Transport Of Pollutants Research Articles

Fluid dynamics challenges in predicting plastic pollution transport in the ocean: A perspective

Fluid dynamics challenges in predicting plastic pollution transport in the ocean: A perspective

Seasonal dynamics of coastal pollution migration in open waters with intensive marine ranching

Mariculture activities have been recognized as one of the major sources of contamination for marine pollutants, such as the excessive discharging of nitrogen and phosphate. The fully understanding of the pollutants emission and transportation is crucial for coastal environment management. However, the influence of such highly dynamic coastal process on the pollutant migration remain unclear, such as the effects of coastal seasonal hydrodynamics on the dissolved pollutant transportation, especially under intensive marine ranching activities in open waters. This study investigated the seasonal transport mechanisms of pollutants released from three typical mariculture methods (floating raft, cage and bottom pond) in the Wangjia Island (WJ), Yellow Sea, China. We have conducted three field surveys to monitor the coastal dynamics and measure the distribution of dissolved pollutants in the ranching area. Results from these field surveys show that the WJ and adjacent area experienced significant degradation in terms of water quality with the development of regional marine ranching. The average of calculated index for eutrophication Ei increases from 0.12 in the non-farming area to 0.78 in the farming area. In order to delineate the impacts area of pollutant transport associated with these highly dynamics of water exchange, a Eulerian passive tracer-tracking module is applied to simulate the pollutant transport processes based on a field scale three-dimensional Finite Volume Coastal Ocean Model (FVCOM). Then after, the impacts of barotropic and baroclinic coastal dynamics on the migration of dissolved pollutants were evaluated. The transport of pollutants was greatly influenced by the different farming modes. The travel distance of pollutants released from the bottom pond farming mode was limited, whereas pollutants from the surface-farming methods were transported over a longer distance. In this study, there are three folders of finding: 1) The migration direction varies with seasons, with a landward direction in winter and an offshore direction in summer; 2) In winter, strong wind (wind speed over 10 m/s) is the dominant factor for water exchange, which is conducive to the dispersion of pollutants in the study area. However, in summer, the thermal stratification controls pollutant migration; 3) The results of breakthrough time illustrate that the pollutants travelled slower during summer, especially for pollutants discharged from the bottom pond farming method. In summary, this study demonstrates that even in open waters with stronger water exchange capacity, the pollutants from intensive marine ranching can still increase the risk of eutrophication. The finding of this study has important implications for the management and regulation of offshore aquaculture activities, particularly for mitigating pollutants from marine ranching.

Phthalate esters delivery to the largest European lagoon: Sources, partitioning and seasonal variations

Phthalate esters (PAEs) due to their ability to leach from plastics, widely used in our daily life, are intensely accumulating in wastewater water treatment plants (WWTP) and rivers, before being exported to downstream situated estuarine systems. This study aimed to investigate the external sources of eight plasticizers to the largest European lagoon (the Curonian Lagoon, south-east Baltic Sea), focusing on their seasonal variation and transport behaviour through the partitioning between dissolved and particulate phases. The obtained results were later combined with hydrological inputs at the inlet and outlet of the lagoon to estimate system role in regulating the transport of pollutants to the sea. Plasticizers were detected during all sampling events with a total concentration ranging from 0.01 to 6.17 μg L−1. Di(2-ethylhexyl) phthalate (DEHP) was the most abundant PAEs and was mainly found attached to particulate matter, highlighting the importance of this matrix in the transport of such contaminant. Dibutyl phthalate (DnBP) and diisobutyl phthalate (DiBP) were the other two dominant PAEs found in the area, mainly detected in dissolved phase. Meteorological conditions appeared to be an important factor regulating the distribution of PAEs in environment. During the river ice-covered season, PAEs concentration showed the highest value suggesting the importance of ice in the retention of PAEs. While heavy rainfall impacts the amount of water delivered to WWTP, there is an increase of PAEs concentration supporting the hypothesis of their transport via soil leaching and infiltration into wastewater networks. Rainfall could also be a direct source of PAEs to the lagoon resulting in net surplus export of PAEs to the Baltic Sea.

