Frequency Dependence Research Articles

Conjugated safflower seed oil and its oleogels stabilization properties: Thermodynamic properties, rheology, oxidative stability

Conjugated safflower seed oil (CSSO) was used as the base oil, and beeswax (BW) was used as the gelling agent to prepare BW-CSSO oleogel. The effects of different additions of wax on the properties of BW-CSSO oleogel, as well as their oxidative stability, were investigated. The results indicated that an oleogel could be formed with CSSO at a BW concentration of 5 wt% at 25 °C, and the oil-holding capacity and hardness of the oleogel increased significantly as the BW concentration increased from 5 wt% to 11 wt%. Differential scanning calorimetry results showed that the peak crystallization and melting temperatures of the oleogel generally increased with the increase of wax addition, and both the crystallization and melting peaks became clearer and sharper. The rheological results indicated that all the samples showed shear-thinning behavior and higher concentrations of BW-CSSO oleogel were more capable of forming robust structures with lower frequency dependence. The free fatty acid release rate from BW-CSSO oleogel decreased with increasing BW concentration because the oleogel was stronger due to the formation of a more robust network, and the network of strong crystals influences the contact between lipase and oil, slowing down the release of oil from the interior of the oleogel structure and affecting the hydrolysis of oil. The network structure of the oleogel could inhibit the generation of CSSO secondary oxidation products and improve the oxidative stability of CSSO. This study provides the relevant parameters of the BW-CSSO oleogel and lays the foundation for subsequent studies.

Multiphysics modeling of magnetoelectric composite disks by a 2D axisymmetric finite element approach

A 2D axisymmetric finite element multiphysics model is proposed to study magnetoelectric composite disks. This modeling approach includes a nonlinear magneto-elastic model to replicate the behavior of magnetostrictive materials under static conditions. Additionally, it offers a harmonic regime resolution that considers frequency dependence, including the implicit inclusion of eddy currents in the formulation, as well as electrical load. To validate the model, simulation results regarding the dependence of the static magnetic field and frequency are presented and compared with experimental measurements from literature.

PARAMETERS OF THE PERTURBED STATE OF THE DENDRITE TIP IN DEEPLY SUPERCOOLED NICKEL AND COPPER MELTS

The object of study is the morphological stability of the tip of a free dendrite in a supercooled melt of a pure substance. Areas of deep supercooling are considered: for nickel DT > 166 K, for copper – DT > 180 K. A distinctive feature of the processes being studied is the presence of two propagation velocities of small disturbances (velocities of “sound”). The dependences of these rates on the supercooling of the melt were determined. The periodic and coordinate-aperiodic modes of perturbation of the growth line have been studied in detail. For these stable regimes, the possibility of observing the same speed of the disturbance wave in two processes, differing from each other in the size of the spatial inhomogeneity of the background in front of the wave and the characteristic wave attenuation times, was discovered. It is shown that aperiodic instability appears if, after the passage of the wave front, the width of the growth line inhomogeneity zone decreases. The resonant excitation mode of the dendrite tip demonstrates important differences between the properties of the nickel and copper melts. First of all, this relates to the temperature dependences of the resonant frequency and the speed of a standing wave formed in the vicinity of the vertex. Numerical calculations are presented and graphic information is presented illustrating the patterns of growth of nickel and copper dendrites.

Trap states and carrier diffusion lengths in NiO/β-Ga2O3 heterojunctions

We report the electrical properties, deep trap spectra, and diffusion lengths of non-equilibrium carriers in Ni Schottky diodes and NiO/Ga2O3 heterojunctions (HJs) prepared on the same n−/n+ β-Ga2O3 epi structures. The heterojunctions decrease the reverse current of Ga2O3 high-power rectifiers. In HJs, in contrast to Schottky diodes, the capacitance and AC conductance show a prominent frequency and temperature dependence, suggesting the presence of two temperature activation processes with activation energies of 0.17 and 0.1 eV. The deep trap spectra of the Schottky diodes and HJs differ by the absence in the HJ of deep electron traps E2* with level near Ec − 0.7 eV considered to be an important center of non-radiative recombination. This correlates with the observed increase in the diffusion length of non-equilibrium charge carriers in the HJs to 370 nm compared to 240 nm in the Schottky diodes. The diffusion length of charge carriers in p-NiO was found to be quite short, 30 nm. Possible reasons for the observed differences and possible origin of the minority-trap-like feature commonly reported to be present in the deep level spectra of HJs and also observed in our experiments are discussed.

