Low-temperature System Research Articles

Mineralized structures from the Alhué mining district, Chile: Using fluid inclusions and textures

The Alhué mining district (AMD) of the Coastal Range in Central Chile is situated approximately 70 km southwest of the city of Santiago and hosted in stratified Jurassic and Early Cretaceous sequences which are common in central Chile. More than 79 faults and veins are recognized in the AMD hosted in andesites and tuffs with clear structural control showing two distinct trends. Precious‐metal mineralization locally extends over strike lengths of up to 1000 m along these structures with grades averaging at 5 ppm gold and 23 ppm of silver. In this study, a University of Chile – YAMANA GOLD joint research project was created to better understand this particular deposit and explore the origin of gold anomalies found in the district using drill core, mine, and surface samples. Wide internal variations in homogenization temperature and electrolytes were observed at all scales: on the district scale, in mineralized structures intersected in drill core, and in hand specimens. This variability may reflect the diversity of ore-forming conditions in the mining district in addition to the different processes (including fault motion over time) and geochemical components within the district. Textural analyses and fluid inclusion assemblages (FIA) provide evidence for boiling and flashing mechanisms at several localities. Raman spectroscopy and LA-ICP-MS techniques allowed a better characterization of the fluid composition and mineral paragenesis. The presence of gold (∼3.8 ppm) and silver (∼1424 ppm) in both vapor-rich only FIAs (i.e. that contain 99 % vapor) hosted in quartz and liquid-rich FIA hosted in sphalerite implies that gold was transported as sulfide and chloride complexes. The AMD shows a transition from a high temperature environment (sometimes containing calc-silicate minerals) to a low temperature (epithermal) system. This mineralization depended on the type of vein system which tend to be mineralized in strike slip faults e.g. Maqui and Lorena structures. The consequence of flashing documented at dilational jogs, structural intersections and fault bends was likely an important outcome leading to the precipitation of metals at the AMD.Coexisting liquid-rich and vapor-rich fluid inclusions contained in a FIA were observed at the deepest levels in the Chilco vein and the proportion of samples showing boiling increases with depth, indicating that additional precious metal resources may be present below current exploration depths. In summary, our new results reveal that gold, silver and base metal veins found at the AMD in Chile are unique hydrothermal polymetallic ore deposits that are structurally controlled and related to an orogenic environment. A general model for the AMD is one where high temperature fluids from deep crustal mafic magmatic systems, probably as products of a devolatilization and far-from-equilibrium conditions, reach subsurface conditions along faults and are mineralized along these faults. Because having a truly unique ore deposit in the geologic record is very unlikely, the AMD forms an important case study that helps understand structurally controlled ore deposits. Thus our work can form a model for future exploration in the AMD and provide insight into exploration in other sites in Chile and along continental margin settings worldwide, in both poorly characterized known deposits and at greenfield sites.

Assessing the efficacy of an atmospheric air DC glow discharge system for sustainable nitrogen fixation: a vibrational coherent anti-Stokes Raman scattering study

In addressing the substantial greenhouse gas emissions produced by the energy-intensive Haber–Bosch synthesis, this study investigates the viability of sustainable nitrogen fixation (NF) via low-temperature plasma systems energized by renewable sources. Utilizing vibrational coherent anti-Stokes Raman scattering as a diagnostic tool, we probed the nitrogen rovibrational temperature and population dynamics within a DC glow discharge in atmospheric air, a setting with considerable promise for eco-friendly fertilizer production. Besides, density for atomic N , O , and NO was quantified by laser-induced fluorescence (LIF) or two-photon absorbed LIF methods. Our findings reveal a quasi-equilibrium between rotational and vibrational energy states in the DC glow discharge environment, reaching an approximate value of 3500 K at the discharge core. The discharge parameters, discharge current, air flow rate, and discharge gap influence the rovibrational temperature, density distribution of species of interest, and the NF energy cost. However, the influences induced by these parameters are of limitations. Further analysis implies that the high gas temperature and its induced significant vibrational-rotational and vibrational-translational energy exchange are mainly responsible for the non-ideal NF energy cost.

