Solid Surface Research Articles

Synthesis and Characterization of Bis-Acetylacetonatozink (II) [(Zn(acac)2(H2o)

The synthesis of the bis-acetylacetonate zink (II) monohydrate complex [Zn(acac)2(H2O)] has been conducted. FTIR analysis, TGA-DSC, and SEM micrographic analysis performed complex characterization. The yield of the complex compound [Zn(acac)2(H2O)] was 36.24% using NaOH as a pH regulator. Based on the FTIR characterization of the typical absorption complex [Zn(acac)2(H2O)] appears at 763.88 cm-1 for Zn-O, C-H at 933.9 cm-1 and 1020 cm-1, C=C and C=O at 1516 cm-1, 1610 cm-1 and OH at 3450 cm-1 respectively. Thermal analysis of the complex shows that the decomposition temperature was obtained at 186oC. Based on the micrographic results, the complex has a non-uniform surface relief. The complex has an even distribution of pores with non-uniform pore sizes. Zn particles are deposited on the complex surface with various sizes to produce pores on the solid surface.

Effects of surface wettability and density change during solidification of paraffin phase change materials

Phase change materials (PCMs) are widely used for thermal energy storage and other applications. During the solidification of a PCM, a volume change occurs due to thermal expansion and structural change of the molecules. A concave shape may be created during the solidification shrinkage. This paper investigates the shrinkage profile formed during the solidification of paraffin wax and its relationship with the surface wettability (contact angle), considering the effect of density changes. The contact angle of a paraffin droplet on a surface indicates the extent of adhesion between the solid surface and paraffin. The experimental study examines a mixture of wax with nanoparticles, wax with surfactants, different coatings on the container surface, and different solidification temperatures. Enhanced adhesion and increased shrinkage height are observed due to the non-polar interaction between coated surfaces and paraffin, facilitated by induced dipole-induced dipole forces. The addition of 3% octadecylamine enhances adhesion between paraffin and the container, as driven by dipole–dipole forces between the hydroxyl group on epoxy resin-container surfaces and the hydrophilic amine group of octadecylamine. The shrinkage height increases with a decrease in the contact angle of paraffin on the surface. The shrinkage profile also changes with the solidification temperature. The highest shrinkage profile is achieved for the highest solidification temperature.

In-Plane Movement of Isolated Poly(methacrylate) Chains on a Hydrophilic Solid Surface

In-Plane Movement of Isolated Poly(methacrylate) Chains on a Hydrophilic Solid Surface

Aeroacoustics computation for propellers based on harmonic balance solution

In this paper, a novel open-source framework is presented for the evaluation of noise emissions produced by aerodynamic bodies exhibiting dominant motion at specific frequencies. This behavior is frequently encountered in propellers used for urban air mobility applications. The reduced order model called harmonic balance is employed to compute the unsteady flow solution, reducing the computational cost. The approach tackles K different frequencies by capturing the flow solution at N discrete time instances within a single period, where N is defined as 2K+1. The time history of the conservative variables on the solid surfaces is reconstructed through a Fourier interpolation. The Kirchhoff Ffowcs Williams Hawkings integral formulation, integrated into SU2, is used to compute the sound pressure level perceived by farfield observers. The integral formulation propagates the acoustic solution with a computational cost independent of observer distance. The noise emission of a pitching wing and a propeller is computed with the proposed framework. Regarding a small, isolated propeller operating at low Reynolds numbers in forward flight, we conducted a comparison of the aerodynamic and aeroacoustic results between a fully time-accurate solution and a steady-state Reynolds Averaged Navier-Stokes solution within a rotating reference frame. The harmonic balance results demonstrated improved agreement with the fully unsteady solution across the first three blade-pass frequencies and exhibited this consistency over a broader range of propagation angles.

Environmental fate of monosodium methanearsonate (MSMA)-Part 1: Conceptual model.