Temperature and frequency dependence of conductivity, density of states, and dielectric permittivity of ternary metal chalcogenide PbSnSe2 flake

The mechanically cleaved flake of ternary metal chalcogenide PbSnSe2 was transferred onto the interdigitated electrodes to form electrical contacts. The temperature dependent (180 K–250 K) electrical properties were then analyzed employing complex impedance spectroscopy from 2 kHz to 2 MHz. A detailed analysis of Nyquist plots proposed the space charge dependent behavior and negative temperature coefficient of PbSnSe2 flake. The AC conductivity followed Jonscher's power law with s-parameter value being less than unity. The values of s-parameter increased with rise in temperature suggesting the presence of non-overlapping small polaron tunneling (NSPT) in the PbSnSe2 flake. From this NSPT model, tunneling distance, hopping energy, and density of states (DOS) were estimated at temperatures from 180 K–250 K. The dielectric permittivity showed dispersion at lower frequencies and the tangent loss was also found to be directly related to temperature. A single semicircular arc in complex modulus analysis showed the dominance of bulk effect in the material.

Frequency dependence of human thresholds: both perceptual and vestibuloocular reflex thresholds.

Although perceptual thresholds have been widely studied, vestibuloocular reflex (VOR) thresholds have received less attention, so the relationship between VOR and perceptual thresholds remains unclear. We compared the frequency dependence of human VOR thresholds to human perceptual thresholds for yaw head rotation in both upright ("yaw rotation") and supine ("yaw tilt") positions, using the same human subjects and motion device. VOR thresholds were generally a little smaller than perceptual thresholds. We also found that horizontal VOR thresholds for both yaw rotation about an Earth-vertical axis and yaw tilt (yaw rotation about an Earth-horizontal axis) were relatively constant across four frequencies (0.2, 0.5, 1, and 2 Hz), with little difference between yaw rotation and yaw tilt VOR thresholds. For yaw tilt stimuli, perceptual thresholds were slightly lower at the lowest frequency and nearly constant at all other (higher) frequencies. However, for yaw rotation, perceptual thresholds increased significantly at the lowest frequency (0.2 Hz). We conclude 1) that VOR thresholds were relatively constant across frequency for both yaw rotation and yaw tilt, 2) that the known contributions of velocity storage to the VOR likely yielded these VOR thresholds that were similar for yaw rotation and yaw tilt for all frequencies tested, and 3) that the integration of otolith and horizontal canal signals during yaw tilt when supine contributes to stable perceptual thresholds, especially relative to the low-frequency perceptual thresholds recorded during yaw rotation.NEW & NOTEWORTHY We describe for the first time that human VOR thresholds differ from human forced-choice perceptual thresholds, with the difference especially evident at frequencies below 0.5 Hz. We also report that VOR thresholds are relatively constant across frequency for both yaw rotation and yaw tilt. These findings are consistent with the idea that high-pass filtering in cortical pathways impacts cognitive decision-making.

Dynamical properties of solid and hydrated collagen: Insight from nuclear magnetic resonance relaxometry.

1H spin-lattice Nuclear Magnetic Resonance relaxometry experiments have been performed for collagen and collagen-based artificial tissues in the frequency range of 10 kHz-20MHz. The studies were performed for non-hydrated and hydrated materials. The relaxation data have been interpreted as including relaxation contributions originating from 1H-1H and 1H-14N dipole-dipole interactions, the latter leading to Quadrupole Relaxation Enhancement effects. The 1H-1H relaxation contributions have been decomposed into terms associated with dynamical processes on different time scales. A comparison of the parameters for the non-hydrated and hydrated systems has shown that hydration leads to a decrease in the dipolar relaxation constants without significantly affecting the dynamical processes. In the next step, the relaxation data for the hydrated systems were interpreted in terms of a model assuming two-dimensional translational diffusion of water molecules in the vicinity of the macromolecular surfaces and a sub-diffusive motion leading to a power law of the frequency dependencies of the relaxation rates. It was found that the water diffusion process is slowed down by at least two orders of magnitude compared to bulk water diffusion. The frequency dependencies of the relaxation rates in hydrated tissues and hydrated collagen are characterized by different power laws (ωH-β, where ωH denotes the 1H resonance frequency): the first of about 0.4 and the second close to unity.

