Methane Air Research Articles

Estimation of total landfill surface methane emissions using geospatial approach combined with measured surface ambient air methane concentrations

ABSTRACT The concentration of surface air methane (CH4) measured in parts per million by volume (ppmv) near the soil/atmosphere interface should, in theory, have a positive correlation with surface methane emissions fluxes, measured in grams per square meter per day (gm−2d−1). Some researchers suggest that CH4 flux can be reasonably inferred from simple measurements of CH4 concentrations near the landfill surface. Ground-based and drone-based surface emissions monitoring (SEMs) were performed at several municipal solid waste landfills as tracer correlation method (TCM) testing was being used to measure total methane emissions from the same landfills. The TCM data and SEM data were used to establish a new simple correlation to convert surface methane concentrations in ppmv to localized surface methane emission flux in gm−2d−1. The SEM data obtained from ten ground and drone monitoring campaigns were log-transformed and geospatially treated using inverse distance weighting to the power of 2 to predict methane surface concentrations in the entire footprint of the SEM measurements area. The developed new correlation equation was then used to convert every predicted surface methane concentration to an emissions flux. The total estimate of surface emissions from the entire landfill was obtained by integrating the predicted fluxes over the area of the footprint of the SEM measurement area. The use of the new developed correlation resulted in higher total emissions estimates than other correlations reported in the literature and should be considered more conservative. Not including other factors, the proposed approach provides estimate of total methane emissions with a coefficient of variation of 20%. This study introduces a novel approach that utilizes a developed correlation between surface methane concentrations and surface emissions fluxes to estimate total methane emissions from municipal solid waste landfills or from a specified area. This study provides an additional use of the quarterly SEM data. Implications: The proposed approach provides an occasion for additional use of the easily obtainable quarterly SEMs data that can be performed by most landfills. The SEMs data are the most abundant landfill methane concentrations data. This approach gives them more benefit for the user. It is intended to convert ambient air concentrations to some estimates of surface emissions that can help landfill owners with decision making such as remediation activities or adjustments of their gas collection a systems.

How pulse energy affects ignition efficiency of DBD plasma-assisted combustion

This work aims to find how coupled energy per pulse influences the ability of a pulsed dielectric barrier discharge (DBD) plasma to ignite fuel-lean methane–air flow. For that, experiments are performed on a custom-built DBD flow reactor with a variable dielectric thickness and the discharge is operated by bursts of 10 ns duration pulses at 3 kHz repetition rate. With an increase in dielectric thickness, we observe that the coupled energy per pulse decreases even though applied voltage conditions are similar and so more pulses are required to ignite the lean mixture. Interestingly, we observe a significant increase in the minimum ignition energy (MIE) with an increase in the thickness beyond 3 mm. Moreover, the ignition kernel growth rate is much slower in the thicker dielectric cases even though total energy coupling per burst is similar. This phenomenon is investigated further by evaluating plasma parameters using electrical and optical diagnostics. Effective dielectric capacitance, discharge current, and voltage drop across the gas gap are derived from an equivalent circuit analysis, whereas plasma gas temperature and effective reduced electric field ( E/N ) are estimated from optical emission spectroscopy. From these analyses, we conclude that a thicker dielectric limits the discharge current and so the plasma filament temperature. For more than 3 mm thick dielectric cases, the filament heating per pulse is too low to achieve strong enough plasma pulse-to-pulse coupling which eventually leads to higher MIE and slower ignition kernel growth rate or the inability to ignite at all.

Oxide Scale Formation of Stainless Steels with Different Heating Methods – Effect of Hydrogen as Fuel

The evolution from natural gas usage to new technologies, such as the use of hydrogen as fuel or electricity‐based heating, strongly influences the oxidation of the stainless steel surface in the reheating furnace. Thermogravimetric tests using different simulated combustion and induction reheating conditions are performed for austenitic AISI 301, AISI 304, and ferritic AISI 444 steel grades. Simulated furnace atmospheres in combustion methods are based on methane–air, methane–oxygen, hydrogen–oxygen, and methane–hydrogen–oxygen combinations. For induction simulations, air and nitrogen are used as furnace atmospheres. The results indicate that changes in heating conditions to H2‐fueled combustion or induction only have a minor influence on the oxidation of the ferritic grade; whereas, their effects on the austenitic grades are more pronounced. The transition from a methane–air to H2–oxyfuel combustion increases the total oxidation by 1.7 and 4 times for steel grades 304 and 301, respectively; therefore, grade 304 can be considered better suited for transition for H2–oxyfuel use. The shorter induction heating considerably decreases the amount of oxide scale for austenitic grades, but the nitrogen atmosphere produces a subscale inside the steel matrix, which can hinder the descaling process.

