Photoacoustic Sensor Research Articles

A New 3-D-Printed Nondestructive H-Like Resonant Fiber-Optic Photoacoustic Sensor for High-Sensitivity Remote Gas Sensing

A New 3-D-Printed Nondestructive H-Like Resonant Fiber-Optic Photoacoustic Sensor for High-Sensitivity Remote Gas Sensing

A Review on Photoacoustic Spectroscopy Techniques for Gas Sensing.

The rapid growth of industry and the global drive for modernization have led to an increase in gas emissions, which present significant environmental and health risks. As a result, there is a growing need for precise and sensitive gas-monitoring technologies. This review delves into the progress made regarding photoacoustic gas sensors, with a specific focus on the vital components of acoustic cells and acoustic detectors. This review highlights photoacoustic spectroscopy (PAS) as an optical detection technique, lauding its high sensitivity, selectivity, and capability to detect a wide range of gaseous species. The principles of photoacoustic gas sensors are outlined, emphasizing the use of modulated light absorption to generate heat and subsequently detect gas pressure as acoustic pressure. Additionally, this review provides an overview of recent advancements in photoacoustic gas sensor components while also discussing the applications, challenges, and limitations of these sensors. It also includes a comparative analysis of photoacoustic gas sensors and other types of gas sensors, along with potential future research directions and opportunities. The main aim of this review is to advance the understanding and development of photoacoustic gas detection technology.

A miniaturized multi-mechanism resonance-enhanced fiber optic photoacoustic multi-gas sensor

A multi-mechanism resonance-enhanced fiber-optic photoacoustic multi-gas sensor (MR-FOPMS) is reported, in which the acoustic resonance of the T-type resonator is employed for C2H2 gas sensing and the mechanical resonance of the silicon cantilever is employed for the detection of CH4 gas sensing. The silicon cantilever fiber-optic microphone and T-type photoacoustic resonator are designed using theoretical and finite element methods. The optimized cavity volume of the entire sensor is only 9.3 cm3 and the optimized silicon cantilever microphone has an ultra-high sensitivity of 62540.2 nm/Pa at the resonance. The ability of the sensor to detect multiple gases is demonstrated by simultaneous measurement of C2H2 and CH4 using two DFB lasers at 1532.8 nm and 1650.96 nm as excitation sources. The lowest detection limits of the sensor are determined to be 158 and 382 ppb for C2H2 and CH4, respectively, corresponding to normalized noise equivalent absorption coefficients of 2.82 × 10-9, 1.43 × 10-9 cm−1 W Hz−1/2, respectively.

All Fiber-Optic Photoacoustic Spectroscopy Sensor Combining Resonance and Nonresonance Photoacoustic Cells for High-Sensitivity Simultaneous Dual-Gas Sensing

All Fiber-Optic Photoacoustic Spectroscopy Sensor Combining Resonance and Nonresonance Photoacoustic Cells for High-Sensitivity Simultaneous Dual-Gas Sensing

Miniature optical fiber photoacoustic spectroscopy gas sensor based on a 3D micro-printed planar-spiral spring optomechanical resonator

Photoacoustic spectroscopy (PAS) gas sensors based on optomechanical resonators (OMRs) have garnered significant attention for ultrasensitive trace-gas detection. However, a major challenge lies in balancing small size with high performance when developing ultrasensitive miniaturized optomechanical resonant PAS (OMR-PAS) gas sensors for space-constrained applications. Here, we present a miniature optical fiber PAS gas sensor based on a planar-spiral spring OMR (PSS-OMR) that is in situ 3D micro-printed on the end-face of a fiber-optic ferrule. Experimental results demonstrate that mechanical vibrational resonance can enhance the sensor's acoustic sensitivity by over two orders of magnitude. Together with a 1.4 μL non-resonant photoacoustic cell, it can detect C2H2 gas concentration at the 45-ppb level, and its response is very fast approximating 0.2seconds. This optical fiber OMR-PAS gas sensor holds great promise for the detection or monitoring of rapidly varying trace gas in many applications ranging from production process control to industrial environmental surveillance.