Design and multi-criteria optimization and financial assessment of an innovative combined power plant and desalination process

Geothermal power generation programs are crucial due to their long-term sustainability and environmentally friendly characteristics, particularly for potential energy-based applications in the future. Innovative designs can yield improve efficien by mitigating irreversibility, resulting in enhanced power production. Hence, this study investigates an innovative cascade thermal design model that employs geothermal resources to enhance the efficiency and output of low-temperature power generation systems, specifically through the integration of organic flash and organic Rankine cycles. Additionally, this model introduces a novel cogeneration approach by incorporating a desalination unit based on humidification-dehumidification processes, aiming to concurrently produce electricity and fresh water. Employing a combination of thermodynamic analysis and financial assessment, the system's performance was simulated and optimized in MATLAB, using the Multi-Objective Particle Swarm Optimization (MOPSO) method. A sensitivity analysis preceded the optimization, leading to the development of three distinct optimization scenarios focused on balancing power and freshwater production, maximizing exergetic efficiency and net present value, and optimizing fixed capital investment for maximum financial viability. The results highlight the second scenario as particularly effective, achieving a power generation of 254.3 kW, an exergetic efficiency of 44.84 %, and a net present value of $405,099. Conversely, the third scenario offers the best balance between freshwater production capacity (0.504 kg/s), fixed capital investment ($820,822), and a payback period of 7.12 years. This research demonstrates the potential of integrating advanced thermal models with geothermal resources for sustainable and efficient energy and freshwater production, marking a significant step forward in the development of eco-friendly cogeneration systems.

Performance Optimization and Numerical Simulation Study of Sludge Low-Temperature Drying System

Performance Optimization and Numerical Simulation Study of Sludge Low-Temperature Drying System

Thermal conductivity and mechanical properties of polymeric aerogels for cryogenic insulation applications

Non-vacuum insulation systems are frequently applied in the thermal management of low temperature systems as well as for the use and storage of cryogens. Aerogels are known for their low density, high mesoporosity, high surface areas, low thermal conductivity and high acoustic impedance. This study focuses on polymeric aerogels that can be mass produced as large monoliths while maintaining the low thermal conductivity over a wide temperature range. The manufacturing flexibility of polymeric aerogels allows fabrication of monolithic blocks and sheets that can be applied in various configurations to insulate cryogenic and superconducting devices. To measure the thermal conductivity, an immersion calorimeter was developed and has been operated at different cold boundary temperatures. The calorimeter heats a hollow cylinder of insulating material on the inside surface and the surrounding bath maintains a cold boundary. This calorimeter was used to measure the thermal conductivity of commercially available FoamGlass and a hollow cylinder of a polymeric aerogel machined from a cast cylinder. The thermal conductivity of the FoamGlass and the polymeric aerogel are compared at room temperature (290 K), ice bath (273 K), and at liquid nitrogen (80 K) cold boundary temperatures. Room temperature measurements of the modulus of elasticity and yield strength using an optical technique are also reported for flat specimens of the aerogel made from the same stock as the cylindrical specimens tested for thermal conductivity. Mechanical properties of aerogels are also reported under compression and both at room temperature and at cryogenic temperature (Liquid nitrogen).

Multi-scale investigation of heat and momentum transfer in packed-bed TES systems up to 800 K

With the rising cost of energy and the advancement of corporate social responsibility, there is a growing interest in addressing the challenge of recovering and storing high-temperature waste heat. Sensible heat storage in packed beds stands out as a cost-effective and seemingly straightforward solution for high-temperature Thermal Energy Storage (TES). Engineering models developed to design low-temperature TES systems were tentatively used to design this new generation of high-temperature systems. Delving into the physics of coupled heat and mass transfer reveals a lack of validation of this approach. This study seeks to establish a comprehensive bottom-up methodology - from the particle scale up to the system level - to provide informed and validated engineering models for the design of high-temperature TES systems. To achieve this goal, we developed a multi-scale numerical model to explore the physics of heat and momentum transfer in packed-bed TES systems. At the microscopic scale (pore/particle), we consider the flow of a compressible high-temperature gas between the particles, coupled to transient heat conduction within the particles, with particular attention given to incorporating accurate temperature-dependent viscosity for the gas phase and thermal conductivity and density for both solid and gas phases. At the macroscopic scale (engineering), we propose a high-temperature extension of state-of-the-art two-equation TES models. The governing equations considered are the volume-average conservation laws for gas-mass, gas-momentum and energy of both phases. The multi-scale strategy is applied to a randomly packed bed of spherical particles generated with the discrete element method (DEM) software LIGGGHTS. Numerical models for both scales were implemented in the Porous material Analysis Toolbox based on OpenFoam (PATO), which is made available in Open Source by NASA. Microscopic scale simulations were used to infer the effective parameters needed to inform the macroscopic model, namely, permeability, Forchheimer coefficient, effective thermal conductivities, and the heat transfer coefficient. The informed macroscopic model reproduces with excellent accuracy the average temperature fields of the physics-based microscopic model. Pore-scale analysis shows highly three-dimensional flow characterized by reverse flow and strong cross-flow in the packed bed system. Moreover, it indicates the coupling between temperature and velocity fields, where a nonuniform velocity field results in uneven temperature distributions across the fluid and the solid spheres within the packed bed, subsequently affecting the macroscopic heat transfer coefficient. The overall strategy is validated by comparison to available experimental data. This bottom-up methodology contributes to the understanding and opens new perspectives for a more precise design and monitoring of high-temperature TES systems.