Causality analysis of large-scale structures in the flow around a wall-mounted square cylinder

The aim of this work is to analyse the formation mechanisms of large-scale coherent structures in the flow around a wall-mounted square cylinder, due to their impact on pollutant transport within cities. To this end, we assess causal relations between the modes of a reduced-order model obtained by applying proper orthogonal decomposition to high-fidelity simulation data of the flow case under study. The causal relations are identified using conditional transfer entropy, which is an information-theoretical quantity that estimates the amount of information contained in the past of one variable about another. This allows for an understanding of the origins and evolution of different phenomena in the flow, with the aim of identifying the modes responsible for the formation of the main vortical structures. Our approach unveils that vortex-breaker modes are the most causal modes, in particular, over higher-order modes, and no significant causal relationships were found for vortex-generator modes. We validate this technique by determining the causal relations present in the nine-equation model of near-wall turbulence developed by Moehliset al.(New J. Phys., vol. 6, 2004, p. 56), which are in good agreement with literature results for turbulent channel flows.

Efficiency of five samplers to trap suspended particulate matter and microplastic particles of different sizes

Suspended particulate matter (SPM) plays a major role in nutrient cycles and for the transport of pollutants within local and transboundary water catchments. Obtaining representative SPM samples from rivers, lakes, inland and coastal waters is crucial for quantitative and qualitative chemical analyses to correctly describe the chemical status of a water body. However, a representative sampling of SPM over time is challenging due to the heterogeneity of SPM particles sizes, their non-uniform distribution in rivers, and a variety of sampling devices being in use. Therefore, we investigated the efficiencies of five different sampling devices commonly used in national and international monitoring programs to collect representative SPM samples. We tested three passive sedimentation-based samplers (SBSs: sedimentation box, SB; sedimentation tank, ST; Raetz Sampler, RS), and two active separation techniques (continuous flow centrifuge, CFC; vacuum filtration, VF) in an experimental laboratory setup using in-house SPM standard suspensions (mineral, organic, and microplastic particles) with defined particle sizes. The mass-based efficiencies of the three examined SBSs were 0–66% for the mineral and organic particles <75 μm, where the mean particle sizes of collected samples were always shifted to bigger sizes compared to the initial suspensions. The efficiencies of the three SBSs to collect microplastic particles <80 μm were <20% due to the lower densities of microplastic compared to organic and mineral particles. In contrast to the SBSs, VF and CFC units showed excellent efficiencies >86% for all tested materials, with similar particle size distributions of the sampled material compared to those of the inlet suspensions. In conclusion, SPM sampling efficiencies of sampling units have to be carefully considered and compared to the respective aims of the monitoring approaches, especially when statements are derived from quantitative results on SPM.

Bilevel spatial–temporal aircraft taxiing optimization considering carbon emissions

Air transportation pollution is mainly caused by aircraft carbon emissions. One of the key methods for reducing aircraft carbon emissions is to optimize the taxiing route on the airport surface. In view of this, a bilevel spatial–temporal taxiing optimization model considering carbon emissions is proposed in this paper. A bilevel programming method is deployed in the model to minimize the carbon emissions, taxiing waiting time, and conflicts of aircraft, which not only facilitates environmentally friendly airport establishment but also improve airport operation efficiency. Particularly, the influence of taxiing conflicts and turning action are considered when calculating the carbon emissions in the paper, which provides a more effective subjective for the model. An iterative neighborhood search algorithm is proposed to solve the model. The operation data of Baiyun Airport in China are utilized to validate the model. The results indicate that, compared with the first-come first-serve (FCFS), the proposed model reduces the total carbon emissions of aircraft by 814 kg on the premise of no taxiing conflict or 2% of the total. Compared with tabu search, it can reduce carbon emissions by 375 kg. This study can provide a more environmentally friendly taxiing strategy for aircraft and reduce carbon emissions.

