Application Of Cement Research Articles

Phase change microcapsules with high encapsulation efficiency using Janus silica particles as stabilizers and their application in cement

This study reports the preparation of phase change microcapsules (PCMs) which possess high encapsulation efficiency, this is achieved by using Janus silica particles (JSPs) as stabilizers in combination with Pickering emulsion and suspension polymerization methods. The inner shell and outer shell of the PCMs are polyacrylate and JSPs respectively. The morphologies and particle sizes of the PCMs can be controlled well, as evidenced by SEM and optical microscopy characterization. The amount of JSPs and functional monomer methacrylic acid play key roles in controlling the morphologies of the PCMs. The encapsulation ratio of PCMs can be adjusted with the encapsulation efficiency reaching as high as 99.6%. The phase change enthalpy of the PCMs is 175.1 J/g when the core/inner shell/outer shell weight ratio of n-octadecane/polyacrylate/silica microcapsules is 70:21:1. The TGA result indicates that the PCM is stable up to 150 °C. The enthalpy of PCM remains almost unchanged after 7560 phase change cycles, illustrating the PCM exhibits excellent thermal reliability and durability. The PCM-modified cement plate shows a remarkable cooling effect, which means that this type of PCM has promising applications in the construction field.

Production of Plastic Cement Concrete from PVC Waste

The disposal of plastic wastes into the environment is a serious concern due to its limited biodegradability and production in excess quantity. The accumulation of enormous volumes of plastic waste is considered to be a major pollution problem and it is essential to find an alternate method to address such issues in an environmental-friendly and cost-effective way. The current research focused on the production of plastic cement concrete from waste polyvinyl chloride (PVC) generated from a polymer processing industry in varying proportions, and to modify the concrete properties. Polyvinyl chloride was partially replaced with Ordinary Portland Cement (OPC) by varying its compositions from 15% to 35% by weight (i.e. 15%, 20%, 25%, 30% and 35% OPC). The curing period was kept for 7 days after casting process. The produced plastic cement concrete was tested for compressive strength through Universal Testing Machine (UTM). Density and water absorption tests were also carried out on hardened concrete to assess the application of plastic cement concrete as a building material. The other characterization techniques employed are Fourier Transform Infrared Spectroscopy (FTIR) and X-Ray Diffraction (XRD) analyses. It was observed that up to 15% by weight of polyvinyl chloride could be replaced with OPC which exhibited higher compressive strength (19.25 MPa) compared to other mix proportions. A maximum density of 2.051 g/cm3 was obtained at a concrete mix composition corresponding to 25% replacement. The maximum water absorption percentage (5.86%) was observed at 35% plastic waste replacement. The studies demonstrate that the waste plastic material is considered to be a cost-effective, viable and sustainable way of reducing the environmental pollution.

The Effect of Curing Pressure on Shear Bond Strength of Zirconia to Resin Cement

Background: Nowadays, the esthetics demand is continuously increasing; therefore, metal-free materials are widely used, like a zirconia-based ceramic, which is conveniently fabricated via computer-aided design and computer-aided manufacturing (CAD/CAM) system for restorations from single to full mouth rehabilitation. Objective: This study evaluated the effect of pre-curing pressure on the shear bond strength of zirconia to the resin cement. Methods: A total of sixty-three sandblasted cylindrical zirconia mounted in autopolymerizing resin were randomly assigned to three groups; Group 1: no treatment (control), Group 2: negative pressure, and Group 3: positive pressure to resin cement after resin cement application and resin composite columns bonded to zirconia. Thirty-three of the samples were stored in distilled water at 37 °C for 24 hr before the shear bond strength test for thirty samples and three samples were cross-sectionally cut for interfacial observation with FESEM. Another thirty samples were thermocycled for 5,000 cycles in distilled water at 5°C to 55 °C before testing. The shear bond strength and failure mode were evaluated. Examination of the bonding interface was also done. Results: The results were analyzed using two-way ANOVA. The means of shear bond strength of non-thermocycle of the control group were 8.01 ±1.74 MPa, 9.10 ±1.90 MPa, and 9.14 ±2.58 MPa, whereas that of thermocycle group were 5.71 ±0.84 MPa, 5.53 ±0.68 MPa, and 5.68 ±0.77 MPa in zero pressure group, negative pressure group, and positive pressure group, respectively. It showed no statistically significant differences in shear bond strength in all pressure groups (p > 0.05). The pre-curing pressure did not influence the shear bond strength of the zirconia and resin cement. Conclusion: There was no difference in the shear bond strength between the pressure groups and the no treatment control group. The positive and negative pressure did not influence the shear bond strength of the zirconia and resin cement.

