Industrial Side Streams Research Articles

Protein Recovery of Tra Catfish (Pangasius hypophthalmus) Protein-Rich Side Streams by the pH-Shift Method.

Increasing protein demand has led to growing attention being given to the full utilization of proteins from side streams in industrial fish processing. In this study, proteins were recovered from three protein-rich side streams during Tra catfish (Pangasius hypophthalamus) processing (dark muscle; head-backbone; and abdominal cut-offs) by an optimized pH-shift process. Physicochemical characteristics of the resulting fish protein isolates (FPIs) were compared to industrial surimi from the same raw material batch. The pH had a significant influence on protein extraction, while extraction time and the ratio of the extraction solution to raw material had little effect on the protein and dry matter recoveries. Optimal protein extraction conditions were obtained at pH 12, a solvent to raw material ratio of 8, and an extraction duration of 150 min. The resulting FPI contained <10% of the fat and <15% of the ash of the raw material, while the FPI protein recovery was 83.0–88.9%, including a good amino acid profile. All FPIs had significantly higher protein content and lower lipid content than the surimi, indicating the high efficiency of using the pH-shift method to recover proteins from industrial Tra catfish side streams. The FPI made from abdominal cut-offs had high whiteness, increasing its potential for the development of a high-value product.

Diet Fermentation Leads to Microbial Adaptation in Black Soldier Fly (Hermetia illucens; Linnaeus, 1758) Larvae Reared on Palm Oil Side Streams

Insects offer a promising alternative source of protein to mitigate the environmental consequences of conventional livestock farming. Larvae of the black soldier fly (Hermetia illucens; Linnaeus, 1758) efficiently convert a variety of organic side streams and residues into valuable proteins, lipids, and chitin. Here, we evaluated the suitability of two palm oil industry side streams—empty fruit bunches (EFB) and palm kernel meal (PKM)—as larval feed, and their impact on the larval gut microbiome. Among 69 fungal species we screened, Marasmius palmivorus, Irpex consors, and Bjerkandera adusta achieved the fastest growth and lignin degradation, so these fungi were used for the pretreatment of 7:3 mixtures of EFB and PKM. Larvae reared on the mixture pretreated with B. adusta (BAD) developed significantly more quickly and reached a higher final weight than those reared on the other pretreatments or the non-fermented reference (NFR). Amplicon sequencing of the BAD and NFR groups revealed major differences in the larval gut microbiome. The NFR group was dominated by facultatively anaerobic Enterobacteriaceae (typical of H. illucens larvae) whereas the BAD group favored obligately anaerobic, cellulolytic bacteria (Ruminococcaceae and Lachnospiraceae). We hypothesize that fungal lignin degradation led to an accumulation of mycelia and subsequent cellulolytic breakdown of fiber residues, thus improving substrate digestibility.

Improving the flotation recovery of Cu from flash smelting slags by utilizing cellulose-based frother formulationss

• First published study using polymer-surfactant mixes as frothers in Cu slag flotation. • Using the PS-mix improved overall Cu recovery compared to commercial frother. • PS-mix significantly increased productivity, i.e. similar froth product in less time. • PS-mix demonstrated superior tolerance in performance when reducing xanthate dosage. Froth flotation is an operation currently used for the recovery of Cu from pyrometallurgical smelting slags due its simple operation and relatively low operational costs. While it has been utilized for many decades, it may be necessary to develop strategies that improve Cu recovery from slags, as the unprecedented increase in Cu demand has made industrial waste and side streams economically relevant sources of metals. This study presents a novel chemistry-based approach for the flotation of Cu from smelting slags by utilizing an amphiphilic cellulose-surfactant mixture as a flotation frother, hereby referred to as CellFroth. The present work pursues two main objectives: i) to improve the performance of flotation for the treatment of smelting slags and ii) to accomplish a first proof of concept for frothers produced from renewable sources in the context of industrial waste treatment. The flotation performance of CellFroth was compared with a commercially available additive (i.e., DowFroth250) and hydroxypropyl methyl cellulose (HPMC). The results showed significant advantages in performance for CellFroth. At the highest collector concentration, Cu recovery was higher with CellFroth compared to DowFroth 250 and pure HPMC (73%; 62% and 65% respectively). A 75% reduction in xanthate concentrations had negligible effects on Cu recovery for CellFroth (70%), while recoveries decreased drastically with DowFroth250 (47%) and pure HPMC (50 %). Finally, CellFroth consistently reached comparable concentrate productivity (grade and recovery) as DF250 within significantly shorter flotation times. The use of CellFroth thus offers the possibility of increasing the Cu recovery from flash smelting slags, while reducing the environmental impact of the process by using a frother produced from sustainable sources and simultaneously reducing xanthate consumption.