Blowoff mechanism of airburst blast extinguishment of a methane air jet diffusion flame with micro explosive

In the study, experiments of airburst blast extinguishment of a methane-air jet diffusion flame have been conducted with 20 mg silver azide pellets, and the extinguishing processes have been observed using a high-speed camera and schlieren method. From the experimental results, we have examined the extinguishing mechanisms. When the blast wave interacts with the diffusion flame, vortex pair is generated in the flame due to the baroclinic effect which is caused by the misalignment between the pressure gradient of the blast wave and the density gradient in the combustion region. The vortical motion leads to the local extinction, and finally, the whole flame is blown off. In airburst, a reflected shock wave occurs on the ground surface. Depending on the height of burst and the distance between the explosion location and the extinguishing target, the reflected blast wave merges with the incident blast wave and the Mach stem is formed before the blast wave interferes with the diffusion flame. As a result, it is found that the extinguishing effectiveness is increased by the presence of the Mach Stem. Moreover, the optimal height of burst in the airburst blast extinguishment is clarified.

Flames with Alternating-Sign Velocity in Methane–Air and Methane–Air–Coal Dust Mixtures in a Closed Vertical Tube

Flames with Alternating-Sign Velocity in Methane–Air and Methane–Air–Coal Dust Mixtures in a Closed Vertical Tube

Parametric instability in propagating flames and the impact of hydrogen enrichment on the onset of secondary instability

A self-excited acoustic instability of laminar premixed flames propagating in an open-ended tube with a length of 700 mm and a radius of 10 mm was simulated by solving the reacting unsteady compressible Navier–Stokes equations, to understand the way of massive acoustic generation and its onset behaviors. Four fuel–air mixtures with an equivalence ratio of 1.2 were considered, namely, methane–air and methane–hydrogen–air mixtures, to identify the role of hydrogen in rich methane–air mixture. Parametric instability, which generated huge acoustic disturbance and violent flame pulsations, was observed only for a particular methane–hydrogen–air mixture with RH = 0.2, consistent with previously reported experimental observations. For the investigation of the reinforcement mechanism of acoustic instability under parametric instability, the flame surface area modulation was examined. It was found that violent subharmonic flame front pulsations could strongly modulate the flame surface area in the fundamental mode, resulting in a fluctuating heat release rate and increased thermoacoustic coupling. When hydrogen addition was small, attaining a higher level of primary instability, which is the precursor of the parametric instability, was more dominant than increasing the threshold level for the onset of the parametric instability. With larger hydrogen addition, the increase in the threshold level was more dominant than attaining a higher level of the primary instability. In particular, as the flame propagation time decreased, the level of the primary instability was saturated in larger hydrogen addition. This study elucidates the mechanism for the acoustic generation of propagating flames under the parametric instability, and the effects of hydrogen enrichment within rich methane–air mixtures.

Effect of the Ignition Position and Obstacle on Vented Methane–Air Deflagration

Effect of the Ignition Position and Obstacle on Vented Methane–Air Deflagration

Subgrid-Scale Models for Predicting Premixed Methane–Air Flame Propagating in a Chamber with a Rectangular Obstacle

Subgrid-Scale Models for Predicting Premixed Methane–Air Flame Propagating in a Chamber with a Rectangular Obstacle

Role of condensate bubbles in enhancing oil droplets and organic acid flotation

Poor adhesion of oil droplet-bubble and the inability to manage dissolved organic matter have hindered flotation efficiency. X-ray photoelectron spectroscopy (XPS) was used for this research to describe the surface chemistry of oil droplets. Multi-component condensate droplet vaporization experiments in produced water (PW). PW at different temperatures was used to investigate droplet vaporization behavior, and the interfacial energy theory and vapor boiling theory were employed to explain the vaporization nucleation mechanism. Contact angle, induction time measurements, and flotation analyses were used to assess the surface chemistry of condensate bubbles and the oil removal effect. The results revealed that when multi-component condensate was vaporized in PW at different temperatures, the light components nucleated inside the condensate droplets and generated bubbles enveloped by the condensate film, and the diameter of the bubbles rose as the temperature increased. X-ray photoelectron spectrometry (XPS) investigation showed the existence of hydrophilic oxygen-containing functional groups on the crude oil's surface. The contact angle between the condensate bubbles and the mask oil surface in PW is >150° and spreads faster, while the contact angle between the methane bubbles, the air bubbles and the oil surface are both <90°. The contact angle and the induction time decrease as the organic acid content of the water increases. Condensate bubble flotation has a greater oil removal efficiency than methane bubble and air bubble, which can achieve the extraction and flotation of emulsified oil droplets (83 %) and dissolved acid (63 %).

