Rare Earth Minerals Research Articles

In situ purification of ammonium nitrogen wastewater in rare earth mine by native bacteria isolating from original mining area

Ammonium sulfate ((NH4)2SO4) leaching method to extract rare earth elements (REEs) of mine has produced a large amount of NH4+-N-enriched wastewater derived from ore body, leading to many serious environmental pollution problems. This study was the first time to establish an in-situ treatment for real REEs wastewater outside and inside the ore body by an isolated indigenous microorganism. The results stated that Citrobacter sp. X-9 achieved the highest NH4+-N removal efficiency among the isolated six microbial strains. Moreover, the microbe to treat the REEs wastewater outside ore body gave the greatest NH4+-N removal efficiency under the optimized conditions in the Erlenmeyer flask (250-mL) and bioreactor (10-L). Furthermore, compared to the others’ modes, the in-situ treatment by cyclic mode with Citrobacter sp. X-9 possessed superior performance in NH4+-N removal efficiency for wastewater inside of ore body, showing that the established in-situ treatment was the potential approach for REEs wastewater purification.

Microbial diversity in siliceous-ferruginous sedimentary rocks from the Urals massive sulfde deposits: a review

Paleozoic siliceous-ferruginous oxide sedimentary rocks of the Urals massive sulfde deposits contain well-preserved textural and structural evidence indicating the role of microorganisms in their formation. Filamentous, rod-shaped, spherical and tubular micron-scale bacterial forms mineralized with hematite, hematite-siliceous and siliceous material are described. The flamentous forms are morphologically dominant. Authigenic apatite, Mn-calcite, Ti oxides, illite and rare earth minerals (phosphates and carbonates) are constantly associated with bacteriomorphic structures. The structures of fossil bacteria based on their size, shape, cell division, distribution in colonies and comparison with ferruginous sediments of modern hydrothermal systems and massive sulfde deposits worldwide indicate that they correspond to mineralized stalks of iron bacteria Leptothrix ochracea and Gallionella ferruginea, coccoidal forms and sulfur-oxidizing Thiobacillus Ferrooxidans and giant Beggiatoa-like organisms. These observations indicate bacterial biocatalysis in the processes of halmyrolysis of sulfdes and hyaloclasts during the formation of iron oxide deposits.

A stable method for ionic rare earth element extraction and quantitative analysis of total quantity and composition of batch samples.

The development of a stable, high-precision and batch ion-adsorption rare earth element detection method is highly anticipated in the delineation and evaluation of the mining value of rare earth element mines. In this study, a novel mixed extractant of ammonium sulfate + ammonium citrate + aceto-sodium acetate buffer was used to significantly improve the extraction efficiency of rare earth elements. Following a series of parameter optimizations, an off-line internal standard addition method and the collision mode of the inductively coupled plasma-mass spectrometer were used to improve the detection efficiency for batch samples, effectively eliminating oxide interference between the rare earth elements and improving the detection accuracy. The detection limit for ion-adsorption rare earth elements was 3.4 μg g-1 and the detection range was 12-8000 μg g-1. More importantly, the spiked and recovery experiments carried out in multiple laboratories with internal quality control samples show that the relative deviation was -5.61 to 3.79%, which indicates that the method has sufficient stability. Establishment of this method will help to improve the comprehensive utilization efficiency of rare earth resources and provide important support for rare earth element mining.

Rare earth element erbium induces immune toxicity through the ROS/NF-κB pathway in zebrafish.

