The influence of various process parameters during silicon production in a 22.5 MVA submerged arc furnace (SAF) was studied to achieve energy-saving effects. This paper analyzed how the main impurities (Fe2O3, Al2O3, CaO) in the main components (fixed carbon, ash, volatile matter, and moisture) of the raw materials used during industrial silicon smelting affected the process using correlation coefficients and contour maps. The results showed that the effect of the main components of the raw materials in a large-capacity furnace was fixed carbon > volatile content > moisture. The effects were significantly reduced compared with a 12.5 MVA. Under the same fixed carbon ratio, coal was more conducive to silicon production than petroleum coke, and the large-capacity furnace had a higher effective utilization rate of raw materials. The falls into order of the influence of metal oxide content on power consumption was Fe2O3 >Al2O3 >CaO.