Drinking Water Wells Research Articles

Microbes-Assisted Arsenate Reduction Activity in Bangladesh Drinking Water Wells as Revealed by Enrichment Cultivation

Arsenate-reducing microorganisms may mobilize arsenic into groundwater. Phylogenetic DNA sequence information cannot exclusively be used to infer arsenate reduction, as the spotted homologies may not translate to biochemical activities. We here develop a cultivation-based metagenomic strategy for inferring actual activities: we complement a cultivation-independent microbial community survey covering 22 arsenic-contaminated drinking water wells in Bangladesh, with the characterization of enrichments of anaerobic arsenate reducers. All investigated samples revealed microbial arsenate reduction activity. The enriched microbial communities were phylogenetically diverse within and between the enrichments. The enrichment also unveiled species: the arsenate-reducing enrichments held 16S rRNA gene sequences closest to Dechloromonas sp., Azonexus fungiphilus, Youngiibacter fragile, Methanogenic prokaryote and Fusibacter sp., in addition to arsenate-reducing Sulfurospirillum strains NP4, b10 and dissimilatory iron-reducing Geobacter species. The enriched arsenate reductase gene (arrA) sequences were closest to sequences in known arsenate reducing Sulfurospirillum barnesii. This study bridges the knowledge gap between cultivation-independent and cultivation-dependent analyses. It clarifies the mechanism for arsenic mobilization and redistribution in rural drinking water wells, as a balance between bioremediation and harmful activities. The identified, potentially dissimilatory arsenate and iron-reducing microbes, constitute a risk for arsenic bioremediation. Appropriate metagenomic and dynamic analyses should help design and maintain safer, effective bioremediation.

Impacts of climate change on Swiss alluvial aquifers – A quantitative forecast focused on natural and artificial groundwater recharge by surface water infiltration

The sensitivity of future groundwater recharge and temperature development was investigated for three alluvial aquifers in the urban agglomeration of the city of Basel, Switzerland. For selected climate projections groundwater recharge and the associated temperature imprinting of aquifers, which are mainly determined by artificial groundwater recharge and infiltrating surface water, were investigated.3D numerical groundwater flow and heat-transport modeling, allowed quantifying and differentiating between natural and artificial groundwater recharge and thermal impacts. For aquifers where the infiltration of river water is an important component in the groundwater balance, the effects of climate change will be influenced by changes in river flow and thermal regimes and also by artificial groundwater recharge of surface water. Considering all climate scenarios investigated, the net heat input from river water infiltration for the Lange Erlen case study area increases by an average of 42 % by 2055 and 62 % by 2085 compared to the reference year 2000. Together with further heat inputs, particularly by artificial groundwater recharge, the temperatures of the extracted drinking water would increase by 0.4 to 1.3 K by 2055 and 0.7 to 3.1 K by 2085. In the Hardwald case study area, the most significant heat exchange occurs by artificial groundwater recharge. As a result, and considering all climate scenarios investigated, heat loss by groundwater extraction increases by an average of 38 % during the winter months from the year 2000 to the year 2085. The increased heat input, especially in the summer months, results in a temperature increase of the extracted drinking water of 0.2 to 1.0 K by 2055 and 0.6 to 4.0 K by 2085. In the Lower Birs Valley case study area, net heat input from river water infiltration increases by an average of 42 % by 2055 and 62 % by 2085. Correspondingly, the temperatures of the extracted drinking water increase by 0.9 to 3.2 K by 2055 and by 0.3 to 5.4 K by 2085.The quantitative assessment of climate change impacts on the groundwater resources presented allows to differentiate between hydraulic and thermal impacts of natural and artificial groundwater recharge processes. Accordingly, individual drinking water wells are exposed differently to the various components of groundwater recharge. Seasonal shifts in natural groundwater recharge processes and adaptation strategies related to artificial groundwater recharge could therefore be an important factor affecting groundwater resources in future. Moreover, increased groundwater recharge from artificial groundwater recharge systems in summer months and the interaction with surface waters during high runoff periods, which will occur more often in winter months, are likely to strongly influence groundwater recharge and temperatures.