The large-scale mining and utilization of rare earth elements have significantly increased their concentration in the environment, especially in regions surrounding mining areas. These environmentally-enriched rare earth elements accumulate in agricultural products and organisms through soil and water, potentially impacting in human health through the food chain. Erbium (Er), a rare earth element of the lanthanide series (Group IIIB), plays a crucial role in various modern technological applications. It is primarily utilized in ceramics, glass coloring, optical fibers, laser technology, and the nuclear industry, among others. However, a paucity of information on the health effects and ecotoxicity of erbium is currently available. In this study, we used the zebrafish as experimental animal to investigate the potential impact of the rare earth element erbium on the immune system. We exposed fertilized zebrafish embryos to different concentrations of erbium (0, 4, 8 and 16mg/L) from 6hours post-fertilization (hpf) until 72 hpf. We found that with increasing concentrations of erbium exposure, there was an increasing and dispersing trend in the number of zebrafish neutrophils; a decreasing trend in the number of macrophages. Exposure to erbium was demonstrated to impair the phagocytic capability of macrophages, reduce the recruitment of neutrophils to the wound site, and lower the resistance of zebrafish to Escherichia coli infection. Erbium exposure led to macrophage apoptosis and upregulation of oxidative stress in the zebrafish. The individual application of the reactive oxygen species (ROS) scavenger N-acetyl-L-cysteine, the IKBKB inhibitor resveratrol and the NF-κB inhibitor andrographolide were demonstrated to alleviate erbium-induced immune toxicity, as confirmed by assays including acridine orange staining, neutrophils enumeration and recruitment, and real-time quantitative PCR. Therefore, the rare earth element erbium induced immune toxicity in zebrafish through the ROS/NF-κB pathway. The findings of this study provide information for assessing the impact of rare earth elements on human health and ecosystems.

Recruitment of copiotrophic and autotrophic bacteria by hyperaccumulators enhances nutrient cycling to reclaim degraded soils at abandoned rare earth elements mining sites.

Hyperaccumulators harbor potentials for remediating rare earth elements (REEs)-contaminated soils. However, how they thrive in low-nutrient abandoned REEs mining sites is poorly understood. Three ferns (REEs-hyperaccumulators Dicranopteris pedata and Blechnum orientale, and non-hyperaccumulator Pteris vittata) along with their rhizosphere soils were collected to answer this question by comparing differences in soil nutrient levels, soil and plant REEs concentrations, and bacterial diversity, composition, and functions. Results observed lower soil pH (4.67-4.95 vs. 7.96), total carbon (TC) (0.35-0.62 vs. 2.84 g kg-1), total nitrogen (TN) (20-23 vs. 133 mg kg-1), and total phosphorus (TP) (81-91 vs. 133 mg kg-1) at sites Dp and Bo than site Pv. Hyperaccumulators efficiently extracted soil REEs and translocated them to fronds (up to 6897-7759 mg kg-1). Bacterial α diversity in three soils did not significantly vary. In contrast, bacterial composition at sites Dp and Bo was dominant by higher abundances of copiotrophic bacteria (18 % vs. 12 %, p_Actinomycetota; 3.3-8.3 % vs. 1.9 %, p_Bacteroidota; 8.3-14 % vs. 6.9 %, c_Gammaproteobacteria) and autotrophic bacteria (18 % vs. 13 %, p_Chloroflexota; 13 % vs. 8.6 %, p_Cyanobacteriota) when compared to site Pv. These bacteria likely acted as nutrient cyclers that promoted the growth of hyperaccumulators, based on functional predictions from DiTing analyses. This study provides new insights into nutrient recovery in abandoned REEs mining sites, offering strategies to reclaim degraded soils using phyto-microbial technology.

3D mineral quantification of particulate materials with Rare Earth Mineral inclusions: Achieving sub-voxel resolution by considering the partial volume and blurring effect

3D mineral quantification of particulate materials with Rare Earth Mineral inclusions: Achieving sub-voxel resolution by considering the partial volume and blurring effect

Enhanced treatment efficiency of diluted rare earth mining wastewater using acid-resistant Parachlorella kessleri FM2 in mixotrophic mode

Enhanced treatment efficiency of diluted rare earth mining wastewater using acid-resistant Parachlorella kessleri FM2 in mixotrophic mode