Optimizing ultrasound Doppler measurement precision: a comprehensive experimental approach

Experimental studies were conducted utilizing advanced equipment comprising a generator, tubing system, pump module, sonographer, and PC. The generator serves as the central component connected by tubes to the pump, forming a closed circuit. A tee in the tubing set prevents Doppler fluid leakage, with the fluid poured through a special funnel into the circuit post-connection. The Doppler fluid is evenly mixed by shaking its bottle to enhance signal strength. The entire system is sealed. The centrifugal pump generates continuous flows; different power modes were tested for 30 minutes each, with frequency shifts measured at angles α=15°, 30°, and 60°. Pump disconnection from the power supply prevents liquid entry during tubing connection. The pump module housing includes ventilation holes. A 3 by 8 cm Doppler prism, treated with ultrasonic gel, was connected to the tubing to capture data. A sonographer emitting signals at 2 MHz, with a gain range of 10 to 40 dB, was utilized for sound spectra analysis. High-mode operation, 4 microseconds pulse duration, and a 32 microseconds receiver gate were set. The ultrasound apparatus dimensions were 230 x 236 x 168 mm, with a power consumption of 27 VA. Data visualization was facilitated by an LED panel, with adjustable acoustic signal volume. A USB interface enabled connection to a PC for ease of use and data analysis. Special software facilitated graph generation depicting frequency vs. time dependence measurements. Frequency analysis yielded average (f-mean) and maximum (f-max) frequency values, with f-mean utilized to measure Doppler effect frequency shift. The presented data showcases various pump speeds and incidence angles, each yielding distinctive frequency characteristics.

Physical insight into the abnormal VTH instability of Schottky p-GaN HEMTs under high-frequency operation

In this Letter, we investigate the threshold voltage (VTH) instability of Schottky p-GaN gate high electron mobility transistors (SP-HEMTs) under high-frequency operation by a resistive-load hard switching method. The abnormal VTH instability is observed, which is different between fully and partially depleted SP-HEMTs (FD- and PD-HEMTs). Notably, for FD-HEMT, VTH shifts positively with effective stress time. However, the VTH instability in PD-HEMT is more complex. At low VGS (e.g., 3 V) and high VGS (e.g., 6 V), VTH shifts positively with stress time consistently. Nevertheless, at intermediate VGS levels (e.g., 4 and 5 V), VTH initially shifts positively and then negatively, displaying a non-monotonous variation. Furthermore, the frequency dependence of VTH is contingent upon VGS. At low VGS, VTH exhibits a negative shift with the increase in frequency. This trend inverses when VGS exceeds 4 V. And it should be noted that the extracted VTH under high-frequency operation is lower than their quasi-static values for both transistor types. This work depicts the physical process and mechanism of the abnormal VTH instability; different from the quasi-static case, hole accumulation effects will be enhanced due to the high dV/dt, which results in a lower VTH. The distinct VTH behaviors of FD- and PD-HEMTs are closely related to the trapping effects, as well as hole accumulation and insufficiency, within the two different p-GaN gate layers.

Ultrasound enhanced diffusion in hydrogels: An experimental and non-equilibrium molecular dynamics study.

