Methane Air Research Articles

Explosion mitigation of methane–air mixture in combined application of HFC‐227ea/CO2 and ultrafine water mist in the pipeline

AbstractIn order to reduce the power of methane explosion in natural gas pipelines and effectively improve the explosion suppression efficiency of a single explosion suppressant, we carry out the explosion suppression of HFC‐227ea/carbon dioxide mixed gas as well as mixed gas/ultrafine water mist through a self‐built methane explosion suppression experimental platform. Based on the changes in parameters such as explosion overpressure, flame propagation velocity, and flame propagation structure, the coupling mechanism of methane explosion suppression between mixed gases and between mixed gases and ultrafine water mist is revealed, which provides scientific support for promoting the development of methane explosion suppression technology. The experimental results show that when the mixed gas HFC‐227ea/carbon dioxide and ultrafine water mist synergistically suppresses methane explosion, the addition of the mixed gas can effectively improve the suppression effect of ultrafine water mist on methane explosion.

Influence of initial gas concentration on methane–air mixtures explosion characteristics and implications for safety management

Gas explosions, particularly those involving methane–air mixtures, present considerable hazards in confined spaces, such as coal mines. Comprehending the explosion characteristics and their correlations with initial gas concentrations is vital for devising effective safety measures. This study examines the influence of initial gas concentration on explosion temperature, overpressure, and flame evolution in methane–air premixed gas explosions, utilizing a custom-built 20-L spherical explosion experimental apparatus. The explosion temperatures display an oscillatory pattern, reaching maximum values at 6.5%, 9.5%, and 12% initial gas concentrations, with corresponding temperatures of 995 K, 932 K, and 1153 K. The maximum overpressure exhibits an initial rise and fall trend, modeled by an exponential function. Notably, in proximity to the 9.5% concentration, the pressure wave fosters the reverse propagation of the flame wave, leading to a secondary temperature increase. Flame sensors were employed to investigate the presence, absence, and duration of flames, demonstrating that elevated initial gas concentrations resulted in more prolonged flame durations and increased harm. At an initial gas concentration of 9.5%, a persistent flame is generated instantaneously during the explosion. Furthermore, the study analyzes the interplay between temperature and overpressure, underscoring the significance of mitigating high-temperature burns near tunnel walls and enclosed spaces. These findings advance the understanding of gas explosion dynamics and hold substantial implications for safety measures in coal mines.

Determining the global activation energy of methane–air premixed flames

In this work, the determination of the apparent activation energy of a global chemical reaction mechanism of the methane–air flames is revisited. The one-step formulation allows to derive the theoretical background for the method to measure the activation energy within the burner stabilised flame setup. The validity of this approach is demonstrated by using the numerical simulations with the detailed reaction model and direct thin filament pyrometry measurements of the temperature distribution in flame. The combination of numerical and experimental approaches allows us to find the activation energy for various mixture compositions. The prediction of numerical simulations and measured values of the activation energy is found to be in good agreement with each other and the data known from the literature. It is demonstrated that two critical phenomena need to be taken into account to obtain a reliable estimate of the activation energy: the flame blow-off and the onset of the diffusive-thermal instabilities. The effect of these critical events on the accuracy of the measurements is discussed as well as prospects of further investigation.

Numerical investigation on the initiation of oblique detonation waves in stoichiometric methane–air mixtures

The study investigates the oblique detonation characteristics in a stoichiometric methane–air mixture employing reactive Euler equations coupled with a detailed chemical reaction model. The analysis evaluates the initiation variation for both the inflow Mach number and the wedge angle. The results show that an increase in the Mach number from M0 = 9 to M0 = 12 changes the oblique shock-to-detonation transition from an abrupt to a smooth type. Furthermore, the distinction between high and low Mach numbers is explored through a comparison of the induction length along the wave surface. Additionally, the transition is affected by changes in wedge angle elevation under high Mach numbers, while a large wedge angle generates a second detonation wave surface due to a strong reflection shock downstream under low Mach numbers. Finally, the initiation length is quantitatively compared across varying inflow Mach numbers and wedge angles, which can benefit future investigations of a methane-fueled oblique detonation engine.

