This is a brief description of the current state of the use of software and information tools ICT in the formation of knowledge bases in education. Examples of the latest information and communication technologies (ICT) used in this area are given. The basic principles of the formation of an electronic network knowledge base in education are given. The goal of building an electronic network knowledge base in education has been determined. The described ontological and e-scenario principles of organizing an electronic network knowledge base in education in the format of an object-oriented “Prism of knowledge”. A general characteristic of the ontological method for constructing an electronic network knowledge base is given, it is based on the theory of graphs, namely, on its tree structure. This operational characteristic of the electronic script of the knowledge base, the specific information structure of its data blocks. An example of an operational tree-like graph-structure of an e-scenario of a knowledge base is given on the example of a physics curriculum for grade 10. The general characteristic of the “Web-software complex, the editor of scripts of the knowledge base” (work.inhost.com.ua) is given and its organizational structure is described. The results of the formation of an electronic network knowledge base in education in the “Knowledge Prism” format based on the use of the “Web-software complex, the knowledge base script editor” are presented. Provided like “Prism of Knowledge – Newton’s Law” and describes its characteristics. Discussion of the prospects of using the proposed method for constructing an electronic network knowledge base in the “Prism of knowledge” format, as a means of increasing the efficiency of information support for education. A conclusion is given on the relevance of the practical application of this method of forming an electronic network knowledge base on the platform of using the “Web-software complex, script editor of the knowledge base”, as a means of supporting distance education and a tool for building personal and corporate e-network knowledge bases in the “Prism of knowledge” format ... For example, such as an e-network knowledge base of lessons or curricula, electronic textbooks, presentations, etc.