Possibilities of Application Cement By-Pass Dust into the Garden Architecture Elements

This article deals with the possibility of using cement by-pass dust (CBPD) in the garden architecture elements, specifically in curbs for park use. To increase the positive effect on the environment, other secondary raw materials were also used in the research, specifically blast furnace granulated slag and silica fly ash. Mixtures were based on alkali activation, where cement as a binder was 100% replaced by raw materials with waste properties. In the research, properties of used materials and also the basic physical-mechanical and durability properties of prepared mixtures were determined Part of the research focused on the effect of the tested beams on the grassland planted around the beams. Any significant negative impact was not registered, except for low pH increase of soil. Infrared spectroscopy and thermal analysis were performed on selected samples. Testing has shown that the products are in accordance with the Czech standard requirements for concrete curbs in garden architecture. The samples did not pass only the scaling test, which is, however, a condition for concrete curbs used for roads. For garden architecture this test is not required.

The Effects of Waste Cement on the Bioavailability, Mobility, and Leaching of Cadmium in Soil.

Waste cement is a construction and demolition waste produced from old buildings’ demolition and transformation. In recent years, the recycling of recycled concrete is limited to the use of recycled aggregate, and the research on the utilization of waste cement in waste concrete is scarce. This study explored the effective application of waste cement for the adsorption of cadmium (Cd2+) from an aqueous solution and the bioavailability and immobility of Cd2+ in soil. Results showed that the maximum adsorption capacities of ordinary Portland cement(OPC) paste, fly ash cement (FAC) paste, and zeolite cement (ZEC) paste for Cd2+ were calculated to be 10.97, 9.47, 4.63 mg·g−1, respectively. The possible mechanisms for Cd2+ adsorption in the solution by waste cement mainly involve precipitation by forming insoluble Cd2+ compounds in alkaline conditions, and ion exchange for Cd2+ with the exchangeable calcium ions in waste cement, which were confirmed by XRD and SEM. Results from diethylene triaminepentaacetic acid (DTPA) extraction and toxicity characteristic leaching procedure (TCLP) implied reduction of the Cd2+ mobility. DTPA-extractable Cd2+ decreased by 52, 48 and 46%, respectively, by adding 1% OPC, FAC and ZEC. TCLP-extractable Cd2+ decreased by 89.0, 80.3, and 56.0% after 1% OPC, FAC, and ZEC treatment, respectively. BCR analyses indicate that OPC, FAC, and ZEC applications increased the percentage of Cd2+ in residual fraction and induced a high reduction in the acid-soluble Cd2+ proportion. The leaching column test further confirmed a reduction in Cd2+ mobility by waste cement treated under continuous leaching of simulated acid rain (SAR). Therefore, waste cement exhibited a significant enhancement in the immobilization of Cd2+ under simulated acid rain (SAR) leaching. In summary, the application of alkaline waste cement could substantially remove Cd2+ from wastewater and reduce Cd2+ mobility and bioavailability in contaminated soil.

Influence of the Type of Cement and the Addition of an Air-Entraining Agent on the Effectiveness of Concrete Cover in the Protection of Reinforcement against Corrosion.

