Investigating a broad range of emerging contaminants in a set of anthropogenically impacted environmental compartments

Abstract

Environmental compartments are repositories of probably thousands of emerging contaminants (ECs) released along with treated/untreated wastewater. Despite extensive studies on the detection of ECs in surface water, other environmental compartments such as sediments and groundwater are yet to be thoroughly investigated. To assess the heavy anthropogenic impact on the environment, 24 environmental samples comprising of surface water, sediment and groundwater collected from the Yamuna River basin of India were analyzed via target and suspect screening. The surface water and sediment samples were collected from upstream and downstream of densely populated cities and towns situated along the heavily contaminated river Yamuna. The groundwater samples were collected from shallow drinking water wells of the catchment. Liquid chromatography tandem mass-spectroscopy was used to quantify 10 widely consumed pharmaceuticals in the samples. The study also analyzed the potential health hazards posed by the quantified contaminants. In order to evaluate further, the surface water and groundwater samples were subjected to high resolution mass spectrometry (HRMS) screening against a library resulting in a list of 450 ECs in the surface water and 309 ECs in the groundwater. Agricultural chemicals and pharmaceuticals found abundantly in the samples and half of whom were reported first time. The risk quotient was calculated to assess the potential hazard of the target analytes.