High-frequency measurement of concentration in an isothermal methane–air gas mixture using spontaneous Raman spectroscopy

A high-frequency (1.5 kHz) spontaneous Raman spectroscopy measurement technique is developed and applied to measure external fluctuations generated in the local concentration of an isothermal binary gas mixture of methane and air. Raman excitation is provided by a high-frequency laser at 527 nm in dual-pulsed mode. The Stokes Raman signal is collected using an EMCCD camera coupled to a high-frequency intensifier as a shutter. The emitted signal is collected over the 596–627 nm wavelength range, which allows for the simultaneous tracking of methane and nitrogen Stokes Q-branch mode signals. Calibration curves are initially obtained for each species ({text{CH}}_{4} and {mathrm{N}}_{2}) based on steady-state concentrations, and further corrected during use to detect local unsteady mixture fluctuations at gas pulsation frequencies up to 250 Hz. The main novelty is the demonstration of Raman spectroscopy for the simultaneous multispecies measurement of unsteady concentrations of gas-phase methane and air mixtures using a laser beam with a high-repetition rate, low energy per pulse, combined with a high-frequency intensifier and a single camera.

Geological hazards in the Oujiang estuary in the Zhejiang Province, China: type, distribution, and origin

Introduction: As our understanding of the ocean and its uses continues to advance, countries worldwide with ocean access are implementing new marine strategies. For example, understanding marine geological disasters can help develop the use of ocean resources and oceanic engineering.Methods: Therefore, this study used recent data from the Oujiang Estuary, a nearshore area in China, to determine its geological hazards.Results: The geological hazards were classified as active or restricted based on topography, geomorphology, shallow seismic profile, single-channel seismic profile, and geological drilling data. Active geological hazards primarily include shallow gas and active sand waves, whereas restrictive geological hazards include irregularly buried bedrock, erosion channels, steep submarine slopes, and buried paleochannels. We also evaluated the distribution characteristics and scope, such as the vertical distribution of shallow gas based on the seismic profiles, drilling rock facies, methane, and carbon dioxide contents in the top air, and the isotope values. We found that shallow gas was vertically distributed among multiple layers. The main gas-bearing layers were the clayey silt and sandy (silt) clay layers of the early Holocene and late Pleistocene strata. The shallow gas content was relatively low in the coarse sediment layer at the bottom of the late Pleistocene succession. Generally, the Holocene and late Pleistocene deposits do not contain gas, and the gas content in the middle and late Pleistocene strata (at greater depths) is relatively low.Discussion: The combined effects of the regional geological structure, sea level changes, modern hydrodynamics, and human activities have formed the geological environment of the Oujiang Estuary.

Exploring the environmental consequences of roadside grass as a biogas feedstock in Northwest Europe

The Russo-Ukrainian war has highlighted concerns regarding the European Union's (EU) energy security, given its heavy dependence on Russian natural gas for electricity and heating. The RePowerEU initiative addresses this challenge by targeting a significant increase in biomethane production (up to 35 billion m3 by 2030) to replace natural gas, aligning with the EU methane strategy's emission reduction and air quality improvement goals. However, the use of energy crops as biogas feedstock has raised land-use concerns, necessitating a policy shift towards alternative sources such as agro-residues, livestock manure, and sewage sludge.This study investigates the environmental impacts of using roadside grass clippings (RG) as an alternative feedstock for biogas production, focusing on selected regions in Northwest Europe (Belgium, Netherlands). The aim is to evaluate the environmental performance of RG as a mono- or co-substrate for biogas production, comparing it to the current practice of composting. Additionally, the study assesses the environmental impacts associated with biogas end-use in these regions.The results indicate that co-digestion of RG with pig manure offers a more environmentally friendly alternative compared to mono-digestion of RG or the existing composting practice. This finding is primarily attributed to the avoided emissions resulting from conventional pig manure management. Furthermore, in terms of climate change impacts concerning biogas end-use, the study identifies that combined heat and power (CHP) systems are preferable to biomethane recovery in regions with a natural gas-based electricity mix. However, for reducing fossil resource use, biomethane recovery emerges as the preferred option.By providing insights into the environmental performance of RG as a biogas feedstock and evaluating the impacts of different biogas end-use options, this study offers insights to policymakers for the development of sustainable energy strategies in Northwest Europe.