The concrete cover is the basic protection of the reinforcement against the influence of external factors that may lead to its corrosion. Its effectiveness depends mainly on the composition of the concrete mix, including the cement used. Depending on external environmental factors that may aggressively affect the structure, various types of cements and concrete admixtures are recommended. The paper presents the results of tests that allow us to assess the effect of the type of cement used and the air-entraining agent on the effectiveness of the concrete cover as a layer protecting the reinforcement against corrosion. In order to initiate the corrosion process, the reinforced concrete specimens were subjected to cycles of freezing and thawing in a sodium chloride solution. The degree of advancement of the corrosion process was investigated using the electrochemical galvanostatic pulse technique. Additionally, the microstructure of specimens taken from the cover was observed under a scanning electron microscope. The research has shown that in the situation of simultaneous action of chloride ions and freezing cycles, in order to effectively protect the reinforcement against corrosion, the application of both blast-furnace slag cement and an air-entraining agent performed the best.

The Combined Effect of CKD and Silica Fume on the Mechanical and Durability Performance of Cement Mortar

To manufacture high-strength and high-performance concrete, the incorporation of silica fume with concrete was becoming popular nowadays. When utilizing various amounts of cement substitute products, the design becomes even more complicated. The latest research has been dedicated to researching the applicability of cement substitute products for cement kiln dust (CKD) and silica fume (SF). In permeability and compressive strength terms, the effect of these components on the efficacy of the concrete would be studied. Also, the materials proposed might limit greenhouse gas emissions, which will mitigate climate change on other causes of global pollution. Casting a standard concrete cube (100 percent OPC) equivalent to (150 gm) would initiate the experiment, which was utilized later for comparative purposes. The industrial waste materials (SF and CKD) was be applied as cement substitution proportions (10 percent, 20 percent, and 30 percent) of the dry cement weight at varying percentages of each component (5 percent, 10 percent, and 15 percent). Eventually, after 7, 14, 28 days, the compressive strength shift would be calculated. The permeability of the latest concrete will be checked after (7, 14, and 28) days of healing utilizing ultrasonic pulse velocity (UPV) technology. The experimental findings indicate that with a specimen comprising 20 percent of (SF and CKD) relative to (100 percent OPC) specimen, there is an improvement in compressive intensity and pulse velocity values in various curing times and specimens of various (SF and CKD) specimen M3 have a decrease in pulse velocity value after 7 curing days.

Role of Zoledronic Acid Supplementation in Reducing Post-Surgical Recurrence of Giant Cell Tumor of Bone: A Meta-Analysis of Comparative Studies.

Zoledronic acid is a bisphosphonate that has recently gained interest in adjuvant therapy for giant cell tumor of bone (GCTB). It has an apoptotic effect on osteoclasts that are precursors of GCTB. However, the evidence suggesting the role of zoledronic acid in preventing GCTB recurrence is mixed, and therefore, a consensus is yet to be established. The purpose of the current meta-analysis was to analyze the impact of zoledronic acid supplementation on tumor recurrence in surgical treated GCTB.A systematic search was conducted on PubMed, Embase, and Web of Science databases to identify studies that analyzed the impact of local or systemic zoledronic acid supplementation on clinical outcomes in surgically treated GCTB. The data from the comparative studies were pooled and analyzed to investigate the association of zoledronic acid supplementation with tumor recurrence. Additionally, other factors such as age, gender, soft tissue extension, polymethyl methacrylate (PMMA) cement application, recurrent presentation, and extended curettage were also investigated for any association with tumor recurrence.Of the 271 results, 13 unique studies reported the clinical outcomes in GCTB. Seven studies compared the outcomes of zoledronic acid supplementation with control groups. Six studies presented the tumor recurrence-related data among the comparison groups. The zoledronic acid supplementation was associated with significantly lower tumor recurrence rates (p = 0.007). Additionally, a significant association of soft tissue extension and non-usage of PMMA cement with tumor recurrence were observed.The current meta-analysis suggests that zoledronic acid supplementation reduces tumor recurrence rates in surgically treated GCTB. We, therefore, recommend the use of zoledronic acid following aggressive extended curettage of the tumor. Further, well-planned randomized controlled trials will help strengthen this evidence.