Monosodium methanearsonate (MSMA), the sodium salt of monomethylarsonic acid (MMA), is used as a selective, broad-spectrum contact herbicide to control weeds in cotton and a variety of turf. In water, MSMA dissociates into ions of sodium (Na+) and of MMA-, which is the herbicide's active component. Certain soil microorganisms can methylate MMA to dimethylarsinic acid (DMA) other microorganisms can demethylate MMA to inorganic arsenic (iAs). To predict the groundwater concentration of iAs that may result from MSMA application, the processes affecting the environmental behavior of MSMA must be quantified and modeled. There is an extensive body of literature regarding the environmental behavior of MSMA. There is a consensus among scientists that the fate of MMA in soil is controlled by microbial activity and sorption to solid surfaces and that iAs sorption is even more extensive than that of MMA. The sorption and transformation of MMA and its metabolites are affected by several factors including aeration condition, temperature, pH, and the availability of nutrients. The precise nature and extent of each of these processes vary depending on site-specific conditions; however, such variability is constrained in typical MSMA use areas that are highly managed. Monomethylarsonic acid is strongly sorbed on mineral surfaces and becomes sequestered into the soil matrix. Over time, a greater portion of MMA and iAs becomes immobile and unavailable to soil microorganisms and to leaching. This review synthesizes the results of studies that are relevant for the behavior of MSMA used as a herbicide to reliably predict the fate of MSMA in its use conditions. Integr Environ Assess Manag 2024;20:1859-1875. © 2024 The Author(s). Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

Prehydrated Electrons Activated by Continuous Electron Transfer Stemmed from Peracetic Acid Homolysis Mediated by Diamond Surface Defects for Enhanced PFOA Destruction.

Research on the use of peracetic acid (PAA) activated by nonmetal solid catalysts for the removal of dissolved refractory organic compounds has gained attention recently due to its improved efficiency and suitability for advanced water treatment (AWT). Among these catalysts, nanocarbon (NC) stands out as an exceptional example. In the NC-based peroxide AWT studies, the focus on the mechanism involving multimedia coordination on the NC surface (reactive species (RS) path, electron reduction non-RS pathway, and singlet oxygen non-RS path) has been confined to the one-step electron reaction, leaving the mechanisms of multichannel or continuous electron transfer paths unexplored. Moreover, there are very few studies that have identified the nonfree radical pathway initiated by electron transfer within PAA AWT. In this study, the complete decomposition (kobs = 0.1995) and significant defluorination of perfluorooctanoic acid (PFOA, deF% = 72%) through PAA/NC has been confirmed. Through the use of multiple electrochemical monitors and the exploration of current diffusion effects, the process of electron reception and conduction stimulated by PAA activation was examined, leading to the discovery of the dynamic process from the PAA molecule → NC solid surface → target object. The vital role of prehydrated electrons (epre-) before the entry of resolvable electrons into the aqueous phase was also detailed. To the best of our knowledge, this is the first instance of identifying the nonradical mechanism of continuous electron transfer in PAA-based AWT, which deviates from the previously identified mechanisms of singlet oxygen, single-electron, or double-electron single-path transfer. The pathway, along with the strong reducibility of epre- initiated by this pathway, has been proven to be essential in reducing the need for catalysts and chemicals in AWT.

Synergistic Effect of Multilayered Alginate/Poly(SBMA) Coatings on Marine Antifouling Property.

Alginate (Alg) coatings have attracted attention as protective layers on solid surfaces for marine antifouling applications due to their strong water binding capability and environmentally friendly characteristics. However, the effectiveness of Alg coatings in preventing marine fouling diminishes upon interaction with divalent cations present in seawater. To address this issue, post-modification of the Alg coating is conducted. The carboxyl groups of Alg, which are susceptible sites for interaction with divalent cations, are conjugated with polymerization initiators through metal-mediated coordination bond formation. Subsequently, poly(sulfobetaine methacrylate) (poly(SBMA)) brushes are grown from the initiator-immobilized Alg coatings, resulting in the formation of multilayered Alg/poly(SBMA) coatings. In marine diatom adhesion assays using Amphora Coffeaeformis, multilayered Alg/poly(SBMA) coatings exhibited superior antifouling performance compared to single-layered Alg or poly(SBMA) coating controls.