Photoacoustic Imaging Sensors Based on Integrated Photonics: Challenges and Trends

AbstractUltrasound and photoacoustic imaging are important imaging modalities with significant applications in clinical diagnosis and biomedical research. However, current capacitive and piezoelectric ultrasound detectors face challenges related to sensitivity and bandwidth, particularly at higher frequencies. These challenges can hinder their ability to achieve high spatial resolution and deep penetration for imaging purposes. Optical ultrasound sensors offer high sensitivity and show great potential for developing ultrasound/photoacoustic imaging systems. Among all methods of optical ultrasound detection, integrated photonics, with its superior advantages in miniaturization, sensitivity, and integration capability with electronics, could be next‐generation photoacoustic/ultrasound imaging technology. This review explores the device structure designs and applications of ultrasound/photoacoustic sensing based on integrated photonics, analyzes their performance metrics as ultrasound detectors, and discusses some perspectives on future developments and trends in this field.

Pressure-Compensated Fiber-Optic Photoacoustic Sensors for Trace SO2 Analysis in Gas Insulation Equipment.

A high-sensitivity fiber-optic photoacoustic sensor with pressure compensation is proposed to analyze the decomposition component SO2 in high-pressure gas insulation equipment. The multiple influence mechanism of pressure on photoacoustic excitation and cantilever detection has been theoretically analyzed and verified. In the high-pressure environment, the excited photoacoustic signal is enhanced, which compensates for the loss of sensitivity of the cantilever. A fiber-optic F-P cantilever is utilized to simultaneously measure static pressure and dynamic photoacoustic wave, and a spectral demodulation method based on white light interference is applied to calculate the optical path difference of the F-P interferometer (FPI). The real-time pressure is judged through the linear relationship between the average optical path difference of FPI and the pressure, which gives the proposed fiber-optic photoacoustic sensor the inherent advantages of being uncharged and resistant to electromagnetic interference. The average optical path difference of FPI is positively related to pressure, with a responsivity of 0.6 μm/atm, which is based on changes in the refractive index of gas. In the range of 1-4 atm, the SO2 sensor has a higher detection sensitivity at high-pressure, which benefits from the pressure compensation effect. With the pressure environment of gas insulation equipment at 4 atm as the application background, the SO2 gas is tested. The detection limit is 20 ppb with an averaging time of 400 s.

High-Precision Low-Cost Mid-Infrared Photoacoustic Gas Sensor Using Aspherical Beam Shaping for Rapidly Measuring Greenhouse Gases

A high-precision low-cost mid-infrared photoacoustic sensor for greenhouse composite gases based on aspherical beam shaping is proposed and demonstrated. The assembled optical source module and luminous characteristics of infrared source are innovatively investigated and analyzed with aspherical beam shaping. The proposed aspherical-beam-shaping-technique could effectively reduce optical loss and enhance system sensitivity, achieving an effective power utilization ratio of a radiation source of 91% and sidewall noise ratio of 8.9%. Experiments verify the 1.7 times improvement in responsivity and 50% enhancement in minimum detection limit (MDL) on average. In terms of comprehensive greenhouse gas composites and with short integration time of 1 s, MDLs of CO2, CH4, N2O, NF3, SF6, PFC-14, and HFC-134a are 73 ppb, 267 ppb, 72 ppb, 81 ppb, 14 ppb, 9 ppb and 115 ppb, respectively. Furthermore, a 48 h continuous monitoring of H2O, CO2 and CH4 in the atmosphere is conducted and verifies the performance of the gas sensor. The developed sensor allows for the rapid route of low-cost and high-precision detection of multiple greenhouse gases.

Multi-pass enhanced photoacoustic sensor for open gas sensing

Multi-pass enhanced photoacoustic sensor for open gas sensing

Highly sensitive photoacoustic gas sensor based on near-concentric cavity.