Experimental Study on Mechanical Properties and Structural Characteristics of Modified Sludge in Foundation Pit

To explore the efficient method of sludge modification, Ultra-fine Portland cement (UPC) was introduced as a sludge modifier regarding Ordinary Portland Cement (OPC) modified sludge as a reference. The mechanical properties and microstructural changes of UPC-modified sludge with different curing time and cement content were carried out by unconfined compressive strength (UCS), X-ray diffraction (XRD), mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM) tests. Results show that the UCS of UPC-modified sludge varies with curing time and cement content in the same way as that of OPC-modified sludge. However, compared with OPC-modified sludge, UPC has a higher sludge modification efficiency, and the UPC-modified sludge has greater compressive strength, significantly early-strength, and stronger resistance to deformation. The stress-strain curves of UPC-modified sludge present significant peak stresses, and which show a brittle failure mode. The combination of the hydration products calcium silicate hydrate (C-S-H) gels and ettringite (Aft) crystals are the essential reason for the improvement of the macroscopic strength of the modified sludge. In contrast to OPC, the UPC hydrates faster and more fully. The UPC-modified sludge can generate more hydration products under the same conditions, this is why that has high efficiency and early-strength. The conclusions obtained in this study can provide a reference for the similar engineering application of ultra-fine cement in modified sludge.

Application and Clinical Effectiveness of Antibiotic-Loaded Bone Cement to Promote Soft Tissue Granulation in the Treatment of Neuropathic Diabetic Foot Ulcers Complicated by Osteomyelitis: A Randomized Controlled Trial.

This study explored the clinical effectiveness of antibiotic-loaded bone cement on primary treatment of diabetic foot infection. This is a randomized controlled study, including thirty-six patients with diabetic foot ulcer complicated by osteomyelitis who had undergone treatment between May 2018 and December 2019. Patients were randomly divided into control group (group A) and study group (group B). Patients in the intervention group received antibiotic-loaded bone cement repair as primary treatment, while patients in the control group received conventional vacuum sealing draining treatment. Clinical endpoints were assessed and compared between the two groups, including wound healing time, wound bacterial conversion, NRS pain score, number of wound dressing changes, and average hospitalization time. All patients were followed up for a period of 12 months after discharge. Results show that compared with the control group, patients in the study group had significant difference in the number of patients for baseline pathogens eradication, short NRS pain score, hospital length of stay and cost, wound surface reduction, healing time, low rate of complications, and infection recurrence. Based on the findings, we conclude that antibiotic-loaded bone cement can be used for treatment of wound in patient with diabetic foot infection. It can help to control wound infections, shorten hospital length of stay, reduce medical cost, and relieve both doctors' and patients' burden. The application of antibiotic-loaded bone cement is suitable for diabetic wound with soft tissue infection or osteomyelitis.

Meta-Analysis of In-Vitro Bonding of Glass-Ionomer Restorative Materials to Primary Teeth.

Restoration of primary teeth is among the main clinical applications of glass-ionomer cements (GIC). The aim of the study was to review and summarize existing evidence of in vitro bond strength of glass-ionomer (GI) restoratives to enamel and dentin of primary teeth. A literature search was performed in PubMed/Medline, Scopus, Web of Science, Cochrane, and Google Scholar databases to identify studies published until April 2021. The search strategy was: (“glass”) and (“ionomer”) and (“primary” or “deciduous”) and (“bond” or “tensile” or “shear”). Two researchers independently retrieved articles that reported on the bond strength of GIC to primary dentin and/or enamel. The meta-analysis was performed to compare the bond strength values of conventional (C) GIC and resin-modified (RM) GIC to different substrates. From 831 potentially eligible articles, 30 were selected for the full-text examination, and 7 were included in the analysis. Studies were rated at high (3), medium (3), and low (1) risk of bias. RM-GIC showed higher bond strength to primary enamel and dentin compared to the C-GIC. Meta-analysis of in vitro studies, evaluating bonding properties of GI restoratives to primary teeth, suggests the superior performance of RM-GIC. However, there is a lack of studies that examine the properties of novel GI formulations.