ОСОБЕННОСТИ ФОРМИРОВАНИЯ ЭЛЕМЕНТНОГО СОСТАВА ПОЧВ В КОНТРАСТНЫХ ГЕОЛОГИЧЕСКИХ УСЛОВИЯХ (р. МЗЫМТА, ЧЕРНОМОРСКОЕ ПОБЕРЕЖЬЕ РОССИИ)

The Mzymta River (Black Sea coast, Russia) erodes different types of rocks. Among them, mudstones, siltstones and shales are predominating, and carbonate and clay-carbonate rocks are present in smaller quantities, and occasionally eruptive rocks are encountered. The area is characterized by the occurrence of polymetallic, gold, sulphide, rare-metal and rare-earth mineralization. The studies have shown that the differences in the quantitative and qualitative elemental composition of soils in the Mzymta River valley (determined by mass-spectrometric method for 61 elements) correlate with underlying rocks. The amount of rare-earth elements and their fractionation distinguishes soils formed on igneous or sedimentary soil-forming rocks. Ca/Mg ratio can be considered as a diagnostic sign of soils formed on clayey or carbonate rocks. The influence of ore mineralisation zones on soils is manifested in the close correlation of the main ore and associated elements (As, Co, Pb, Cu, Ni, Bi, Sb and Zn) with Fe and Al.

Analysis of the Effects of Different Spectral Transformation Methods on the Estimation of Chlorophyll Content of Reclaimed Vegetation in Rare Earth Mining Areas

Ion adsorption rare earths are an important strategic resource, but their leach mining causes post-mining wastelands and tailings to suffer from soil sanding, acidification, and heavy metal contamination. This makes natural vegetation recovery difficult, relying mainly on artificial reclamation; however, the reclaimed vegetation grows poorly due to environmental stress. Hyperspectral remote sensing technology, with its high efficiency, non-destructive nature, and wide-range monitoring capability, can accurately estimate the physiological parameters of reclaimed vegetation. This provides support for environmental regulation in mining areas. In this study, three typical types of reclaimed vegetation in the Lingbei Rare Earth Mining Area, Dingnan County, Ganzhou City, were analyzed. Hyperspectral data and the corresponding chlorophyll content were collected to compare the spectral differences between reclaimed and normal vegetation. The spectral data were processed using mathematical transformation, fractional order differentiation, discrete wavelet transform, and continuous wavelet transform. Sensitive bands were extracted, and multispectral transformed feature bands were integrated. Linear and machine learning regression models were used to estimate chlorophyll content. The effects of different spectral processing methods on chlorophyll estimation were then analyzed. The results showed that reclaimed vegetation had higher spectral reflectance than normal vegetation, with the red valley shifting towards the long-wave direction and a steeper red edge slope. Different spectral transformation methods impact the accuracy of chlorophyll content estimation. Using appropriate methods can improve estimation accuracy. Fusing multi-spectral transformation features can achieve relatively good results. Among the models, the random forest regression model provides the best performance in estimating the chlorophyll content of reclaimed vegetation. This study provides a scientific basis for rapid and accurate monitoring of reclaimed vegetation growth in rare earth mining areas, supporting environmental management and decision-making and contributing to ecological restoration.

Baseflow and Coupled Nitrification-Denitrification Processes Jointly Dominate Nitrate Dynamics in a Watershed Impacted by Rare Earth Mining.

Mining activities cause severe nitrogen pollution in watersheds, yet our understanding of the transport pathways, transformation processes, and control mechanisms of nitrate (NO3-) in these areas is limited. Based on nearly 4-year observations of groundwater and river in China's largest ion-adsorption rare earth mining watershed, we revealed the dynamics of NO3- and its drivers using stoichiometry-based load model, molecular biological, and multi-isotope approaches. Results indicated that the NO3- dynamics were jointly controlled by sources (precipitation, terrestrial inputs, and sediment supply) and processes (hydrological and biological). The monthly NO3- export load from the 444.4 km2 watershed was 3.72 × 105 kg. Groundwater (36 ± 26%) and soil nitrogen (25 ± 17%) were the primary exogenous sources of NO3-. Baseflow was the main hydrological pathway for legacy nitrogen into the river, contributing 66.8% of the NO3- load. Coupled nitrification-denitrification were key biological processes affecting the NO3- transformation, with denitrification contributing 58%. Burkholderia were most associated with NO3- transformation. Dissolved organic carbon and oxygen were major drivers affecting the NO3- production and consumption. This study highlights effective control and management strategies for nitrogen pollution in mining-affected watersheds, considering not only reducing nitrogen inputs but also integrating hydrological pathways and nitrogen transformation mechanisms.

