Ultraviolet Laser Research Articles

Ultraviolet Organic Laser from Rhombus Microcrystal: Benefits of Single-Molecule Emission from Twisted Structure.

Light-emitting molecular crystals with efficient emission behavior are crucial for fabricating low-threshold ultraviolet organic lasers. Herein, we demonstrated a rhombus microcrystal from a fluorene-based conjugated molecule (CL-1) with robust emission behavior for an ultraviolet organic laser. Due to the synergistic effect of twisted intramolecular conformation and weak π-interaction, the CL-1 single crystal showed an extremely high photoluminescence quantum yield (PLQY) of ∼82%, due to their single-molecule excitonic behavior. Considering the diverse noncovalent interactions, CL-1 molecules easily self-assembled into the rhombus microcrystals. Finally, a low-threshold ultraviolet organic laser was fabricated with a sharp emission at 379 nm, attributed to the 0-1 vibration band of a single CL-1 molecule, also further confirming the single twisted-molecule emission in crystal states. Precisely controlling the intramolecular twisted structure and intermolecular interaction of organic conjugated molecules is a precondition to obtain robust ultraviolet emission for optoelectronic applications.

Gradient-Pattern Micro-Grooved Wicks Fabricated by the Ultraviolet Nanosecond Laser Method and Their Enhanced Capillary Performance.

Capillary-gradient wicks can achieve fast or directional liquid transport, but they face fabrication challenges by traditional methods in terms of precise patterns. Laser processing is a potential solution due to its high pattern accuracy, but there are a few studies on laser-processed capillary-gradient wicks. In this paper, capillary step-gradient micro-grooved wicks (CSMWs) were fabricated by an ultraviolet nanosecond pulsed laser, and their capillary performance was studied experimentally. The CSMWs could be divided into three regions with a decreasing capillary radius. The equilibrium rising height of the CSMWs was enhanced by 124% compared to the non-gradient parallel wick. Different from the classical Lucas-Washburn model describing a uniform non-gradient wick, secondary capillary acceleration was observed in the negative gradient direction of the CSMWs. With the increase in laser power and the decrease in scanning speed, the capillary performance was promoted, and the optimal laser processing parameters were 4 W-10 mm/s. The laser-enhanced capillary performance was attributed to the improved hydrophilicity and reduced capillary radius, which resulted from the increased surface roughness, protrusion morphology, and deep-narrow V-shaped grooves induced by the high energy density of the laser. Our study demonstrates that ultraviolet pulsed laser processing is a highly efficient and low-cost method for fabricating high-performance capillary gradient wicks.

Experimental study of a temperature measurement system for an overhead power line using sensors based on TFBG

This article presents the use of an inclined fiber sensor Bragg grid to control the extension of wires in overhead lines. An aspect of the technological novelty of the project is the development of an innovative optoelectronic system for monitoring and diagnosing the condition of building structures based on a combination of conventional Bragg gratings. The lighting power sensor is installed directly on the controlled transmission of the power line in the form of fittings with a copper plate. A photosensitive multimode optical fiber is attached to the copper plate, at the end of which an inclined fiber Bragg grating is fixed, connected to a multimode optical fiber using a fiber-optic connector through an optical connector. An ultraviolet excimer laser and a light power detector are connected to a fiber-optic connector. The study showed that by selecting the appropriate mechanical parameters of the extension transformer, taking into account the optical parameters of the sensor, and using a special filter, the optical-mechanical system can be configured in the required range to control the sagging of the overhead line wire. During measurements to simulate the operation of a power line wire, the temperature was forced to vary in the range of 10-60°C. This led to the lengthening of the test wire from 38.987 m to 49.275 m; the error was within 4%. The deflection range depends on the distance between the supports, the type of wire, and its actual length in the span, which actually determines the deflection.

Laser Dynamic Control of the Thermal Emissivity of a Planar Cavity Structure Based on a Phase-Change Material.