The evaluation of chemical admixtures on the performance of cement stabilized materials in cold weather

The application of cement stabilized materials (CSM) in cold weather is prohibited by many federal and state agencies, as low temperatures can mitigate the cement hydration efficacy and retard the strength and stiffness growth of CSM. Due to the similarities between concrete and CSM, chemical admixtures that make concrete achieve full service capabilities under extreme conditions are quite likely to be successful in soil stabilization. This study evaluated the effect of four types of promising admixtures on the freezing point (FP) and strength development of CSM under cold temperature. The laboratory results indicated that all the admixtures made the FP values decrease with dosage increase, and the optimum dosages existed on three admixtures, which could provide the peak unconfined compressive strength (UCS). AC122 and AC534 were more effective on reducing the FP values, thus they were combined together at various percentages and used in CSM mixtures for FP and UCS tests. The results showed that the FP values decreased more from the admixture combinations than the superposition of individual admixtures. Using the measured FP data, a model was developed to predict the FP decrease at different admixture dosages. The UCS of CSM with different admixture combinations did not change significantly after 7-day curing at 35°F. In addition, for the CSM with different admixture dosages cured at the temperatures slightly above the FP, the UCS values were close to each other when the curing temperature was identical, and decreasing the curing temperature reduced the UCS.

Cementing technique for total knee arthroplasty in cadavers using a pastry bone cement

BackgroundIn cemented primary total knee arthroplasty (TKA), aseptic loosening remains a major cause for failure. Cementing techniques and characteristics of a chosen cement play a key role for good fixation and implant survival. A pastry bone cement was developed to facilitate the cement preparation and to rule out most of preparation-associated application errors. The pastry bone cement was compared to a conventional polymethyl methacrylate cement in a TKA setting.MethodsStandardized implantations of total knee endoprostheses were performed in bilateral knee cadavers to investigate handling properties, variables of cement application, working time, and temperature development. Mechanical aspects and cementation quality were assessed by pull-out trials and microscopic interface analysis.ResultsBoth cements expressed similar characteristics during preparation and application, only the curing time of the pastry cement was about 3 min longer and the temperature peak was lower. Fractures of the conventional cement specimens differed from the pastry cement specimens in the tibial part, while no differences were found in the femoral part. Penetration depth of the pastry cement was similar (tibia) or deeper (femur) compared to the conventional cement.ConclusionsThe pastry cement facilitates the feasibility of cemented TKA. The pre-clinical tests indicate that the pastry bone cement fulfills the requirements for bone cement in the field of knee arthroplasty. A clinical trial is needed to further investigate the approach and ensure patient safety.

Selection of Dental Cements in Prosthodontics: A Review Paper

The cementation procedures of crown and bridge is consider as an important stage, however, the selection of the proper cement is a significant, because the quality of the cement affects the durability of the restoration. In modern dentistry, many cementing and luting materials have been introduced. These materials differ in their properties and applications. This makes selection of suitable cement for specific clinical situation often difficult. The aim of this paper is to review and analyze dental cements used in dentistry, mainly in fixed prosthodontics in order to help practitioners select the most convenient cement material in dental practice. Moreover, this review paper will consider the structures, properties and the application of dental cements in specific clinical situations.

Nano-Porous Silica-Aerogel-Incorporated Composite Materials for Thermal-Energy-Efficient Pitched Roof in the Tropical Region

Silica aerogel possesses an ultra-low thermal conductivity by virtue of its nano-structure. Owing to the fragility of monolithic aerogel, the development and production of aerogel-based insulation materials involve the incorporation of granular aerogel with other materials to form composite materials. In the present study, the application of silica-aerogel-incorporated composite cement paste as render on the roof-top surface is coupled with the installation of a novel silica-aerogel-incorporated composite insulation board below the roof tiles. Control and silica-aerogel-incorporated samples of the composite cement paste and insulation were prepared. Thermal conductivity and strength tests were performed on the samples. A simulation study was performed on a Building Information Model subjected to a tropical climate to project the resultant impact of the cement render coupled with the insulation board on the thermal-energy-efficiency of the roof. For optimization of thermal and strength performances, silica aerogel contents of 4 wt.% and 3 wt.% were selected for the cement render and insulation board, respectively. The projected annual cooling load and energy savings revealed that the application of a 20-mm cement render, coupled with the installation of a 100-mm thick insulation board, is recommended as the optimum roof configuration.