Strategies for heat recovery in a reverse flow reactor designed to lessen coal mine methane emissions test

ABSTRACT Thermal pollution resulting from the release of ventilation air methane (VAM) has emerged as a pressing concern in coal mining. This study aims to address this issue by harnessing the waste VAM energy and converting it into reusable resources, employing an efficient thermal flow reversal reactor. The research investigates five distinct heat extraction strategies and compares their performance. The numerical analysis focuses on transient heat recovery performance by employing a two-step reaction mechanism. Furthermore, the study uncovers the heat transfer characteristics of heat exchange tubes and conducts an analysis of construction costs and profit periods for the different strategies. The findings indicate that the central heat recovery strategy exhibits inferior recovery performance, resulting in higher outlet temperatures and lower extracted power. Conversely, the end recovery strategy successfully reduces heat loss by 56%. The two-sided strategy demonstrates better recovery performance, maintaining an average outlet temperature of 311 K. Additionally, the heat recovery efficiency of the heat exchange tube is approximately 85.6%. Although the combination strategy appears to reduce outlet heat loss, it results in an extended investment payback period.

Ignition limits of hydrogen–methane–air mixtures over metallic Rh at a pressure of 1–2 atm

The ignition temperatures and effective activation energies of the ignition limits of mixtures (40–70% H2 + 60–30% CH4)stoich + air over Rh were experimentally determined at a pressure of 1 atm in the temperature range 20–300 °C. Over an ignition-treated Rh surface, the ignition temperature of a mixture of 70% H2 + 30% methane + air is 62 °C. This indicates the potential of using Rh to markedly lower the ignition temperature of fuels based on hydrogen–methane mixtures.

Distinctive Features of Propagation of the Flame of a Coal–Methane–Air Mixture in a Cylindrical Channel

Distinctive Features of Propagation of the Flame of a Coal–Methane–Air Mixture in a Cylindrical Channel

On the Velocity of Propagation of a Flame in a Coal–Methane–Air Suspension

On the Velocity of Propagation of a Flame in a Coal–Methane–Air Suspension

Environmental risks and opportunities of orphaned oil and gas wells in the United States

Hundreds of thousands of documented and undocumented orphaned oil and gas wells exist in the United States (U.S.). These wells have the potential to contaminate water supplies, degrade ecosystems, and emit methane and other air pollutants. Thus, orphaned wells present risks to climate stability and to environmental and human health, which can be reduced by plugging. To quantify environmental risks and opportunities of well plugging at the national level, we analyze data on 81 857 documented orphaned wells across the U.S. We find that 4.6 million people live within 1 km of a documented orphaned well. 35% of the documented orphaned wells are located within 1 km of a domestic groundwater well, yet only 8% of the wells have groundwater quality data within a 1 km radius. Methane emissions from the documented orphaned wells represent approximately 3%–6% of total U.S. methane emissions from abandoned oil and gas wells, but this estimate is based on measurements at 0.03% of U.S. abandoned wells. 91% of the documented orphaned wells overlie formations favorable for geologic storage of carbon dioxide and hydrogen, meaning that orphaned well plugging can reduce leakage risks from future storage projects. Finally, we estimate plugging costs for documented orphaned wells to exceed the $4.7 billion federal funding by 30%–80%, emphasizing the importance of prioritizing federal spending on wells with large remediation benefits. Overall, environmental monitoring data are not extensive enough to quantify risks, especially those related to air and water quality and human health. Plugging orphaned wells can provide opportunities for geologic storage of carbon dioxide and hydrogen and geothermal energy development, thereby facilitating efforts to transition to net-zero energy systems. Our analysis on environmental risks and opportunities of orphaned wells provides a framework that can be used to manage the millions of documented and undocumented orphaned wells in the U.S. and abroad.

Large-eddy simulation of dual-fuel spray ignition at varying levels of methane diluted ambient oxidizer using FGM