Meteorological Formation Mechanisms and Potential Sources of an Ozone Pollution Process in Winter of 2022 in Guangdong Province

Meteorological conditions play an important role in seasonal ozone variations. In order to understand the meteorological formation mechanisms of ozone pollution in Guangdong Province in winter, the moderate ozone pollution process in Guangdong Province from January 3-6, 2022 was selected for comparison with that in autumn (high pollution season) of 2015 to 2021. The research was based on ground and vertical sounding data and reanalysis data of air quality and meteorological elements. Eight cities exceeded the standard during the pollution process, among which Zhaoqing showed moderate pollution (219 μg·m-3) on January 4th. The average O3-8h concentration in Guangdong Province was 123 μg·m-3, which was 21% higher than that in historical autumn. However, its scope of pollution was less than the historical pollution processes in autumn. Lower wind speed, longer sunshine hours, and airflow reflux effect under local circulation were the most important ground-level meteorological conditions for the ozone pollution process, whereas lower temperature might be an important reason for its small scope of pollution. Vertical detection analysis showed that the combined effect of low-level temperature inversion layer, stronger downdraft, and lower wind speed kept the NO2 concentrations at a high level, and further induced a higher increment of ozone concentration in the morning (34.2 μg·m-3 higher than that in the non-pollution period). The downward transport of ozone in the residual layer aggravated the ozone pollution on January 4th. The accumulation of ozone and its precursors was an important factor of the aggravation of ozone pollution the following day. Airflow trajectory analysis revealed that the ground-level ozone was affected by horizontal transport and vertical mixing of pollutants. Potential sources at 10 m were mainly distributed in the coastal areas from Fujian to Guangdong, and the scope of potential sources was concentrated in Guangdong as the height increased. Airflow backward trajectories at different heights during the ozone process passed over the areas of potential sources in Guangdong, which indicated that the local emissions in Guangdong had a greater impact on the ozone pollution process.

Simulation Analysis of the Dispersion of Typical Marine Pollutants by Fusion of Multiple Processes

The rapid development of coastal economies has aggravated the problem of pollution in the coastal water bodies of various countries. Numerous incidents of massive-scale marine life deaths have been reported because of the excessive discharge of industrial and agricultural wastewater. To investigate the diffusion of typical pollutants after discharge, in this study, a multi-process fusion simulation analysis model of pollutants under the action of ocean currents was established based on the concentration analysis method. Furthermore, key technologies involved, such as the parameter value, data selection, and visualization, were investigated. The iterative analysis and programming realization of three independent sub-processes, such as pollutant diffusion and transport, and the drift path and concentration distribution of pollutants after their discharge into the sea, were visualized. The case study revealed that the increase in the concentration of pollutants in the ocean was affected by the diffusion sub-process, and the transport sub-process plays a critical role in the long-distance transport of pollutants. The proposed method can provide technical support for marine environmental risk assessment and dynamic tracking of marine pollutants.

Interpretation of odor complaint records with BTEX pollutants and meteorological factors: Çorlu case study

Air pollution in urban areas increases as a result of emitted air from different sources within the mixing layer of troposphere. Odor pollution is amongst the primary reasons behind environmental nuisance and occurrence of citizen complaints. Frequent exposure to odorous compounds and/or odor nuisance are increasingly associated with air pollution problems. Besides, there is no universally accepted environmental odor management method reported so far. Level of air pollutants emission, distance of emission sources to residential areas, to-pography, geographical and meteorological conditions have influence on imposed level of air pollution and odor pollution in cities.&#x0D; &#x0D; This study is built on the citizen odor complaint data (based on frequency, intensity, duration, odor tone and location (namely the FIDOL factors) collected in Çorlu/Tekirdağ through the GIS integrated public participated platform, namely the Çorlu KODER mobile application. The annual odor complaint data was briefly introduced and given an evaluation with the mo-bile app users demographic information. The obtained data between August 28-November 2 of 2021, was subjected to interpretative evaluation and statistical analysis with BTEX (benzene, toluene, ethylene benzene and xylen) concentrations, inorganic air pollution concentrations and meteorological factors. In light of the obtained results, temperature, wind speed, relative humidity and toluene concentration were found to play a significant role on the number of citizen odor complaints. The EU reported limit value, lower rating threshold and upper rating threshold for BTEX pollutants have been exceeded several times.&#x0D; &#x0D; The average Toluene/benzene ratios obtained during the study show that; non-traffic sources contribute significantly to VOC emissions. Air pollutants transportation mechanism from neighbouring OIZ settlements become a prominent justification and support the hypothesis that residential areas of Corlu are under the effect of industrial air pollution and odor pollution con-stituents. There is low level of negative correlation between the benzene measured in Çorlu and WS (r=-0.63). Below 2.4 m/s, the average number of odor complaints (ANOC) tend to increase, while above this level odor complaints are diminished). The ANOC remained around 4 for[C] &lt; 4 ug/m3 and reached to 18 for [C]BTEXtotal &gt; 8 ug/m3. Above [C]Toluen=3 ug/m3 conditions, Daily ANOC increase from 7 to 19. Over [C]Toluen= 4 ug/m3 conditions, it reached up to 23. Increses in the number of daily ANOC by temperature is distinct over 21 C0 and reaches to 35. &#x0D; &#x0D; The GIS integrated citizen complaint collection platforms are critical for real-time data collection of environmental complaints with high spatiotemporal accuracy. Citizen odor complaint surveys are useful monitoring tools and obtained data sets can be used to identify sensitive areas where and when specific actions should be taken and air pollutants measuement studies be performed.