Focused ultrasound has experimentally been found to enhance the diffusion of nanoparticles; our aim with this work is to study this effect closer using both experiments and non-equilibrium molecular dynamics. Measurements from single particle tracking of 40nm polystyrene nanoparticles in an agarose hydrogel with and without focused ultrasound are presented and compared with a previous experimental study using 100nm polystyrene nanoparticles. In both cases, we observed an increase in the mean square displacement during focused ultrasound treatment. We developed a coarse-grained non-equilibrium molecular dynamics model with an implicit solvent to investigate the increase in the mean square displacement and its frequency and amplitude dependencies. This model consists of polymer fibers and two sizes of nanoparticles, and the effect of the focused ultrasound was modeled as an external oscillating force field. A comparison between the simulation and experimental results shows similar mean square displacement trends, suggesting that the particle velocity is a significant contributor to the observed ultrasound-enhanced mean square displacement. The resulting diffusion coefficients from the model are compared to the diffusion equation for a two-time continuous time random walk. The model is found to have the same frequency dependency. At lower particle velocity amplitude values, the model has a quadratic relation with the particle velocity amplitude as described by the two-time continuous time random walk derived diffusion equation, but at higher amplitudes, the model deviates, and its diffusion coefficient reaches the non-hindered diffusion coefficient. This observation suggests that at higher ultrasound intensities in hydrogels, the non-hindered diffusion coefficient can be used.

When does antimicrobial resistance increase bacterial fitness? Effects of dosing, social interactions, and frequency dependence on the benefits of AmpC β-lactamases in broth, biofilms, and a gut infection model

When does antimicrobial resistance increase bacterial fitness? Effects of dosing, social interactions, and frequency dependence on the benefits of AmpC <i>β</i>-lactamases in broth, biofilms, and a gut infection model

Analysis of Deep-Water Low-Frequency Sound Multipath Arrivals and Interference Striation Patterns

The deep-water sound multipath arrivals and interference striation patterns not only vary with range and depth but also with frequency. The first two cases can be solved using a ray-mode method in the high-frequency limit. However, this method may cause unsatisfactory results in treating low-frequency sounds (as low as tens of Hertz) because of the Wentzel-Kramers-Brillouin (WKB) high-frequency approximation assumption. To overcome this problem, the authors exploited phase information to modify the ray parameters, such as the propagation range, the time delay, and the group velocity. Following that, a waveguide invariant (WI) expression was derived to address low-frequency sound interference problems. Numerical investigations demonstrated that the physical mechanism of the frequency dependence of the multipath arrivals and interference striation patterns could be better understood using this modified ray-mode method. In addition, the influence of bottom sound speed on multipath interference structures is also considered.

Liquid mass gauging during propellant transfer in microgravity

Advancing the precision of low-gravity liquid propellant mass gauging is a roadmap challenge for NASA and a significant obstacle to expanding human presence in space. We report flight test data for an implementation of a low-gravity liquid propellant mass gauging technology that is both non-invasive and propellant agnostic. The TRIO payload experiment flew twice on the Blue Origin New Shepard suborbital rocket and validated computational models of liquid distribution in microgravity at three different fill levels. The Propellant Refueling and On-orbit Transfer Operations (PROTO) payload experiment also flew twice on New Shepard and acquired mass gauging data before, during, and after a tank drain and fill that simulated in-space propellant transfers. Propellant volume estimates were derived at 1 Hz using the Modal Propellant Gauging (MPG) system. Analytical, semi-empirical, and finite element (FE) model results for predicted mode frequencies are compared to flight data for mode frequencies across a range of fill levels during the simulated propellant transfer. Flight (0-g), ground (1-g) and FEM mode frequencies for both 0- and 1-g are well-predicted by the semi-empirical models for frequency dependence on tank fill level.

Poly (aniline-co-aniline-2,5-disulfonic acid) / L-ascorbic acid / Ag@SiO2 / polysafranin nanocomposite: synthesis, characterization and anomalous electrical behaviour.