Tailoring the thermal emission of a material in the long-wave infrared (IR) range of 8-13 μm is crucial for many IR-adaptive applications, including personal thermal management, IR camouflage, and radiative cooling. Although various materials and surface structures have been proposed for these purposes, space-selective and dynamic control of their emissivity is challenging. In this study, we present a planar surface cavity structure consisting of a Ge2Sb2Te5 (GST) film on top of a thin metal reflector to modulate its emissivity by using an ultraviolet laser beam. A laser-induced phase change in GST allowed for the local control of emissivity. The average emissivity in the long-wave IR range was tunable from 0.15 to 0.77 simply by changing the laser energy deposited on the GST film. This enabled the laser printing of high-contrast emissivity patterns, which were erasable by subsequent thermal annealing. Emissivity-modulated GST cavities could be fabricated on not only rigid substrates but also flexible plastic substrates such as polyimide. The GST surface cavity was highly flexible and remained stable upon repeated bending to a curvature radius of 0.5 cm. This study provides a promising route for realizing scalable and flexible thermal emitters with tunable surface emissivity.

Performance improvement of 263 nm AlGaN DUV LDs with different doping concentration and composition graded EBL Techniques

As part of this study, we present a study on the act of electrically driven Laser Diode (LD) using trinary Aluminum Gallium Nitride (AlGaN) with optimized doping concentrations. To increase the LD’s output power and capabilities, we focused on utilizing different doping concentrations in the electron-blocking layer (EBL). We conducted the calculations with PICS 3D software; we obtained simulation results indicating that the designed LD structure successfully emitted an ultraviolet (UV) laser class-c at a wavelength of 263.7 nm. By implementing this approach, we anticipate achieving higher optical output power by 6%, enhancing the concentration of electron and hole, and reducing the electron current density (356.1 to 342.8) and threshold voltage (4.516 to 4.5 V), and hole current density increases in AlGaN-based ultraviolet LDs. These promising outcomes can be attributed to the effective conduction band barrier height achieved by the optimized electron-blocking layer (EBL).

UV-ultrashort pulsed laser ablation of fused silica

The authors report on ultraviolet ultrashort pulsed laser ablation of fused silica and compare the achievable micromachining results to those obtained by using the fundamental emission wavelength in infrared. Ablation in ultraviolet reveals a stable efficiency for increasing fluences, whereas using an infrared beam exhibits a decreasing trend of the ablation efficiency at higher and increasing fluences. In addition, a significant improvement in the surface quality is found by using an ultraviolet wavelength in a fluence range up to 20 J/cm2 compared to infrared, e.g., revealing an Ra of down to 0.45 μm on using the ultraviolet wavelength compared to Ra = 0.56 μm on using infrared at fluences up 15 J/cm2. Moreover, taking advantage of the high available pulse energy, the authors compare the achievable ablation efficiency and surface roughness using a conventionally focused ultraviolet beam and a defocused ultraviolet beam, finding that the defocused ultraviolet beam possesses a processing quality comparable to that of the focused beam. Finally, the authors exemplify the potential of ultraviolet ultrashort pulsed laser ablation by using a Tesla mixer for microfluidic integration of fused silica.

Carbon nanotube/liquid metal hybrid coating-based flexible pressure piezoresistive sensors

This work prepared carbon nanotubes/liquid metal (CNT/LM) coating films on a PDMS/Ecoflex (PE) blend substrate with a proportion of 2:1. An ultraviolet laser was used to improve the bonding between CNT/LM and PE 2:1, resulting in the formation of a robust and innovative conductive layer. The interaction between CNT and LM droplets, coupled with laser treatment on the CNT/LM coating, led to a reduced liquid metal oxide layer. The CNT/LM solution demonstrated highly stable CNTs particles with the assistance of liquid metal. The result demonstrated that CNT-assisted liquid metal could improve the electrical resistance compared to the CNT-only layer. Furthermore, the PE/CNT/LM/PE fabricated sensor exhibited enhanced sensitivity and recoverability under lower and higher applied compressive strains with a gauge factor ranging from 20.6 (10 %) to 57 (30 %) and a relatively fast response time (70 ms). The PE/CNT/LM/PE sensor showed extremely high load-bearing capacity confirming the potential of PE 2:1 to bear the load without disrupting the electrical signal. The electromechanical properties confirmed the potential of PE/CNT/LM/PE in wearable electronics and various sensing characteristics.

