Properties Of Droplets Research Articles

Regulating the lipid droplet interface based on milk fat globule membrane and milk proteins to improve lipid digestion of model infant formula emulsion

The interfacial properties of lipid droplets play a crucial role in lipid digestion. In this study, milk fat globule membrane (MFGM) was used to improve the lipid droplet interface of model infant formula emulsions (IFEs). We focused on the effects of the addition sequence of MFGM and milk proteins commonly used in infant formula (IFE1: Milk proteins added before homogenization, MFGM added after homogenization; IFE2: MFGM added before homogenization, milk proteins added after homogenization; IFE3: MFGM and milk proteins added before homogenization) on lipid droplets' interfacial compositions, structure, and lipid digestion behaviors and compared with human milk (HM) and commercial infant formula (IF). The results showed that the interfacial protein load was significantly lower (P < 0.05), and the interfacial phospholipid load was significantly higher (P < 0.05) in IFE2 compared to IFE1, IFE3, and IF. The lipid droplet structure of IFE2 is closer to that of HM. MFGM fragments-covered lipid droplets can be observed in IFE2. In contrast, the lipid droplets in IFE1, IFE3, and IF were covered by casein micelles, and MFGM fragments were free in the serum phase. After digestion, the lipolysis degree of IFE2 (91.7 ± 1.51%) was comparable to that of HM (94.98 ± 1.08%) and significantly higher than other samples (P < 0.05). During digestion, IFE1 and IFE3 formed thicker and denser protein knit networks compared to IFE2. The lipid droplets in IFE1 and IFE3 were embedded in protein networks, thereby inhibiting lipid digestion. These results indicated that changes in the interfacial composition of lipid droplets improved lipid digestion by mitigating the aggregate and coalescence of protein and lipid droplets.

Investigation of factors enhancing droplets spreading on leaves with burrs.

Spread effect is one of the aspects on deposition quality evaluation of pesticide droplets. It could be affected by many factors such as the microstructure of the target plant leaf surface, physical features of the droplets, and the concentration of spray additives. In this study, using a high-speed photography system, 2.3% glyphosate ammonium salt solution with different concentration of the additive was applied to investigate the impact process of single droplet deposition on the plant leaf surface with burrs. Effect of droplet sizes and velocities on spreading area and dynamic deposition procedure was analyzed using image processing programs. The diffusion factor in the process of droplet spreading was changed over time. The occurrence of bubbles in the droplets was observed in the results. With the bubble generation, the droplet diameter expands and a better diffusion effect is obtained. As a result, better spreading effect was obtained as the droplet diameter was expanded with the generation of bubbles. The significant effects of each physical property of droplets on droplet spreading and the interaction effects between the influencing factors were analyzed. A significant correlation was found between additive concentration, droplet impact velocity, droplet diameters and droplet spreading area. All interactions of concentration:velocity, concentration:diameter, velocity:diameter, and concentration:velocity:diameter had a significant effect on the spreading area of droplets. The study of the factors influencing the process of pesticide droplet impact on the leaf surface contributes to the efficient use of pesticides. Thus, the consumption of pesticides and the resulting impact on the environment can be reduced.

Versatile Liquid Metal/Alginate Composite Fibers with Enhanced Flame Retardancy and Triboelectric Performance for Smart Wearable Textiles.

Liquid metal (LM) shows the superiority in smart wearable devices due to its biocompatibility and electromagnetic interference (EMI) shielding. However, LM based fibers that can achieve multifunctional integrated applications with biodegradability remain a daunting challenge. Herein, versatile LM based fibers are fabricated first by sonication in alginate solution to obtain LM micro/nano droplets and then wet-spinning into LM/alginate composite fibers. By mixing with high-concentration alginate solution (4-6wt.%), the LM micro/nano droplets stability (colloidal stability for > 30d and chemical stability for > 45d) are not only improved, but also facilitate its spinning into fibers through bimetallic ions (e.g., Ga3+ and Ca2+ ) chelation strategy. These resultant fibers can be woven into smart textiles with excellent flexibility, air permeability, water/salt resistance, and high temperature tolerance (-196-150°C). In addition, inhibition of smoldering result from the LM droplets and bimetallic ions is achieved to enhance flame retardancy. Furthermore, these fibers combine the exceptional properties of LM droplets (e.g., photo-thermal effect and EMI shielding) and alginate fibers (e.g., biocompatibility and biodegradability), applicable in wearable heating devices, wireless communication, and triboelectric nanogenerator, making it a promising candidate for flexible smart textiles.