MONITORING OF MICROBIOLOGY QUALITY RAW WATER AND REFILLED DRINKING WATER DURING COVID-19

Introduction: Riau province regency / city data for drinking water depots in 2020 show that the largest number of Pekanbaru City in Riau Province has refill drinking water depots, there are 440 depots consisting of 220 feasible depots while 227 depots are not feasible. This research was conducted in the Tampan sub-district which is the most densely populated city of Pekanbaru. The purpose of this study was to evaluate the microbiological quality standards (Coliform) for refill drinking water depot, raw water source quality standards and population well quality standards during Covid-19. Methods: This research is quantitative descriptive analytic with triangulation methods observation with laboratory tests, in-depth interviews with correspondents of depot officers and residents of drinking water wells. The test was carried out at the UPT health and environment laboratory of the Riau provincial health office. Result: Data analysis compared 7 samples with laboratory test results according to quality standards. The results of the analysis stated that there were no Coliform bacteria in the tested samples. The source of raw water from housing will have better standard of quality the deeper it is. Conclusion: There is no periodic supervision from the health office / Puskesmas to drinking water depot during the Covid-19 period which is usually routinely carried out every 3-6 months according to regulation of ministers of health no.736,2010 concerning supervision of drinking water quality. Housing developers are required to provide a clean water source from a proper borehole from the start of housing development.

Survey of 226Ra/228Ra and inorganic constituents in Iowa private drinking water wells

AbstractRadium is a naturally‐occurring radioactive element found in Upper Midwest aquifers, yet exposure risks for unregulated water sources in this region are unknown. A survey of 226/228Ra and other inorganic constituents in 94 private wells was conducted in 2019 across 10 Iowa counties. Within private wells, 53% measured below minimum detectable activity whereas 6.3% have 226/228Ra levels above the United States Environmental Protection Agency Maximum Contaminant Level. 226/228Ra occurrence was not associated with well‐depth or chemical surrogates, but were generally consistent with the lithology and historical water quality trends for aquifers. In 2020, 11 of the 226/228Ra‐impacted wells were re‐sampled to assess the efficacy of in‐home water treatment. Water softeners reduced 226/228Ra to non‐detectable activities, but other inorganic constituents persisted and their removal required more advanced treatment. This study suggests that 226/228Ra occurrence in private wells can reasonably be anticipated from public water supply data if reliable information is available to identify the source aquifer.

Biogeochemical behaviour of geogenic As in a confined aquifer of the Sologne region, France.

Arsenic (As) is one of the main toxic elements of geogenic origin that impact groundwater quality and human health worldwide. In some groundwater wells of the Sologne region (Val de Loire, France), drilled in a confined aquifer, As concentrations exceed the European drinking water standard (10μgL-1). The monitoring of one of these drinking water wells showed As concentrations in the range 20-25μgL-1. The presence of dissolved iron (Fe), low oxygen concentration and traces of ammonium indicated reducing conditions. The δ34SSO4 was anticorrelated with sulphate concentration. Drilling allowed to collect detrital material corresponding to a Miocene floodplain and crevasse splay with preserved plant debris. The level that contained the highest total As concentration was a silty-sandy clay containing 26.9mgkg-1 As. The influence of alternating redox conditions on the behaviour of As was studied by incubating this material with site groundwater, in biotic or inhibited bacterial activities conditions, without synthetic organic nutrient supply, in presence of H2 during the reducing periods. The development of both AsV-reducing and AsIII-oxidising microorganisms in biotic conditions was evidenced. At the end of the reducing periods, total As concentration strongly increased in biotic conditions. The microflora influenced As speciation, released Fe and consumed nitrate and sulphate in the water phase. Microbial communities observed in groundwater samples strongly differed from those obtained at the end of the incubation experiment, this result being potentially related to influence of the sediment compartment and to different physico-chemical conditions. However, both included major Operating Taxonomic Units (OTU) potentially involved in Fe and S biogeocycles. Methanogens emerged in the incubated sediment presenting the highest solubilised As and Fe. Results support the hypothesis of in-situ As mobilisation and speciation mediated by active biogeochemical processes.

