First, I show how to use the concept of phlogiston to teach oxidation and reduction reactions, based on the historical context of their discovery, while also teaching about the history and nature of science. Second, I discuss the project as an exemplar for integrating history, philosophy and sociology of science in teaching basic scientific concepts. Based on this successful classroom experience, I critique the application of common constructivist themes to teaching practice. Finally, this case shows, along with others, how the classroom is not merely a place for applying history, philosophy or sociology, but is also a site for active research in these areas. This potential is critical, I claim, for building a stable, permanent interdisciplinary relationships between these fields.