Blending eco-efficient calcium sulfoaluminate belite ferrite cement to enhance the physico–mechanical properties of Portland cement paste cured in refrigerated and natural winter conditions

The acceleration impacts of calcium sulfoaluminate belite ferrite (CSABF)—a cement produced from industrial side streams—on the hydration and strength development of Portland cement (PC) paste cured at −5 °C with and without pre-curing at room temperature were investigated. The impacts of eco-friendly CSABF cement content and pre-curing on the setting time and hardened properties of pastes were investigated. Freezing point of the paste and the amount of freezable water (FW) decreased with CSABF cement content and pre-curing. Hydration rate increased with CSABF cement content. By adding an optimal CSABF cement content, the compressive strength of paste cured at −5 °C increased by 500%. The effects of pre-curing on the compressive strength of the subzero-cured pastes were highly dependent on CSABF cement content and curing period. After 6 months, the outdoor-cured 70%PC/30%CSABF paste gained compressive strength comparable to that in the 90-day-old pair cured at −5 °C and continuous strength gain was detected up to one-year. The microstructural observations and porosity results are consistent with compressive strength measurements.

Techno-economic assessment of DHA-rich Aurantiochytrium sp. production using food industry by-products and waste streams as alternative growth media

Reducing the production cost of DHA algae oil is a necessary step to obtain a sustainable omega-3 source able to compete with fish oil. In this study, a techno-economic analysis was carried out for the production of a DHA rich thraustochytrid using food industry by products and waste. Three cultivation scenarios were developed: the first using standard bulk materials as source of nutrients, the second with the utilization of brewery by-product and spent osmotic solutions; the third scenario using a mix of dairy wastewater, brewery by-product and spent osmotic solution. The operating costs were reduced by an average of 35% with food wastes scenarios, increasing up to 8% the return on investment respect to the standard cultivation method. Depending from plant dimension, sensitivity analysis showed a decrease in unit production cost up to 38% when using food industry side-streams.

Behaviour of Extractives in Norway Spruce (Picea abies) Bark during Pile Storage.

The current practices regarding the procurement chain of forest industry sidestreams, such as conifer bark, do not always lead to optimal conditions for preserving individual chemical compounds. This study investigates the standard way of storing bark in large piles in an open area. We mainly focus on the degradation of the most essential hydrophilic and hydrophobic extractives and carbohydrates. First, two large 450 m3 piles of bark from Norway spruce (Picea abies) were formed, one of which was covered with snow. The degradation of the bark extractives was monitored for 24 weeks. Samples were taken from the middle, side and top of the pile. Each sample was extracted at 120 °C with both n-hexane and water, and the extracts produced were then analysed chromatographically using gas chromatography with flame ionisation or mass selective detection and high-performance liquid chromatography. The carbohydrates were next analysed using acidic hydrolysis and acidic methanolysis, followed by chromatographic separation of the monosaccharides formed and their derivatives. The results showed that the most intensive degradation occurred during the first 4 weeks of storage. The levels of hydrophilic extractives were also found to decrease drastically (69% in normal pile and 73% in snow-covered pile) during storage, whereas the decrease in hydrophobic extractives was relatively stable (15% in normal pile and 8% in snow-covered pile). The top of the piles exhibited the most significant decrease in the total level of extractives (73% in normal and snow-covered pile), whereas the bark in the middle of the pile retained the highest amount of extractives (decreased by 51% in normal pile and 47% in snow-covered pile) after 24-week storage.