Phase diagrams of CoSO4-H2O and CoSO4-H2SO4-H2O systems for CoSO4·nH2O (n = 6,7) recovery by cooling and eutectic freeze crystallization

This paper reports the solid-liquid phase equilibria of the CoSO4-H2O and CoSO4-H2SO4-H2O systems at low temperatures. Binary and ternary phase diagrams, including the stable solid phases CoSO4·6H2O and CoSO4·7H2O were established using experimental data and thermodynamic modeling applying the mixed-solvent electrolyte (MSE) model. The results showed that the addition of H2SO4 shifts the eutectic temperature and concentration to lower values for cobalt sulfate and ice crystallization. The trends obtained from the experimental data and the modeling are consistent for the binary CoSO4-H2O system with good agreement, but the ternary CoSO4-H2SO4-H2O system shows some deviations. In general, the MSE model is shown to be reliable for inferring and establishing the phase diagram of the low-temperature system. The phase diagrams are helpful for designing the pathways of cooling crystallization and eutectic freeze crystallization and assessing the performance of the low-temperature crystallization process in the production of CoSO4 hydrates. In addition, some practical examples of cooling crystallization and eutectic freeze crystallization of CoSO4 solutions are provided.

Experimental study of a novel in-tube spray evaporative condenser for geothermal power generation

To enhance the efficiency of medium to low-temperature geothermal power systems, we designed a novel in-tube spray evaporative condenser. Experimental setups for single-tube heat exchange were devised, examining both water-water and working fluid-water configurations. The study analyzed the impact of air volume and hot water flow rate on heat transfer. Economic comparisons were made in laboratory conditions among the novel evaporative condenser, traditional evaporative condenser, water-cooled condenser, and air-cooled condenser. Results indicated: (1) The novel evaporative condenser exhibited 1.5–1.7 times higher heat flux density and 2.0–2.7 times higher mass transfer coefficient, indicating superior heat transfer performance compared to the traditional one. (2) Variations in hot water flow rate within a certain range had minimal impact on condenser performance when the condenser size was constant, providing valuable insights for condenser selection and structural design. (3) Both total power and water consumption of the novel evaporative condenser were lower than the other three types. Its daily operating cost was approximately 3/4 of the traditional evaporative condenser, 1/2 of the air-cooled condenser, and 1/4 of the water-cooled condenser, demonstrating superior economic feasibility.

Decreasing the Return Temperature in District Heating Networks Thanks to a Switch to Alternative Substation Architectures

District heating networks (DHN) are key systems for managing heating and reducing carbon emissions at a large scale. Therefore, increasing their efficiency is a key to reduce climate change. DHNs with centralized production are supplying hot water to building substations (interface between the DHN and the buildings) for domestic hot water (DHW) production and space heating (SH) using heat exchangers. Colder water is returned to the centralized district heating system by the return pipe. One of the crucial factors to improve the efficiency of DHNs is to decrease the return temperature in the network to keep the same amount of energy transferred to the buildings while reducing the thermal losses and the flow rate, leading to more savings. In this paper, we model and simulate two of the most common DHN substation architectures used in a typical third-generation DHN to identify their flaws and propose new district heating substation architectures that can increase the DHN efficiency. The main result from our study is the consistent reduction in the average return temperature across all scenarios when implementing our proposed architectures. The reduction ranged between 3.7 °C and 10.2 °C. We also found that the lower the heating temperature, the greater the reduction. This is particularly beneficial as buildings are increasingly equipped with low-temperature heating systems, especially new constructions. Moreover, these architectures showed optimal efficiency with new buildings that have a high water heating demand compared to heating demand. This is due to the higher impact of cold water preheating.

