Brilliant Green Dye Research Articles

Process optimization of adsorptive phytoremediation of mutagenic brilliant green dye for health risk management using chemically activated Symplocos racemosa agro-waste

Textile industries use large amounts of water as well as dyes. These dyes containing water are then discharged into the water bodies causing a significant role in water pollution. Brilliant Green dye contributes to many harmful diseases related to the respiratory and gastrointestinal tract. In this study, Symplocos racemosa (SR) agro-waste was chemically treated with acid (SR-HCl) and base (SR-NaOH) and then used for removing Brilliant Green Dye (BGD) on the batch scale. They were characterized by SEM, EDX, FTIR, XRD, TGA and DSC. Optimized conditions were 30 °C temperature, pH 6, adsorbent dose of 0.10 g/25 ml dye solution, shaking speed of 100 revolutions per minute, initial dye concentration of 50 ppm and 35 min time for shaking adsorbent and dye solution. Adsorption data obtained were analyzed using isotherms. The experimental data was found to fit well with the Langmuir model and the maximum adsorption capacity (qmax) of BGD on the SR, SR-HCl, and SR-NaOH was revealed to be 62.90, 65.40, and 71 mg/g respectively. Kinetic data (pseudo-first-order and pseudo-second-order) were evaluated and adsorption tends to follow the pseudo-2nd-order, which indicated the chemisorption mechanism. The results revealed that Symplocos racemosa agro-waste can be considered as the potential biosorbent.

3D kaolinite/g-C3N4-alginate beads as an affordable and sustainable photocatalyst for wastewater remediation

Graphitic carbon nitride (GCN) is an efficient visible-light-driven metal-free semiconductor with superior photocatalytic activity. However, the main drawbacks of GCN include lower adsorption capacity, poor reusability and recoverability. To address these drawbacks, kaolinite/g-C3N4-alginate beads were fabricated using a cross-linking method to remove brilliant green dye from wastewater via photocatalysis. The characterization studies proved the alginate's potential capability in altering photocatalyst bandgap (2.78 to 2.55 eV) and minimizing recombination of electron-hole pairs. Kaolinite/g-C3N4-alginate photocatalyst removed 97 % of brilliant green (10 mg/L) in 90 min under visible light irradiation. The superior performance of the kaolinite/g-C3N4-alginate beads was ascribed to its improved adsorption and effective utilization of visible light. The key advantages of kaolinite/g-C3N4-alginate beads were their quick recovery and extended reusability upto ten cycles. The sustainability metrics analysis of kaolinite/g-C3N4-alginate beads confirmed the environmental suitability and practicability in wastewater remediation. This study provides new insights into the low-cost and sustainable preparation of highly reusable g-C3N4-based photocatalysts for environmental remediation.

Development of lattice defects and oxygen vacancies in Zn-doped CdAl2O4 nanoparticles for improving the photocatalytic efficiencies of brilliant green and brilliant blue dyes under visible illumination

In this research, a novel spinel architecture of pure CdAl2O4 and Zn (0.025–0.075 M) doped CdAl2O4 nanoparticles were synthesized. The PL and ESR outcomes shows that the Zn doping played an effective role to prevent the e−-h+ pairs recombination in CdAl2O4 during photocatalysis. Zn (0.075 M)-CdAl2O4 provided the maximum photodegradation efficiencies for BB and BG with a removal efficiency of 91 and 96% in just 90 min as compared to other samples and remain stable after the fifth cycle. Such outcomes pave the approach for sustainable photocatalytic technologies to diminish the global influence of organic and inorganic dyes.

Design and function of lignin/silk fibroin-based multilayer water purification membranes for dye adsorption