Manipulating the hydrophilic / hydrophobic balance in novel cationic surfactants by ethoxylation: The impact on adsorption and self-assembly

HypothesisCationic surfactants have a wide range of applications, often associated with their affinity for a range of solid surfaces and their anti-microbial properties. Manipulating their adsorption and self-assembly properties is key to most applications, and this is commonly achieved through surfactant mixtures or manipulating their headgroup or alkyl chain structure. Achieving this through adjustments to their headgroup structure is less common in cationic surfactants than in anionic surfactants. Ethoxylation provides the ability to adjust the hydrophilic / hydrophobic balance, as extensively demonstrated in a range of anionic surfactants. ExperimentsThis same approach has been applied here to a range of ethoxylated cationic surfactants in the form of the quaternary ammonium salts, and their tertiary nonionic equivalents before quaternisation. Their adsorption and self-assembly properties are investigated using predominantly the neutron scattering techniques of neutron reflectivity, NR, and small angle neutron scattering, SANS. FindingsThe trends in the adsorption at the air–water interface and the self-assembly in aqueous solution demonstrate how the hydrophilic / hydrophobic balance can be adjusted by varying the degree of ethoxylation and the alkyl chain length, and illustrate the degree of interdependence of the different structural changes. The variation in the adsorption and the micelle structure shows how the surfactant conformation / packing changes as the degree of ethoxylation and alkyl chain length increases and how the introduction of charge induces further changes.

Modelowanie cyfrowe w celu przewidywania zagrożenia osuwania się gruntu na wybranym obszarze; Przypadek testowy Ponzano (Włochy)

Creating a digital model is one of the aims of the geotechnical engineers, to predict the land sliding hazard which occur in different regions in the world. In February 2017, an extensive landslide occurred in the hamlet of Ponzano as a sloped area in the Abruzzo region in Italy. In this regard, predicting the land sliding hazard is one of the important issues to prevent hazard to the civilizations. In this project we created a model in the 3D dimension through the Plaxis 3D numerical solution software from the data based of the region Abruzzo in 2007 to evaluate the land sliding hazard before happened and then compare the results with the data from the drone data surveyed recently in the 2022. In this regard, the data from the Abruzzo resources from 2007 imported into the QGIS as the open-source cross-platform software to analysis the geospatial data and then imported into the Recap software to work on the point cloud data and then imported into the Civil 3D software to create a solid surface from the TIN surface and finally since the solid surface contains a large number of irrelative details, they were imported into the Rhinoceros software to create a NURBS surface to be smoothed for better performance in the analysis. The NURBS surface imported into the Plaxis and all of the geometry and geotechnical engineering parameters by considering the investigated geotechnical survey that was conducted in parallel in the area, defined for the model. The “Hardening Soil” model considered for the 1st layer as the “clay and lime” and the “Hoek-Brown” model defined for the 2nd layer as the “marl-flysch”. A fine mesh elements distribution assessed also for the model. The phases defined as the “gravity” to define the unit weight of the soil layers, the “plastic” phase to calculate the instant deformations and the “consolidation” to analyze the plastic deformations in the sloped area of the model. In parallel, the drone data achieved in 2022, were imported into the CloudCompare as the 3D point cloud processing software and different methods such as the “segment”, “statistical outlier Filter”, “CSF filter”, “noise filter”, “cross section” etc. were performed to clean the data and then imported into the Recap software to work on data and then imported into the Civil 3D software to create solid surface of the current data after the land sliding. In this regard, to evaluate the displacement occurred from the year 2007 toward the 2022, a TIN volume surface as the colored map created through the Civil 3D software to show the displacements in the z direction and all of the results were compared with the Plaxis 3D numerical solution software. The results showed that the colored map with the displacement in the positive and negative direction of the z is the same of the analyzed model and the values match each other’s and we created a digital model of the selected area to predict the land sliding hazard in the region in the following.