The Role of Logistics in Industrial Side Stream Utilisation – Case: Aqueous Paint Sludge

Purpose: In this article, the utilisation of a case side stream, aqueous paint sludge is studied in accordance with the principles of the circular economy. The study's main objective is to find new potential utilisation possibilities for aqueous paint sludge generated in the region and take a closer look at the role of logistics in the industrial side stream utilisation-based business cases and value chains. Study design/methodology/approach: In this article, the utilisation of aqueous paint sludge is studied via a descriptive case study in the context of Northern Ostrobothnia, Finland. The current state of the paint sludge problem was analysed by interviewing five company representatives. In addition, a workshop was organised, and before the workshop, a questionnaire was sent to all invited. Findings: As a result, the most feasible solutions for aqueous paint sludge utilisation were identified and evaluated from economic, technical, and environmental points of view in the context of this study. In all the proposed solutions, one general challenge was the logistics for narrow material flows from decentralised sources in a relatively large geographical area. Originality/value: Prior case studies of paint sludge utilisation as a raw material have been conducted, but the logistics have not played a significant role in the studies. Logistics has been an important part of the circular economy in the literature. This study reaffirms this notion and finds logistics to have an important and decisive role in industrial side stream utilisation-based business cases and value chains.

Potential of neglected biomass and industrial side-streams utilization in biofuels production

Potential of neglected biomass and industrial side-streams utilization in biofuels production

Improving sustainability in wood coating: testing lignin and cellulose nanocrystals as additives to commercial acrylic wood coatings for bio-building

Wood use in bio-building should be considered as one of the main pillars of sustainability. According to international standards, beech wood (Fagus sylvatica L.) is a rather less durable species as it is subject to degradation due to weathering, though it is abundantly available to a more intense use. Service life of beech products and wood products in general can be enhanced by different methods, such as heat treatments, but new chances are offered by coating technologies. However, to ensure protection from wood-destroying organisms, most commercial coatings include components that could harm human health, other organisms and the environment. Therefore, coating industry has to develop more eco-friendly solutions in order to decrease its impact on human health and environment. The objective of this article was to modify commercial acrylic varnish by adding cellulose nanocrystals (CNC) and lignin (LN) extracted from beech wood and investigate their effect on water sorption, additive dispersion in the coating matrix and coating resistance to bacterial attack. Contact angle, weight gain and colour difference were analysed and FT-IR mapping was applied. The performance of CNC was promising, as it enhanced water sorption of the modified coating. However, protection against bacterial attack was not satisfying. On the other hand, chemically unmodified lignin did not show positive effects as component in the coating formulation. Nevertheless, the currently limited usage of these two renewable and abundant resources urgently calls for their more efficient utilization, in order to create additional value with industry side-streams producing novel bio-based materials. Further experiments are needed in order to obtain better dispersion of the particles and higher resistance to bacterial attacks.

High strength fiber reinforced one-part alkali activated slag composites from industrial side streams

This paper details the effect of fiber reinforcement on mechanical characteristics of by-products based one-part alkali activated material (AAM). Two different binder matrices were considered in this study, such as, plain slag, and ternary blended slag, to understand their efficiency in fiber reinforced system. These matrices were reinforced with 1% v/v of three different fibers (steel, glass and basalt) to improve the flexural performance of high strength mortar blends. Steel fiber reinforced one-part AAM outperforms mineral fibers in compressive strength contribution. The fracture energy of steel fiber reinforced compositions was roughly 4 times higher than that of mineral fiber reinforced materials. In addition, the flexural performance of ternary blended matrix was higher than that of slag-based composition regardless fiber types and properties. Finally, preliminary finite element modelling was considered to assess the applicability of the concrete damage plasticity constitutive model in predicting the nonlinear behavior of the developed composites. The numerical predictions proved the accuracy of the model with good agreement between experimental and numerical results.

Plant-Based Structures as an Opportunity to Engineer Optical Functions in Next-Generation Light Management.