Influence of hot water consumption patterns on the viability of low-temperature solar thermal systems in the food industry

The thermal demand in agri-food industries is characterised by its considerable variability, hindering the implementation of Solar Water Heating Systems (SWHS). The main objective of the study is to provide an overview of how consumption patterns influence the profitability and energy savings of SWHS in the sector, while also identifying additional key variables that affect their viability. For this purpose, approximately 1,300,000 cases have been examined, considering a wide range of consumption patterns, economic variables, and locations. Demand seasonality, weekly frequency and energy prices exhibit the greatest impact on the feasibility of SWHS. Uniformity of daily demand, location and investment cost are also determinants. Thus, single-day-per-week consumption patterns make SWHS unviable in most scenarios. However, with only three non-consecutive days, feasibility increases significantly, achieving paybacks of less than 5 years and energy savings of over 40 % when conditions are highly favorable. In strongly seasonal industries, the viability of SWHS is seriously compromised. The payback in patterns with a peak consumption in the early morning can double the value with uniform one (e.g., from 4 to 8 years in the most favorable scenarios at a price of 0.1 €/kWh). The results tables reflecting payback and energy savings in thousands of different scenarios represent a valuable tool for decision-making in industries. By looking for the scenario with the most similar characteristics, it is possible to estimate the profitability and savings of the SWHS in a given industry, as well as the possible variations when changing the assumed variables.

Evaluation on novel Kalina power generation system through exergoenvironmental analysis

First law analysis assesses the performance of the system considered for investigation in the energy aspect. Low-temperature power generation system suitable to recover waste heat from a renewable source is investigated in the present work. The system is adopted to work at hot sink conditions and investigation on performance assessment is carried out in exergy aspect. Exergy analysis in both conventional and advanced methods proposes the system components which need improvements in themselves and associated with other components more properly. Exergoenvironmental analysis using the Life cycle assessment (LCA) method is examined in the system under the same sink conditions. Exergy analysis reveals that the component with a high source will yield more losses resulting in higher irreversibility. Hence turbine and evaporator need investigation in improving the system’s performance. Exergoenvironmental investigation suggests that the highest impact results in the low-temperature regenerator (LTRGN). The improvement in these components' designs and limitations in the characteristics of the material chosen and the manufacturing methods involved will favor a higher performance of the system. LTRGN has resulted in with high relative cost difference value of 23.85 % and seeks improvement. The exergy destruction is in a larger amount in the components evaporator and turbine with 70.66 kW and 30.99 kW respectively. Avoidable exergy destruction value of evaporator, condenser results 51.11 $/hr and 16.64 $/hr respectively. The LTRGN has an environmental effect rate of 54.83 mPts/hr and device-related environmental effects of 45.16 mPts/hr. The (ĖD/ĖP), (Ẏ/ĖP) and (Ż/ĖP), values at 85% pump efficiency results 2.16, 0.00946 and 0.30871.

Paddle design based on continuous low-temperature vacuum drying system in fishmeal production

With the rapid development of aquaculture, fishmeal is gradually processed into high-quality aquafeed, and there is a great demand for fishmeal in China. In order to solve the problems in the traditional processing process, the process research, focusing on the fishmeal processing process of the most critical link - drying paddle research. This paper mainly focuses on the continuous low-temperature vacuum drying equipment research, on the basis of the existing process to improve the design of the paddle structure. Compared with the current process, the fishmeal produced by continuous low-temperature vacuum dryer, under the same raw materials and the same time conditions, the transport capacity of the dryer per unit of time and the drying area of the paddle have been effectively improved.