Transport and removal of spores of Bacillus subtilis in an alluvial gravel aquifer at varying flow rates and implications for setback distances

To guarantee proper protection from fecally transmitted pathogen infections, drinking water wells should have a sufficiently large setback distance from potential sources of contamination, e.g. a nearby river. The aim of this study was to provide insight in regards to microbial contamination of groundwater under different flow velocities, which can vary over time due to changes in river stage, season or pumping rate. The effects of these changes, and how they affect removal parameters, are not completely understood. In this study, field tracer tests were carried out in a sandy gravel aquifer near Vienna, Austria to evaluate the ability of subsurface media to attenuate Bacillus subtilis spores, used as a surrogate for Cryptosporidium and Campylobacter. The hydraulic gradient between injection and extraction was controlled by changing the pumping rate (1, 10 l/s) of a pumping well at the test site, building upon previously published work in which tracer tests with a 5 l/s pumping rate were carried out. Attachment and detachment rate coefficients were determined using a HYDRUS-3D model and ranged from 0.12 to 0.76 and 0–0.0013 h−1, respectively. Setback distances were calculated based on the 60-day travel time, as well as a quantitative microbial risk assessment (QMRA) approach, which showed similar results at this site; around 700 m at the highest pumping rate. Removal rates (λ) in the field tests ranged from 0.2 to 0.3 log/m, with lower pumping rates leading to higher removal. It was shown that scale must be taken into consideration when determining λ for the calculation of safe setback distances.

Private drinking water wells in Denmark: monitoring and predicting nitrate levels

Private drinking water wells in Denmark: monitoring and predicting nitrate levels

Public health threats of diminished treatment of onsite sewage

Public health threats of diminished treatment of onsite sewage

Groundwater Health Risk Assessment Based on Monte Carlo Model Sensitivity Analysis of Cr and As—A Case Study of Yinchuan City

Groundwater is an important resource for domestic use and irrigation in the Yinchuan region of northwest China. However, the quality of groundwater in this region is declining due to human activities, with adverse effects on human health. In order to study the effects of chemical elements in groundwater on human health, the human health risk of drinking groundwater was calculated based on the actual situation in China and on the U.S. Environmental Protection Agency (USEPA) model. Moreover, the sensitivity of contaminant exposure in drinking water wells was quantified using Monte Carlo simulation to minimize uncertainty in conjunction with USEPA risk assessment techniques, with the aim to identify the major carcinogenic factors. In addition, Visual Minteq was used to analyze the possible ionic forms of the major factors in the hydrogeological environment of the study area. The results showed that the mean CR values for As were 2.94 × 10−0.5 and 5.93 × 10−0.5 for the dry and rainy seasons, respectively, while for 2018 they were 5.48 × 10−0.5 and 3.59 × 10−0.5, respectively. In parallel, the CR values for children for 2017 were 6.28 × 10−0.5 and 1.27 × 10−0.4, respectively, and 1.17 × 10−0.4 and 7.67 × 10−0.5, respectively, indicating a considerably higher carcinogenic risk for children than for adults. results of the sensitivity analysis of Cr6+ and As using Crystal Ball software showed association values of 0.9958 and 1 for As and 0.0948 and 0 for Cr in the dry and rainy seasons in 2017, and 0.7424 and 0.5759 for As and 0.6237 and 0.8128 for Cr in the dry and rainy seasons in 2018, respectively. Only in the rainy season of 2018, the association values for As were lower than those for Cr, indicating that As is more sensitive to total carcinogenic risk. The results of the visual coinage model analysis showed that among all the possible ionic forms of As, the activity of HAsO42− had the largest logarithmic value and that of H3AsO4 had the smallest value, regardless of pH changes. This indicates that HAsO42− is the ionic form of As with the main carcinogenic factor in the hydrogeological environment of the study area. Therefore, corresponding environmental control measures need to be taken in time to strengthen the monitoring and control of As, especially HAsO42−, in the groundwater of the study area. This study is of great significance for Yinchuan city to formulate groundwater pollution risk management and recovery.