This review addresses the reconstruction of structural plant components (cellulose, lignin, and hemicelluloses) into materials displaying advanced optical properties. The strategies to isolate the main building blocks are discussed, and the effects of fibrillation, fibril alignment, densification, self-assembly, surface-patterning, and compositing are presented considering their role in engineering optical performance. Then, key elements that enable lignocellulosic to be translated into materials that present optical functionality, such as transparency, haze, reflectance, UV-blocking, luminescence, and structural colors, are described. Mapping the optical landscape that is accessible from lignocellulosics is shown as an essential step toward their utilization in smart devices. Advanced materials built from sustainable resources, including those obtained from industrial or agricultural side streams, demonstrate enormous promise in optoelectronics due to their potentially lower cost, while meeting or even exceeding current demands in performance. The requirements are summarized for the production and application of plant-based optically functional materials in different smart material applications and the review is concluded with a perspective about this active field of knowledge.

Utilization of a Wheat Sidestream for 5-Aminovalerate Production in Corynebacterium glutamicum.

Production of plastics from petroleum-based raw materials extensively contributes to global pollution and CO2 emissions. Biotechnological production of functionalized monomers can reduce the environmental impact, in particular when using industrial sidestreams as feedstocks. Corynebacterium glutamicum, which is used in the million-ton-scale amino acid production, has been engineered for sustainable production of polyamide monomers. In this study, wheat sidestream concentrate (WSC) from industrial starch production was utilized for production of l-lysine–derived bifunctional monomers using metabolically engineered C. glutamicum strains. Growth of C. glutamicum on WSC was observed and could be improved by hydrolysis of WSC. By heterologous expression of the genes xylA Xc B Cg (xylA from Xanthomonas campestris) and araBAD Ec from E. coli, xylose, and arabinose in WSC hydrolysate (WSCH), in addition to glucose, could be consumed, and production of l-lysine could be increased. WSCH-based production of cadaverine and 5-aminovalerate (5AVA) was enabled. To this end, the lysine decarboxylase gene ldcC Ec from E. coli was expressed alone or for conversion to 5AVA cascaded either with putrescine transaminase and dehydrogenase genes patDA Ec from E. coli or with putrescine oxidase gene puo Rq from Rhodococcus qingshengii and patD Ec . Deletion of the l-glutamate dehydrogenase–encoding gene gdh reduced formation of l-glutamate as a side product for strains with either of the cascades. Since the former cascade (ldcC Ec -patDA Ec ) yields l-glutamate, 5AVA production is coupled to growth by flux enforcement resulting in the highest 5AVA titer obtained with WSCH-based media.

Life cycle assessment of a low-height noise barrier for railway traffic noise

Life cycle assessment (LCA) methodology was applied to assess five locally developed mix designs for a 20 m low-height noise barrier (LHNB) categorized as: precast Portland cement concrete (S0-baseline scenario), two precast geopolymer composites (S1; S2), and two additive-manufactured geopolymer composites (S3; S4). The objective of the study is to carry out a LCA study of the mix designs, to identify environmental hotspots and evaluate the influence of durability and service life on the LCA results. Environmental impact categories assessed are global warming potential (GWP), fossil depletion, photochemical ozone formation, and acidification. Results show that when a fixed service life of 40 years is chosen for all mix designs, S4 is the most environmentally sustainable with 73% reduced GWP when compared to S0. When sensitivity analysis was used to determine the effect of varying service life (10–40 years) on S1–S4; S4 shows equivalent to better environmental performance than S0. Carbonation was considered and result shows up to 8% of CO2 uptake can be achieved. In conclusion, S4 depicts solutions and concepts that result in environmental improvement potentials for a LHNB from geopolymer composites. The results from this study supported decision-making and guided in the development a 20 m LHNB from 83% industrial side-streams and 0.3% alkali activator maintaining a 10 dB absorption capacity.

Printing Parameter Requirements for 3D Printable Geopolymer Materials Prepared from Industrial Side Streams.