The treatment of dye wastewater poses a significant challenge to the sewage recycling industries. However, the reduction of secondary pollution resulting from the membrane residues, to maintain high performance, remains a considerable obstacle. A novel approach for the fabrication of multilayer nanofiber structures using a layer-by-layer electrostatic spinning technique with biological materials was reported in this study. Incorporating the chemical adsorption advantages of lignin nanofiber and the physical adsorption advantages of silk fibroin (SF) nanofiber enabled the full realization of excellent dye interception performance. A comparative analysis was conducted on the lignin derived from eucalyptus, pine, and straw to determine the most suitable option. Notably, eucalyptus lignin exhibited superior antimicrobial properties. The adsorption of crystal violet by eucalyptus lignin/SF membrane was consistent with the Freundlich isotherm model and the pseudo-second-order kinetic model, revealing a chemisorption mechanism involving Π-Π conjugation, hydrogen bonding, and the binding of anions and cations. The lignin/SF membrane exhibited a retention rate exceeding 99.5 % for crystal violet, methylene blue, and brilliant green dyes. Furthermore, it demonstrated efficacy in retaining heavy metal ions, including cadmium and copper. The original biomass material imparts the property of rapid degradation to a multilayer membrane that can be used as an effective and eco-friendly water purification material.

Development and Characterization of a Molecularly Imprinted Polymer for the Selective Removal of Brilliant Green Textile Dye from River and Textile Industry Effluents.

In this paper, we present an alternative technique for the removal of Brilliant Green dye (BG) in aqueous solutions based on the application of molecularly imprinted polymer (MIP) as a selective adsorbent for BG. The MIP was prepared by bulk radical polymerization using BG as the template; methacrylic acid (MAA) as the functional monomer, selected via computer simulations; ethylene glycol dimethacrylate (EGDMA) as cross-linker; and 2,2'-azobis(2-methylpropionitrile) (AIBN) as the radical initiator. Scanning electron microscopy (SEM) analyses of the MIP and non-molecularly imprinted polymer (NIP)-used as the control material-showed that the two polymers exhibited similar morphology in terms of shape and size; however, N2 sorption studies showed that the MIP displayed a much higher BET surface (three times bigger) compared to the NIP, which is clearly indicative of the adequate formation of porosity in the former. The data obtained from FTIR analysis indicated the successful formation of imprinted polymer based on the experimental procedure applied. Kinetic adsorption studies revealed that the data fitted quite well with a pseudo-second order kinetic model. The BG adsorption isotherm was effectively described by the Langmuir isotherm model. The proposed MIP exhibited high selectivity toward BG in the presence of other interfering dyes due to the presence of specific recognition sites (IF = 2.53) on its high specific surface area (112 m2/g). The imprinted polymer also displayed a great potential when applied for the selective removal of BG in real river water samples, with recovery ranging from 99 to 101%.

Activated carbon from noodles food waste via microwave-assisted KOH for optimized brilliant green dye removal

Activated carbon from noodles food waste via microwave-assisted KOH for optimized brilliant green dye removal

Hydroxyapatite nanoparticles decorated with metal–organic framework, Co‐Cu/ZIF@HAp, and evaluation of photocatalytic performance of the prepared nanocomposite in the degradation of organic pollutants

In this study, a novel hydroxyapatite (HAp)‐based composite, Co‐Cu/ZIF@HAp, was constructed through in situ growth and simultaneous sonication followed by magnetic string. Herein, the HAp‐based nanocomposite was obtained in which HAp was coated with cobalt–copper bimetallic zeolitic imidazolate framework (ZIF) in one‐pot synthesis method. The as‐synthesized composite was characterized by PXRD, FTIR, FE‐SEM, EDS, HR‐TEM, TGA‐DTG, XPS, BET, and UV‐DRS techniques, which suggested that HAp was well coated with bimetallic ZIF. The prepared composite was utilized as a catalyst in degradation of organic pollutants. Removal of organic pollutants such as organic dyes has become indispensable due to their higher stability, toxicity, and mutagenic nature. Two commonly found organic dyes, namely, Eosin Yellow (EY) and Brilliant Green (BG), were chosen for the investigation of photocatalytic activity of the as‐prepared catalyst. The degradation process was carried out under solar radiation, and there was no utilization of any oxidizing and reducing agent. Several parameters such as amount of catalyst dose, initial concentration of the dye solution, and effect of different pH conditions were evaluated for better understanding of photocatalytic performance of Co‐Cu/ZIF@HAp composite. Both EY and BG dyes were almost degraded up to 98.3% and 99.5%, respectively, within 50 min by the as‐prepared nanocomposite. Also, quenching test was performed that confirmed the formation of superoxide radicals (O2−.) as reactive oxygen species (ROS) in the photodegradation process. The as‐synthesized catalyst was repeatedly used for five times to ascertain the stability and reusability of catalyst.