We report the synthesis of sulfonated copolyaniline/polysafranin/L-ascorbic acid/Ag@SiO2 fine powdered nanocomposites and investigate the influence of incorporating the dye on their conductivity. The composite was characterized via IR, UV, cyclic voltammetry (CV), electric, dielectric, SEM, TEM, TGA and DSC measurements. Microscopy images revealed intensified spherical particles that were dispersed across the entire surface, and the SiO2/Ag particles were distributed on the surface. The XRD results exhibited peaks at many 2q values, and their interatomic spacing (d) and crystallite (grain) sizes were calculated. The thermal degradation curves exhibited an interesting model of stability. The cyclic voltammogram exhibited redox peaks identical to those of the reported analogues. The d.c. conductivity of the oligomer varied from 0.06 - 0.016 (s/cm), and that of the composite varied from 0.008 to 0.016 (s/cm). The material changed from a semiconductor to a metallic material. The observed conductivity is mainly attributed to self-doping between the sulfonate groups and the charged nitrogen atoms in the polymer chains. The frequency dependence of the permittivity, ε', showed a marked effect on the frequency window under consideration. The permittivity, ε', is independent of the increase in the frequency of the oligomer and the composite. This behavior supports the non-Debye dependency by confirming the occurrence of electrode polarization and space charge effects. In conclusion, the incorporation of safranin dye with a thermally stable, highly sulfonated polyaniline derivative/Ag@SO2 nanocomposite achieved improved conductivity after heating. The d.c. conductivities are comparable to those of many commercial inorganic or organic composites, and because of their attractive electrical properties, we suggest that these materials are promising for electronic field applications.

From Brownian to Deterministic Motor Movement in a DNA-Based Molecular Rotor.

Molecular devices that have an anisotropic periodic potential landscape can be operated as Brownian motors. When the potential landscape is cyclically switched with an external force, such devices can harness random Brownian fluctuations to generate a directed motion. Recently, directed Brownian motor-like rotatory movement was demonstrated with an electrically switched DNA origami rotor with designed ratchet-like obstacles. Here, we demonstrate that the intrinsic anisotropy of DNA origami rotors is also sufficient to result in motor movement. We show that for low amplitudes of an external switching field, such devices operate as Brownian motors, while at higher amplitudes, they behave deterministically as overdamped electrical motors. We characterize the amplitude and frequency dependence of the movements, showing that after an initial steep rise, the angular speed peaks and drops for excessive driving amplitudes and frequencies. The rotor movement can be well described by a simple stochastic model of the system.

Transport and dielectric properties of MIS structure with embedded Si QDs (AuPd/SiO2:Si QDs/n-Si) grown by MBE

This study focuses on the growth of silicon quantum dots (Si QDs) on insulator substrates via solid-state dewetting of ultrathin silicon films deposited by molecular beam epitaxy (MBE). The resulting Si QDs exhibit well-defined spherical shapes, low size dispersion with an average diameter of 6 nm, and a high density (1012/cm2), making them ideal for microelectronic applications. Current-voltage spectroscopy and impedance spectroscopy were employed to investigate the electrical transport and dielectric properties of Si QDs integrated into a metal-insulator-semiconductor (MIS) structure (AuPd/SiO2: Si QDs/n-Si). Current-voltage measurements reveal that the insertion of Si QDs into the MIS structure improves the electrical transport by introducing new conduction mechanisms. Impedance measurements demonstrate the influence of Si QDs on the frequency dependence of the real part of the dielectric constant (ε′) and the loss tangent (tan δ). Furthermore, Si QDs impact both the real (M′) and imaginary (M″) parts of the electric modulus. Despite slight deviations in dielectric properties, the MIS structure retains its fundamental nature. These investigations affirm the high electrical quality of Si QDs grown via solid-state dewetting and offer valuable insights for researchers engaged in the development of Si QD-based devices, such as non-volatile memories and MIS photodetectors.

Plug‐and‐play adaptive surrogate modeling of parametric nonlinear dynamics in frequency domain

AbstractWe present an algorithm for constructing efficient surrogate frequency‐domain models of (nonlinear) parametric dynamical systems in a non‐intrusive way. To capture the dependence of the underlying system on frequency and parameters, our proposed approach combines rational approximation and smooth interpolation. In the approximation effort, locally adaptive sparse grids are applied to effectively explore the parameter domain even if the number of parameters is modest or high. Adaptivity is also employed to build rational approximations that efficiently capture the frequency dependence of the problem. These two features enable our method to build surrogate models that achieve a user‐prescribed approximation accuracy, without wasting resources in “oversampling” the frequency and parameter domains. Thanks to its non‐intrusiveness, our proposed method, as opposed to projection‐based techniques for model order reduction, can be applied regardless of the complexity of the underlying physical model. Notably, our algorithm for adaptive sampling can be used even when prior knowledge of the problem structure is not available. To showcase the effectiveness of our approach, we apply it in the study of an aerodynamic bearing. Our method allows us to build surrogate models that adequately identify the bearing's behavior with respect to both design and operational parameters, while still achieving significant speedups.