An integrated optofluidic droplet lens driven by a fast thermoelectric cooler

This work demonstrates a tunable optofluidic droplet lens with a controllable liquid-air interface. The lens is actuated using a fast membrane-free thermo-pneumatic actuator. A liquid droplet with a clear aperture of 2mm is pinned at a circular hole that was fabricated using high-precision 3D printing technology. Movement of the liquid interface is performed by changing the temperature of a thermoelectric cooler (TEC) automatically. The properties of the TEC actuator are compared with those of a membrane thermal actuator through analytical solutions obtained from multi-physics finite element simulations. The average thermal response time of the lens is measured using an infrared thermal imager. The temperature distribution over the device and that over the optical liquid are compared in detail. Finally, the tunability properties of the liquid droplet, including its side profile, optical response time, back focal length, and image performance, are verified experimentally.

Thermodynamic properties of oil droplets in oil-injected screw compressors and their influencing factors

As a typical positive displacement compressor, screw compressors are widely used in various industrial fields with a fast-growing trend, especially with the boost of the application of oil injection technology. The oil injection process inside the screw compressor is complicated and difficult to be captured by direct observation experiment, so is the accompanying heat transfer process. On the basis of single particle dynamics, the Lagrangian method is used to establish a spatial kinematic model of oil droplets in the simplified chamber of an oil-injected screw compressor, the droplet trajectory is analyzed. The relationship between the oil droplet diameter, injection velocity and temperature and the free flight time of oil droplets in the compression chamber is obtained. In order to investigate the liquid-gas two-phase flow after oil injection, the Level Set Method is adopted to simulate the oil distribution in the compression chamber. The impacting process of oil droplet on a hot wall is simulated, the influence of oil injection parameters such as the injection speed, temperature difference, droplet diameter, and the initial velocity on the heat transfer between oil droplets and hot gas and the wall is analyzed theoretically. For the simulated cases studied, the oil droplet diameter has the greatest effect on the gas-liquid heat transfer, while the temperature difference plays a greater role in the heat transfer between the oil droplet and the hot wall than other factors. The research in this paper helps to further understand and accurately predict the heat transfer process in oil-injected screw compressors, which is important for improving the energy efficiency of screw compressor.

Emission and purification of evaporated–condensed oil droplets affected by condensation nuclei during machining

Fine oil droplets emitted by evaporation–condensation during machining are typical indoor air contaminants. Airborne particles can act as condensation nuclei, facilitating the condensation of oil vapor. The physical properties of these resultant droplets significantly affect their purification efficiency. Herein, this study aimed to elucidate the emission characteristics of oil droplets formed by evaporation–condensation affected by condensation nuclei and the purification efficiency of intense field dielectric (IFD) technology for the droplets under varying airflow velocities. Results show that the removal of condensation nuclei can effectively reduce the mass of evaporated–condensed oil droplets, and the increment in the mass of oil droplets reached 1.7 times the increment in the mass of condensation nuclei. It was more effective to reduce the mass of oil droplets by removing large condensation nuclei and decreasing the amount of evaporated soluble oil, as compared to removing smaller condensation nuclei or using straight oil. Condensation nuclei mainly contributed to the generation of oil droplets below 5 µm. For droplet diameters of 0.3–5.0 µm and airflow velocities of 0.5–2.0 m/s, the purification efficiency was within the 84–96% range. The purification efficiency of the IFD purifier for oil droplets could be improved either by increasing the size of the oil droplets or by reducing the airflow velocity.

In Situ Probing of the Surface Properties of Droplets in the Air.