Rare Earth Elements Induce Drought Tolerance in Dicranopteris pedata from Ion-Adsorbed Rare Earth Mining Area in Southern China

The ion adsorption rare earth (IARE) mining areas in southern China frequently experience severe seasonal drought, posing significant challenges to plant growth. This study investigates the hypothesis that rare earth elements (REEs) present in these mining areas induce drought resistance in Dicranopteris pedata (D. pedata). An experiment was designed with three drought stress intensities (0%, 5%, and 10% PEG6000) and three levels of rare earth element (REE) addition (none, low, and high). After 72 h of drought stress, physiological indices and metabolomic profiles of D. pedata were examined. The results showed that under drought conditions, the REE additions increased the catalase and peroxidase activities of D. pedata by 99.04% and 81.25%, respectively, and the contents of proline, soluble proteins, and soluble sugars by 97.52%, 71.24%, and 61.81%, respectively. Metabolomic analysis revealed up-regulation of lipid and lipid-like molecules, as well as flavonoid metabolism, which contribute to improved drought resistance in D. pedata under stress. Furthermore, REE addition further up-regulated flavonoid and anthocyanin synthesis compared to drought stress alone, enhancing the plant’s resilience to drought. These findings suggest that D. pedata responds to drought stress by modulating enzyme activities, osmoregulatory substances, and metabolic pathways upon REE exposure. This study underscores the dual role of REEs in enhancing both the drought tolerance and enrichment capacity of D. pedata in IARE mining areas, which is crucial for sustaining plant growth amidst drought stress, and provides new ideas for the ecological restoration and sustainable development of IARE mining areas.

Analysis of vegetation dynamics from 2001 to 2020 in China's Ganzhou rare earth mining area using time series remote sensing and SHAP-enhanced machine learning

Rare earth mining, essential for modern industries and economic growth, often leads to severe environmental degradation. Previous research has explored the ecological impacts of rare earth mining but has not fully investigated the intricate interplay and subdivisions of environmental and anthropogenic factors driving vegetation changes over extended periods. This study addresses this gap by employing time series remote sensing and SHAP-enhanced machine learning to analyze vegetation dynamics in China's Ganzhou rare earth mining area from 2001 to 2020. Using the kNDVI derived from Landsat data, we identified three distinct vegetation trajectory types: pro-environment, des-environment, and res-environment. An ensemble machine learning model combined with SHAP analysis revealed the cropland area proportion, PM10 levels, and shrubland area proportion as the most influential factors affecting vegetation across all mining types. Additionally, after 2012, the palmer drought severity index and downward surface shortwave radiation emerged as positive contributors to vegetation health, while population pressure had a more substantial negative influence in des-environment areas. Our findings highlight spatial heterogeneity in vegetation recovery patterns and highlight the complex interactions among land cover changes, air quality, climate factors, and human activities in shaping vegetation dynamics. This study provides valuable insights for developing targeted, context-specific restoration strategies in rare earth mining areas, contributing to more sustainable mining practices and global environmental management.