The HTAP_v3 emission mosaic: merging regional and global monthly emissions (2000–2018) to support air quality modelling and policies

Abstract. This study, performed under the umbrella of the Task Force on Hemispheric Transport of Air Pollution (TF-HTAP), responds to the global and regional atmospheric modelling community's need of a mosaic emission inventory of air pollutants that conforms to specific requirements: global coverage, long time series, spatially distributed emissions with high time resolution, and a high sectoral resolution. The mosaic approach of integrating official regional emission inventories based on locally reported data, with a global inventory based on a globally consistent methodology, allows modellers to perform simulations of high scientific quality while also ensuring that the results remain relevant to policymakers. HTAP_v3, an ad hoc global mosaic of anthropogenic inventories, has been developed by integrating official inventories over specific areas (North America, Europe, Asia including Japan and South Korea) with the independent Emissions Database for Global Atmospheric Research (EDGAR) inventory for the remaining world regions. The results are spatially and temporally distributed emissions of SO2, NOx, CO, non-methane volatile organic compounds (NMVOCs), NH3, PM10, PM2.5, black carbon (BC), and organic carbon (OC), with a spatial resolution of 0.1∘ × 0.1∘ and time intervals of months and years, covering the period 2000–2018 (https://doi.org/10.5281/zenodo.7516361, Crippa, 2023, https://edgar.jrc.ec.europa.eu/dataset_htap_v3, last access: June 2023). The emissions are further disaggregated into 16 anthropogenic emitting sectors. This paper describes the methodology applied to develop such an emission mosaic, reports on source allocation, differences among existing inventories, and best practices for the mosaic compilation. One of the key strengths of the HTAP_v3 emission mosaic is its temporal coverage, enabling the analysis of emission trends over the past 2 decades. The development of a global emission mosaic over such long time series represents a unique product for global air quality modelling and for better-informed policymaking, reflecting the community effort expended by the TF-HTAP to disentangle the complexity of transboundary transport of air pollution.

Intimately tracking NO2 pollution over the New York City - Long Island Sound land-water continuum: An integration of shipboard, airborne, satellite observations, and models