Surface properties of nanodroplets and microdroplets are intertwined with their immense applicability in biology, medicine, production, catalysis, the environment, and the atmosphere. However, many means for analyzing droplets and their surfaces are destructive, non-interface-specific, not conducted under ambient conditions, require sample substrates, conducted ex situ, or a combination thereof. For these reasons, a technique for surface-selective in situ analyses under any condition is necessary. This feature article presents recent developments in second-order nonlinear optical scattering techniques for the in situ interfacial analysis of aerosol droplets in the air. First, we describe the abundant utilization of such droplets across industries and how their unique surface properties lead to their ubiquitous usage. Then, we describe the fundamental properties of droplets and their surfaces followed by common methods for their study. We next describe the fundamental principles of sum-frequency generation (SFG) spectroscopy, the Langmuir adsorption model, and how they are used together to describe adsorption processes at planar liquid and droplet surfaces. We also discuss the history of developments of second-order scattering from droplets suspended in dispersive media and introduce second-harmonic scattering (SHS) and sum-frequency scattering (SFS) spectroscopies. We then go on to outline the developments of SHS, electronic sum-frequency scattering (ESFS), and vibrational sum-frequency scattering (VSFS) from droplets in the air and discuss the fundamental insights about droplet surfaces that the techniques have provided. Finally, we describe some of the areas of nonlinear scattering from airborne droplets which need improvement as well as potential future directions and utilizations of SHS, ESFS, and VSFS throughout environmental systems, interfacial chemistry, and fundamental physics. The goal of this feature article is to spread knowledge about droplets and their unique surface properties as well as introduce second-order nonlinear scattering to a broad audience who may be unaware of recent progress and advancements in their applicability.

The Wetting Behavior of Water Droplets on Silane and Silane/GO-Modified Ettringite Surfaces: Insights into Molecular Dynamics Simulations

The use of rapid-hardening cementitious materials for the emergency repair of critical infrastructure in coastal environments is becoming increasingly widespread, and concrete surface hydrophobic protection treatment is equally necessary to improve the durability of both new and old concrete. Among them, silane-based hydrophobic materials play an important role in concrete hydrophobic protection. Graphene oxide (GO)-modified silane materials can significantly improve the hydrophobic performance of coatings, but the hydrophobic mechanism of coatings modifying the sulfoaluminate cement’s main hydration product ettringite (AFt) has not yet been explored. In this study, molecular dynamics simulations were conducted to investigate the wetting properties of water droplets on the surface of AFt, isobutyltriethoxy silane (IBTS)-modified AFt, and IBTS/GO-modified AFt. It was found that the AFt substrate had good hydrophilicity, and the droplets could wet the interface through Ca-O ionic bonds and H-bonds. The IBTS coating initially impeded droplet wetting, but the adsorption stability of IBTS on the AFt substrate surface was poor under droplet action, leading to droplet penetration and dispersion of the IBTS coating on the AFt surface. However, the IBTS/GO coating significantly restricted droplet wetting due to the stable adsorption of GO on the AFt surface and the strong stability of hydrogen bonds between IBTS and GO. In conclusion, selecting a suitable bridging material between AFt and silane is crucial for improving the hydrophobic stability of silane coatings on sulfoaluminate cement materials.

Effects of higher-order fluctuations on the bulk and surface properties of quantum droplets in a heteronuclear Bose-Bose mixture

Effects of higher-order fluctuations on the bulk and surface properties of quantum droplets in a heteronuclear Bose-Bose mixture

Acoustic droplet vaporization for on-demand modulation of microporosity in smart hydrogels.