Physiochemical analysis of clay and polyoxometallate composite used for sorptive detoxification of mutagenic Brilliant Green dye

Water pollution is a grave risk to mankind. Water pollutants including organic toxins, dyes effluents, and heavy metals have posed great stress on water quality in recent years. This has necessitated the search for an affordable, eco-friendly, inexpensive, stable, and effective strategy for wastewater remediation. In this work, a pollyoxometallate K6[H2AlBW11O40].9H2O (KAB) was impregnated on kaolin clay to synthesize a clay-based nanocomposite KAB-K which was then evaluated for adsorptive removal of brilliant green dye (BG) from wastewater. The prepared composite was characterized by different techniques such as FTIR, SEM, and EDX analysis. The characterization results indicated the fine distribution of KAB on kaolin’s surface. The adsorption studies of BG involved evaluation of optimum parameters such as time contact (30 min), quantity of adsorbent (20 mg), pH (5), temperature (40 °C), and agitation speed (125 rpm). 99.5% of BG was removed by KAB-K within 30 min. The assessment of kinetic data was performed via Langmuir, Freundlich, and Temkin models. The experimental data was found to be in good agreement with the Langmuir model (R2 > 0.9965) as compared to other models. Qmax value of KAB-K (144.92 ± 0.005 mg/g) was much higher than simple kaolin (33.22 ± 0.01 mg/g). The applicability of the pseudo-second-order kinetic model suggested that the process was predominately chemisorption. KAB-K was easier to recycle and efficiently removed up to 68.7% dye in 3 subsequent cycles. Thus rapid adsorption rate, high adsorption capacity, efficient recovery, and reusability of KAB-K endorses that the synthesized composite is an effective adsorbent for wastewater pollutants.

Experimental and theoretical study on the photocatalytic degradation of brilliant green dye by N-doped Zn2GeO4

In this study, experimental and theoretical insights on the photocatalytic degradation of BG in an N-doped Zn2GeO4/UV irradiation system were explored. Kinetic experiments, degradation mechanisms analysis, and toxicity evaluation of intermediates were involved. The catalytic performance of N-doped Zn2GeO4 was optimum when the molar ratio of CO(NH2)2 and GeO2 is 1: 1. BG was almost 100% degraded within 10 min. Catalyst dosage and initial concentration had effects on the photodegradation of BG. Materials Studio calculations indicated that the nitrogen atoms are interstitially doped into Zn2GeO4 in the form of Zn–N–Ge. The N 2 s orbital contributes more than the N 2p orbital to the PDOS of N-doped Zn2GeO4, suggesting the difficult recombination of e- and h+. According to mass spectrometry analysis, de-ethylation, hydroxylation, condensation, carboxylation, and ring-opening were the main photocatalytic degradation pathways of BG. ∙OHs and O2∙-s played important roles in the Hg lamp/N-doped Zn2GeO4 reaction system, while h+ was existed in this system using quenching experiments. The 2FED2HOMO and (FED2HOMO + FED2LUMO) values implied the locations vulnerable to attack by free radicals of BG, which validated the reasonableness of the LC-MS/MS analysis result. Toxicity evaluations by the ECOSAR program suggested that photocatalytic degradation can exacerbate the aquatic toxicity of BG in the initial stage.

Synthesis of new alginate-silver nanoparticles/mica (Alg-AgNPs/MC) bionanocomposite for enhanced adsorption of dyes from aqueous solution

Wastewater treatment is of utmost importance in providing equitable and safe drinking water to all. In that bid, herein, a novel and potential Alginate-Silver nanoparticle/Mica (Alg-AgNPs/MC) bio-nanocomposite has been synthesized by the green method. The synthesized nanocomposite was further harnessed for the removal of methylene blue (MB) and brilliant green (BG) dyes from an aqueous solution for the first time and has not been reported in literature till now. The Alg-AgNPs/MC bionanocomposite was thoroughly characterized through FTIR, SEM-EDX, TEM, XRD, and TGA/DTA analysis. Moreover, Alg-AgNPs/MC bionanocomposite was further employed to remove both dyes from the aqueous solution in batch mode. The Alg-AgNPs/MC bionanocomposite could remove 99.07% of MB and 91.53% of BG at an initial concentration of (20 mg L−1), adsorbent dosage (0.01 g), time (180 min), pH-8 for MB dye and pH-9 for BG. The Alg-AgNPs/MC bionanocomposite achieved maximum adsorption capacities of 352 and 249 mg g−1 for BG and MB dyes, respectively. The equilibrium adsorption data for both dyes were best fitted to the Freundlich model with R2, 0.9945 and 0.9799 for BG and MB dyes, respectively. The adsorption dynamics were best followed by a pseudo second order kinetic model for both dyes. The positive value of thermodynamic parameter ΔH indicates the process to endothermic and spontaneous in nature. The exhausted Alg-AgNPs/MC bionanocomposite can be regenerated up to the 4th cycle successfully.