Occurrence of Banned and Currently Used Herbicides, in Groundwater of Northern Greece: A Human Health Risk Assessment Approach.

The presence of pesticide residues in groundwater, many years after their phase out in European Union verifies that the persistence in aquifer is much higher than in other environmental compartments. Currently used and banned pesticides were monitored in Northern Greece aquifers and a human health risk assessment was conducted. The target compounds were the herbicides metolachlor (MET), terbuthylazine (TER), atrazine (ATR) and its metabolites deisopropylatrazine (DIA), deethylatrazine (DEA) and hydroxyatrazine (HA). Eleven sampling sites were selected to have representatives of different types of wells. Pesticides were extracted by solid-phase extraction and analyzed by liquid chromatography. MET was detected in 100% of water samples followed by ATR (96.4%), DEA and HA (88.6%), DIA (78.2%) and TER (67.5%). ATR, DIA, DEA, HA, MET and TER mean concentrations detected were 0.18, 0.29, 0.14, 0.09, 0.16 and 0.15 μg/L, respectively. Obtained results were compared with historical data from previous monitoring studies and temporal trends were assessed. Preferential flow was the major factor facilitating pesticide leaching within the month of herbicide application. Moreover, apparent age of groundwater and the reduced pesticide dissipation rates on aquifers resulted of long-term detection of legacy pesticides. Although atrazine had been banned more than 18 years ago, it was detected frequently and their concentrations in some cases were over the maximum permissible limit. Furthermore, human health risk assessment of pesticides was calculated for two different age groups though drinking water consumption. In all examined wells, the sum of the HQ values were lower than the unity. As a result, the analyzed drinking water wells are considered safe according to the acute risk assessment process. However, the presence of atrazine residues causes concerns related with chronic toxicity, since ATR R values were greater than the parametric one of 1 × 10−6 advised by USEPA, for both age groups.

Tertiary butyl alcohol plumes in southern california groundwater from leaking underground storage tank sites

Tertiary butyl alcohol in the groundwater was evaluated using closed leaking underground storage tank sites in Southern California between 2016 and 2019. Tertiary butyl alcohol is not regulated and lacks a maximum contaminant level in California. The current level of 12 µg per liter in drinking water (notification level) is advisory and not enforceable. As high as 88% of sites during 2018–2019 fiscal year were closed with tertiary butyl alcohol higher than its notification level in groundwater. Twenty-five percent of the time, the maximum tertiary butyl alcohol concentrations in the groundwater at closure were higher than 2,300 µg per liter during 2016–2017, 7,600 µg per liter during 2017–2018, and 4,400 µg per liter during 2018–2019, respectively. The plume length of the maximum tertiary butyl alcohol increased from 649 feet in 2016 to 1,128 feet in 2019. Considering the proximity of drinking water wells to the leaking underground storage tank sites in California, this points to an increase risk of impact on the drinking water resources. Tertiary butyl alcohol remained above 12 µg/L in a substantial percentage (70% in 2016–1017, 72% in 2017–2018, and 88% in 2018–2019) of sites. Site closure practices at Los Angeles Regional Water Quality Control Board should be more stringent toward tertiary butyl alcohol contamination. Despite documented health hazards, tertiary butyl alcohol has not received sufficient attention from government agencies. The toxicological evaluation of tertiary butyl alcohol indicates significant human health concerns. Based upon the toxicological evidence, an MCL should be considered for tertiary butyl alcohol in drinking water.

Understanding factors influencing total coliform and E. coli sampling outcomes in new private water wells in North Carolina, USA