The objective of this investigation is to study the printing parameter requirements for sustainable 3D printable geopolymer materials. Side streams of the paper, mining, and construction industries were applied as geopolymer raw materials. The effect of printing parameters in terms of buildability, mixability, extrudability, curing, Al-to-Si ratio, and waste materials utilisation on the fresh and hardened state of the materials was studied. The material performance of a fresh geopolymer was measured using setting time and shape stability tests. Standardised test techniques were applied in the testing of the hardened material properties of compressive and flexural strength. The majority of developed suitable 3D printable geopolymers comprised 56–58% recycled material. Heating was used to improve the buildability and setting of the material significantly. A reactive recyclable material content of greater than 20% caused the strength and material workability to decrease. A curing time of 7–28 days increased the compressive strength but decreased the flexural strength. The layers in the test samples exhibited decreased and increased strength, respectively, in compressive and flexural strength tests. Geopolymer development was found to be a compromise between different strength values and recyclable material contents. By focusing on specialised and complex-shape products, 3D printing of geopolymers can compete with traditional manufacturing in limited markets.

The Effect of Fibrous Reinforcement on the Polycondensation Degree of Slag-Based Alkali Activated Composites.

Alternative cementitious binders, based on industrial side streams, characterized by a low carbon footprint, are profitably proposed to partially replace Portland cement. Among these alternatives, alkali-activated materials have attracted attention as a promising cementitious binder. In this paper, the chemical stability of the matrix, in fiber-reinforced slag-based alkali-activated composites, was studied, in order to assess any possible effect of the presence of the reinforcement on the chemistry of polycondensation. For this purpose, organic fiber, cellulose, and an inorganic fiber, basalt, were chosen, showing a different behavior in the alkaline media that was used to activate the slag fine powders. The novelty of the paper is the study of consolidation by means of chemical measurements, more than from the mechanical point of view. The evaluation of the chemical behavior of the starting slag in NaOH, indeed, was preparatory to the understanding of the consolidation degree in the alkali-activated composites. The reactivity of alkali-activated composites was studied in water (integrity test, normed leaching test, pH and ionic conductivity), and acids (leaching in acetic acid and HCl attack). The presence of fibers does not favor nor hinder the geopolymerization process, even if an increase in the ionic conductivity in samples containing fibers leads to the hypothesis that samples with fibers are less consolidated, or that fiber dissolution contributes to the conductivity values. The amorphous fraction was enriched in silicon after HCl attack, but the structure was not completely dissolved, and the presence of an amorphous phase is confirmed (C–S–H gel). Basalt fibers partly dissolved in the alkaline environment, leading to the formation of a C–N–A–S–H gel surrounding the fibers. In contrast, cellulose fiber remained stable in both acidic and alkaline conditions.

Estimating the Cost-Competitiveness of Recycling-Based Geopolymer Concretes

The cement industry is a major contributor to greenhouse gas emissions on a global scale. Consequently, there has been an increasing interest, in both academia and business, in low-carbon concretes in which Ordinary Portland Cement (OPC) is partially or fully replaced with industrial side streams. However, the realization of the environmental benefits of such materials depends on how competitive they are in the construction market, where low costs are a major competitive factor. This is not straightforward, as many types of concretes exist. Raw material prices vary, and costs can be influenced by governmental regulations via carbon pricing. This study presents a case study estimating the cost prices of four different geopolymer concretes with different material compositions and carbon footprints, considering the raw material price variability and the potential impact of carbon emissions regulation (carbon price). The case study demonstrates how material mix cost comparisons can be made openly and systematically. The results imply that carbon pricing, at the rates currently applied, does not significantly change the cost price difference between traditional and geopolymer concretes. Instead, cost-competitiveness of low carbon concretes depends heavily on the material mix type and the availability of critical side streams.

High strength one-part alkali-activated slag blends designed by particle packing optimization

This paper focuses on the development of high-strength and eco-friendly one-part (i.e., dry-mix) alkali-activated mortar with ground granulated blast furnace slag as the main precursor. In addition to slag, phyllite dust and silica fume were used as co-binders in binary and ternary blends to improve mechanical properties. Particle packing optimization was employed for the mix proportioning to achieve a compact matrix skeleton. The results revealed that a 10% increase in mortar strength was gained after adjusting the particle packing and an additional 20% increment was observed after blending the slag with other mineral admixtures. Ternary blend with all three binders achieved a mortar compressive strength value of 145 MPa (at 28 d age), which is the highest strength reported in one-part alkali-activated materials. Additionally, ternary blends present potential economic benefits because of their ability to replace slag with lower-cost industrial side streams.

