The betavoltaic effect is characterized by multiple random scatterings and high energy density exchange. The conversion of beta-particles’ energy to electric current is a sophisticated process. A GEANT4-based code is used to model the energy-loss mechanisms of emitted electrons from 63Ni radioisotope, considering the physics behind these losses (such as Coulomb scattering, nuclear stopping, and Bethe-Bloch theory) while taking into account self-absorption and backscattering factors. The study indicates the existence of a significant non-ionizing energy-loss of penetrating beta-particles that may stimulate remarkable local heating in the absorbing structure, which results in a degradation in the performance of betavoltaic batteries using 63Ni as nuclear fuel
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