In the current work, the Flamelet Generated Manifold (FGM) method is applied with large-eddy simulation (LES) to investigate the effect of methane on dual-fuel (DF) spray ignition. The diesel surrogate n-dodecane is injected as the so-called pilot fuel into selected lean methane–air mixtures, ranging from ϕCH4=0 to ϕCH4=0.75, at engine relevant conditions. The operating conditions are those of the completely characterized Engine Combustion Network (ECN) Spray A configuration, for which the modeling approach adopted in the present study was extensively validated. The specific purpose of this study is to extend and validate the FGM approach for dual-fuel combustion. In order to understand the interplay of chemistry and mixing, the ignition behavior of selected cases is investigated. It is found that both low and high temperature combustion (LTC and HTC, respectively) are increasingly retarded by higher values of ϕCH4, while the induction time between LTC and HTC is relatively insensitive compared to the ignition delay time (IDT). Analysis reveals a more prominent role of mixing for increased ϕCH4. The development of LTC and HTC are quantitatively analyzed for different cases. The transition from LTC to HTC is found to be highly correlated with the evolution of lift-off length (LOL), which on its turn is seriously affected by ϕCH4. The local flame behavior is analyzed via chemical explosive mode analysis (CEMA), suggesting a clear flame propagation due to diffusion towards lean mixtures after the ignition of the pilot fuel. Besides, it is found that diffusion helps to stabilize the flame in leaner mixtures, which is more important in DF combustion. The results show FGM to be a promising tool in modeling the DF sprays.

Effects of ammonia on combustion of coal in stoichiometric premixed methane–air flames

NH3 has long been considered a promising alternative fuel·NH3 from renewables can be used for energy storage·NH3 is a zero-carbon molecule and can be burned directly and used as a hydrogen carrier. Compared with hydrocarbon fuels, NH3 has several drawbacks, such as an inferior flammability limit, flame temperature, and flame burning velocity, resulting in a lower reactivity rate and the production of pollutants.Therefore, cofiring coal with NH3 is an approach that has been growing in popularity. This study investigated the combustion of coal cofired with NH3 and conducted two-color pyrometry to measure the temperature profiles of coal particles in hybrid flames, that is, methane–coal–air and methane–NH3–coal–air premixed flames. The axial temperature distribution at the center of the flame was measured using two-color pyrometry and a thermocouple. The temperature values obtained were not identical but exhibited similar trends. The results indicated that the temperature at the origin significantly decreased upon ammonia addition, but as the measuring height increased, the final temperatures approached similarity.In addition, the emissions of pollutants such as CO and NOx were also measured. The results indicate that the addition of coal particles without ammonia gas leads to an increase in CO concentration due to the pyrolysis of the pulverized coal. However, there was no significant impact on NOx emissions.In contrast, the addition of coal particles under CH4 − NH3 gas combustion conditions results in a significant decrease in both CO and NOx concentrations. Specifically, under the 80 %CH4 + 20 %NH3 condition and with a coal particle feeding rate increasing from 0 to 0.24 g/min, there was a reduction of approximately 34% in CO concentration and 35% in NOx concentration.In order to confirm the coal consumption rate, coal particles were captured before and after flame sheet using a metal grid, and the particle projected area was determined based on scanning electron microscopy (SEM) images. These results provided evidence that the addition of NH3 to the CH4 − air flame enhances coal combustion, as indicated by a decrease in the particle shrinkage rate and sampling density.

Effects of Abrupt Cross-Section Area Change on theMultiparameter Propagation Characteristics of Premixed Methane–Air Explosion in Pipes

This paper explores the effects of an abrupt cross-section area change of gas pipes on the propagation law of explosion. For this, an explosion pipe experimental system was established, and a numerical research was conducted. By experimental and numerical simulation, the evolution of the overpressure, temperature, vorticity, and kinetic energy of shock waves of gas explosion in abrupt pipelines was investigated. This allowed us to obtain expressions for the attenuation coefficient, increase coefficient, and reflection coefficient of gas explosion overpressure. The study indicates that an abrupt increase of the pipeline cross-section area leads to a decrease of shock wave overpressure and vice versa. For a given change of cross-section area, the attenuation coefficient gradually increases as the initial peak overpressure rises, whereas the increase coefficient and reflection coefficient both present a decreasing trend. An abrupt change in the pipe structure can inhibit the propagation of gas explosion flames. The explosive gas is affected by the turbulence effect after passing through the middle large-diameter pipe, and the vorticity curve exhibits a clear peak. In addition, the large eddy motion caused by strong confinement increases the kinetic energy of the gas in pipes. The above research outcomes contribute to further enriching the basic theory of gas explosion for the study of gas explosion propagation in mining laneway.