Tailoring the Structure of Lipids, Oleogels and Fat Replacers by Different Approaches for Solving the Trans-Fat Issue-A Review.

The issue of the adverse effects of trans-fatty acids has become more transparent in recent years due to researched evidence of their link with coronary diseases, obesity or type 2 diabetes. Apart from conventional techniques for lipid structuring, novel nonconventional approaches for the same matter, such as enzymatic interesterification, genetic modification, oleogelation or using components from nonlipid origins such as fat replacers have been proposed, leading to a product with a healthier nutritional profile (low in saturated fats, zero trans fats and high in polyunsaturated fats). However, replacing conventional fat with a structured lipid or with a fat mimetic can alternate some of the technological operations or the food quality impeding consumers’ acceptance. In this review, we summarize the research of the different existing methods (including conventional and nonconventional) for tailoring lipids in order to give a concise and critical overview in the field. Specifically, raw materials, methods for their production and the potential of food application, together with the properties of new product formulations, have been discussed. Future perspectives, such as the possibility of bioengineering approaches and the valorization of industrial side streams in the framework of Green Production and Circular Economy in the production of tailored lipids, have been highlighted. Additionally, a schematic diagram classifying conventional and nonconventional techniques is proposed based on the processing steps included in tailored lipid production as a convenient and straightforward tool for research and industry searching for healthy, sustainable and zero trans edible lipid system alternatives.

Characterisation of Industrial Side Streams and Their Application for the Production of Geopolymer Composites

This study focuses on characterisation of side streams including biomass fly ash, biomass bottom ash, coal fly ash, green liquor dregs, limestone mine tailings, and electric arc furnace steel slag from different industrial locations in Finland. It was found that the fly ash samples contained the highest Al2O3 and SiO2 concentrations, a large number of spherical particles of small sizes and high specific surface areas. Fly ashes and steel slag were observed to contain higher amounts of amorphous phases compared to the other side streams. The high loss on ignition value of the coal fly ash and green liquor dregs was found to exceed the limitations for their application in geopolymer composites. Despite their relatively high concentrations in ashes and steel slag, the leaching tests have shown that no hazardous metal leached out from the streams. Finally, test specimens of geopolymer composites (GP2) were prepared by the application of biomass fly ash, bottom ash, and limestone mine tailings without any pre-treatment process, in addition to the ordinary Portland cement-(R) and metakaolin-based geopolymer composites (GP1). The measured compressive (14.1 MPa) and flexural strength (3.5 MPa) of GP2 suggest that it could be used in concrete kerbs and paving flags. The data has also shown that over 500% of the compressive strength was developed between 7 and 28 days in GP2, whereas in the case of reference concrete (R) and the metakaolin-based geopolymer composite (GP1) it was developed in the first 7 days.

Alkali-Activated Materials as Catalysts for Water Purification

In this study, novel and cost-effective alkali-activated materials (AAMs) for catalytic applications were developed by using an industrial side stream, i.e., blast furnace slag (BFS). AAMs can be prepared from aluminosilicate precursors under mild conditions (room temperature using non-hazardous chemicals). AAMs were synthesized by mixing BFS and a 50 wt % sodium hydroxide (NaOH) solution at different BFS/NaOH ratios. The pastes were poured into molds, followed by consolidation at 20 or 60 °C. As the active metal, Fe was impregnated into the prepared AAMs by ion exchange. The prepared materials were examined as catalysts for the catalytic wet peroxide oxidation (CWPO) of a bisphenol A (BPA) aqueous solution. As-prepared AAMs exhibited a moderate surface area and mesoporous structure, and they exhibited moderate activity for the CWPO of BPA, while the iron ion-exchanged, BFS-based catalyst (Fe/BFS30-60) exhibited the maximum removal of BPA (50%) during 3 h of oxidation at pH 3.5 at 70 °C. Therefore, these new, inexpensive, AAM-based catalysts could be interesting alternatives for catalytic wastewater treatment applications.