Résistance à l’arrachement des vis iliaques cimentées dans les fixations spino-pelviennes

IntroductionSpino-pelvic fixation has been widely accepted for surgical treatment of sacral tumor, scoliosis surgery and pelvic fractures. Cement augmentation of screws is an option to improve implant stability in osteoporotic bone quality. Aim of the present study is to compare iliac screw fixation without cement fixation and two cement application options in a biomechanical testing. HypothesisCement augmentation of iliac screws leads to superior pull-out strength. Material and methodsThirty female and osteoporotic human iliac bones were used. Three operation treatment groups were generated: Screw fixation (cannulated screws) without cement augmentation (Operation treatment [OT] A), screw fixation with cement augmentation before screw placement (cannulated screws) (OT B) and screw fixation with perforated screws and cement augmentation after screw placement (OT C). Pull-out tests were performed with a rate of 6mm/min. A load versus displacement curve was generated. Maximum pull-out force (N) was measured in the load-displacement curve. ResultsPaired group 1 (OT A vs. OT B): Screw fixation without cement augmentation: 592.6N±335.07 and screw fixation with cement augmentation before screw placement: 996N±287.43 (p=0.0042). Paired group 2 (OT A vs. OT C): Screw fixation without cement augmentation: 716.2N±385.86 and fenestrated screw fixation with cement augmentation after screw placement: 1324.88N±398.76 (p=0.0489). Paired group 3 (OT B vs. OT C): Screw fixation with cement augmentation before screw placement: 1077.2±486.66 and fenestrated screw fixation with cement augmentation after screw placement: 1298.2N±726.19 (p=0.3286). DiscussionRegarding iliac screw fixation for spino-pelvic ostesynthesis in osteoporotic bone, cement augmentation is significantly superior to solid iliac screw fixation respecting pull-out-strength. Nevertheless, further biomechanical studies are needed to verify these findings. Level of evidenceNot applicable; Biomechanical cadaver study.

3D printed rodent skin-skull-brain model: A novel animal-free approach for neurosurgical training.

In neuroscience, stereotactic brain surgery is a standard yet challenging technique for which laboratory and veterinary personnel must be sufficiently and properly trained. There is currently no animal-free training option for neurosurgeries; stereotactic techniques are learned and practiced on dead animals. Here we have used three-dimensional (3D) printing technologies to create rat and mouse skin-skull-brain models, specifically conceived for rodent stereotaxic surgery training. We used 3D models obtained from microCT pictures and printed them using materials that would provide the most accurate haptic feedback for each model—PC-ABS material for the rat and Durable resin for the mouse. We filled the skulls with Polyurethane expanding foam to mimic the brain. In order to simulate rodent skin, we added a rectangular 1mm thick clear silicone sheet on the skull. Ten qualified rodent neurosurgeons then performed a variety of stereotaxic surgeries on these rat and mouse 3D printed models. Participants evaluated models fidelity compared to cadaveric skulls and their appropriateness for educational use. The 3D printed rat and mouse skin-skull-brain models received an overwhelmingly positive response. They were perceived as very realistic, and considered an excellent alternative to cadaveric skulls for training purposes. They can be made rapidly and at low cost. Our real-size 3D printed replicas could enable cost- and time-efficient, animal-free neurosurgery training. They can be absolute replacements for stereotaxic surgery techniques practice including but not limited to craniotomies, screw placement, brain injections, implantations and cement applications. This project is a significant step forward in implementing the replacement, reduction, and refinement (3Rs) principles to animal experimentation. These 3D printed models could lead the way to the complete replacement of live animals for stereotaxic surgery training in laboratories and veterinary studies.