Characterization of Nonlinear Responses of Non-Premixed Flames to Low-Frequency Acoustic Excitations

The response of flames’ heat release to acoustic excitation is a critical factor for understanding combustion instability. In the present work, the nonlinear heat release response of a methane–air non-premixed flame to low-frequency acoustic excitations is experimentally investigated. The flame describing function (FDF) was measured based on the overall CH* chemiluminescence intensity and the velocity fluctuations obtained by the two-microphone method. The CH* chemiluminescence and schlieren images were analyzed for revealing the mechanism of nonlinear response. The excitation frequency ranges from 10 Hz to 120 Hz. The forced relative velocity fluctuation amplitude ranges from 0.10 to 0.50. The corresponding flame Strouhal number (Stf) ranges from 0.43 to 4.67. The study has shown that the flame length responds more sensitively to changes in excitation amplitude when subjected to relatively high-frequency excitations. The normalized flame length (Lf/D) decreases from 3.79 to 2.37 with the increase in excitation amplitude at an excitation frequency of 100 Hz. The number of oscillation zones along the flame increases with increasing excitation frequency, which is consistent with the increase in the Stf. The low-pass filtering characteristic of FDF is caused by the dispersion of multiple oscillation zones, as well as the cancellation effect of the adjacent oscillation zones under relatively high-frequency excitation. The main mechanism for the local gain peak and valley is the cancellation effect of positive and negative oscillation zones with various Stf. When two adjacent oscillation regions have similar amplitudes, the overall phase-lag becomes more sensitive to changes in excitation frequency and amplitude. This sensitivity leads to nonlinear anomalous changes in the phase-lag near the frequency corresponding to the gain valley. The calculated disturbance convection time is consistent with the measured time delay in the short flame scenario. Further research is required to determine whether the identified agreement is a result of the consistent occurrence of the oscillation zone in close proximity to the flame’s center of mass, in conjunction with a precise determination of the average convective velocity.

Sea–air methane flux estimates derived from marine surface observations and instantaneous atmospheric measurements in the northern Labrador Sea and Baffin Bay

Abstract. Vast amounts of methane (CH4) stored in submarine sediments are susceptible to release in a warming Arctic, further exacerbating climate change in a positive feedback. It is therefore critical to monitor CH4 over pan-regional scales to detect early signs of CH4 release. However, our ability to monitor CH4 is hampered in remote northern regions by sampling and logistical constraints, and few good baseline data exist in many areas. From high-resolution atmospheric CH4 measurements and discrete surface water samples, we estimated instantaneous sea–air CH4 fluxes at various locations. We also created a baseline study of current background levels of CH4 in North Atlantic waters based on the atmospheric CH4 data over 22 d in summer 2021 on a roughly 5100 km voyage in the northern Labrador Sea and Baffin Bay between 55 and 72∘ N. In addition, we measured CH4 concentrations across the water column at various stations. Measured atmospheric mixing ratios of CH4 ranged from 1944 to 2012 ppbv, with a mean of 1966 ± 8 ppbv and a baseline of 1954–1981 ppbv. Dissolved CH4 concentrations in the near-surface water peaked at 5.3 nmol L−1 within 1 km down-current of a known cold seep at Scott Inlet and were consistently oversaturated throughout the water column in Southwind Fjord, which is an area that has been recently affected by submarine landslides. Local sea–air CH4 fluxes ranged from 0.003–0.119 µmol m−2 d−1, indicating that the ocean released only small amounts of CH4 to the atmosphere at all stations. Atmospheric CH4 levels were also driven by meteorological, spatial, and temporal variations, and both onshore and ocean-based contributions to atmospheric CH4 mixing ratios are likely. Coupled high-resolution measurements of marine and atmospheric CH4 data have the potential to provide ongoing monitoring in a region susceptible to CH4 releases, as well as critical validation data for global-scale measurements and modelling.

