted fabrics from these fibers, evaluating their water vapor permeability, air permeability, burst strength, water absorbency, abrasion resistance, and antibacterial properties according to international standards. Results showed that bamboo and cotton fibers have similar water vapor permeability, both higher than viscose fibers. Bamboo fiber's air permeability is notably higher than cotton and viscose fibers. Moreover, bamboo's water absorption surpasses cotton and viscose, leading to better sweat absorption. Bamboo fiber also demonstrated superior antibacterial properties compared to cotton and viscose, with higher bacterial eradication rates. Fabrics made from bamboo exhibited higher bursting strength and comparable pilling values to cotton, outperforming viscose. Overall, bamboo fiber demonstrated better air permeability, water absorbency, antibacterial properties, abrasion resistance, and bursting strength compared to cotton and viscose, making it a desirable choice for cool and comfortable textiles.

Small oases below the canopy: The cooling effects of water-filled tree holes on the local microclimate in oak-dominated stands

The relevance of forests in mitigating biodiversity loss and the negative effects of climate change on the biota is largely shaped by below-canopy microclimatic conditions, which are buffered, cooler and more humid compared to adjoining open habitats. Water-filled tree holes (dendrotelms, DTs) are special tree-related microhabitats that host semi-aquatic communities and are important substrates or water sources for numerous taxa (e.g., birds, mammals, insects, fungi, bryophytes). Despite their microrefugia-role might be more pronounced under climate change-induced drought events, little is known about their microclimate and its potential drivers.In an abandoned Turkey oak-dominated coppice stand in Hungary, the microclimates of 80 paired dendrotelms and adjacent forest plots were measured in the summer of 2021. Compared to nearby open areas, under closed forests, air temperature maxima were up to 5 °C cooler, DTs had an additional negative offset of 2.5 °C and increased air humidity by 15 percentage points (5% vs. 20 %). The local microclimate of DTs and the adjacent closed forest differed significantly in means and extremes of air temperature, relative humidity and vapour pressure deficit, which was mainly driven by DT entrance area and water volume and seemed independent from local stand structure. On the contrary, nearby below-canopy microclimate was shaped by the distance from forest edge, incoming light and tree density. Water volume in DTs also influenced local forest microclimates up to 0.5–1 m from the entrances.As the frequency and severity of extreme weather events such as heatwaves are likely to intensify due to climate change, the importance of microhabitats and habitat trees for invertebrates and vertebrates will increase further, and will additionally contribute to the microclimatic refugia role of forests. Active protection of veteran trees under the scheme of continuous cover forestry or conservation-oriented management is essential facing climate change to mitigate its negative effects on forest biodiversity.

Impact of canopy environmental variables on the diurnal dynamics of water and carbon dioxide exchange at leaf and canopy level

