In marine environments, bridge piers and columns are prone to corrosion caused by harmful media, particularly chloride ions. This corrosion can lead to cracking of the steel bars in the protective layer of the bridge piers. To enhance the corrosion resistance of concrete in bridge piers, this article introduces the use of nanoclay-modified cement mortar. This innovative material offers high-performance surface treatment options that can effectively slow down the erosion process of harmful media and reduce the risk of bridge pier column cracking. To evaluate the ion erosion resistance of this nanoclay-modified cement mortar, we conducted detailed experiments on the pore structure of cement paste. The pore structure of cement paste with different dosages of nano-kaolinite clay and the dispersion method was studied using mercury intrusion porosimetry (MIP). The fractal dimension of the pore surface area of the net cement paste was calculated from the fractal model based on thermodynamic relationships of the pore structure-related parameters obtained with mercury pressure experiments. The relationship among the multiple fractal dimensions, pore structure parameters, dispersion mode, and permeability is explored. The results show that the addition of nano-kaolinite clay particles can improve the internal pore structure of cement materials. When 1.5% nano-kaolinite clay is mechanical dispersed, the total specific pore volume and the most probable pore size are reduced by 47.83% and 56.87%, respectively, compared with the control group. The fractal dimension image of cement-based materials with nano-kaolinite clay has a range of singular points and does not have fractal characteristics in this range. Nano-kaolinite clay has a significant effect on the fractal dimension of pore size range I. The fractal dimension of the whole pore size range is not suitable for the analysis of permeability, and the fractal dimension calculated by selecting less than the critical pore size range has a good correlation with permeability.
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