Numerical simulation of magnetohydrodynamics double-diffusive natural convection in a cavity with non-uniform heated walls

The fluid flow in a closed domain with heat and mass transfer has enormous applications in thermal engineering. Specifically, the natural convection with fin has applications in cooling electronic devices, automobile engines, solar collectors, etc. So, this research aims to explore the simultaneous aspects of the natural convection flow of heat and mass transfer, as well as the entropy generation in a square cavity with four fins attached diagonally at each corner and a circular object in the center. The enclosure is filled with non-Newtonian fluid and an inclined magnetic field is applied. The left and right walls are heated by non-uniform linear increasing temperature (Th) having higher concentration (CL). The governing equations are first transformed to dimensionless form and then the finite element method is utilized to resolve it. The parameters and inclusion of fins are deeply analyzed to flow particularities. It is inspected that flow is more consistent in the absence of fins giving rise to more heat and mass transport. The maximum entropy is found in the vicinity of fins corners and solid surfaces. Due to non-uniform heating, negative gradients can also be achieved on the heated walls. Parameters impacts revealed that increasing the Hartmann number (Ha) decreases the kinetic energy, heat and mass transfer rate, and entropy generation. Almost three times lesser kinetic energy (K.Eavg) is obtained in the considered range of Ha. The velocity, temperature and entropy generation lead to amplification as Casson parameter (β) is enhanced. The inclusion of fins produces more resistance to fluid motion resulting in lower Nusselt (Nuavg) and Sherwood number (Shavg). The Higher Rayleigh number (Ra) can motivate the velocity and result in smaller Bejan number.

ГРАФИЧЕСКИЕ СРЕДСТВА ОПЕРАЦИОННЫХ СИСТЕМ

The methods of processing multimedia and graphical information in operating systems are studied using the example of MCI, API and GDI interfaces of Windows operating system. The interfaces of GDI and GDI+ graphics devices are examined in detail. The capabilities and features of the OpenGL graphics library, which is commonly used in the Windows operating system, are presented. The principles of operation of the GDI interface are given. Three types of drawing tools supported by the context of the GDI interface are examined in detail: pen, brush and font. The stages of coordination of logical and physical coordinate systems are considered. The OpenGL library graphics elements (bits arrays, polygons, segments, polylines, etc.), as well as basic geometric objects and a set of polyhedra: cube, cone, torus, octahedron, icosahedron, dodecahedron and tetrahedron are considered. As an example of OpenGL library usage, a three-dimensional graphics editor was studied. It works with three-dimensional objects of various types and allows reproduction of an object in two modes (lines and a solid surface), as well as performance of following operations with a graphic object: deformation, rotation, transpositionong along axes, loading and saving on hard drive.

Clathrate Hydrate-Solid Surface Adhesive Shear Strength Measurements on Carbon Steel Surfaces.

Oil and gas flowlines operating in subsea or cold terrestrial environments face the risk of forming hydrate deposits and plugs. The pressure differential across a hydrate plug can cause the plug to detach from the pipe wall and travel through the pipeline, potentially impacting a bend or inline equipment, causing damage or injury to personnel. Therefore, the hydrate-solid adhesive shear strength is of interest in estimating the maximum allowable differential pressure across a plug during depressurization procedures before the plug is likely to detach from the pipe wall. Quantifying the changes in adhesive shear strength with time and operational conditions is essential in estimating the potential of hydrate deposits to slough from the pipe wall. This work used a force meter with a cylindrical "pig-style" probe mounted to a single axis motorized test stand to measure the force required to dislodge model THF structure II hydrate plugs in carbon steel pipes. Profilometry measurements were used to quantify the mean surface roughness and relative peak frequency of the pipe surfaces. Contact angle measurements were performed of a water droplet on pristine, sanded, and corroded pipe surfaces immersed in nonpolar solvents. The adhesive shear strength of the hydrate plugs was measured for different subcoolings, solid surface roughness, and surface wettabilities. Subcooling was shown to impact the hydrate-solid adhesive shear strength, and a mixed adhesive/cohesive failure mechanism was observed at the highest subcooling tested. The surface roughness and wettability were also shown to influence the hydrate-solid adhesive shear strength, with readily wetting corroded and sanded carbon steel surfaces resulting in greater interface adhesive strength than the pristine carbon steel system. This is likely due to a Wenzel wetting mode at the interface, resulting in a higher ratio of actual to apparent wetted area as well as establishing a mechanical interlocking mechanism.