Possibility assessment of the low-temperature district heating systems implementation in Ukraine

These researches concern the application of renewable energy sources in district heating systems. In Ukraine, district heating systems cover approximately 50% of the demand for thermal energy in the residential and communal sector. District heating systems 2G are most often used, which are characterized by high temperatures of the heat coolant, the lack of accounting for heat energy consumption during transportation of the heat coolant, and the use of fossil fuels. In the countries of the European Union, the introduction of district heating systems is considered one of the key directions for the transition to a decarbonized, environmentally safe and efficient energy system. The development of district heating systems technologies makes it possible to lower the temperature of the heat coolant in heat networks and increase the use of renewable energy sources. Ukraine will eventually become a full-fledged member of the European Union, and this determines the need to find ways to bring Ukraine's heat supply systems to the 4G level, in particular to low-temperature district heating systems with the most efficient use of renewable energy sources and waste heat. This article examines climatic, physical-geographical and social features, regulatory, technical and financial-economic opportunities and barriers to the implementation of low-temperature district heating systems in Ukraine. As a result of analytical studies, it was established that there are prerequisites for the introduction of low-temperature heat supply systems in Ukraine, however, a number of technical, regulatory, social and financial and economic measures need to be implemented to bring district heating systems up to 4G indicators. These studies allow establishing measures that require further research for the possibility of introducing low-temperature district heating systems in particular and environmental safety of heat supply systems in general.

Optimization study of a closed-cycle low-temperature evaporation system based on mathematical model and CFD

Treating high salt and high organic matter wastewater (HHW) generated during rapid socio-economic development is a significant challenge. This study aims to optimize a closed-cycle low-temperature evaporation (CCLE) system using mathematical modelling to be adapted to industrial applications. By using mathematical modelling and computational fluid dynamics (CFD), this study investigated the operating mechanism of the system under different operating conditions. Parametric analysis shows that increasing the compressor evaporation temperature and decreasing the condensation temperature is conducive to improving the performance of the heat pump unit, thereby increasing the wastewater treatment efficiency of the system and that a smaller heat transfer coil windward area is conducive to heat and mass transfer within the humidifier. The unique characteristics of the CCLE system are identified, and the wastewater treatment process under various operating conditions is explained. These findings may provide supporting information for the treatment of HHW by the CCLE system.

Progress in the development of acrylic resin-based powder coatings – an overview

Powder coatings, due to the lack of solvents and volatile organic compounds (VOCs), have gained in importance compared to conventional liquid systems. They fulfill key criteria such as effectiveness, economics, energy efficiency, environmental compliance, and excellent surface finish. Recently, low curing temperature and UV-cured systems have been increasingly used. These techniques offer a lot of advantages such as, application of powder coatings on the heat-sensitive materials and energy savings. Acrylic resins are rarely used in powder systems, mainly due to their price. Nevertheless, they are an attractive alternative in low temperature curing or UV-cured systems (free radical or cationic polymerization) thanks to their chemical structure. The review article focuses on the correlation between the chemical structure of the corresponding monomers in the resin and their properties and application in powder coatings. Moreover, the correlation between the structure of acrylic resin and the powder coating formulation process was described.

Development of the Low-Temperature Inducible System for Recombinant Protein Production in Escherichia coli Nissle 1917.

The pET system is commonly used for producing foreign proteins in Escherichia coli, but its reliance on the costly and metabolically demanding inducer IPTG limits its industrial use. This study engineered a low-temperature inducible system (LTIS) in E. coli Nissle 1917 (EcN) by combining the T7 expression system with the thermal inducible mechanism CI857-λPRPL to generate the new LTIS strain, ENL7P. The strain ENL7P-sfGFP-Km underwent overnight culture at 37 °C for 14-16 h, followed by subculturing at 30 °C for 24 h. This resulted in a notable 5.53-fold increase in the sfGFP induction rate when the strain was cultivated under 37-30 °C conditions. Moreover, gene expression was induced using a two-stage strategy. Initially, the strain was cultured overnight at 39 °C for 14-16 h, followed by a subculture at 30 °C for 6 h, and finally, another subculture at 30 °C for 24 h. This cultivation strategy led to an impressive 158.37-fold induction rate for sfGFP. Similar effects could be achieved through utilization of the LTIS system for inducing the production of thermophilic trehalose synthase from Thermus antranikianii (TaTS). The results of this study proved that the LTIS system has the potential for industrial applications.