Abatement of Greenhouse Gas Emissions from Ventilation Air Methane (VAM) Using Ionic Liquids: A Review of Experimental Methods and Modelling Approaches

Ventilation Air Methane (VAM) refers to the release of fugitive methane (CH4) emissions into the atmosphere during underground coal mining operations. Growing concerns regarding the greenhouse effects of CH4 have led to a worldwide effort in developing efficient and cost-effective methods of capturing CH4. Among these, absorption-based processes, particularly those using Ionic Liquids (ILs) are appealing due to their advantages over conventional methods. In this study, the solubility of CH4 in various ILs, expressed by Henry’s law constant, is first reviewed by examining a wide range of experimental techniques. This is followed by a review of thermodynamic modelling tools such as the extended Henry’s law model, extended Pitzer’s model, Peng–Robinson (PR) equation of state, and Krichevsky−Kasarnovsky (KK) equation of state as well as computational (Artificial Neural Network) modelling approaches. The comprehensive analysis presented in this paper aims to provide a deeper understanding of the factors that significantly influence the process of interest. Furthermore, the study provides a critical examination of recent advancements and innovations in CH4 capture by ILs. ILs, in general, have a higher selectivity for methane compared to conventional solvents. This means that ILs can remove methane more effectively from VAM, resulting in a higher purity of the recovered methane. Overall, ILs offer several advantages over conventional solvents for the after treatment of VAM. They are more selective, less volatile, have a wider temperature range, are chemically stable, and can be made from renewable materials. As a result of their many advantages, ILs are becoming increasingly popular for the after treatment of VAM. They offer a more sustainable, efficient, and safe alternative to conventional solvents, and they are likely to continue gaining market share in the coming years.

Experimental Study on the Effect of Hydrogen Addition on the Laminar Burning Velocity of Methane/Ammonia–Air Flames

Variations in methane–ammonia blends with hydrogen enrichment can modify premixed flame behavior and play a crucial role in achieving ultra-low carbon emissions and sustainable energy consumption. Current combustion units may co-fire ammonia/methane/hydrogen, necessitating further investigation into flame characteristics to understand the behavior of multi-component fuels. This research aims to explore the potential of replacing natural gas with ammonia while making only minor adjustments to equipment and processes. The laminar burning velocity (LBV) of binary blends, such as ammonia–methane, ammonia–hydrogen, and hydrogen–methane–air mixtures, was investigated at an equivalence ratio of 0.8–1.2, within a constant volume combustion chamber at a pressure of 0.1 MPa and temperature of 298 K. Additionally, tertiary fuels were examined with varying hydrogen blending ratios ranging from 0% to 40%. The results show that the laminar burning velocity (LBV) increases as the hydrogen fraction increases for all mixtures, while methane increases the LBV during blending with ammonia. Hydrogen-ammonia blends are the most effective mixture for increasing LBV non-linearly. Enhancement parameters demonstrate the effect of ternary fuel, which behaves similarly to equivalent methane in terms of adiabatic flame temperature and LBV achieved at 40% hydrogen. Experimental data for neat and binary mixtures were validated by different kinetics models, which also showed good consistency. The ternary fuel mixtures were also validated with these models. The Li model may qualitatively predict well for ammonia-dominated fuel. The Shrestha model may overestimate results on the rich side due to the incomplete N2Hisub-mechanism, while lean and stoichiometric conditions have better predictions. The Okafor model is always overestimated.

Vortex zone dynamics in premixed flame under complex gravity and acoustic impact

An inverted conical, plane-symmetrical premixed methane–air flame stabilized by a bluff body under acoustic excitation and various gravity conditions was experimentally investigated. Recirculation zone characteristics were found by means of the phase-resolved particle image velocimetry method. An increase in the size of the longitudinal vortex zone was shown with an increase in both fuel concentration and flow velocity under normal and reverse gravity. The longitudinal size of the vortex zone is independent of frequency, regardless of the direction of gravity at low flow velocity (≤5 m/s) in a stoichiometric flame under the considered excitation frequency range (40–420 Hz). With a flow velocity increase, the size of the vortex zone becomes sensitive to the excitation frequency. An increase in the excitation frequency results in a length decrease in the vortex zone. In rich flames, an inverse relation of the longitudinal vortex zone size to the excitation frequency is observed at lower velocities (5 m/s) for normal gravity conditions. Whereas, under conditions of inverted gravity, the fuel air ratio increase does not lead to such a relation; the vortex zone has a constant length under various excitation frequencies. An external acoustic excitation causes a periodic change in the vortex zone longitudinal size, and for a stoichiometric mixture, the amplitude does not depend on the disturbance frequency. For a rich mixture, a frequency increase results in an amplitude decrease. For selected frequencies and flow velocities, desynchronization of the vortex zone oscillations with external disturbances is observed.