NIR-Driven Self-Healing Phase-Change Solid Slippery Surface with Stability and Promising Antifouling and Anticorrosion Properties.

Slippery liquid-infused porous surfaces (SLIPSs) have great potential to replace traditional antifouling coatings due to their efficient, green, and broad-spectrum antifouling performance. However, the lubricant dissipation problem of SLIPS severely restricts its further development and application, and the robust SLIPS continues to be extremely challenging. Here, a composite phase-change lubricant layer consisting of paraffin, silicone oil, and MXene is designed to readily construct a stable and NIR-responsive self-healing phase-change solid slippery surface (PCSSS). Collective results showed that PCSSS could rapidly achieve phase-change transformation and complete self-healing under NIR irradiation and keep stable after high-speed water flushing, centrifugation, and ultrasonic treatment. The antifouling performance of PCSSS evaluated by protein, bacteria, and algae antiadhesion tests demonstrated the adhesion inhibition rate was as high as 99.99%. Moreover, the EIS and potentiodynamic polarization experiments indicated that PCSSS had stable and exceptional corrosion resistance (|Z|0.01Hz = 3.87 × 108 Ω·cm2) and could effectively inhibit microbiologically influenced corrosion. The 90 day actual marine test reveals that PCSSS has remarkable antifouling performance. Therefore, PCSSS presents a novel, facile, and effective strategy to construct a slippery surface with the prospect of facilitating its application in marine antifouling and corrosion protection.

Single-Electron Qubits Based on Quantum Ring States on Solid Neon Surface.

Single electrons trapped on solid-neon surfaces have recently emerged as a promising platform for charge qubits. Experimental results have revealed their exceptionally long coherence times, yet the actual quantum states of these trapped electrons, presumably on imperfectly flat neon surfaces, remain elusive. In this Letter, we examine the electron's interactions with neon surface topography, such as bumps and valleys. By evaluating the surface charges induced by the electron, we demonstrate its strong perpendicular binding to the neon surface. The Schrödinger equation for the electron's lateral motion on the curved 2D surface is then solved for extensive topographical variations. Our results reveal that surface bumps can naturally bind an electron, forming unique quantum ring states that align with experimental observations. We also show that the electron's excitation energy can be tuned using a modest magnetic field to facilitate qubit operation. This study offers a leap in our understanding of electron-on-solid-neon qubit properties and provides strategic insights on minimizing charge noise and scaling the system to propel forward quantum computing architectures.

Thermal Surface Properties, London Dispersive and Polar Surface Energy of Graphene and Carbon Materials Using Inverse Gas Chromatography at Infinite Dilution.

The determination of these surface properties is carried out using inverse gas chromatography at infinite dilution, which leads to the retention volume of organic solvents adsorbed on solid surfaces. This experimental and fundamental parameter actually reflects the surface thermodynamic interactions between injected probes and solid substrates. The London dispersion equation and the Hamieh thermal model are used to quantify the London dispersive and polar surface energy of graphenes and carbon fibers as well their Lewis acid-base constants by introducing the coupling amphoteric constant of materials. The London dispersive and polar acid-base surface energies, the free energy of adsorption, the polar enthalpy and entropy, and the Lewis acid-base constants of graphenes and carbon materials are determined. It is shown that graphene exhibited the highest values of London dispersive surface energy, polar surface energy, and Lewis acid-base constants. The highest characteristics of graphene justify its great potentiality and uses in many industrial applications.

Edge-enhanced super microgenerator based on a two-dimensional Schottky junction

Super microgenerator (SMG) refers to a generator that can efficiently convert extremely weak external stimuli into electrical energy and has a small size, high power density and long lifespan, offer ground-breaking solutions for powering wearable devices, wireless distributed sensors and implanted medical equipment. However, the friction and wear between the interfaces of ordinary microgenerator results in an extremely low lifespan. Here, we present a prototype of SMGs based on a 2D–2D (graphite–MoS2) Schottky contact in the state of structural superlubricity (no wear and nearly zero friction between two contacted solid surfaces). What is even more interesting is when the graphite flake is slid from the bulk to the edge of MoS2, the output current will enhance from 31 to 56 A m−2. Through the I–V curve measurement, we found that the conductive channel across the junction can be activated and further enhanced at the edge of MoS2 compare to bulk, which provide the explanation for the above-mentioned edge enhancement of power generation. Above results provide the design principles of high-performance SMGs based on 2D–2D Schottky junctions.