The mechanism behind pressure-induced isosymmetric second-order phase transitions

Abstract Pressure-induced polymorphic phase transitions are important in fundamental physics, chemistry, materials science, and geoscience. The isosymmetric phase transition is unique in that it retains crystal symmetry through the transition and exhibits both first- and second-order characteristics. However, the underlying mechanisms of the isosymmetric second-order phase transition have not been well constrained under high pressures. Here, we report a novel case of pressure-induced isosymmetric phase transition in cerite, a rare earth element (REE) mineral, using a diamond anvil cell combined with in-situ synchrotron single-crystal X-ray diffraction. This phase transition is triggered by an increase in coordination number (CN) and exhibits characteristics of second-order. By combining our findings with previous research, we identify five distinct types of pressure-induced isosymmetric phase transitions. Furthermore, we propose an explanation for the nature (first- or second-order) of phase transitions triggered by coordination number increases under pressure. The complexity of a mineral's crystal structure plays a crucial role in determining the type of isosymmetric phase transition observed. Single-building unit crystal structures tend to exhibit first-order transitions, while those with multiple building units exhibit greater flexibility and are more prone to second-order transitions. This study provides new evidence for pressure-induced coordination number increase-triggered isosymmetric second-order phase transitions and offers valuable insights into the mechanisms governing pressure-induced isosymmetric phase transitions.

One-step pyrolysis of ZIF-8 after recovering rare earth elements from mining wastewater as a functional fenton-like catalyst

The management of rare earth elements (REEs) from mining wastewater has consistently a key issue. Our previous research has demonstrated the selective adsorption of REEs in mining wastewater by ZIF-8. Herein, one-step pyrolysis of ZIF-8 after recovering REEs from mining wastewater as a high-value product was further proposed. The resulting REEs-based magnetic nanoporous carbon materials (REEs-MPC) was utilized for the activation of peroxymonosulfate (PMS) in the removal of bisphenol A (BPA). Experimental results indicate substantial BPA removal efficiencies of 74.62 %, 83.57 %, and 70.06 % with REEs-MPC synthesized at different pyrolysis temperatures (700 °C, 800 °C, and 900 °C). The detailed characterizations reveal the REEs-MPC at 800 °C was obtained (REEs-MPC/800) exhibit prominent graphitic and defective characteristics. In addition, electrochemical analysis revealed that the REEs-MPC/800 demonstrate elevated conductivity and superior capacitive current, with Tafel slopes as high as 294 mV/dec. Functional theory (DFT) calculations demonstrate that the presence of graphitic-N and REEs-N species significantly enhance PMS activation. Finally, a neural network model constructed through machine learning techniques provided a comprehensive overview of the structure–property relationship. Overall, the proposal to synthesize a high-value product using mining wastewater has been put forward. This initiative is expected to contribute to the advancement of the green economy within the rare earth mining industry.

Pressure–temperature–time and REE mineral evolution in low- to medium-grade polymetamorphic units (Austroalpine Unit, Eastern Alps)

Abstract. We investigated rare earth element (REE) minerals in low- to medium-grade metapelites sampled in two nappes of the Austroalpine Unit (Eastern Alps, Austria). Combining microstructural and chemical characterization of the main and REE minerals with thermodynamic forward modeling, Raman spectroscopy on carbonaceous material (RSCM) thermometry and in situ U–Th–Pb dating reveal a polymetamorphic evolution of all samples. In the hanging wall nappe, allanite and REE epidote formed during Permian metamorphism (275–261 Ma, 475–520 °C, 0.3–0.4 GPa). In one sample, Cretaceous (ca. 109 Ma) REE epidote formed at ∼440 °C and 0.4–0.8 GPa at the expense of Permian monazite clusters. In the footwall nappe, large, chemically zoned monazite porphyroblasts record both Permian (283–256 Ma, 560 °C, 0.4 GPa) and Cretaceous (ca. 87 Ma, 550 °C, 1.0–1.1 GPa) metamorphism. Polymetamorphism produced a wide range of complex REE-mineral-phase relationships and microstructures. Despite the complexity, we found that bulk rock Ca, Al and Na contents are the main factor controlling REE mineral stability; variations thereof explain differences in the REE mineral assemblages of samples with identical pressure and temperature (P–T) paths. Therefore, REE minerals are also excellent geochronometers to resolve the metamorphic evolution of low- to medium-grade rocks in complex tectonic settings. The recognition that the main metamorphic signature in the hanging wall is Permian implies a marked P–T difference of ∼250 °C and at least 0.5 GPa, requiring a major normal fault between the two nappes which accommodated the exhumation of the footwall in the Cretaceous. Due to striking similarities in setting and timing, we put this low-angle detachment in context with other Late Cretaceous low-angle detachments from the Austroalpine domain. Together, they form an extensive crustal structure that we tentatively term the “Austroalpine Detachment System”.

