It is well known that magnetic iron oxide (Fe3O4) and carbon-based materials are good microwave absorbing materials. However, the frequency bands in which Fe3O4 absorbs electromagnetic waves are usually concentrated in the low-frequency region, whereas carbon materials are in the high-frequency region. Therefore, this study aims to deal with the limitation of the absorption bands of these two substances. In this work, this Fe3O4/C composite with high performance microwave absorption was successfully adoption of hydrothermal-calcination process using mangosteen shells as a biomass carbon material, and with a thickness of 1.97 mm, the optimal reflection loss of the sample can reach −67.49 dB, and the frequency band that can be absorbed is 4.32 GHz. The interface polarization, dipolar polarization and eddy current loss in Fe3O4 and carbon materials produce synergistic effects, and the porous conductive network increases the electromagnetic wave transmission path and generates conductive losses, which results in composites with excellent electromagnetic wave absorption properties. The findings indicated that a composite compound of Fe3O4 and carbon-based material was successfully synthesized by hydrothermal method and obtained a materials with outstanding electromagnetic wave absorption properties and high absorption bandwidth.
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