Microporosity in hydrogels is critical for directing tissue formation and function. We have developed a fibrin-based smart hydrogel, termed an acoustically responsive scaffold (ARS), which responds to focused ultrasound in a spatiotemporally controlled, user-defined manner. ARSs are highly flexible platforms due to the inclusion of phase-shift droplets and their tunable response to ultrasound through a mechanism termed acoustic droplet vaporization (ADV). Here, we demonstrated that ADV enabled consistent generation of micropores in ARSs, throughout the entire thickness (∼5.5 mm), utilizing perfluorooctane phase-shift droplets. Size characteristics of the generated micropores were quantified in response to critical parameters including acoustic properties, droplet size, and shear elastic modulus of fibrin using confocal microscopy. The findings showed that the length of the generated micropores correlated directly with excitation frequency, peak rarefactional pressure, pulse duration, droplet size, and indirectly with the shear elastic modulus of the fibrin matrix. The ADV-generated micropores in ARSs were further compared with cavitation-mediated micropores in fibrin gels without droplets. Additionally, the Keller-Miksis equation was used to predict an upper bound for micropore formation in ARSs at varying driving frequencies and droplet sizes. Finally, our in vivo studies showed that host cell migration following ADV-induced micropore formation was frequency-dependent, with up to 2.6 times higher cell migration at lower frequencies. Overall, these findings demonstrate a new potential application of ADV in hydrogels. STATEMENT OF SIGNIFICANCE: Interconnected micropores within a hydrogel can facilitate many cell-mediated processes. Most techniques for generating micropores are typically not biocompatible or do not enable controlled, in situ micropore formation. We used an ultrasound-based technique, termed acoustic droplet vaporization, to generate microporosity in smart hydrogels termed acoustically responsive scaffolds (ARSs). ARSs contain a fibrin matrix doped with a phase-shift droplet. We demonstrate that unique acoustic properties of phase-shift droplets can be tailored to yield spatiotemporally controlled, on-demand micropore formation. Additionally, the size characteristics of the ultrasound-generated micropores can be modulated by tuning ultrasound parameters, droplet properties, and bulk elastic properties of fibrin. Finally, we demonstrate significant, frequency-dependent host cell migration in subcutaneously implanted ARSs in mice following ultrasound-induced micropore formation in situ.

ON THE EFFECT OF VISCOSITY RELAXATION ON ELECTROMAGNETIC RADIATION INTENSITY OF AN OSCILLATING CHARGED DROPLET

Theoretical asymptotic calculations linear with respect to small dimensionless amplitude of oscillations have been employed to study the influence of the viscoelastic properties of a charged droplet of an electrically conducting viscous liquid on the intensity of its electromagnetic radiation. It has been shown that allowance for the effect of viscosity relaxation leads to a decrease in the damping decrement value, which is determined by energy losses for electromagnetic wave emission, and the intensity of high-frequency electromagnetic radiation; a substantial reduction in the viscous damping decrement of small cloud droplets; and an essential dependence of the viscous damping decrement on the characteristic relaxation time. It has been found that the viscosity relaxation of a liquid has no significant effect on damped capillary oscillations and electromagnetic radiation of rain droplets. Viscoelasticity and viscosity of the liquid do not influence the conditions critical for the realization of the electrostatic instability of a droplet with respect to its own charge.

Atomization mechanisms of a wall-impinging jet in a shallow pool

Atomization of a liquid jet in an immiscible liquid–liquid system is essential for maintaining safety in the nuclear industry. The Japan Atomic Energy Agency has developed a method to evaluate the behavior of molten fuel entering a shallow coolant pool using numerical and experimental simulations in an immiscible liquid–liquid system, focusing on hydrodynamic interaction between the fuel and pool. However, the atomization behavior associated with the spreading of the wall-impinging liquid jet immediately after entering a shallow pool in the system is quite different from jet-breakup regimes in a deep pool, and there are a few reports. Such atomization behavior can change subsequences in severe accidents in the nuclear industry, and the investigation of the atomization behavior of the wall-impinging liquid jet is significant. Herein, we investigate the atomization behavior of a wall-impinging liquid jet in terms of droplet formation and its flow field using numerical simulation and a dispersed-phase tracking method. The results show that the atomization behavior comprises droplet formation with three patterns. We obtain droplet properties immediately after droplet formation and develop theoretical boundaries enclosing two regions for droplet formation using dimensionless numbers. We characterize the patterns by comparing them with the theoretical regions and elucidate the droplet formation mechanisms of each source. Moreover, we establish the relationship between droplet formation as the local behavior and atomization as the whole behavior of the jet. Thus, this paper clarifies the atomization mechanisms in the liquid film flow of the wall-impinging liquid jet in a shallow pool.