Effect of optimized quaternary waveguides on the performance of deep ultraviolet laser diodes

Efficient ultraviolet (UV) laser diodes (LD) emitting in the 260–270 nm range have been proposed numerically in this work. Using engineered quaternary waveguides (QWGs) in place of conventional ternary waveguides, in the p-region, results in much higher output power as well as internal quantum efficiency (IQE) and lower the lasing threshold. The electron outflow is reduced and the injection of holes is enhanced which results in high efficiency and high light power output.

355 nm Nanosecond Ultraviolet Pulsed Laser Annealing Effects on Amorphous In-Ga-ZnO Thin Film Transistors.

Bottom-gate thin-film transistors (TFTs) with n-type amorphous indium-gallium-zinc oxide (a-IGZO) active channels and indium-tin oxide (ITO) source/drain electrodes were fabricated. Then, an ultraviolet (UV) nanosecond pulsed laser with a wavelength of 355 nm was scanned to locally anneal the active channel at various laser powers. After laser annealing, negative shifts in the threshold voltages and enhanced on-currents were observed at laser powers ranging from 54 to 120 mW. The energy band gap and work function of a-IGZO extracted from the transmittance and ultraviolet photoelectron spectroscopy (UPS) measurement data confirm that different energy band structures for the ITO electrode/a-IGZO channel were established depending on the laser annealing conditions. Based on these observations, the electron injection mechanism from ITO electrodes to a-IGZO channels was analyzed. The results show that the selective laser annealing process can improve the electrical performance of the a-IGZO TFTs without any thermal damage to the substrate.

Bond dissociation energy of N2 measured by state-to-state resolved threshold fragment yield spectra.

The precise determination of the bond dissociation energy of N2 is crucial for thermochemistry database and theoretical calculations. However, there has been ongoing debate regarding its exact value. In this study, we used the velocity map imaging method combined with an extreme ultraviolet laser to measure the threshold fragment yield (TFY) spectra of N2 in the N(2D) + N(2D) photodissociation channels. By integrating the signals within a small circular area on the fragment velocity map images, we were able to obtain TFY spectra at nine different dissociation thresholds. These spectra are rotational state-resolved for the N2(J″) molecules and spin-orbit state-resolved for the dissociation channels involving N(2D) fragments. By employing the Wigner threshold law to simulate the TFY spectra and conducting statistical analysis on the comprehensive dataset, we determined the N2 bond dissociation energy to be 78 691.09 ± 0.15cm-1. This work now places N2 among the few diatomic molecules with bond dissociation energies measured at sub-wavenumber precision.

Interface behavior and pore distribution of Ti6Al4V/CFRTP joints affected by groove profile

This study investigated the effect of groove profile on interface behavior, pore distribution, and bonding mechanism between Ti6Al4V (TC4) and carbon fiber reinforced thermoplastic (CFRTP). Using an ultraviolet picosecond laser system, grooves with varying depth-width ratios (R) and distances between adjacent grooves (T) were precisely etched on the TC4 surface. Experiment results revealed that grooves effectively impede bubble coalescence and growth, reduce pore defects at the grooves’ outer interface, and promote closer bonding between TC4 and CFRTP, thereby enhancing joint strength. In this study, grooves significantly improved joint strength by 40.2 % to 147.5 %, primarily due to increased mechanical interlocking and bonding area. Differences in joint strength among grooved joints are mainly attributed to variations in interface behavior and pore distribution caused by R and T. Appropriate R and T are crucial for inhibiting large-volume pores and reducing pores at the grooves’ outer. When R = 1/5 and T = 360 μm, the joint with small-volume pores, no pores at the grooves' outer, and the lowest porosity exhibits the highest strength (2830.3 N). Grooves showed no significant impact on chemical bonding (CTi0.42V1.58 carburization phase and TiOS). Furthermore, no significant effect of grooves on the chemical bonding (CTi0.42V1.58 carburization phase and TiOS).