The precise detection of trace gases in the atmosphere is vital for both environmental preservation and human health. Addressing the inherent challenges in enhancing the sensitivity of photoacoustic spectroscopy, a highly sensitive photoacoustic gas detection method utilizing a near-concentric cavity was proposed. By constructing a near-concentric optical cavity, laser reflections within the photoacoustic cell were substantially amplified, resulting in enhanced sensitivity of photoacoustic signal detection. Additionally, to align with the optical path characteristics of the near-concentric cavity, a miniaturized dumbbell-like photoacoustic cell was designed. Characterized by its high-frequency resonance, this design effectively mitigated background noise while maintaining a high sound pressure level. Experimental results demonstrated a remarkable enhancement in both signal intensity and signal-to-noise ratio by factors of 22.06 and 21.26, respectively, compared to traditional excitation methods. According to the 1σ standard, with a laser power of 21 mW, the setup achieved a detection limit of 10.15 ppb for NO2. The corresponding normalized noise equivalent absorption was calculated to be 2.84 × 10-9 cm-1WHz-1/2, with a gas consumption rate of merely 15.19 mL.

Fiber-Optic Photoacoustic Gas Microsensor Dual Enhanced by Helmholtz Resonator and Interferometric Cantilever.

A high-sensitivity fiber-optic photoacoustic (PA) gas microsensor is demonstrated with dual enhancement based on acoustics and detection. Due to the characteristic of small size, a Helmholtz resonator is integrated into a miniature PA sensor. The acoustically amplified PA signal is detected by a high-sensitivity fiber Fabry-Perot (F-P) interferometric cantilever. The first-order resonant frequencies of the interferometric cantilever and Helmholtz resonator are matched by subtle adjustments. The weak PA signal is significantly enhanced in a volume of only 0.35 mL, which breaks the volume limitation of the resonance modes in traditional PA sensing systems. To improve the resolution of the microsensor, a white light interferometry (WLI)-based spectral demodulation algorithm is utilized. The experimental results indicate that the minimum detection limit of acetylene (C2H2) drops to about 15 ppb with an averaging time of 100 s, corresponding to the normalized noise equivalent absorption (NNEA) coefficient of 2.7 × 10-9 W·cm-1·Hz-1/2. The dual resonance enhanced fiber-optic PA gas microsensor has the merits of high sensitivity, intrinsic safety, and compact structure.

New silicon-based micro-electro-mechanical systems for photo-acoustic trace-gas detection

The achievable sensitivity level of photo-acoustic trace-gas sensors essentially depends on the performances of the acoustic transducer. In this work, the mechanical response of different silicon-based micro-electro-mechanical systems (MEMS) is characterized, aiming at investigating both their mechanical properties, namely the resonance frequency and the quality factor, and the minimum detection limit (MDL) achievable when they are exploited as an acoustic-to-voltage transducer in a trace-gas photoacoustic setup. For this purpose, a 4.56µm Continuous-Wave (CW) quantum cascade laser (QCL) is used to excite a strong N2O roto-vibrational transition with a line strength of 2.14 × 10−19 cm/molecule, and the detection of MEMS oscillations is performed via an interferometric readout. As a general trend, the minimum detection limit decreases when the resonance frequency investigated increases, achieving a value of 15 parts per billion with a 3 dB cut-off lock-in bandwidth equal to 100 mHz, around 10 kHz.

Wavelength-modulated photoacoustic spectroscopic instrumentation system for multiple greenhouse gas detection and in-field application in the Qinling mountainous region of China

We present a sensitive and compact quantum cascade laser-based photoacoustic greenhouse gas sensor for the detection of CO2, CH4 and CO and discuss its applicability toward on-line real-time trace greenhouse gas analysis. Differential photoacoustic resonators with different dimensions were used and optimized to balance sensitivity with signal saturation. The effects of ambient parameters, gas flow rate, pressure and humidity on the photoacoustic signal and the spectral cross-interference were investigated. Thanks to the combined operation of in-house designed laser control and lock-in amplifier, the gas detection sensitivities achieved were 5.6 ppb for CH4, 0.8 ppb for CO and 17.2 ppb for CO2, signal averaging time 1 s and an excellent dynamic range beyond 6 orders of magnitude. A continuous outdoor five-day test was performed in an observation station in China’s Qinling National Botanical Garden (E longitude 108°29’, N latitude 33°43’) which demonstrated the stability and reliability of the greenhouse gas sensor.