Investigating the Ignition and Stability Limits of Premixed Methane/Air Combustion in Micro-Channels

Understanding and improving the performance of miniature devices powered by micro-combustion have been the focus of continued attention of researchers recently. The goal of the present work is to investigate the behavior of premixed methane–air combustion in a quartz microreactor with an externally controlled wall temperature. Specifically, the impacts of the flow inlet velocity, the equivalence ratio, and the microreactor channel size are examined. This study is conducted by means of computational simulations, and the results are validated against prior experimental data, as well as by other similar studies in the literature. Utilizing simulation results with detailed chemistry, the present work provides more in-depth insight into a variety of phenomena, such as ignition, flame propagation, flames with repetitive extinctions and ignitions (FREI), and flame stabilization. In particular, the ignition, the flame span, and the FREI-related characteristics are scrutinized to understand the underlying physics of the flame stability/instability modes. It is shown that the flames appear stable at higher inlet velocities, while the FREI mode is detected at a lower inlet velocity, depending on the equivalence ratio and the channel size. The findings also explain how different operating conditions impact the flame characteristics in both stability modes.

Effect of a single nanosecond pulsed discharge on a flat methane–air flame

Successful implementation of plasma-assisted combustion in applied thermal processes heavily relies on how the plasma can be formed as it interacts with the reactive flow and what the effects are of such a plasma on the combustion process. The current study is an experimental investigation of a plasma-assisted lifted flat methane–air flame by a nanosecond pulsed discharge at atmospheric pressure. The nanosecond pulsed discharge, with a pulse duration of 4 ns and an amplitude of 30 kV to 50 kV, is used to stimulate the flame with a repetition rate of 1 Hz. The flame/plasma interactions are investigated with electrical and optical/laser diagnostics to study plasma-formation and its effect on the temperatures and formaldehyde formation. The flame speed seems to be accelerated for tens of milliseconds after the plasma stimulation, without noticeable gas temperature increase at the flame front and in the post-flame region. Formaldehyde is formed in the unburnt region while there is a slight increase in formaldehyde signal in the preheat zone. These results show that a volumetric effect of plasma-assisted combustion can be achieved with a short nanosecond plasma from a single excitation.

Characteristics of Explosion Hazards in Methane–Air Mixtures Diluted by Hydrogen

The combustion efficiency of methane can be effectively enhanced with the occurrence of hydrogen. However, the combustion characteristic of premixed methane/hydrogen/air is not fully understood. In this study, the effect of the amount of hydrogen addition on the explosion risk of premixed CH4/air combustion was fully investigated through experiments and simulations. The explosion overpressure of premixed CH4/air combustion with various hydrogen additions was measured in a standard 20 L spherical closed vessel. Meanwhile, the microscopic flame structures for the same cases were simulated using 2022 Chemkin-Pro software. The results showed that hydrogen could increase the explosion risks of premixed CH4/air combustion. The rate of key elementary reactions R38: H + O2 &lt;=&gt; O + OH and R84: OH + H2 &lt;=&gt; H + H2O in the system could be accelerated by hydrogen. The peak explosion overpressure in the closed chamber is boosted and the arrival time of peak overpressure rise rate is shortened, which raises the danger. Especially under lean and rich combustion conditions, hydrogen could potentially lead to more dangerous situations. With the increase in hydrogen concentration, the reaction rate of key elementary reactions accelerates faster, the peak explosion overpressure increases more, and the peak overpressure rise rate arrives earlier.

Explosion mitigation of methane–air mixture in combined application of HFC‐227ea/CO2 and ultrafine water mist in the pipeline

AbstractIn order to reduce the power of methane explosion in natural gas pipelines and effectively improve the explosion suppression efficiency of a single explosion suppressant, we carry out the explosion suppression of HFC‐227ea/carbon dioxide mixed gas as well as mixed gas/ultrafine water mist through a self‐built methane explosion suppression experimental platform. Based on the changes in parameters such as explosion overpressure, flame propagation velocity, and flame propagation structure, the coupling mechanism of methane explosion suppression between mixed gases and between mixed gases and ultrafine water mist is revealed, which provides scientific support for promoting the development of methane explosion suppression technology. The experimental results show that when the mixed gas HFC‐227ea/carbon dioxide and ultrafine water mist synergistically suppresses methane explosion, the addition of the mixed gas can effectively improve the suppression effect of ultrafine water mist on methane explosion.