Effects of sodium gluconate on hydration reaction, setting, workability, and strength development of calcium sulfoaluminate belite cement mixtures

Fast setting is an important reason restricting the applications of eco-friendly calcium sulfoaluminate belite (CSAB) cement. To help spread the application of CSAB cement, this study investigated the influence of sodium gluconate (SG) as a setting retarder on the setting, workability, and strength development of CSAB cement mixtures. Quantitative X-ray diffraction (QXRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) were performed to understand the effects of SG on the hydration and microstructure of CSAB cement mixtures. The results showed that SG effectively extended the setting time and improved the workability of CSAB cement pastes since it retarded ye’elimite hydration and impeded the loss of workability caused by ettringite formation. Low dosages (≤0.5%) of SG increased the unconfined compressive strength (UCS) of CSAB cement mortars at all ages (from 2 h to 90 days) due to the reduction in void content, fast diminishment of the retarding effect at early ages, and slight acceleration on belite hydration at later ages. However, high dosages (≥1%) significantly degraded the UCS of CSAB cement mortars at all ages since high dosages of SG strongly retarded ye’elimite hydration at early ages and caused a looser microstructure at later ages.

Cleaning Zirconia Surface Prior To Bonding: A Comparative Study of Different Methods and Solutions

To evaluate resin cement bond strength after removal of salivary contamination from a zirconia surface using different cleaning solutions and air-borne particle abrasion. One-hundred and twenty zirconia specimens (KATANA STML, Noritake) were prepared and divided into 12 groups (n = 10). Groups were subjected to a notched-edge shear bond strength test (ISO 29022) to analyze the bonding efficiency of a resin cement (Panavia V5, Kuraray Noritake Dental Inc.) before and after contamination with saliva. Group 1 (control) was prepared and cemented without salivary contamination. Group 2 was coated with ceramic primer (Clearfil Ceramic Primer Plus, Kuraray Noritake Dental Inc.) then subjected to salivary contamination then tested. Group 3 was contaminated, cleaned by air-borne particle abrasion, ceramic primer and resin cement applied, and tested. Groups 4 to 12 were contaminated, and then different cleaning solutions (water, 4.5% hydrofluoric acid, 35% phosphoric acid, Ivoclean, KATANA cleaner, Zirclean, sodium hypochlorite 4%, and 7.5%) were used to decontaminate the zirconia surface, followed by ceramic primer, resin cement application, and tested.One-way ANOVA and Tukey post-hoc analysis was used to analyze the data. One-way ANOVA showed statistical differences among cleaning procedures (p < 0.001, F = 13.48). Air-borne particle abrasion was the only group which provided a bond strength (21 ± 2.8 MPa) that was not statistically different than the control group in which no contamination occurred (25.3 ± 3.3 MPa) (p = 0.247). The use of hydrofluoric acid and zirconia cleaning solutions resulted in bond strengths values which were not statistically different from each other (17.5-19.1 MPa). Air-borne particle, zirconia cleaning solutions and hydrofluoric acid are feasible to decontaminate the zirconia surface from saliva prior to bonding the restoration.

Hydration and improved properties of magnesium oxysulfate cement modified by phosphoric acid

Magnesium oxysulfate (MOS) cement is often seen as a ‘green engineering material in the twenty-first century’. However, low mechanical strength is one of the major drawbacks for large-scale applications of MOS cement. In this paper, MOS cement with desirable strength was prepared by adding phosphoric acid. The effects of phosphoric acid on the hydration process, hydration products and microstructure of MOS cement were studied in detail using isothermal calorimetry, X-ray diffraction, Fourier transform infrared spectrometry, mercury intrusion porosimetry and scanning electron microscopy. It was found that the incorporation of phosphoric acid could retard the hydration process and increase the setting time of MOS cement. Furthermore, the incorporation of phosphoric acid was shown to increase the compressive strength through its effect in promoting the formation of 5Mg(OH)2·MgSO4·7H2O. The space-filling properties and directional growth characteristics of 5Mg(OH)2·MgSO4·7H2O contributed to a more compact and uniform microstructure of the MOS cement formed.