Nitrogen dioxide (NO2) pollution remains a serious global problem, particularly near highly populated urbanized coasts that face increasing challenges with climate change. Yet, the combined impact of urban emissions, pollution transport, and complex meteorology on the spatiotemporal dynamics of NO2 along heterogeneous urban coastlines remains poorly characterized. Here, we integrated measurements from different platforms – boats, ground-based networks, aircraft, and satellites – to characterize total column NO2 (TCNO2) dynamics across the land-water continuum in the New York metropolitan area, the most populous area in the United States that often experiences the highest national NO2 levels. Measurements were conducted during the 2018 Long Island Sound Tropospheric Ozone Study (LISTOS), with a main goal to extend surface measurements beyond the coastline – where ground-based air-quality monitoring networks abruptly stop – and over the aquatic environment where peaks in air pollution often occur. Satellite TCNO2 from TROPOMI correlated strongly with Pandora surface measurements (r = 0.87, N = 100) both over land and water. Yet, TROPOMI overall underestimated TCNO2 (MPD = -12%) and missed peaks in NO2 pollution caused by rush hour emissions or pollution accumulation during sea breezes. Aircraft retrievals were in excellent agreement with Pandora (r = 0.95, MPD = -0.3%, N = 108). Stronger agreement was found between TROPOMI, aircraft, and Pandora over land, while over water satellite, and to a lesser extent aircraft, retrievals underestimated TCNO2 particularly in the highly dynamic New York Harbor environment. Combined with model simulations, our shipborne measurements uniquely captured rapid transitions and fine-scale features in NO2 behavior across the New York City - Long Island Sound land-water continuum, driven by the complex interplay of human activity, chemistry, and local scale meteorology. These novel datasets provide critical information for improving satellite retrievals, enhancing air quality models, and informing management decisions, with important implications for the health of diverse communities and vulnerable ecosystems along this complex urban coastline.

Dispersion of Traffic Pollutants in the Built Environment

Environmental modelling software can be useful for evaluating design interventions and formulating strategies to achieve a specific purpose, such as providing outdoor thermal comfort. It is less commonly used in predicting the dispersion of street pollutants. The aim of this research is to test selected morphological patterns with respect to their influence on wind conditions and the transport of traffic pollutants, and to verify the results against previous studies. The objective of the research is to evaluate relations between building typology in interactions with urban atmosphere. The method utilises a wind tunnel simulation with a static line source of emissions. Experiment results show that the exposed urban morphology models display an impact on flow conditions and consequently on the dispersion of traffic pollutants. At the same time, the results highlight the importance of urban aerodynamic perspective, particularly of urban spaces that can be expected to be subject to higher traffic pollutants in terms of urban air pollution.

Optimizing Air Pollution Modeling with a Highly-Convergent Quasi-Monte Carlo Method: A Case Study on the UNI-DEM Framework

In this study, we present the development of an advanced air pollution modeling approach, which incorporates cutting-edge stochastic techniques for large-scale simulations of long-range air pollutant transportation. The Unified Danish Eulerian Model (UNI-DEM) serves as a crucial mathematical framework with numerous applications in studies concerning the detrimental effects of heightened air pollution levels. We employ the UNI-DEM model in our research to obtain trustworthy insights into critical questions pertaining to environmental preservation. Our proposed methodology is a highly convergent quasi-Monte Carlo technique that relies on a unique symmetrization lattice rule. By fusing the concepts of special functions and optimal generating vectors, we create a novel algorithm grounded in the component-by-component construction method, which has been recently introduced. This amalgamation yields particularly impressive outcomes for lower-dimensional cases, substantially enhancing the performance of the most advanced existing methods for calculating the Sobol sensitivity indices of the UNI-DEM model. This improvement is vital, as these indices form an essential component of the digital ecosystem for environmental analysis.

Global nitrogen and sulfur deposition mapping using a measurement–model fusion approach

Abstract. Global reactive nitrogen (N) deposition has more than tripled since 1860 and is expected to remain high due to food production and fossil fuel consumption. Global sulfur emissions have been decreasing worldwide over the last 30 years, but many regions are still experiencing unhealthily high levels of deposition. We update the 2010 global deposition budget for reactive nitrogen and sulfur components with new regional wet deposition measurements from Asia, improving the ensemble results of 11 global chemistry transport models from the second phase of the United Nations Economic Commission for Europe's Task Force on Hemispheric Transport of Air Pollution (HTAP II). The observationally adjusted global N deposition budget is 114.5 Tg N, representing a minor increase of 1 % from the model-only derived values, and the adjusted global sulfur deposition budget is 88.9 Tg S, representing a 6.5 % increase from the modeled values, using an interpolation distance of 2.5∘. Regionally, deposition adjustments can be up to ∼ 73 % for nitrogen and 112 % for sulfur. Our study demonstrates that a global measurement–model fusion approach can improve N and S deposition model estimates at a regional scale, with sufficient availability of observations; however, in large parts of the world, alternative approaches need to be explored. The analysis presented here represents a step forward toward the World Meteorological Organization's goal of global fusion products for accurately mapping harmful air pollution deposition.