A dual‐resonance enhanced photoacoustic spectroscopy gas sensor based on a fiber optic cantilever beam microphone and a spherical photoacoustic cell

AbstractWe propose a novel high‐performance dual‐resonance enhanced photoacoustic spectroscopy (DRE‐PAS) gas sensor based on a highly sensitive fiber optic cantilever beam microphone and a high‐Q spherical photoacoustic cell (PAC). The first‐order resonant frequency (FORF) of the spherical PAC is analyzed by finite element analysis to match the FORF of the cantilever microphone for the double resonance enhancement of the photoacoustic signal. The photoacoustic spectroscopy (PAS) system, including the DRE‐PAS sensor, a 1532.8 nm distributed feedback laser, and a high‐speed spectrometer, has been successfully exploited for trace acetylene (C2H2) detection. The experimental results show that the limit of detection (LOD) is 106.8 parts‐per‐billion (ppb) with an integral time of 1 s, and the LOD can be further reduced to 11.03 ppb by Allan‐Werle deviation for 100 s integral time. The normalized noise equivalent absorption coefficient can be obtained as 2.44 × 10−8 cm−1 WHz−1/2. The reported DRE‐PAS gas sensor has the superior characteristics of photoacoustic signal enhancement, high sensitivity, and strong antielectromagnetic interference capability, which can provide a new solution for PAS development.

Photoacoustic trace gas detection of OCS using a 2.45 mL Helmholtz resonator and a 4823.3 nm ICL light source

A miniaturized photoacoustic spectroscopy-based gas sensor is proposed for the purpose of detecting sub-ppm-level carbonyl sulfide (OCS) using a tunable mid-infrared interband cascade laser (ICL) and a Helmholtz photoacoustic cell. The tuning characteristics of the tunable ICL with a center wavelength of 4823.3 nm were investigated to achieve the optimal driving parameters. A Helmholtz photoacoustic cell with a volume of ∼2.45 mL was designed and optimized to miniaturize the measurement system. By optimizing the modulation parameters and signal processing, the system was verified to have a good linear response to OCS concentration. With a lock-in amplifier integration time of 10 s, the 1σ noise standard deviation in differential mode was 0.84 mV and a minimum detection limit (MDL) of 409.2 ppbV was achieved at atmospheric pressure and room temperature.

Fiber optic photoacoustic gas sensor enhanced by multi-pass cell with overlapping phantom spots

A neotype fiber optic photoacoustic gas sensor with overlapping phantom spots based multi-pass is proposed, which greatly improves the reflection times and the length of gas absorption path. Moreover, the detection accuracy of photoacoustic spectroscopy (PAS) system is independent of the optical interference effect caused by overlapping spots, which is different from tunable diode laser absorption spectroscopy (TDLAS) technology. A mathematical model including light beam motion space, spot size and overlap discrimination of multi-pass structure based on overlapping phantom spots is established. The incident light is reflected up to dozens of times in the resonator with a diameter of only 8 mm. The emergent light does not need to converge on a photodetector, which reduces the difficulty of adjusting the optical path and promotes the realization of overlapping phantom spots. The experimental results show that the amplitude of photoacoustic signal is improved by about 40 times compared with the single spot structure. Appling high-sensitivity optical fiber cantilever to detect the sound pressure signal. The detection limit of C2H2 gas reaches 8.2 ppt. The normalized noise equivalent absorption (NNEA) coefficient of the gas sensor is achieved to be 9.3×10−11 cm−1WHz−1/2.

Recent Technologies for Transcutaneous Oxygen and Carbon Dioxide Monitoring.