Effects of molecular entanglements in amylopectin on the anti-thixotropy, gel properties and viscosity properties

Amylopectin with different side chain architecture and distribution were prepared by ɑ-amylase (AM) and maltogenic α-amylase (MA). The purpose of the study was to investigative the effect of molecular entanglement on the anti-thixotropy, gel properties, water distribution and viscosity properties. The results showed that MA specificity hydrolyzed chains ranging from DP 10–17 while retaining the long internal chains, while AM tended to trim the relatively longer chains of DP ≥ 12. The special (ŋsp) in a double-logarithmic plot versus concentration exhibited two linear regions with changes of gradient at AM-M and MA-M polymer concentrations of about 6.20% and 1.31% (w/v), respectively. Higher storage modulus (G′) and final viscosity, and lower frequency dependence indicated the stronger gels of waxy maize starch were formed by MA modification, despite exhibiting a similar thixotropic loop area to AM samples. The microstructure of MA gels showed a more compact honeycomb-like network structure observed by SEM. These results confirmed the chain length profile of the amylopectin pruned by MA was more conducive to produce anti-thixotropic starch-based material. This study is beneficial to provide insights for customizing starch skeleton structure to meet specific industrial application requirements of starch-based products, especially where the rheological properties need to be precisely controlled.

Low-frequency pulse-jitter measurement with the uGMRT I : PSR J0437–4715

Abstract High-precision pulsar timing observations are limited in their accuracy by the jitter noise that appears in the arrival time of pulses. Therefore, it is important to systematically characterise the amplitude of the jitter noise and its variation with frequency. In this paper, we provide jitter measurements from low-frequency wideband observations of PSR J0437–4715 using data obtained as part of the Indian Pulsar Timing Array experiment. We were able to detect jitter in both the 300 - 500 MHz and 1260 - 1460 MHz observations of the upgraded Giant Metrewave Radio Telescope (uGMRT). The former is the first jitter measurement for this pulsar below 700 MHz, and the latter is in good agreement with results from previous studies. In addition, at 300 - 500 MHz, we investigated the frequency dependence of the jitter by calculating the jitter for each sub-banded arrival time of pulses. We found that the jitter amplitude increases with frequency. This trend is opposite as compared to previous studies, indicating that there is a turnover at intermediate frequencies. It will be possible to investigate this in more detail with uGMRT observations at 550 - 750 MHz and future high sensitive wideband observations from next generation telescopes, such as the Square Kilometre Array. We also explored the effect of jitter on the high precision dispersion measure (DM) measurements derived from short duration observations. We find that even though the DM precision will be better at lower frequencies due to the smaller amplitude of jitter noise, it will limit the DM precision for high signal-to-noise observations, which are of short durations. This limitation can be overcome by integrating for a long enough duration optimised for a given pulsar.

Analysis of muscle implanted antenna performance with the variation of implantation depth

Abstract Implantation depth of Implantable Medical Devices (IMDs) is an important factor of communication quality between implantable antennas in IMDs and external devices. Therefore, it is required to study the effect of implantation depth on implantable antenna performance. In this article, dependence of resonant frequency and scattering parameters of a two-antenna system where one miniaturized meander-line antenna is placed within human muscle tissue layer operating at 2.45 GHz ISM (industrial, scientific and medical) band and a rectangular patch antenna placed outside human body, are tested. Here 15 values of implantation depth ranging over 5–35 mm inside muscle layer are taken and for each case resonant frequency and scattering parameters (S 11 and S 21) of the system are recorded. Statistical analysis has been performed to observe how these performance parameters are dependent on depth of implantation which may be varied at the time of surgery.