Superlattice ferroelectric-metal field-effect transistor (SL-FeMFET) based three-dimensional NAND architecture (3D NAND) is investigated for triple-level cell (TLC) operations. The SL-FeMFET shows a novel approach for designing the gate-stack using a superlattice of ferroelectric/dielectric/ferroelectric for achieving large memory window ∼3.48 V with program/erase voltage ±7 V for 3D NAND architecture. By TCAD modeling, we demonstrate TLC operation of SL-FeMFET with improving memory window and alleviating variability caused by floating metal layer in FeMFET structure. In addition, as the vertical gate stack increases from 256-layer to 512-layer, the read-out current with worst cases in seven read operations for TLC sensing are examined using page buffer circuit for sensing operation. The simulation results suggest that SL-FeMFET based 3D NAND architecture can operate 512-layer with sufficient sense margin for TLC operation.