The measurement of partial pressures of oxygen (O2) and carbon dioxide (CO2) is fundamental for evaluating a patient's conditions in clinical practice. There are many ways to retrieve O2/CO2 partial pressures and concentrations. Arterial blood gas (ABG) analysis is the gold standard technique for such a purpose, but it is invasive, intermittent, and potentially painful. Among all the alternative methods for gas monitoring, non-invasive transcutaneous O2 and CO2 monitoring has been emerging since the 1970s, being able to overcome the main drawbacks of ABG analysis. Clark and Severinghaus electrodes enabled the breakthrough for transcutaneous O2 and CO2 monitoring, respectively, and in the last twenty years, many innovations have been introduced as alternatives to overcome their limitations. This review reports the most recent solutions for transcutaneous O2 and CO2 monitoring, with a particular consideration for wearable measurement systems. Luminescence-based electronic paramagnetic resonance and photoacoustic sensors are investigated. Optical sensors appear to be the most promising, giving fast and accurate measurements without the need for frequent calibrations and being suitable for integration into wearable measurement systems.

All-fiber-coupled mid-infrared quartz-enhanced photoacoustic sensors

Infrared laser-based gas sensors are mature to take the leap from laboratory prototype to outdoor operation. Considering the demand of high robustness and compactness, the reliability of the optical alignment in a sensor is the top priority. This paper proposes a solution designing an optical system embedded within a sealed metallic cylinder containing an aspheric micro-lens to couple a single-mode interband cascade laser with an indium fluoride glass fiber. The fiber output is plug & play connected to an acoustic detection module of a quartz-enhanced photoacoustic sensor (QEPAS) equipped with a fiber port, avoiding the use of any free-space optics, from the source to the detection module. To demonstrate the operability, three all-fiber-coupled QEPAS sensors were realized for detection of CH4, CO2 and NO reaching sub-ppm ultimate detection limits with a signal integration time of 100 ms.

Wavelet-Based Machine Learning Algorithms for Photoacoustic Gas Sensing

The significance of intelligent sensor systems has grown across diverse sectors, including healthcare, environmental surveillance, industrial automation, and security. Photoacoustic gas sensors are a promising type of optical gas sensor due to their high sensitivity, enhanced frequency selectivity, and fast response time. However, they have limitations such as dependence on a high-power light source, a requirement for a high-quality acoustic signal detector, and sensitivity to environmental factors, affecting their accuracy and reliability. Machine learning has great potential in the analysis and interpretation of sensor data as it can identify complex patterns and make accurate predictions based on the available data. We propose a novel approach that utilizes wavelet analysis and neural networks with enhanced architectures to improve the accuracy and sensitivity of photoacoustic gas sensors. Our proposed approach was experimentally tested for methane concentration measurements, showcasing its potential to significantly advance the field of gas detection and analysis, providing more accurate and reliable results.

Dense Multibutterfly Spots-Enhanced Miniaturized Optical Fiber Photoacoustic Gas Sensor.

A miniaturized optical fiber photoacoustic gas sensor enhanced by dense multibutterfly spots is reported for the first time. The principle of space light transmission of neglecting paraxial approximation is theoretically analyzed for designing a dense multibutterfly spots-based miniature multipass cell. In a multipass photoacoustic tube with a diameter of 16 mm, the light beam is reflected about a hundred times. The light spots on the mirror surfaces at both ends of the photoacoustic tube form a dense multibutterfly distribution. The volume of the micro multipass gas chamber is only 5.3 mL. An optical fiber cantilever based on F-P interference is utilized as a photoacoustic pressure detector. Compared with that of the single-pass structure, the gas detection ability of the photoacoustic system with dense multibutterfly spots is improved by about 50 times. The proposed miniaturized sensor realizes a detection limit of 3.4 ppb for C2H2 gas with an averaging time of 100 s. The recognized coefficients of minimum detectable absorption (αmin) and normalized noise equivalent absorption are 1.9 × 10-8 cm-1 and 8.4 × 10-10 W cm-1 Hz-1/2, respectively.