Modern industrial processes generate many dynamic, associated, and multi-scale variables, which are more likely to implicit spatial-temporal associations knowledge for describing irregular changes at different times. Inspired by this, a novel spatial-temporal associations representation method is proposed for process monitoring. Specifically, numerous variables and their associations simultaneously can be utilized to construct a static graph network snapshot. Then, graph network snapshots corresponding to process states at different times are fed into a graph convolutional neural network to implement graph classification. Finally, process monitoring is realized by continuously identifying each snapshot. Monitoring feasibility and applicability are demonstrated by the Tennessee Eastman (TE) benchmark and cobalt removal process application.