Influence of initial gas concentration on methane–air mixtures explosion characteristics and implications for safety management

Gas explosions, particularly those involving methane–air mixtures, present considerable hazards in confined spaces, such as coal mines. Comprehending the explosion characteristics and their correlations with initial gas concentrations is vital for devising effective safety measures. This study examines the influence of initial gas concentration on explosion temperature, overpressure, and flame evolution in methane–air premixed gas explosions, utilizing a custom-built 20-L spherical explosion experimental apparatus. The explosion temperatures display an oscillatory pattern, reaching maximum values at 6.5%, 9.5%, and 12% initial gas concentrations, with corresponding temperatures of 995 K, 932 K, and 1153 K. The maximum overpressure exhibits an initial rise and fall trend, modeled by an exponential function. Notably, in proximity to the 9.5% concentration, the pressure wave fosters the reverse propagation of the flame wave, leading to a secondary temperature increase. Flame sensors were employed to investigate the presence, absence, and duration of flames, demonstrating that elevated initial gas concentrations resulted in more prolonged flame durations and increased harm. At an initial gas concentration of 9.5%, a persistent flame is generated instantaneously during the explosion. Furthermore, the study analyzes the interplay between temperature and overpressure, underscoring the significance of mitigating high-temperature burns near tunnel walls and enclosed spaces. These findings advance the understanding of gas explosion dynamics and hold substantial implications for safety measures in coal mines.

Determining the global activation energy of methane–air premixed flames

In this work, the determination of the apparent activation energy of a global chemical reaction mechanism of the methane–air flames is revisited. The one-step formulation allows to derive the theoretical background for the method to measure the activation energy within the burner stabilised flame setup. The validity of this approach is demonstrated by using the numerical simulations with the detailed reaction model and direct thin filament pyrometry measurements of the temperature distribution in flame. The combination of numerical and experimental approaches allows us to find the activation energy for various mixture compositions. The prediction of numerical simulations and measured values of the activation energy is found to be in good agreement with each other and the data known from the literature. It is demonstrated that two critical phenomena need to be taken into account to obtain a reliable estimate of the activation energy: the flame blow-off and the onset of the diffusive-thermal instabilities. The effect of these critical events on the accuracy of the measurements is discussed as well as prospects of further investigation.

Numerical investigation on the initiation of oblique detonation waves in stoichiometric methane–air mixtures

The study investigates the oblique detonation characteristics in a stoichiometric methane–air mixture employing reactive Euler equations coupled with a detailed chemical reaction model. The analysis evaluates the initiation variation for both the inflow Mach number and the wedge angle. The results show that an increase in the Mach number from M0 = 9 to M0 = 12 changes the oblique shock-to-detonation transition from an abrupt to a smooth type. Furthermore, the distinction between high and low Mach numbers is explored through a comparison of the induction length along the wave surface. Additionally, the transition is affected by changes in wedge angle elevation under high Mach numbers, while a large wedge angle generates a second detonation wave surface due to a strong reflection shock downstream under low Mach numbers. Finally, the initiation length is quantitatively compared across varying inflow Mach numbers and wedge angles, which can benefit future investigations of a methane-fueled oblique detonation engine.

High-frequency measurement of concentration in an isothermal methane–air gas mixture using spontaneous Raman spectroscopy

A high-frequency (1.5 kHz) spontaneous Raman spectroscopy measurement technique is developed and applied to measure external fluctuations generated in the local concentration of an isothermal binary gas mixture of methane and air. Raman excitation is provided by a high-frequency laser at 527 nm in dual-pulsed mode. The Stokes Raman signal is collected using an EMCCD camera coupled to a high-frequency intensifier as a shutter. The emitted signal is collected over the 596–627 nm wavelength range, which allows for the simultaneous tracking of methane and nitrogen Stokes Q-branch mode signals. Calibration curves are initially obtained for each species ({text{CH}}_{4} and {mathrm{N}}_{2}) based on steady-state concentrations, and further corrected during use to detect local unsteady mixture fluctuations at gas pulsation frequencies up to 250 Hz. The main novelty is the demonstration of Raman spectroscopy for the simultaneous multispecies measurement of unsteady concentrations of gas-phase methane and air mixtures using a laser beam with a high-repetition rate, low energy per pulse, combined with a high-frequency intensifier and a single camera.

