Multilayer Ceramic Chip Capacitors Research Articles

Exceptional dielectric and varistor properties of Sr, Zn and Sn co-doped calcium copper titanate ceramics.

Calcium copper titanate (CCTO) powders associated with the chemical formula Ca1-x Sr x Cu3-y Zn y Ti4-z Sn z O12 (where x, y, z varying from 0 to 0.1) were synthesized via a solid-state reaction route. Dense ceramics (>96% of theoretical density) were obtained by sintering these powders comprising micrometer-sized grains at appropriate temperatures. X-ray powder diffraction studies confirmed the formation of monophasic CCTO cubic phase, with no traceable secondary phases present. The lattice parameter 'a' was found to increase on increasing the dopant concentration. The microstructural studies performed on these ceramics confirmed a decrease in mean grain size (18 μm to 5 μm) with the increase in Sr, Zn and Sn doping concentrations as compared to that of undoped CCTO ceramics though they were sintered at the same temperature and duration (1100 °C/15 h). The dielectric studies (dielectric constant (ε') and the dielectric loss (D)) conducted in a wide frequency range (102-107 Hz) demonstrated an increase in ε' and a decrease in D on increasing the doping concentration. Impedance analysis (Nyquist plots) performed on these ceramics revealed a significant increase in grain boundary resistance. The highest value of grain boundary resistance (6.05 × 108 Ω) (in fact this value was 100 times higher than that of pure CCTO) was obtained for the composition corresponding to x = y = z = 0.075 and intriguingly the ceramic pertaining to this composition exhibited enhanced ε' (1.7 × 104) and lower D (0.024) at 1 kHz. Further, these co-doped CCTO ceramics exhibited substantial improvement in breakdown voltages and nonlinear coefficients (α). The temperature independent (30 -210 °C) dielectric response of these samples qualifies them to be suitable dielectric materials for the fabrication of multilayer ceramic chip capacitors.

Electrocaloric Performance of Multilayer Ceramic Chips: Effect of Geometric Structure Induced Internal Stress

Driven by an ever-growing demand for environmentally benign cooling systems, the past decade has witnessed the booming development in the field of electrocaloric (EC) cooling technology, which is considered as a promising solid-state cooling approach. Multilayer ceramic chip capacitors (MLCCs) represent the optimum structure for EC cooling elements because of large breakdown strengths, low driving voltages, and high macroscopic volumes of active EC materials. However, fundamental relationships between the geometric parameters of MLCCs and the EC coefficient are less understood. In this study, 0.92Pb(Mg1/3Nb2/3)O3-0.08PbTiO3 (PMN-PT) MLCCs with controlled configurations, such as active/inactive layer thickness, number of layers, and active volume ratio, were fabricated, and their EC performance was evaluated. The electric properties of the MLCCs are confirmed to be closely related to the geometric structure, which influences not only the heat flow but also the internal stress, resulting in the variability of EC performance and reliability/breakdown strength. The internal stress arises due to the residual thermal stress originating from the densification-related shrinkage, thermal expansion mismatch during the sintering, and clamping stress arising from the inactive area due to the large strain from the active area under a high electric field. The geometric structure-based stress distribution and the magnitude of stress on the active layers in MLCCs were determined by finite element modeling (FEM) and correlated with the experimental EC coefficients. The results reveal that a low inactive volume percentage is beneficial toward increasing the breakdown field and enhancement of EC performance because of reduced clamping stress on active EC material.

Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing.

This paper shows a straightforward method for printing multilayer composite capacitors with three dielectric layers on flexible substrates. As known from multilayer ceramic chip capacitors (MLCCs), it is possible to create a parallel connection of the layers without enlarging the needed area. Hence, the overall capacitance is increased, as the capacitances of the single dielectric layers add up. To realize printed capacitors, a special ceramic/polymer composite ink is used. The ink consists of surface-modified Ba0.6Sr0.4TiO3 (BST), a polymeric crosslinking agent and a thermal initiator, which allows an immediate polymerization of the ink, leading to very homogenous layers. The dielectric behavior of the capacitors is examined for each completed dielectric layer (via impedance spectroscopy) so that the changes with every following layer can be analyzed. It is demonstrated that the concept works, and capacitors with up to 3420 pF were realized (permittivity of ~40). However, it was also shown that the biggest challenge is the printing of the needed silver electrodes. They show a strong coffee stain effect, leading to thicker edge areas, which are difficult to overprint. Only with the help of printed supporting structures was it possible to lower the failure rate when printing thin dielectric layers.