Provision of safe drinking water is critical for human health and survival. Indicator bacteria (i.e., total coliforms and fecal coliforms) are typical indicators of microbial water quality. In North Carolina (NC), new private drinking water wells are required for total coliform and E. coli testing. Such wells are typically only tested once before use in NC, so consistent and accurate testing is critical. Herein, we analyzed a large data set (n = 32,839) of water samples collected from private drinking water wells, representing 80 of North Carolina's 100 counties, and analyzed for significant differences in E. coli and total coliform positive rates depending on county and region of collection, transport method, sampling collection point, day of week, month, year, season, treatment method, time elapsed between collection and incubation, method used for detection, and the personnel reporting sample results. Our results showed that 34.1% of samples tested positive for total coliform, while 1.38% tested positive for E. coli. The total coliform positive rate ranged from 16.4% to 60.0% among the 80 counties. While nine counties reported no positive E. coli samples, positive E. coli rates for the remaining counties ranged from 0.17% to 12.7%. Samples from the Inner Coastal Plain were more likely to be positive for total coliforms, while samples from the Outer Coastal Plain were more likely to be positive for both the E. coli and total coliforms. Delivery method, sampling site, month, year and season of collection, treatment type, elapsed time between collection and analysis, and person reporting sample results were correlated with positive total coliform results. Similarly, sampling point, month, treatment type, test type, and the person reporting the results were correlated with positive E. coli results. These results can be used to prioritize limited public health resources for maximum impact on new private well drinking water safety. Further, providing clear and complete information by the sample collector could improve future research to better inform well water sampling practices.

An Assessment on the Safety of Drinking Water Resources in Yasouj, Iran

The health of drinking water is an important criterion for developed countries and around half of the world’s population is deprived of sanitary and safe drinking water. By identifying the time of pollution occurrence and the places that are most sensitive to pollution the management of the quality of drinking water can be planned. Since the landfill for Yasouj, a city in Iran, was located in a higher place than the drinking water wells, which were drilled in a karst aquifer, the safety of the drinking water resources (including eight wells) of Yasouj were investigated in the present study. For this purpose, different parameters, comprising the concentration of eight heavy metals and eight ions, alkalinity, total harness, pH, biological oxygen demand (BOD5) and total coliform, were measured over 12 months and the obtained data were compared with the WHO’s and Iran’s drinking water standards. To assess the measured data statistically, SPSS software was applied. From the reported results, the water characterizations of the wells complied with the mentioned standards; however, four of the wells were more prone to supply higher quality water. It is noted that Hg, Cd, and the total coliform of wells were close to the permissible values reported by both the aforementioned standards. Therefore, the water obtained from wells should be disinfected before using and Hg and Cd concentrations need to be monitored regularly to prevent poisoning. Due to the rapid movement of pollutants in karst areas, it is very important to detect their presence in the water resources over time. Consequently, continuous monitoring and sampling is one of the most important protection dealings for karst aquifers.

Seasonal variation of pesticides in surface water and drinking water wells in the annual cycle in western Poland, and potential health risk assessment

Drinking water wells on a riverbank filtration sites are exposed to contamination from farmlands (like pesticides) that had migrated from the contaminated river. In this study, pesticide contamination of the Warta River and riverbank filtration water at the Mosina-Krajkowo well field (Poland) were examined during the annual cycle. Among the 164 pesticides analysed, 25 were identified. The highest concentrations occurred in the river water and decreased along the flow path from the river to wells. Only the most persistent substances were detected at the farthest points. During the study, seasonal changes in pesticide concentrations and differences in the types of occurring substances were observed. Most substances and the highest concentrations were detected in May 2018, while the lowest number and the lowest concentrations were detected in February 2018. Spring is the period of increased exposure of water to pollution, which is correlated with increased pesticides use and increased rainfall. Seven toxic and persistent pesticides were found with the highest concentrations in water: isoproturon, nicosulfuron, imidacloprid, terbuthylazine, chlorotoluron, S-metalachlor, and prometryn. Pesticides are widely used in the study area; therefore, a potential health risk assessment was performed. The hazard quotient (HQ) values did not exceed one, which indicated a less significant health risk.

The deterioration asymmetry of engineering structures

Engineering structures are known to withstand significant applied loads, in order to respect static requirements. With time, the environmental sustainability became an important aspect for construction systems. Therefore, the durability issues acquired an increased attention. Materials and systems are subjected to atmospheric degradation. Geographic location, orientation, degree of exposition, construction details, height and degrading agents such as, sun irradiation, wind, rainfall, and chemical agents influence the intensity of the deterioration. This latter mainly takes place in an asymmetric manner. Within short distance, the damage of a structure may significantly vary. The present work outline the asymmetry in the degradation of some main infrastructure such as buildings, tunnels, waste water plants, drinking water reservoirs, bridges, drinking water wells and artifacts exposed to stray currents. The asymmetry largely affects the deterioration process. In some cases, a relevant damage was observed after short time. Thus, a wise planning of infrastructure and materials may increase their general durability.