Numerical simulation of TTIP/[formula omitted]-xylene precursor solution spray flames in the counterflow configuration

Sprays of precursor solutions are used in flame spray pyrolysis (FSP) to produce functional nanoparticles with specific properties. The present study concerns the precursor titanium(IV) isopropoxide (TTIP) in p-xylene. A dilute monodisperse spray carried by an air stream is directed against an air stream to establish a counterflowing laminar spray flame. The complex thermophysical properties of the bi-component droplets are incorporated into the code as well as the detailed chemical reactions of the system with 213 chemical reactions among 52 species; the chemical reaction mechanism includes thermal decomposition of the TTIP and the combustion of p-xylene. The droplets are modeled using the multicomponent evaporation model. Drag and gravity forces are considered in the equation of droplet motion. Monodisperse spray flame structures are presented depending on the gas strain rate, the initial droplet size, the precursor mass loading as well as the equivalence ratio. The preferential evaporation of the more volatile p-xylene provides the gaseous fuel for combustion, and the thermal decomposition of the precursor TTIP considerably reduces the flame temperature.

Surfactants Improving the Wetting Behavior and Adhesion Mechanism of Pesticide Dilution Droplets on Jujube Leaf Surfaces.

Fruit tree leaves have different chemical compositions and diverse wax layer structures that result in different patterns of wetting and pesticide solution spreading on their surface. Fruit development is a time when pests and diseases occur, during which a large number of pesticides are needed. The wetting and diffusion properties of pesticide droplets on fruit tree leaves were relatively poor. To solve this problem, the wetting characteristics of leaf surfaces with different surfactants were studied. The contact angle, surface tension, adhesive tension, adhesion work, and solid-liquid interfacial tension of five surfactant solution droplets on jujube leaf surfaces during fruit growth were studied by the sessile drop method. C12E5 and Triton X-100 have the best wetting effects. Two surfactants were added to a 3% beta-cyfluthrin emulsion in water, and field efficacy tests were carried out on peach fruit moths in a jujube orchard at different dilutions. The control effect is as high as 90%. During the initial stage when the concentration is low, due to the surface roughness of the leaves, the surfactant molecules adsorbed at the gas-liquid and solid-liquid interfaces reach an equilibrium, and the contact angle on the leaf surface changes slightly. With increasing surfactant concentration, the pinning effect in the spatial structure on the leaf surface is overcome by liquid droplets, thereby significantly decreasing the contact angle. When the concentration is further increased, the surfactant molecules form a saturated adsorption layer on the leaf surface. Due to the existence of a precursor water film in the droplets, surfactant molecules on the interface continuously move to the water film on the surface of jujube tree leaves, thus causing interactions between the droplets and the leaves. The conclusion of this study provides theoretical guidance for the wettability and adhesion of pesticides on jujube leaves, so as to achieve the purpose of reducing pesticide use and improving pesticide efficacy.

Polarized radiative transfer in seawater-in-oil emulsions floated on seawater considering the impact of oil absorption on seawater droplet scattering.

Among various remote sensing approaches, optical polarization remote sensing shows great advantages in identifying oil-water emulsions in seawater and has become one of the most promising detection technologies. Herein, we focus on exploring the sensitivity of polarized radiative transfer properties for oil emulsion polarization detection to the influence factors of viewing angle, droplet volume fraction and radius, incident wavelength, and emulsion thickness. The radiative properties of seawater droplets dispersed in crude oil are calculated using the improved Lorenz-Mie theory considering the absorption of crude oil as the host medium, after which the reflected Stokes vector and the degree of linear polarization (DOLP) of seawater-in-oil emulsions floating on seawater are obtained using the spectral element method. By analyzing the calculation results of a 0° viewing azimuth angle, the detection wavelength and viewing zenith angles corresponding to the highest sensitivity of the DOLP to the above factors are significantly different; thus, quantitative remote sensing detection of the droplet volume fraction, droplet diameter, and emulsion thickness is possible. Exploring the sensitivity of polarized remote sensing signals for oil emulsion polarization detection to the above factors is a prerequisite for quantitative polarization detection of oil emulsions.

