Abstract

The issue of the adverse effects of trans-fatty acids has become more transparent in recent years due to researched evidence of their link with coronary diseases, obesity or type 2 diabetes. Apart from conventional techniques for lipid structuring, novel nonconventional approaches for the same matter, such as enzymatic interesterification, genetic modification, oleogelation or using components from nonlipid origins such as fat replacers have been proposed, leading to a product with a healthier nutritional profile (low in saturated fats, zero trans fats and high in polyunsaturated fats). However, replacing conventional fat with a structured lipid or with a fat mimetic can alternate some of the technological operations or the food quality impeding consumers’ acceptance. In this review, we summarize the research of the different existing methods (including conventional and nonconventional) for tailoring lipids in order to give a concise and critical overview in the field. Specifically, raw materials, methods for their production and the potential of food application, together with the properties of new product formulations, have been discussed. Future perspectives, such as the possibility of bioengineering approaches and the valorization of industrial side streams in the framework of Green Production and Circular Economy in the production of tailored lipids, have been highlighted. Additionally, a schematic diagram classifying conventional and nonconventional techniques is proposed based on the processing steps included in tailored lipid production as a convenient and straightforward tool for research and industry searching for healthy, sustainable and zero trans edible lipid system alternatives.

Highlights

  • Composition as human milk low trans-fatty acids with desired spreadability zero-trans structured lipids used for high temperature applications better storage quality for palm stearin and rapeseed oil blend higher crystallization temperature, homogenous crystal network, reducing low-density lipoproteins (LDL)

  • The revolution in genetic engineering opened the door in structuring the lipids and altering the fatty acid profile directly into plant by identification, extraction, cloning and transferring targeted genes that will induce the synthesis of oil in a desirable, flexible manner

  • Lipid structuring as an idea was developed decades ago, leading to the extensive exploration and industrialization of the techniques, which nowadays are being used in the production of margarines, shortenings and creams

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Summary

Fractionation

Fractionation is widely used conventional technique for lipid structuring and their chemical and physical property alterations for better performance and suitability in various applications. Dry fractionation was improved with introducing multistep crystallizations separated with membrane press filters allowing the manufacturing of fractions for different applications, such as top oleins, palm red fractions and palm mid fractions (solvent-free cocoa butter equivalent; CBE) [33]. Cocoa butter improver (CBI) is used in blends together with cocoa butter for manufacturing heat-resistant chocolate products for tropical climates It is usually made from high-melting symmetrical monounsaturated TAG. Jin et al [35] reported CBI production from mango (Mangifera indica L) kernel fat in three-staged acetone fractionation, where the second fraction showed the highest high-melting symmetrical monounsaturated. Symmetric monounsaturated TAG with a high yield and free of tripalmitin were produced from the second fractionation in two-stage acetone fractionation from palm stearin as the starting material [37]. Sunflower oil by dry fractionation, which were further processed by solvent fractionation for high-melting sunflower stearin production. Besides many advantages that this modification process has, there are several drawbacks, such as high energy and material costs, safety issues, consumer acceptance, solvent recovery, low separation efficiency or the palm and other tropical fat sustainability

Chemical Synthesis
Genetically Modified Lipids
Conventional Oleogels
Bioengineered Oleogels
Structuring Methodology
Fat Replacers of Nonlipid Origin
Conclusions
Findings
Limitation
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