Geological hazards in the Oujiang estuary in the Zhejiang Province, China: type, distribution, and origin

Introduction: As our understanding of the ocean and its uses continues to advance, countries worldwide with ocean access are implementing new marine strategies. For example, understanding marine geological disasters can help develop the use of ocean resources and oceanic engineering.Methods: Therefore, this study used recent data from the Oujiang Estuary, a nearshore area in China, to determine its geological hazards.Results: The geological hazards were classified as active or restricted based on topography, geomorphology, shallow seismic profile, single-channel seismic profile, and geological drilling data. Active geological hazards primarily include shallow gas and active sand waves, whereas restrictive geological hazards include irregularly buried bedrock, erosion channels, steep submarine slopes, and buried paleochannels. We also evaluated the distribution characteristics and scope, such as the vertical distribution of shallow gas based on the seismic profiles, drilling rock facies, methane, and carbon dioxide contents in the top air, and the isotope values. We found that shallow gas was vertically distributed among multiple layers. The main gas-bearing layers were the clayey silt and sandy (silt) clay layers of the early Holocene and late Pleistocene strata. The shallow gas content was relatively low in the coarse sediment layer at the bottom of the late Pleistocene succession. Generally, the Holocene and late Pleistocene deposits do not contain gas, and the gas content in the middle and late Pleistocene strata (at greater depths) is relatively low.Discussion: The combined effects of the regional geological structure, sea level changes, modern hydrodynamics, and human activities have formed the geological environment of the Oujiang Estuary.

Exploring the environmental consequences of roadside grass as a biogas feedstock in Northwest Europe

The Russo-Ukrainian war has highlighted concerns regarding the European Union's (EU) energy security, given its heavy dependence on Russian natural gas for electricity and heating. The RePowerEU initiative addresses this challenge by targeting a significant increase in biomethane production (up to 35 billion m3 by 2030) to replace natural gas, aligning with the EU methane strategy's emission reduction and air quality improvement goals. However, the use of energy crops as biogas feedstock has raised land-use concerns, necessitating a policy shift towards alternative sources such as agro-residues, livestock manure, and sewage sludge.This study investigates the environmental impacts of using roadside grass clippings (RG) as an alternative feedstock for biogas production, focusing on selected regions in Northwest Europe (Belgium, Netherlands). The aim is to evaluate the environmental performance of RG as a mono- or co-substrate for biogas production, comparing it to the current practice of composting. Additionally, the study assesses the environmental impacts associated with biogas end-use in these regions.The results indicate that co-digestion of RG with pig manure offers a more environmentally friendly alternative compared to mono-digestion of RG or the existing composting practice. This finding is primarily attributed to the avoided emissions resulting from conventional pig manure management. Furthermore, in terms of climate change impacts concerning biogas end-use, the study identifies that combined heat and power (CHP) systems are preferable to biomethane recovery in regions with a natural gas-based electricity mix. However, for reducing fossil resource use, biomethane recovery emerges as the preferred option.By providing insights into the environmental performance of RG as a biogas feedstock and evaluating the impacts of different biogas end-use options, this study offers insights to policymakers for the development of sustainable energy strategies in Northwest Europe.

Strategies for heat recovery in a reverse flow reactor designed to lessen coal mine methane emissions test

ABSTRACT Thermal pollution resulting from the release of ventilation air methane (VAM) has emerged as a pressing concern in coal mining. This study aims to address this issue by harnessing the waste VAM energy and converting it into reusable resources, employing an efficient thermal flow reversal reactor. The research investigates five distinct heat extraction strategies and compares their performance. The numerical analysis focuses on transient heat recovery performance by employing a two-step reaction mechanism. Furthermore, the study uncovers the heat transfer characteristics of heat exchange tubes and conducts an analysis of construction costs and profit periods for the different strategies. The findings indicate that the central heat recovery strategy exhibits inferior recovery performance, resulting in higher outlet temperatures and lower extracted power. Conversely, the end recovery strategy successfully reduces heat loss by 56%. The two-sided strategy demonstrates better recovery performance, maintaining an average outlet temperature of 311 K. Additionally, the heat recovery efficiency of the heat exchange tube is approximately 85.6%. Although the combination strategy appears to reduce outlet heat loss, it results in an extended investment payback period.