Abstract. Quantifying water vapor and carbon dioxide (CO2) exchange dynamics between the land and the atmosphere through observations and modeling is necessary in order to reproduce and project near-surface climate in coupled land–atmosphere models. The exchange of water and CO2 occurs at the leaf surface (leaf level) and in a net manner through exchanges at all the leaf surfaces composing the vegetation canopy and at the soil surface (canopy level). These exchanges depend on the meteorological forcings imposed by the overlying atmosphere (atmospheric boundary layer level). In this paper, we investigate the effect of four canopy environmental variables (photosynthetic active radiation (PAR), water vapor pressure deficit (VPD), air temperature (T), and atmospheric CO2 concentration (Ca)) on the local individual leaf exchange and canopy exchange of water and CO2 at hourly timescales. Additionally, we investigate the effect of atmospheric boundary layer (ABL) processes on the local exchange. To that end, we simultaneously investigated the exchanges of water and CO2 at leaf level and canopy level for an alfalfa field in northern Spain over 1 day in summer 2021. We used comprehensive observations ranging from stomatal conductance to ABL measurements collected during the Land Surface Interactions with the Atmosphere in the Iberian Semi-Arid Environment (LIAISE) experiment. To support the observational analysis, we used a coupled land–atmosphere model (CLASS model) that has representations at all levels considered. To relate how temporal changes of the four environmental variables modify the fluxes of water and CO2, we studied tendency equations of the leaf gas exchange. These mathematical expressions quantify the temporal evolution of the leaf gas exchange as a function of the temporal evolution of PAR, VPD, T, and Ca. To investigate the effects of ABL processes on the local exchange, we developed three modeling experiments that impose surface radiative perturbations by a cloud passage (which perturbed PAR, T, and VPD), entrainment of dry air from the free troposphere (which perturbed VPD), and advection of cold air (which perturbed T and VPD). The model results and observations matched the leaf gas exchange (r2 between 0.23 and 0.67) and canopy gas exchange (r2 between 0.90 and 0.95). The tendency equations of the modeled leaf gas exchange during the study day revealed that the temporal dynamics of PAR were the main contributor to the temporal dynamics of the leaf gas exchange, with atmospheric CO2 temporal dynamics being the least important contributor. From the three modeling experiments with ABL perturbations, the surface radiative changes induced by a cloud perturbed the CO2 exchange the most, whereas all of them perturbed the water exchange to a similar extent. Second-order effects on the dynamics of the leaf gas exchange were also identified using the tendency equations. For instance, the decrease in the net CO2 assimilation rate during the cloud passage caused by a decrease in surface radiation was further enhanced due to the decrease in air temperature also associated with the cloud. With this research we showcase that the proposed tendency equations can disentangle the effect of environmental variables on the leaf exchange of water and CO2 with the atmosphere, as represented in land–surface parameterization schemes. As such, this framework can become a useful tool with which to analyze these schemes in weather and climate models.

Turbulent natural convection in an air–water system with evaporation across the free surface

In this paper we report on direct numerical simulations of turbulent convection in a cuboidal pool that contains liquid water in the lower part and air in the upper one. The bottom wall is uniformly heated and natural convection is established in both phases, accompanied by water evaporation across the free surface of the water. The descent of the free surface due to evaporation is computed via a newly developed tracking algorithm based on the ghost-fluid method. We present results for three different cases which correspond to different pool heights. In all of them, the natural convection in the water lies in the soft-turbulence regime. Whereas in the gas, it lies in the laminar, transitional and soft-turbulence regimes, respectively. Our analysis focuses on the characteristics of the convective patterns in the two phases and the statistics of the various flow quantities of interest. According to our simulations, the flow in the water is organized in a single-roll Large-Scale Circulation (LSC). In the gas, it is organized in single or dual-roll LSCs, depending on the aspect ratio of the pool. Interestingly, the impingement points of the LSCs of the two phases at the free surface remain very close to one another, which is attributed to the continuity of the shear stresses across the free surface. Further, after the initial transient period, both the free-surface temperature and the evaporative mass flux are stabilized and remain almost constant, but they exhibit small-scale fluctuations in time due to turbulence. Also, the transport of water vapor in air has similar properties as the heat transport, and the ratio between the Sherwood and Nusselt numbers is very close to the Lewis number for air.

Impacts of elevated temperature and vapour pressure deficit on leaf gas exchange and plant growth across six tropical rainforest tree species.

Elevated air temperature (Tair) and vapour pressure deficit (VPDair) significantly influence plant functioning, yet their relative impacts are difficult to disentangle. We examined the effects of elevated Tair (+6°C) and VPDair (+0.7 kPa) on the growth and physiology of six tropical tree species. Saplings were grown under well-watered conditions in climate-controlled glasshouses for 6 months under three treatments: (1) low Tair and low VPDair, (2) high Tair and low VPDair, and (3) high Tair and high VPDair. To assess acclimation, physiological parameters were measured at a set temperature. Warm-grown plants grown under elevated VPDair had significantly reduced stomatal conductance and increased instantaneous water use efficiency compared to plants grown under low VPDair. Photosynthetic biochemistry and thermal tolerance (Tcrit) were unaffected by VPDair, but elevated Tair caused Jmax25 to decrease and Tcrit to increase. Sapling biomass accumulation for all species responded positively to an increase in Tair, but elevated VPDair limited growth. This study shows that stomatal limitation caused by even moderate increases in VPDair can decrease productivity and growth rates in tropical species independently from Tair and has important implications for modelling the impacts of climate change on tropical forests.