Tablet coating in lab-scale drum coaters: Combining DEM simulations and spray experiments to predict tablet coating

In pharmaceutical industry the coating of granulates or tablets is an essential production step, which is often realised in a rotating drum moving the tablet bed and a number of spray nozzles installed above this bed. The nozzles atomise the coating liquid through a high-velocity annular air-stream and apply steering air nozzles for producing an oval-shaped spray. The operational conditions determine the produced droplet size spectrum. The collision of the droplets with the solid particles or tablets in the drum and the resulting coating and film thickness strongly influences the product properties of granulates or tablets. In order to be able to predict the coating result, without running time-consuming lab-scale experiments, it is intended to numerically simulate the entire tablet coating process by combining Computational Fluid Dynamics (CFD), the Discrete Element Method (DEM) and the Lagrangian Parcel Concept (LPC) for simulating the spray propagation originating at the nozzle. For doing so, knowledge on the spray droplet properties produced by the two-fluid spray nozzles is indispensable. Therefore, it is necessary to characterise as a first step the local droplet size and velocity distributions in different spray cross-sections, which is the main focus of the present contribution. Such measurements are efficiently done by applying Phase Doppler Anemometry (PDA). It was found that the velocity of the spray emitted from the two-fluid nozzle exceeds almost 200 m/s and the number mean droplet diameter was well below 20 μm. In the initial spray region droplet break-up was observed whereas downstream of 50 mm a slight growth of the mean droplet size indicated further coalescence. Due to the applied pattern air, the spray flux distribution at the normally located tablet bed (i.e., 100–150 mm downstream the nozzle) has an oval shape and the mean droplet velocity still exceeds almost 50 m/s with a mean droplet diameter of about 10 μm. The cross-sectional measurements are used to provide proper inlet conditions for the spray simulations, while the other cross-sections are used for validating the computed spray expansion and dispersion. For demonstrating the effect of a real measured spray flux distribution on the tablet coating quality, additionally DEM simulations were conducted. Here, the measured spray flux data were mapped onto the temporarily evolving and moving tablet surface simulated for a lab-scale test drum by DEM. The uniformity of tablet coating (inter-tablet variability) was judged by calculating the Coefficient Of Variation (COV) for the considered different tablet shapes and operational conditions.

Combined effects of nanoparticle size, and nanoparticle and surfactant concentrations on the evaporative kinetics, dried morphologies, and plasmonic property of gold colloidal dispersion droplets

Understanding the combined influence of various parameters on the formation and morphologies of distinct solute deposit patterns obtained after droplet drying is essential for developing numerous real-time applications. In this work, gold nanoparticle (Au-NP) dispersion droplets are dried on a hydrophilic substrate and the coupled effects of nanoparticle size, and nanoparticle and surfactant (CTAB) concentrations on the evaporative kinetics and evaporation-induced nanoparticle assemblies in dried deposit patterns are studied using optical and scanning electron microscopy. The distinct stages of drying of a cetyltrimethylammonium bromide (CTAB) stabilized Au-NP dispersion droplet, such as the evolutions of pinning, depinning, and a depletion region, change drastically for a combined increase of CTAB concentration and nanoparticle size for different nanoparticle concentrations. Accordingly, the dried pattern is composed of distinct regions of closely bound ordered Au-NP assemblies coexisting with loosely bound disordered packings of Au-NPs that form inside and outside the coffee stain pattern. The multilayers of densely packed and hexagonally arranged Au-NPs at the outer coffee stain edge are tested for surface-enhanced Raman scattering activity against a standard probe molecule (Rhodamine B—RhB). The least detection limit of RhB at the outer coffee stain edge improves by three orders of magnitude with increasing nanoparticle concentrations and nanoparticle sizes. The present study demonstrates that the drying kinetics, distinct dried deposit morphologies, and the limit of plasmonic activity of the deposited Au-NPs can be fine-tuned via a combined variation of CTAB concentration, nanoparticle size, and nanoparticle concentration in the Au-NP dispersion droplet.