Multi-Isotope-Based Tracing of Drainage Nitrogen Behavior and Surface and Groundwater Pathways in High-Nitrogen Rare Earth Mines

High-nitrogen mining drainage (HNMD) is a significant source of watershed nitrogen pollution, influencing the nitrogen distribution in streams through various pathways, including surface runoff (HNMDs) and subsurface runoff (HNMDg). In this study, the nitrogen contributions of HNMDs and HNMDg were characterized by using water chemistry analysis, isotope analysis, and a Bayesian stable isotope mixing model. The combined effects of HNMDs, HNMDg, and domestic sewage (DS) were found to substantially impact nitrogen dynamics in the study area. On average, HNMDs and HNMDg contributed 60.5 ± 8.8% and 19.8 ± 12.5%, respectively, to riverine nitrogen. After accounting for the exclusion of DS, the dominance of HNMDs became more pronounced, contributing 67.0 ± 4.1% and 81.9 ± 0.1% of the HNMD nitrogen in the Chakeng and Caiyang Rivers, respectively. HNMDs and HNMDg displayed distinct nitrogen discharge behaviors within the watershed, which influenced the observed variations in nitrogen fluxes. Precipitation had a stronger influence on nitrogen discharge from HNMDs compared to HNMDg. Furthermore, NH4+-N from HNMD was more likely to enter streams via surface runoff, while HNMDg served as a critical and relatively stable source of nitrogen discharge.

Development of a physical separation pre-concentration process for the extraction of Rare Earth bearing ore

This paper investigated the pre-concentration amenability of sovite (carbonatite) ore to enhance the grade of rare earth elements (REE) bearing minerals by rejecting calcite, and to improve total rare earth elements (TREE) recovery using gravity and magnetic separation. A high proportion of calcite affects downstream processes like leaching due to high acid consumption. Multiple flowsheets combining gravity and magnetic separation were employed to target > 60% TREEs recovery to the final concentrate and > 60% calcite rejection to the tailings. Head analysis of the feed showed the sample's main constituents as Fe (15.61%), Ca (16.04%), SiO2 (7.13%), and lastly TREEs (1.12%). Mineralogy liberation data at 2mm top size indicated poor liberation of TREEs, with the majority of minerals displaying < 30% mass greater than 80% liberated. Grain size distribution data showed that the majority of REE minerals are fine grained and report to the < 20 μm size class. Calcite liberation mineralogy showed < 60% mass greater than 80% liberation.A combination of a single-stage shaking table with a wet high intensity magnetic separator at a magnetic intensity of 7520 G was found to be the optimum flowsheet. For a shaking table feed with P80 of 150 μm followed by tails regrind to P80 of 45 μm as feed to wet high intensity magnetic separator, the overall mass balance results showed that 60.5% TREEs are recovered to the concentrate while 63.0% calcite is rejected to the tails. However, due to the fine-grained nature of TREEs, no flowsheet improved their grade.