Characterization of Multi-Layer Ceramic Chip Capacitors up to mm-Wave Frequencies for High-Speed Digital Signal Coupling

Characterization of Multi-Layer Ceramic Chip Capacitors up to mm-Wave Frequencies for High-Speed Digital Signal Coupling

Multi-Objective Optimization of Decoupling Capacitors for Placement and Component Value

A multiobjective evolutionary method is proposed for the optimization of surface mount device (SMD) multilayer ceramic chip (MLCC) capacitors used for decoupling on printed circuit boards (PCBs) with resonant power–ground plane pairs. The proposed approach provides options for designers to meet power integrity specifications by employing uniform-valued capacitors that help to reduce the bill-of-material (BOM) cost and mitigate the part procurement risk. It is also shown that uniform MLCC capacitors with variable distance from power pins can have a similar decoupling effect to an assortment of capacitors. By simultaneously optimizing the pin-capacitor distance and value, the proposed method is shown to allow for the allocation of fewer decoupling capacitors under the ball-grid-array (BGA) pin field of an integrated circuit (IC) device.

2/3 and 1/2 Reconfigurable Switched Capacitor DC–DC Converter With 92.9% Efficiency at 62 mW/mm2 Using Driver Amplitude Doubler

A 2/3 and 1/2 reconfigurable switched capacitor (SC) dc–dc converter is developed for a per-core dynamic voltage scaling of many-core microprocessors. The power conversion efficiency and the output power density of the SC dc–dc converter in 2/3 mode is degraded, because full-swing and half-swing drivers for power transistors are mixed and the resistive loss of the power MOSFETs with the half-swing drivers is large. To solve the problem, a fully integrated driver amplitude doubler (DAD) is proposed. In DAD, the gate amplitude of the power MOSFETs is increased from half-swing to full-swing by generating a 1/3 input voltage sampled from a flying capacitor. In the fabricated 2.7-V input SC dc–dc converter mounting four 100-nF 0402 (0.4 mm $\boldsymbol {\times } \,\, 0.2$ mm $\boldsymbol \times0.2$ mm) multilayer ceramic chip capacitors on 180-nm CMOS die achieves the highest efficiency of 92.9% at the output power density of 62 mW/mm2 in the published step-down SC dc–dc converters.

Enhanced temperature-stable dielectric properties in oxygen annealed 0.85(K0.5Na0.5)NbO3-0.15SrZrO3 ceramic

The structure, morphology and dielectric properties of the oxygen annealed (O2-annealed) and untreated (as-prepared) 0.85(K0.5Na0.5) NbO3-0·15SrZrO3 (KNN-15SZ) ceramics were investigated. The temperature dependence of dielectric permittivity shows two diffuse dielectric peaks associated with duplex core-shell structure, leading to relatively stable dielectric permittivity in a wide temperature range. Interestingly, the O2-annealed sample with the operating temperature range of −104 °C–157 °C could meet the EIA X8R specification, which is superior to the as-prepared one (−98 °C–130 °C) for the EIA X7R specification. Furthermore, the dielectric contribution from cores and shells of both samples was divided by the Lorentz fitting. The relation between relaxation frequency and temperature of both samples obeyed the Vogel-Fulcher law. This finding could pave a possible way to modify dielectric temperature stability for multilayer ceramic chip capacitors applications.

Nondestructive Failure Analysis and Simulation of Encapsulated 0402 Multilayer Ceramic Chip Capacitors Under Thermal and Mechanical Loading

The use of multilayer ceramic chip capacitors as integrated passive in, e.g., system in package applications needs methods to examine and predict their reliability. Therefore, a nondestructive failure analytical technique is described to detect cracks in the ceramic and the metallic layers within encapsulated 0402 surface mount device (SMD) capacitors. After choosing from techniques to reproducibly generate cracks, it is shown that an in situ capacitance measurement is a convenient method to detect these failures unambiguously. Finite element simulations support the experimental results. A reliability estimate for capacitor integrity under given loading conditions is given.

PREPARATION OF BaTiO3 FILMS FOR MLCCS BY DIRECT VAPOR DEPOSITION

ABSTRACT BaTiO3 films were deposited by the direct vapor deposition (DVD) technique to prepare thin dielectric layers for multilayer ceramic chip capacitors (MLCCs). The BaTiO3 films were successfully prepared by co-evaporation of the BaTiO3 ceramic and Ti metal source. The films deposited at room temperature and 600°C were amorphous and crystalline phases, respectively. The intensity of (110) and (111) peaks increased as Ba/Ti ratios were close to stoichiometric composition. BaTiO3 films deposited with e-beam power of 700 W showed the deposition rate of 33 nm/min. The dielectric constant and dissipation factor of BaTiO3 films measured at 1 kHz were 150 ∼ 180 and 2 ∼ 5%, respectively. The capacitance decreased with increasing the temperature and varied only between 787pF and 752pF in the temperature range 15∼ 125°C.