Investigating a broad range of emerging contaminants in a set of anthropogenically impacted environmental compartments

Environmental compartments are repositories of probably thousands of emerging contaminants (ECs) released along with treated/untreated wastewater. Despite extensive studies on the detection of ECs in surface water, other environmental compartments such as sediments and groundwater are yet to be thoroughly investigated. To assess the heavy anthropogenic impact on the environment, 24 environmental samples comprising of surface water, sediment and groundwater collected from the Yamuna River basin of India were analyzed via target and suspect screening. The surface water and sediment samples were collected from upstream and downstream of densely populated cities and towns situated along the heavily contaminated river Yamuna. The groundwater samples were collected from shallow drinking water wells of the catchment. Liquid chromatography tandem mass-spectroscopy was used to quantify 10 widely consumed pharmaceuticals in the samples. The study also analyzed the potential health hazards posed by the quantified contaminants. In order to evaluate further, the surface water and groundwater samples were subjected to high resolution mass spectrometry (HRMS) screening against a library resulting in a list of 450 ECs in the surface water and 309 ECs in the groundwater. Agricultural chemicals and pharmaceuticals found abundantly in the samples and half of whom were reported first time. The risk quotient was calculated to assess the potential hazard of the target analytes.

Groundwater Quality of Drinking Water Wells in the West Bank, Palestine

Groundwater, the main drinking water source in the West Bank, is highly vulnerable to pollution given the karstic nature of the aquifer. This study was aimed at screening the quality of groundwater used for water supply, in terms of physicochemical and microbiological properties, and heavy metals concentrations. Attention was given to groundwater chemistry, using piper and Durov diagrams, to assess potent impact of pollution on groundwater. Twenty-nine groundwater samples from selected wells, representing the different groundwater fields in the West Bank, were collected and analyzed. The results revealed that the concentration of the ions and parameters affecting the aesthetic and health related water quality, such as Cl−, Na+, NH4+, TDS, and NO3−, and selected (semi) metals, including Cr, Cu, Fe, Mn, Pb, Cd, and As, are within the limits recommended for drinking water. The dominant cations and anions were in the order of Ca2+ > Na+ > Mg2+ > K+ > NH4+ and HCO3− > Cl− > NO3− > SO42−, respectively. The total average groundwater hardness is approximately 2.1 mmol/L and can be attributed to calcium (approximately 60%) and magnesium. The major ground water types in the West Bank were fresh water (Ca-Mg-HCO3), fresh water mixed with another water type (Ca-Mg-Na-HCO3 or Ca-Mg-HCO3-Cl), and extreme water type (Na-Ca-Mg-HCO3-Cl or Na-Ca-HCO3-Cl) showing high TDS, Cl− and Na+. Signs of pollution, namely elevated levels of nitrate and ammonium, were, however, observed even in some deep wells (>600 m), despite the thick cover of soil, tapping the Lower Ceneomanian confined aquifer.

Refining the conceptual model for radionuclide mobility in groundwater in the vicinity of a Hungarian granitic complex using geochemical modeling