Effect of bioaugmentation on gas production and microbial community during anaerobic digestion in a low-temperature fixed-bed reactor.

Low temperature is one of the limiting factors for anaerobic digestion in cold regions. To improve the efficiency of anaerobic digestion for methane production in stationary reactors under low-temperature conditions, and to improve the structure of the microbial community for anaerobic digestion at low temperatures. We investigated the effects of different concentrations of exogenous Methanomicrobium (10, 20, 30%) and different volumes of carbon fiber carriers (0, 10, 20%) on gas production and microbial communities to improve the performance of low-temperature anaerobic digestion systems. The results show that the addition of 30% exogenous microorganisms and a 10% volume of carbon fiber carrier led to the highest daily (128.15 mL/g VS) and cumulative (576.62 mL/g VS) methane production. This treatment effectively reduced the concentrations of COD and organic acid, in addition to stabilizing the pH of the system. High-throughput sequencing analysis revealed that the dominant bacteria under these conditions were Acidobacteria and Firmicutes and the dominant archaea were Candidatus_Udaeobacter and Methanobacterium. While the abundance of microorganisms that metabolize organic acids was reduced, the functional abundance of hydrogenophilic methanogenic microorganisms was increased. Therefore, the synergistic effect of Methanomicrobium bioaugmentation with carbon fiber carriers can significantly improve the performance and efficiency of low-temperature anaerobic fermentation systems.

Investigation of a Hybridized Cascade Trigeneration Cycle Combined with a District Heating and Air Conditioning System Using Vapour Absorption Refrigeration Cooling: Energy and Exergy Assessments

The insufficiency of energy supply and availability remains a significant global energy challenge. This work proposes a novel approach to addressing global energy challenges by testing the supercritical property and conversion of low-temperature thermal heat into useful energy. It introduces a combined-cascade steam-to-steam trigeneration cycle integrated with vapour absorption refrigeration (VAR) and district heating systems. Energetic and exergetic techniques were applied to assess irreversibility and exergetic destruction. At a gas turbine power of 26.1 MW, energy and exergy efficiencies of 76.68% and 37.71% were achieved, respectively, while producing 17.98 MW of electricity from the steam-to-steam driven cascaded topping and bottoming plants. The cascaded plant attained an energetic efficiency of 38.45% and an exergy efficiency of 56.19%. The overall cycle efficiencies were 85.05% (energy) and 77.99% (exergy). More than 50% of the plant’s lost energy came from the combustion chamber of the gas turbine. The trigeneration system incorporated a binary NH3–H2O VAR system, emphasizing its significance in low-temperature energy systems. The VAR system achieved a cycle exergetic efficiency of 92.25% at a cooling capacity of 2.07 MW, utilizing recovered waste heat at 88 °C for district hot water. The recovered heat minimizes overall exergy destruction, enhancing thermal plant performance.

Switched to Low-Temperature Powder Coating System

Switched to Low-Temperature Powder Coating System

Design of an integrated system for electrofuels production through Fischer-tropsch process

There has been a growing recognition in recent years that Electrofuels (e-fuels), also known as renewable and sustainable fuels, which are produced from hydrogen and carbon dioxide as the primary feedstocks, have great potential to reduce carbon footprint and address climate change. In the present study, contrary to most previous studies in which the sources of feedstock's preparation were considered as block boxes, two stand-alone processes are taken into account and incorporated into the e-fuels production system. H2 is obtained by a high-temperature electrolysis system having an overall efficiency nearly twice that of a low-temperature electrolysis system. CO2 is captured from a power plant flue gas stream with a purity of 99.81%. Investigating heat integration potential in such an integrated plant is an up-to-date and interesting topic and has not yet been well explored. Therefore, a heat integration within the three individual processes is implemented to reduce energy consumption. The design of the process-to-process heat transfer section is carried out using pinch design rules. By integrating individual units, approximately 42% of the required cold utility, traditionally supplied by chilled water and refrigerants, is allocated to generate high and medium-pressure steams. Having used the high-temperature steam electrolysis for H2 production, a process that requires less external electricity compared to low-temperature water electrolysis, a power-to-liquid efficiency of 70% is achieved. Furthermore, the results reveal a carbon conversion ratio of 98.6%, indicating the effective converting the carbon from the feedstock into liquid hydrocarbons.