PREPARATION OF BaTiO3 FILMS FOR MLCCS BY DIRECT VAPOR DEPOSITION

ABSTRACT BaTiO3 films were deposited by the direct vapor deposition (DVD) technique to prepare thin dielectric layers for multilayer ceramic chip capacitors (MLCCs). The BaTiO3 films were successfully prepared by co-evaporation of the BaTiO3 ceramic and Ti metal source. The films deposited at room temperature and 600°C were amorphous and crystalline phases, respectively. The intensity of (110) and (111) peaks increased as Ba/Ti ratios were close to stoichiometric composition. BaTiO3 films deposited with e-beam power of 700 W showed the deposition rate of 33 nm/min. The dielectric constant and dissipation factor of BaTiO3 films measured at 1 kHz were 150∼ 180 and 2∼ 5%, respectively. The capacitance decreased with increasing the temperature and varied only between 787pF and 752pF in the temperature range 15∼ 125°C.

A case study: passive component inspection using a 1D wavelet transform

This paper exploits a wavelet-based scheme to inspect the surface defects and basic dimensions of 0805 Multi-layer Ceramic Chip capacitors (MLCC) using machine vision. The image of a passive component is initially processed to show only two solder plates (terminations). Then, the covariance matrix eigenvector for each boundary point generates the 1D θ-p representation to describe the angle variations at the boundaries of each termination. The 1D θ-p representation is further decomposed directly by a one-dimensional wavelet transform (1D WT). Since a single corner (an intersection of two boundary edges) and the jag corners (the surface defects) are local deviations on termination boundaries, their locations are represented as intensive and have a highly fluctuated wavelet energy at the 1st detail scale. Concerning a 0805 MLCC type of passive component, the surface defects and single corners on termination boundaries can be captured by appropriate thresholds (e.g., in wavelet energy). The basic dimensions of a passive component are simply the direct distance between located single corners. Real 0805 MLCCs are testing samples to evaluate the performance of the proposed approach. Experimental results show that the proposed method achieves a precise identification of the surface defects and measurements for basic dimensions. The proposed approach is invariant with respect to the orientation, easy to implement and free from a primitive-matching process. Therefore, it is especially suitable for various types of passive components that are similar to the 0805 MLCC in small-batch production.

Reliability Estimation and Failure Analysis of Multilayer Ceramic Chip Capacitors

This paper presents the failure analysis and the reliability estimation of a multilayer ceramic chip capacitor. For the failed samples used in an automobile engine control unit, failure analysis was made to identify the root cause of failure and it was shown that the migration and the avalanche breakdown were the dominant failure mechanisms. Next, an accelerated life testing was designed to estimate the life of the MLCC. It is assumed that Weibull lifetime distribution and the life-stress relationship proposed Prokopowicz and Vaskas. The life-stress relationship and the acceleration factor are estimated by analyzing the accelerated life test data.

Influence of Amount of BaTiO3 Organometallic-Resinate Additive on Paste and Sintering Properties of Ni Internal Electrode Films

We studied the characteristics of Ni paste used for internal electrodes of multilayer ceramic chip capacitors (MLCCs). The effect of the addition of BaTiO 3 resinate into Ni paste on the green density and sintering characteristics of Ni electrode films were evaluated. The green density of electrode films exhibited the maximum value, 5.7 g/cm 3 , at 1 mass% addition of BaTiO 3 resinate and further addition caused a decrease. From the measurement of sintering shrinkage of the electrode film, it was observed that shrinkage of electrode films increase with an increase in the amount of BaTiO 3 resinate. Similar results were measured on the surface of sintered electrode films by SEM observation.

ＭＬＣＣ端子電極用Ｃｕ粉末の粒径がペースト特性と焼結特性に及ぼす影響

The characteristics of Cu powder used for the fabrication of termination electrodes of multilayer ceramic chip capacitors (MLCCs) was evaluated. The effects of particle diameter on the sintering characteristics of Cu powder for use as electrode films were studied. A high tapping density was obtained for all pulverized Cu powders with average particle diameter of 0.5μm, 1.0μm and 5.0μm. The experimental results revealed that pulverized Cu powders were homogeneously dispersed in the paste. From shrinkage measurements in Cu electrode films with thickness of approximately 200μm, which were formed by an applicator and sintered at temperatures from 650°C to 850°C, it was observed that films composed of 0.5μm and 1.0μm Cu powders showed a larger shrinkage than that from 5.0μm Cu powder. A similar result has been observed for the microstructure of sintered electrode films.

Influence of Preparation Methods of Ni Powder and Amount of BaTiO3 Additive on Sintering Properties of Ni Internal Electrode Films.