A 172 mJ, high-energy picosecond 355 nm ultraviolet laser system at 100 Hz

Abstract A high-energy picosecond 355 nm ultraviolet (UV) laser operating at 100 Hz was demonstrated. A 352 mJ, 69 ps, 1064 nm laser at 100 Hz was realized firstly by cascaded regenerative, laser diode end-pumped single-pass and side-pumped main amplifiers. The stimulated Raman scattering-based beam shaping technique, thermally induced birefringence compensation and 4f spatial filter-image relaying systems were used to maintain a relatively homogeneous beam intensity distribution during the amplification process. By using lithium triborate crystals for second- and third-harmonic generation (THG), a 172 mJ, approximately 56 ps, 355 nm UV laser was achieved with a THG conversion efficiency of 49%. To the best of our knowledge, it is the highest pulse energy of a picosecond 355 nm UV laser so far. The beam quality factor ${M}^2$ and pulse energy stability were ${M}_x^2$ =3.92, ${M}_y^2$ =3.71 and root mean square of 1.48%@3 hours. This laser system could play significant roles in applications including photoconductive switch excitation, laser drilling and laser micro-fabrication.

Tunable ultraviolet laser based on intracavity third harmonic generation of external cavity surface emitting laser

Ultraviolet laser has high frequency, short wavelength, large single-photon energy, and high spatial resolution, and has wide applications in many fields such as fine processing, life sciences, and spectroscopy. In this work, a wavelength tunable ultraviolet laser based on intracavity third harmonic generation from an external-cavity surface-emitting laser is reported. The W-type resonant cavity of the laser is composed of a distributed Bragg reflector (DBR) at the bottom of the gain chip, three plane-concave mirrors, and a rear plane mirror. On the arm containing the gain chip, a birefringent filter is inserted at the Brewster angle as the polarization and wavelength tuning element, which can also narrow the linewidth of the fundamental laser to a certain extent. A type-I phase-matched LBO crystal is placed on the beam waist between the folding mirrors M2 and M3 to convert the 980 nm fundamental laser into 490 nm blue light, and a type-I phase-matched BBO crystal is inserted in the beam waist near the rear mirror to produce a 327 nm ultraviolet output from the remained 980 nm fundamental laser and the frequency-doubled 490 nm second harmonic. Before the BBO crystal, a half-wave plate at 980 nm is employed to change the polarization of the fundamental laser, so as to meet the type-I phase-matching condition of the used BBO crystal. Owing to the larger nonlinear coefficient of the type-I phase-matched BBO crystal, and its obviously higher transmittance at 327 nm wavelength than the usually used LBO crystal, the output power is obtained to be 538 mW at 327 nm ultraviolet wavelength, corresponding to a conversion efficiency of 1.1% from pump light to ultraviolet laser. The experiment is performed under conditions of 15 ℃ temperature, 47 W absorbed pump power, 5 mm-length LBO and 5 mm-length BBO crystals. By using a 2 mm-thick birefringent filter as the tuning element, 34.1 nm tuning range of the 980 nm fundamental laser, 14.3 nm tuning range of the 490 nm second harmonic, and 8.6 nm tuning range of the 327 nm third harmonic are obtained. The ultraviolet laser exhibits good beam quality as well as acceptable power stability with the maximum power fluctuation less than 2% within 4.5 h.

An ultraviolet laser at 228 nm with adjustable repetition rate and narrow pulse width

An ultraviolet laser at 228 nm with adjustable repetition rate and narrow pulse width

Research progress of hydroxy-plane laser induced fluorescence detection based on ultraviolet laser

Research progress of hydroxy-plane laser induced fluorescence detection based on ultraviolet laser

Stable ultraviolet ultrafast laser based on all-polarization-maintaining fiber femtosecond laser

Stable ultraviolet ultrafast laser based on all-polarization-maintaining fiber femtosecond laser

Spatial-temporal characterization of photoemission in a streak-mode dynamic transmission electron microscope.

A long-standing motivation driving high-speed electron microscopy development is to capture phase transformations and material dynamics in real time with high spatial and temporal resolution. Current dynamic transmission electron microscopes (DTEMs) are limited to nanosecond temporal resolution and the ability to capture only a few frames of a transient event. With the motivation to overcome these limitations, we present our progress in developing a streak-mode DTEM (SM-DTEM) and demonstrate the recovery of picosecond images with high frame sequence depth. We first demonstrate that a zero-dimensional (0D) SM-DTEM can provide temporal information on any local region of interest with a 0.37 μm diameter, a 20-GHz sampling rate, and 1200 data points in the recorded trace. We use this method to characterize the temporal profile of the photoemitted electron pulse, finding that it deviates from the incident ultraviolet laser pulse and contains an unexpected peak near its onset. Then, we demonstrate a two-dimensional (2D) SM-DTEM, which uses compressed-sensing-based tomographic imaging to recover a full spatiotemporal photoemission profile over a 1.85-μm-diameter field of view with nanoscale spatial resolution, 370-ps inter-frame interval, and 140-frame sequence depth in a 50-ns time window. Finally, a perspective is given on the instrumental modifications necessary to further develop this promising technique with the goal of decreasing the time to capture a 2D SM-DTEM dataset.