Polyaniline‐Coated Magnesium Ferrite Nanocomposite: Synthesis, Characterization, Fabrication Cost Analysis and Dye Sorption Behavior with Scale‐Up Design

AbstractIn this research, polyaniline‐based magnesium ferrite nanocomposite (Pan−MgF−NC) was synthesized for the sequestration of cationic brilliant green (BG) dye. The Pan−MgF−NC revealed surface area of 56.19 m2/g and pore volume of 0.056 cc/g, with 20 to 40 nm of pore diameter. The impact of numerous parameters namely, solution pH, sorbent dose, dye initial concentration, and sonication time were explored and maximum dye abatement (90.28 %) was detected at solution pH of 8.0. The dominant mechanisms for the sequestration of BG onto Pan−MgF−NC were π‐π interactions, H‐bonding, and electrostatic attraction. The sorption kinetics of experimental data well fitted to pseudo second order analysis and Langmuir isotherm was the most consistent isotherm model with maximum uptake capability of 294.12 mg/g. Response surface methodology (RSM) was exhibited that the experimental BG removal (88.70 %) and model assimilated BG removal (89.13 %) are close to each other. Investigation related to scale‐up design also studied for large volume of industrial effluent. The laboratory scale fabrication cost of Pan−MgF−NC was found to be ∼85.00 USD/kg. The BG elimination efficacy with Pan−MgF−NC decreases from 90.13 % to 81.93 % after the fifth cycle, demonstrating the strong stability and reusability of Pan−MgF−NC.

Eco-Friendly Synthesis of Copper Nanoparticles from Fiber of Trapa natans L. Shells and Their Impregnation Onto Polyamide-12 for Environmental Applications

ABSTRACT In this study, copper nanoparticles were synthesized from Trapa natans L. shells and loaded within polyamide-12 for use as an adsorbent. The synthesized nanocomposite was used for the first time to remove toxic methyl orange and brilliant green dye molecules from synthetic aqueous solutions. In order to characterize the plant-based nanocomposite, its functional groups, surface texture, elemental composition, structure, surface area, and crystallinity were determined. Adsorption efficiency was found to be affected by factors like pH (2–10), time (5–240 min.), and temperature (288–308 K). It was at pH 6 that the adsorbent reached the point of zero charge. During the adsorption process, electrostatic attraction played an influential role. Adsorption isotherms and kinetics data were well-fitted by Langmuir isotherms and pseudo-second-order models, respectively. A maximum adsorption capacity of 166.60 mg/gm was calculated for 93.90% methyl orange removal and 55.24 mg/gm for 97.30% brilliant green removal. The adsorption process was endothermic, spontaneous, and physical. The rapid desorption of dye molecules confirms the potential, and practicality of the nanocomposite as a promising adsorbent for decolorizing colored wastewater on an industrial scale.

Effective removal of dyes along with binary mixture via optimized emulsion liquid membrane

This study aimed to evaluate the removal of harmful cationic dyes, namely brilliant green and safranin-O, from wastewater produced by industries like textile, pigment, and pharmaceutical, which pose a direct threat to human health and the environment. An emulsion liquid membrane (ELM) was employed to eliminate these dyes, and the efficiency of the membrane was measured by calculating the percentage of dye removal and the breaking rate. The study successfully optimized the ELM process to remove the dyes within an hour and demonstrated the membrane’s stability for more than 60 minutes. The results showed that the prepared ELM could remove 100% of the brilliant green dye and 99.6% of the safranin-O dye. A maximum breaking rate of 0.029% was obtained for brilliant green and 0.008% for safranin-O. Furthermore, the study resulted in the maximum removal of 99.36% and 99.15% for brilliant green and safranin-O dyes, respectively, in the binary system. When both dyes were present simultaneously, the maximum breakage observed was only 0.16%. The experimental results were analyzed using a UV–visible spectrophotometer and an optical microscope, and the optimization and analysis of the variance of means and signal-to-noise (S/N) ratio were carried out using the Taguchi L16 orthogonal array.