We studied the characteristics of Ni paste used for the fabrication of internal electrodes of multilayer ceramic chip capacitors (MLCC). The effect of addition of BaTiO3 powders to Ni paste on green density and sintering characteristics of electrode films were also evaluated. Green density of Ni electrode film increased monotonically with an increase in the amount of BaTiO3 powder up to 10mass%. From the measurement of shrinkage of electrode films, it was observed that the shrinkage of Ni electrode film prepared from CVD powder was smaller than that of WCP Ni electrode film at the addition of 10mass% BaTiO3 powder. The results indicated that properties of Ni powder influenced on the shrinkage of electrode films.

Dependence of Electrode Ni Paste Properties on the Amount of Added BaTiO3 Powder.

We evaluated the characteristics of Ni paste used for the fabrication of internal electrodes of multilayer ceramic chip capacitors (MLCs). The effect of addition of BaTiO3 powders to Ni paste on green density and sintering characteristics of electrode films were also evaluated. A green density of electrode film increased monotonically with an increase in the amount of BaTiO3 powder and showed the maximum value, 5.4g/cm3, at 15mass% BaTiO3. The experimental result reversed that the added BaTiO3 particles were located into three pocket of Ni particles up to 15mass% BaTiO3. However, the addition of more BaTiO3 powder (20mass%) resulted in decrease in green density of electrode film. Because an excess addition of BaTiO3 powder may cause random packing of BaTiO3 and Ni particles in electrode films. From the measurement of shrinkage of electrode film, it was observed that the shrinkage of electrode film decreased with an increased in the amount of BaTiO3 powder. The electrode films with 20mass% BaTiO3 powder showed the same tendency as monolithic BaTiO3. The results indicated that an addition of BaTiO3 to Ni paste prevented a sintering of Ni particles. The similar results were observed from SEM observation on the surface of sintered electrode film.

Eftects of Particle Size on Sintering and Electrical Characteristics of Ni Powder for Internal Electrode of MLC.

We evaluated the characteristics of Ni powder used in the fabrication of internal electrodes of multilayer ceramic chip capacitors (MLCs). The effects of particle diameter on the sintering characteristics of Ni powder for use as electrode films were studied. A high tapping density was obtained for all pulverized Ni powders with on average particle diameter of 0.1, 0.2 and 0.4μm. The experimental results revealed that pulverized Ni powders were homogeneously dispersed in the paste. From shrinkage measurements in Ni electrode films with thickness of approximately 200μm, which were formed by an applicator and sintered at temperatures from 400 to 1000°C, it was observed that films composed of 0.1μm and 0.2μm Ni powders showed a larger shrinkage than that from 0.4μm Ni powder. A similar result has been observed for the microstructure of sintered electrode films.

Dependence of Sintered Electrode Ni Paste on Dispersed Ni Paste and Ni Powder Properties.

We evaluated the characteristics of Ni paste used for internal electrodes of multilayer ceramic chip capacitors (MLCs). The effects of dispensability of BaTiO3 powder in Ni paste and Ni powder properties on sintering characteristics of electrode films were studied. The experimental results revealed that an improvement of dispensability of BaTiO3 suppressed shrinkage of the films. It was observed that properties of Ni powder influenced on the shrinkage of electrode films, i.e., Ni powder prepared by the WCP method showed a higher shrinkage than that of the powder made by the CVD method. The similar results were observed on the surface microstructure of sintered electrode films by SEM measurements.

Effect of Sintering Properties on Large Particle Size of Ni Power for MLCs with Ni Internal Electrode.

The authors evaluated the characteristics of large particle size Ni powder used in the fabrication of internal electrodes of multilayer ceramic chip capacitors (MLCs). The effects of large particle size on the sintering characteristics of Ni powder for use as electrode films have been studied. A high green density was obtained for the increase of pulverized Ni powder of 1.0μm. The experimental results revealed that 1.0μm Ni powders were homogeneously dispersed in the paste. From shrinkage measurements of Ni electrode films with thickness of approximately 200μm, which were formed by an applicator and sintered at temperatures from 400 to 800°C, it was observed that films composed of increased amount of 1.0μm Ni powder showed a smaller shrinkage than that of 0.6μm Ni powder only. A similar result has been observed for the microstructure of sintered electrode films.

Effects of Calcination on Life Time of BaTiO3-based Multilayer Ceramic Chip Capacitors with Nickel Electrodes.

The studies on calcination have illustrated clear influence on the life time of multilayer ceramic chip capacitors with Ni electrodes by means of highly accelerated life test. Regarding the life time of the capacitors, the experimen tal results showed remarkable evidence of (1) effects of suitable amount of Fe and Mn additives, (2) homogeneous calcination with maintaining A/B≈a1.01 nonstoichiometry of ABO3 perovskite structure, and (3) high temperature calcination after completion of binder burn out. By computer aided microstructural analysis, the distribution of constituent and impurity ele ments of the capacitors were found to be dependent on calcination tempera ture. The change of the lattice constant of ABO3 at high temperatures and thermal behavior of ABO3 are also discussed.