Geophysical Methods Applied to the Mineralization Discovery of Rare-Earth Elements at the Fazenda Buriti Alkaline Complex, Goiás Alkaline Province, Brazil

In this case study, exploratory techniques were applied for the selection of potential targets for rare-earth elements (REEs) in the Fazenda Buriti Mafic–Ultramafic Complex, part of the Goiás Alkaline Province. The results of the processing and interpretation of aeromagnetic and radiometric data associated with the direct measurements of magnetic susceptibility and radiometry in rock samples collected in the study area allowed for the characterization and delimitation of the geological units. The application of Boolean logic in the radiometric data of uranium (U), thorium (Th), and the U/Th ratio allowed for the generation of a prospective map with the delimitation of two exploration targets. A 100 m deep exploratory drill hole was drilled at the main target, intercepting REE mineralization and validating the developed prospective technique. The results contributed to the detailing of a 1:25,000 scale geological map and the interpretation of shallow and deep magnetic structures. Petrophysical data allowed for the estimation of the magnetite content in the main units of the study area. The delimitation of targets with the applied method proved to be efficient after positive geochemical results for REE from the drilled rocks. The total sum of ∑REEs reached 19,629 ppm in the superficial part of the hole and 3,560 ppm in the fresh rock. Mineralogical results in two follow-up drill core samples indicated that monazite was the main REE mineral. Total REE ranged from 34,746 ppm in HG1 to 30,017 ppm in HG2, with LREEs in its majority. The bulk and clay XRD analyses indicated that monazite consisted of 5.7% (HG1) and 5.1% (HG2). The mineral abundance from the TIMA-X analysis indicated 4.2% (HG1) and 4.4% (HG2) in monazite content.

A 35-Year Analysis of Vegetation Cover in Rare-Earth Mining Areas Using Landsat Data

Fractional vegetation cover (FVC) plays a significant role in assessing ecological quality and protection, as well as soil and water conservation. As a typical rare-earth resource county in China, Dingnan County has experienced rapid development due to rare-earth mining, resulting in significant alterations to vegetation cover. To elucidate the spatio-temporal changes in vegetation within Dingnan County over the past 35 years and the effects of natural and human factors on these changes, the spatial and temporal variations in FVC were analyzed using Landsat-TM/OLI multispectral images taken in 1988, 1995, 1997, 2002, 2006, 2013, 2017, and 2023. The findings indicate that (1) vegetation coverage in Dingnan County decreased from 1988 to 2002, followed by a gradual increase; (2) high vegetation cover is predominantly found in forested areas that maintain their natural state, while the central town and mining areas exhibit generally low coverage; (3) there are regional differences in the relationship between vegetation cover and environmental factors in Dingnan County. This research facilitates the alignment of ion-type rare-earth mining with ecological protection, thereby promoting the sustainable development of the mining area and providing scientific guidance for local governments to formulate more effective management and protection strategies for the mining ecosystem. Additionally, this research offers a scientific foundation for mining areas globally to develop sustainable policies and informed decision-making regarding environmental protection and sustainable development.

Thermal decomposition behavior and kinetic mechanism of waste phosphors during sodium hydroxide roasting

Waste phosphors are critical rare earth secondary resources, and their recycling can help alleviate the depletion of rare earth mineral resources. However, stable Al–Mg spinel structures exist in waste phosphors. The direct acid leaching method remains difficult to use for leaching cerium and terbium. In this paper, the waste phosphors were first pretreated via alkali roasting. NaOH was used as an alkali roasting agent, thus achieving the decomposition of the Al–Mg spinel structure. On the basis of thermodynamic calculations, thermal decomposition experiments were performed. The results showed that when the temperature was greater than 500°C, the waste phosphors could be decomposed into MgO, Eu2O3, Y2O3, CeO2, Tb4O7, NaAlO2, and BaO. The Ce3+ and Tb3+ in the waste phosphors were partially oxidized to Ce4+ and Tb4+, respectively, during the roasting process. The BET surface area and the average pore diameter for the roasted products also increased. Under the conditions of roasting temperature at 900°C, NaOH/sample mass ratio of 2.5, and roasting time of 150 min, the leaching efficiencies of Y, Eu, Ce, and Tb could reach 99.4 %, 99.1 %, 98.5 %, and 98.8 %. The decomposition process of waste phosphors conformed to the unreacted shrinking core model. In addition, the conversion processes of Ce and Tb depended on the chemical reaction. The results may provide a new direction of development for the resource utilization of waste phosphors.