Adsorption of Brilliant Green Dye onto a Mercerized Biosorbent: Kinetic, Thermodynamic, and Molecular Docking Studies.

This study reports the valorization of pistachio shell agricultural waste, aiming to develop an eco-friendly and cost-effective biosorbent for cationic brilliant green (BG) dye adsorption from aqueous media. Pistachio shells were mercerized in an alkaline environment, resulting in the treated adsorbent (PSNaOH). The morphological and structural features of the adsorbent were analyzed using scanning electron microscopy, Fourier transform infrared spectroscopy, and polarized light microscopy. The pseudo-first-order (PFO) kinetic model best described the adsorption kinetics of the BG cationic dye onto PSNaOH biosorbents. In turn, the equilibrium data were best fitted to the Sips isotherm model. The maximum adsorption capacity decreased with temperature (from 52.42 mg/g at 300 K to 46.42 mg/g at 330 K). The isotherm parameters indicated improved affinity between the biosorbent surface and BG molecules at lower temperatures (300 K). The thermodynamic parameters estimated on the basis of the two approaches indicated a spontaneous (ΔG < 0) and exothermic (ΔH < 0) adsorption process. The design of experiments (DoE) and the response surface methodology (RSM) were employed to establish optimal conditions (sorbent dose (SD) = 4.0 g/L and initial concentration (C0) = 10.1 mg/L), yielding removal efficiency of 98.78%. Molecular docking simulations were performed to disclose the intermolecular interactions between the BG dye and lignocellulose-based adsorbent.

High-efficient and rapid removal of anionic and cationic dyes using a facile synthesized sole adsorbent NiAlFe-layered triple hydroxide (LTH)

It would be extremely momentous to familiarize a low-cost sole adsorbent NiAlFe-layered triple hydroxides (LTHs) having a strong sorption affinity towards both anionic and cationic dyes. Using the urea hydrolysis hydrothermal method LTHs were fabricated and by altering the ratio of participant metal cations the adsorbent was optimized. BET analysis revealed that the optimized LTHs possess an elevated surface area (160.04 m2/g) while TEM and FESEM analysis portrayed the stacked sheets-like 2D morphology. LTHs were employed for the amputation of anionic congo red (CR) and cationic brilliant green (BG) dye. The adsorption study showed that within 20 and 60 min, respectively, maximum adsorption capacities were achieved at 57.47 mg/g and 192.30 mg/g for CR and BG dye. Adsorption isotherm, kinetics, and thermodynamics study revealed that both chemisorptions with physisorptions were the assertive factor for the dye encapsulation. This enhanced adsorption performance of the optimized LTH for the anionic dye is attributed to its inherent anions exchange properties and new bond formation with the adsorbent skeleton. Whereas for the cationic dye, it was because of the formation of strong hydrogen bonds, and electrostatic interaction. Morphological manipulation of LTHs, formulates the optimized adsorbent LTH111, provokes the adsorbent for this elevated adsorption performance. Overall, this study revealed that LTHs have a high potential for the effectual remediation of dyes from wastewater as a sole adsorbent at a low cost.

Titania/reduced graphene oxide nanocomposites (TiO2/rGO) as an efficient photocatalyst for the effective degradation of brilliant green in aqueous media: effect of peroxymonosulfate and operational parameters.