Impart of Heterogeneous Charge Polarization and Distribution on Friction at Water-Graphene Interfaces: a Density-Functional-Theory based Machine Learning Study.

Accurately characterizing friction behaviors at water-solid interfaces remains a challenge because of the dynamic nature of water molecules and temporal variations in solid surface charges. By using a density-functional-theory (DFT) based machine learning (ML) technique and long-time ML-parametrized molecular dynamics simulations, we have systematically investigated water-induced charge polarization and redistribution on graphene, as well as its impact on friction at water-graphene interfaces. Heterogeneous charge polarization and distribution are observed for water-covered graphene accompanied by the formation of electric double layers (EDLs). The introduction of defects into graphene significantly enhances the heterogeneity in charge polarization and distribution. Compared to pristine graphene, defected graphene exhibits reduced friction at water-graphene interfaces due to stronger charge heterogeneity, resulting in lower surface charge density and the inverse relationship between slip length and surface charge density for EDLs. Our results highlight the pivotal roles of defects and charge heterogeneity in reducing friction at water-graphene interfaces.

Direct observation of ordered-disordered structural transition of MoS2-confined ionic liquids

Ionic liquids (ILs) are an emerging class of media of fundamental importance for chemical engineering, especially due to their interaction with solid surfaces. Here, we explore the growth phenomenon of surface-confined ILs and reveal a peculiar structural transition behavior from order to disorder above a threshold thickness. This behavior can be explained by the variation of interfacial forces with increasing distance from the solid surface. Direct structural observation of different ILs highlights the influence of the ionic structure on the growth process. Notably, the length of the alkyl chain in the cation is found to be a determining factor for the ordering trend. Also, the thermal stability of surface-confined ILs is investigated in depth by controlling annealing treatments. It is found that the ordered monolayer ILs exhibit high robustness against high temperatures. Our findings provide new perspectives on the properties of surface-confined ILs and open up potential avenues for manipulating the structures of nanometer-thick IL films for various applications.

Three-Dimensional Lattice Boltzmann Simulations for Droplet Impact and Freezing on Cold Surfaces with a Large Density Ratio

Droplet impact and freezing on solid surfaces are ubiquitous in many natural and engineering processes. Simulating the impacting-freezing process of a droplet is still challenging because it involves the complex multiphase flow and the liquid-solid phase change. This paper establishes a three-dimensional lattice Boltzmann model that considers the effects of contact angle hysteresis and volume expansion to simulate this complex process under realistic conditions. We adopt an enhanced cascaded lattice Boltzmann method to calculate the flow field and a multiple-relaxation-time scheme to solve the liquid-solid phase change model. In addition, a new contact angle model based on the pseudopotential multiphase lattice Boltzmann model is proposed to mimic the contact angle hysteresis. The simulations of droplet impact and freezing on both hydrophobic and hydrophilic surfaces with different surface temperatures and Weber numbers are conducted, and the temporal droplet profile and dimensionless contact length agree well with the experiments, which effectively validates the accuracy and robustness of the present model. Finally, the effects of surface temperatures ( 0 , − 15 , − 30 ∘ C ) and Weber numbers (4.4, 19.2, 40.0, 71.1) on droplet dynamics are also examined.

A new framework for soft x-ray transient gratings

The capability to use extreme ultraviolet (EUV) light for generating transient gratings (TGs) has enabled the study of thermoelastic and magnetic dynamics at the nanoscale, in thin solid samples and surfaces, without the need of specially modifying them. However, the current mirror-based setup for generating EUV TG limits both its extension to the soft x-ray photon energy range and the attainment of few femtosecond time-resolution. Here we propose to overcome these limitations with an alternative experimental scheme based on diffractive optical elements that has become feasible with the current technology. In addition, some aspects of the discussed setup may facilitate the implementation of the EUV TG approach at table-top high-harmonic generation sources.