Groundwater is an important freshwater resource, which can be affected by geogenic radionuclide contamination. To make decisions regarding the use and management of groundwater, understanding the controls of radionuclide mobility is critical. In the southern foreland of a granitic outcrop in Hungary, high gross alpha activity concentration was measured in drinking water wells, related probably to the presence of uranium. It has been suggested that understanding of the groundwater flow system may be a key aspect to understand uranium mobility in groundwater. The goal of the present work was to elucidate the conceptual model of radionuclide mobility in the study area, focusing in particular on the geochemical controls of uranium. For this purpose, water samples were collected and nuclide-specific measurements for 226Ra and radon isotopes were carried out, in addition to 234U+238U measurements, to increase the range of radionuclides and better understand their mobility. A geochemical modeling analysis involving redox-controlling kinetic reactions and a surface complexation model was developed to support the conceptual model. The results from the sampling indicate that excess of 234U+238U (3–753 mBq L−1) contribute to the natural radioactivity measured in drinking water to a large degree. 226Ra was measured in relatively low activity concentrations (<5–63 mBq L−1) with the exception of three specific wells. Notable radon activity concentration was measured in the springwaters from Velence Hills (1.01–3.14 × 105 mBq L−1) and in interrelation with the highest (285–695 mBq L−1) 226Ra activity concentrations. The geochemical model suggests that uranium distribution is sensitive to redox changes in the aquifer. Its mobility in groundwater depends on the residence time of groundwater compared to the reaction time controlling the consumption of oxidizing species. The longer the flow path from the recharge point to an observation point where U is measured, the more likely it is that reducing conditions will be found in the aquifer and the elemental concentration U will be low.

Relation between Road-Salt Application and Increasing Radium Concentrations in a Low-pH Aquifer, Southern New Jersey

The Kirkwood–Cohansey aquifer in southern New Jersey is an important source of drinking-water supplies, but the availability of the resource is limited in some areas by high concentrations of radium, a potential carcinogen at elevated concentrations. Radium (226Ra plus 228Ra) concentrations from a network of 25 drinking-water wells showed a statistically significant increase over a decadal time scale (p < 0.05), with a median increase of 0.35 picocuries per liter. Increases in Ra are correlated with road-salt application rates, and we hypothesize that the correlation is causal. Geochemical processes associated with road-salt applications that can mobilize Ra into solution include competition by excess sodium for sorption sites and formation of chloride complexes (RaCl+ and RaCl2). The largest increases in Ra were in groundwater with low pH (≤5), which is an indirect surrogate for low cation-sorption capacity. Correlations with other potential anthropogenic causes for the increase in Ra were not observed, further suggesting a road-salt effect. Given the significant increase in Ra concentrations in this drinking-water source, the known carcinogenic risks from Ra, the direct link to road-salt application, and the likelihood for continued increases, additional monitoring is necessary in areas with similar hydrogeologic and geochemical settings.

Vulnerability of groundwater from elevated nitrate pollution across India: Insights from spatio-temporal patterns using large-scale monitoring data

Agriculture-sourced, non-point groundwater contamination (e.g., nitrate) is a serious concern from the drinking water crisis aspect across the agrarian world. India is one of the largest consumers of nitrogen fertilizers in South-Asia as well as in the world but groundwater nitrate lacks critical attention as a wide-scale drinking water pollutant in the country. Our study provides the first documentation of the distribution of groundwater nitrate and the extent of elevated nitrate contamination across India, along with the delineation of the temporal trends and the natural and anthropogenic factors that influence such occurrence of groundwater nitrate. High resolution, annual-scale spatio-temporal variability of groundwater nitrate concentration and consequent contamination was delineated using groundwater nitrate measurements from ~3 million drinking water wells spread across 7038 administrative blocks between 2010 and 2017 in India. An average 8% of the studied blocks were found affected by elevated groundwater nitrate (> 45 mg/L). Depth-dependent trend demonstrated that nitrate concentrations were about 14% higher in shallow water wells (≤ 35 m) than deep wells (>35 m). The overall temporal trend of groundwater nitrate concentration was decreasing slightly nationwide in the study period. The correlation tests and causality test results indicated that the spatial distribution of groundwater nitrate was significantly associated with agricultural N-fertilizer usage, whereas the decreasing temporal trend corresponded with the overall reduced N-fertilizer usage during the study period. Spatial autocorrelation analysis identified the clustering of high nitrate areas in central, north, and southern India, specifically in areas with higher fertilizer usage. We estimate about 71 million Indians possibly exposed to elevated groundwater nitrate concentrations and the majority of them reside in rural areas. Thus, this study provides the previously unrecognized, wide-scale, anthropogenic, diffused groundwater nitrate contamination across India.