Impacts of shipyard oil leakage on the PAHs and PCBs occurrence in Xiangshan Bay, China

Here, we studied the shipyard impacts on the distribution of PAHs and PCBs in the semi-enclosed Xiangshan Bay, an important mariculture zone in China. The results showed that the shipyard caused a pollution plume for PAHs but not for PCBs. As characteristic pollutants of oil leakage, the PAHs had concentrations of up to 55.82 ng L−1 in the water, 2235.04 ng g−1 in suspended particulate matter (SPM), and 1489.60 ng g−1 in sediment. The PAHs in water and SPM were dominated by phenanthrene and pyrene that were mostly derived from lubricant and diesel, while those in sediments were dominated by the high-molecular-weight PAHs, such as indeno[1,2,3-c,d]pyrene. In contrast, the PCBs concentrations reached up to 10.17 ng L−1, 79.72 ng g−1, and 124.33 ng g−1 in the seawater, SPM, and sediment samples, respectively, and they did not show spatial patterns affected by the shipyard. Moreover, the health risk assessment indicated that the shipyard discharge caused a substantial PAHs ecological risk to the adjacent and downstream water environment. Therefore, point source discharge in semi-enclosed bays should be paid close attention to due to the strong pollutant transport effect.

Comprehensive Assessment of Pollution Sources and Health Impacts in Suburban Area of Shanghai.

Shanghai, one of China's largest metropolises, faces significant environmental pollution challenges due to rapid economic development. Suburban areas of Shanghai are affected by both long-distance transport and local sources of pollutants. This study conducted an integrated analysis that links health-risk assessment of heavy metals and source apportionment of atmospheric constituents to distinguish the contributions of emission sources and the major sources of health risks. Source-apportionment analysis revealed that secondary sources had the greatest contribution to the local pollutants, indicating the significant influence of peripheral and long-distance transport. Health-risk assessment of Cr, Ni, As, and Cd revealed that local residents were exposed to respiratory health risks, in which Cr is the major contributor. This health risk was primarily associated with emissions from nearby industry-related sources. Our study highlights the significant effects of both long-distance transport and local source emissions on atmospheric composition and human health in large urban agglomerations. The findings can inform future efforts to develop more precise emission-reduction strategies and policy improvements to mitigate environmental pollution and protect public health.

Adjoint models with non-Fickian reactive transport to identify pollutant sources in water

Pollutant source identification (PSI) has remained a research topic in environmental sciences for decades for hazardous chemicals, with the assumption that the transport of pollutants is Fickian. Pollutant transport in natural media, however, is usually non-Fickian, characterized by slow retention or preferential movement, and PSI models remained unknown for non-Fickian, reactive transport. To fill this knowledge gap, an adjoint fractional advection-dispersion-reaction equation (fADRE) was derived in this study to identify the source location of reactive pollutants undergoing non-Fickian diffusion with multiple phases in subsurface water with any dimension and boundary conditions. Six fundamental chemical reactions varying from radioactive decay to bimolecular reactions were considered, whose backward-in-time rate equations were simulated by particle tracking combined with backward non-Fickian diffusion. Applications showed that the adjoint fADRE identified the source location of reactive tracer transport in “homogeneous” sand columns repacked in our laboratory and a heterogeneous alluvial aquifer in an actual field site, while the Fickian-based, classical PSI model overestimated by four times the source location of reactive pollutants undergoing strong non-Fickian transport. To expand the applicability of the adjoint fADRE for PSI, we also discussed the impacts of the immobile pollutant phase and reactive kinetics on PSI, pollutant release history recovery, and usage of PSI for complex chemical reactions. The results showed that the fundamental chemical reactions considered in this study can affect PSI by adjusting the location and value of the peak of the probability density functions under conditions such as a relatively large decay constant or a space-dependent reaction rate, and the immobile pollutants can also affect PSI by shortening the source location and elongating the release time for pollutants usually detected only in the mobile phase. Therefore, non-Fickian dynamics and pollutant phases (which were missed by the adjoint ADRE), as well as reaction kinetics, must be captured by the adjoint model, such as the adjoint fADRE derived in this study, for PSI in real-world geological media.