Extended model of bouncing boundary for droplet collisions considering numerous different liquids

Sprays are widely utilised in different technical and industrial applications. The produced droplet size spectrum is one of the most important parameters that determine the spray characteristics and performance. Depending on the operational conditions and the spray structure, the droplet size spectrum obtained after atomisation will be of course modified by collisions between droplets. In numerical calculations, the Euler/Lagrangian approach is a favourable method for obtaining relatively accurate predictions of spraying processes. However, for correctly modelling droplet collisions, reliable boundary line correlations are needed for distinguishing the different droplet collision outcomes, which are bouncing, coalescence, and separations. These boundary lines are summarised in so-called collision maps to demark the various outcome scenarios. The result of a binary droplet collision depends on numerous parameters, namely, the kinetic properties (droplet velocities, droplet diameter ratio, impact angle) and the physical properties of gas and droplets (droplet liquid, density and viscosity, surface tension, type of gas phase, gas phase pressure and temperature). The boundary line for bouncing, primarily used in numerical studies so far, was derived based on experiments with ethanol droplets by Estrade et al. (1999). However, this theoretical derivation, based on an energy balance, unfortunately neglects viscous dissipation effects. Therefore, the deviations of the predicted bouncing region are pretty large for liquids with higher viscosity or other physical properties. Hence, a data-driven model is proposed in this paper, with new assumptions and definitions, considering the dissipated energy during the collision and the shape changes (i.e., deformation) of the collision complex. For that purpose, two new parameters are introduced in the model, namely a shape factor and an energy conversion rate, both depending on the impact parameter B, which describes the lateral displacement of droplets at a collision. Therefore, the new bouncing model is related to the degree of droplet deformation. The dependence on B could be described by linear correlations with two parameters for slope and intercept. These parameters are correlated with the Ohnesorge number, and polynomial fitting functions were derived with the help of numerous available experiments for different liquids. The upper limit of Ohnesorge numbers in the present study was Oh<0.35. Due to the dependence on the Ohnesorge number, the proposed model very well captures the effect of liquid properties on the bouncing boundary, however, not necessarily the influences of environmental conditions and interface modifications. The model was validated by comparison with numerous available experimental results.

Effects of surface micro-structure of fruits on droplet evaporation process: Peach and apple cases

Droplet evaporation at the fruit surface is a common issue related to the efficiency of pesticide spraying as well as freshness preservation. Many works have been carried out demonstrating the impacts of substrate characteristics on the droplet profile, wettability, and evaporation properties in the field of industrial applications. However, the influences of specific fruit skin on the droplet evaporation rate have been rarely studied. Thus, the present works aim to explore the effects of different surface micro-structures of fruits on the droplet properties experimentally through the 3D video microscope, drop shape analyzer, and infrared camera. Apple and peach have been selected respectively as two examples of waxy and hairy skins, and comparisons have been made focusing on the surface roughness, droplet profile including contact angle, contact area, and contact diameter, evaporation rate, and temperature distribution of droplets with a constant initial volume of 2ul. The results show that the differences in micro-structure for apple and peach surfaces have significant impacts on the droplet evaporation performance. A larger evaporation rate has been found for apple skin with three distinct phases including spreading, pinning, and shrinkage periods. However, the pinning phenomenon tends to be broken for the peach case due to the unique properties of super-hydrophobic surfaces and the existence of fluff. Moreover, lower values of temperature at the top center of a droplet can be always observed during the whole evaporating process with peak values of temperature gradient near the triple-phase region.

Forced Wetting Properties of Bacteria-Laden Droplets Experiencing Initial Evaporation.

Microbial adhesion and spreading on surfaces are crucial aspects in environmental and industrial settings being also the early stage of complex surface-attached microbial communities known as biofilms. In this work, Pseudomonas fluorescens-laden droplets on hydrophilic substrates (glass coupons) are allowed to partially evaporate before running wetting measurements, to study the effect of evaporation on their interfacial behavior during spillover or splashing. Forced wetting is investigated by imposing controlled centrifugal forces, using a novel rotatory device (Kerberos). At a defined evaporation time, results for the critical tangential force required for the inception of sliding are presented. Microbe-laden droplets exhibit different wetting/spreading properties as a function of the imposed evaporation times. It is found that evaporation is slowed down in bacterial droplets with respect to nutrient medium ones. After sufficient drying times, bacteria accumulate at droplet edges, affecting the droplet shape and thus depinning during forced wetting tests. Droplet rear part does not pin during the rotation test, while only the front part advances and spreads along the force direction. Quantitative results obtained from the well-known Furmidge's equation reveal that force for sliding inception increases as evaporation time increases. This study can be of support for control of biofilm contamination and removal and possible design of antimicrobial/antibiofouling surfaces.