This study is focused on synthesis of highly efficient Titania/reduced Graphene Oxide (TiO2/rGO) nanocomposites by means of simple hydrothermal technique. The TiO2/rGO were synthesized in different ratios of 0.5, 1.0, 2.0, and 3% by varying the concentration of rGO while the concentration of TiO2 was kept constant and the obtained samples were designated as TrG0.5, TrG1, TrG2, and TrG3 respectively. Different characterization techniques (SEM, TEM, HRTEM, XRD, EDX, TGA, UV-DRS, PL, EIS, and BET) showed high crystallinity, small crystallite size (18.4 nm), high thermal stability, high purity, low band gap energy (Eg = 3.12 eV), and high surface area (65.989 m2/g) for the as-synthesized TiO2/rGO nanocomposite. The efficiencies of TiO2/rGO were determined in terms of brilliant green (BG) dye degradation in aqueous media under UV light. The results revealed that 2% TiO2/rGO (TrG2) showed high efficiency for BG degradation with the kapp of 0.023 min-1 compared to TiO2 alone (kapp of 0.006 min-1). The rate of BG degradation was further synergised by the addition of peroxymonosulfate (PMS) to the system. The degradation of BG was improved to 99.4% by the incorporation of PMS in aqueous media compared to TrG2 alone. Furthermore, the degradation of BG was also examined in various media (neutral, acidic, and basic). The results revealed that by increasing pH of the medium from 3.85 to 8.2 the degradation of BG was enhanced from 99.4 to 99.9% with the corresponding kapp of 0.0602 min-1. Moreover, the photocatalytic degradation of BG followed the pseudo-first-order kinetics. Radical scavenging experiments showed that ●OH and SO4●- were the main species responsible for the degradation of BG under UV light. Besides, for determining the efficiency of as-synthesized TrG2/PMS system, the degradation of BG was also performed in various water types (distilled water, tape water, synthetic wastewater, and industrial wastewater). The degradation products (DPs) of BG and their corresponding pathways were proposed, accordingly.

Assessment of biodegradation kinetics and mass transfer aspects in attached growth bioreactor for effective treatment of brilliant green dye from wastewater

In this study, Bacillus licheniformis immobilized with low-density polyethylene (LDPE) was employed to degrade Brilliant Green (BG) dye from wastewater in a packed bed bioreactor (PBBR). Bacterial growth and extracellular polymeric substance (EPS) secretion were also assessed under different concentrations of BG dye. The impacts of external mass transfer resistance on BG biodegradation were also evaluated at different flow rates (0.3–1.2 L/h). A new mass transfer correlation JD=5.71NRe-0.3 was proposed to study the mass transfer aspects in attached-growth bioreactor. The intermediates, namely 3- dimethylamino phenol, benzoic acid, 1–4 benzenediol, and acetaldehyde were identified during the biodegradation of BG and, subsequently degradation pathway was proposed. Han - Levenspiel kinetics parameters μmax and Ks were found to be 0.185 per day and 115 mg/L, respectively. The new insight into mass transfer and kinetics support the design of efficiently attached growth bioreactor to treat a wide range of pollutants.

Extractive Cloud Point Spectrophotometric Determination of Mesalazine Using Brilliant Green Dye

Extractive Cloud Point Spectrophotometric Determination of Mesalazine Using Brilliant Green Dye

Extractive Cloud Point Spectrophotometric Determination of Mesalazine Using Brilliant Green Dye

Extractive Cloud Point Spectrophotometric Determination of Mesalazine Using Brilliant Green Dye

Kinetics of simultaneous degradation of brilliant green and methyl orange using biosynthesized high functional Ag nanoparticles

Abstract Nanoparticles synthesised using natural resources is a cost-effective and ecofriendly technique with a number of advantages. In current work, silver nanoparticles (AgNPs) have been synthesized using the extract of Fragaria ananassa seeds. The extract was used as a source of phytochemicals that can act as reducing and stabilizing agents. The characteristics of AgNPs were determined by UV/Visible, FTIR, SEM, XRD and Dynamic light scattering (DLS) techniques. The appearance of the distinctive absorption peak in UV-visible spectra at 430 nm confirmed the formation of AgNPs. The involvement of different bioactive functional groups with AgNPs was authenticated by FTIR studies. Particle size and morphology was confirmed by DLS, SEM and XRD analysis. The catalytic potential of AgNPs for the removal of poisonous organic dyes, brilliant green (BG) and methyl orange (MO) was also tested. Effect of different parameters including the catalyst concentration, dyes concentration and presence of different salts on the degradation of dyes was investigated. Nano-size and well-distributed nature of AgNPs, BG and MO dyes were degraded rapidly individually as well as simultaneously. The degradation process obeyed pseudo first order kinetics. Authors concluded that AgNPs synthesized using environment friendly and cost-effective method, can be used as a new tool to combat pollution caused by carcinogenic organic dyes.