Cucurbita pepo contains characteristic proteins without a signal peptide in the xylem sap

Xylem sap is a fluid that transfers water and nutrients from the rhizosphere. This sap contains relatively low concentrations of proteins that originate from the extracellular space among the root cells. One of the characteristic proteins in the xylem sap of the Cucurbitaceae family, which includes cucumber and zucchini, is a major latex-like protein (MLP). MLPs are responsible for crop contamination through the transport of hydrophobic pollutants from the roots. However, detailed information on the content of MLPs in the xylem sap is not available. Proteomic analysis of root and xylem sap proteins from the Cucurbita pepo cultivars Patty Green (PG) and Raven (RA) showed that the xylem sap of cv. RA, a high accumulator of hydrophobic pollutants, contained four MLPs that accounted for over 85% of the total xylem sap proteins in this cultivar. The xylem sap of PG, a low accumulator, mainly contained an uncharacterized protein. The amount of each root protein between the PG and RA cultivars was significantly and positively correlated in spite of being with and without a signal peptide (SP). However, the amount of xylem sap proteins without an SP was not correlated. These results suggest that cv. RA is characterized by MLPs in the xylem sap.

Analytical solutions of flow velocity profile based on the morphological response of flexible vegetation

Hydrodynamics affected by vegetation in channel is one of the hot topics in ecological hydraulics. Flexible vegetation plays an important role in natural flow region, which changes flow structure and affects the transport of pollutants. Therefore, it is important to illustrate the physical process of the interaction between water flow and morphological response of flexible vegetation. Due to the complex resistance characteristics of flexible vegetation, the simulation of velocity distribution is more complicated. In this paper, velocity distribution in the form of Bessel function is derived by solving the governing equation based on linear resistance-velocity expression of flexible vegetation. Meanwhile, a new power law of velocity distribution is established by adopting the concept of vegetated riverbed. Moreover, a new expression of Darcy–Weisbach friction is derived for flow with flexible vegetation, and the relationship between vegetation bending angle and hydraulic parameters is given. Quantitative relationship between the power law index and the Darcy–Weisbach friction coefficient in the free surface layer is derived for flexible vegetated flow. This research reveals the velocity distribution characteristics under the influence of flexible vegetation and the resistance features on vegetated riverbed.

A study of 101 organic substances in gully pot sediments accumulated over a one-year period in Stockholm, Sweden

Stormwater runoff is a key pathway for diffuse pollutants to enter receiving waters. Mitigating measures include pollutant substitution, restricting their release into the urban technosphere and limiting the (re-)mobilisation of substances to minimise their negative impacts on receiving waters. Gully pots (GPs) are one of the most ubiquitous urban drainage infrastructure components, providing both a drainage function and limiting the onward transport of pollutants through in-pot sedimentation processes. In this study, sediments accumulated over a one-year period were collected from 26 GPs in catchments of four land-use types in Stockholm, Sweden. Sediments were analysed for 101 organic substances from eight substance groups (hydrocarbons, polycyclic aromatic hydrocarbons, alkylphenols, polychlorinated biphenyls, phthalates, organotins, per- and polyfluoroalkyl substances and brominated fire retardants) to inform an assessment of their occurrence and net accumulation rates over a typical unit operation period. A total of 63 substances were quantified in at least one GP, with aliphatic hydrocarbons, phthalates and organotins quantified in all GP sediments, highlighting their ubiquitous use. The identification of 14 and 21 organic substances in two pedestrian/bike path GPs emphasise the contribution of non-vehicular sources to diffuse pollutant loads. Significantly higher mass accumulation rates of 4-tert-octylphenol, 4-nonylphenols, formaldehyde, dioctyltin and dibutyltin are identified in commercial catchment GPs suggesting the need to enhance source-tracing and runoff quality-control measures within catchments of this land-use type. Sediments in 25 GPs were identified with at least one substance exceeding toxicology-based threshold values, highlighting the runoff quality-control function of GPs in reducing the potential ecotoxic impacts on recipients.