Enhancement of heat dissipation in β-Ga2O3 Schottky diodes through Cu-filled thermal vias: experimental and simulation investigations

Cu-filled thermal through-vias were formed in β-Ga2O3 Schottky diodes using ultraviolet laser drilling and Cu electroplating, where the temperature increase was suppressed by approximately 21% at the power density of 5.7 W mm−3.

Effect of laser grooving on titanium dental implants surface composition: An in vitro study

Introduction: The aluminum and vanadium contents of the titanium-aluminum-vanadium alloy (Ti-6Al-4V) surface are known to have cytotoxic effect, the use of laser grooving was thought to produce dental implants-controlled surface roughness and a better surface chemical composition. Aims: The aim of the current work was to test the titanium alloy machined and laser grooves surface content of the aluminum and vanadium, and their effect on cellular viability. Materials and Methods: Threaded titanium dental implants were designed, milled and micro-grooved using the Avia coherent pulsed ultraviolet laser and produced 10 µm grooves on their machined surface. The scanning electron microscope was used to evaluate the produced micro-grooves, and the X-ray diffraction to study the surface composition of the titanium alloy before and after laser grooving. And the MC3T3-E1 mouse osteoblasts were cultured on such surfaces to test their cytotoxic effect. Results and Discussion: The laser grooving significantly reduced the alloy surface content of the aluminum and vanadium as proved by the significantly better viability of the cells cultured on it as compared to the machined surface. Conclusion: The laser grooving reduced the Ti-6Al-4V alloy surface content of the cytotoxic elements.

Enhanced production of <sup>199</sup>Hg cold atoms based on two-dimensional magneto-optical trap

Efficient preparation of cold atoms plays an important role in realizing precision measurement including optical lattice clocks (OLCs). Fast preparation of cold atoms reduces Dick noise by shortening dead time in a clock interrogation cycle, which improves the stability of OLCs. Here, we increase the loading rate of the three-dimensional magneto-optical trap (3D-MOT) in the ultra-high vacuum environment by utilizing the two-dimensional magneto-optical trap (2D-MOT) with a push beam, reduce the temperature of cold atoms with the compression-MOT technique which is implemented by reducing the detuning of 3D-MOT rapidly at the end of atom preparation, and realize the enhanced production of cold atoms for <sup>199</sup>Hg OLCs. To achieve 3D-MOT and 2D-MOT of mercury atoms, a deep ultraviolet laser (DUVL) system composed of three DUVLs is developed with one working in lower power for frequency locking and the other two in high power for laser cooling. Such a configuration improves the long-term frequency stability and shows greater robustness than our previous system consisting of two DUVLs. To maximize the 3D-MOT loading rate, we orderly optimize the detuning and the magnetic field gradient of 3D-MOT and those of 2D-MOT as well as the detuning and the power of the push beam. After all parameters are optimized, we measure the maximum loading rate of 3D-MOT to be 3.1×10<sup>5</sup> s<sup>–1</sup> and prepare cold atoms of 1.8×10<sup>6</sup> in 9 s. The loading rate is greatly enhanced by a factor of 51 by using 2D-MOT and the push beam. In order to improve the efficiency of transferring cold atoms from 3D-MOT to optical lattice, we use compression-MOT technique to reduce the temperature of cold atoms and produce cold <sup>199</sup>Hg atoms which are about 45 μK, lower than the expected temperature of Doppler cooling theory. By achieving the high gain of the 3D-MOT loading rate under the ultra-high vacuum and reducing the temperature of cold atoms, this enhanced preparation of cold atoms based on 2D-MOT effectively shortens the preparation time of cold atoms and improves the transfer efficiency of optical lattice, which provides a significant scheme for efficiently preparing cold mercury atoms in other experiments.