The characteristics and the phase composition of high velocity oxy fuel (HVOF) sprayed WC–Co and Cr 3C 2–NiCr coatings applied onto boiler tube steel substrates using liquid petroleum gas (LPG) as the fuel gas, have been evaluated. The coatings were examined using metallography, SEM/EDAX and XRD techniques. An attempt has been made to describe the transformations that take place during HVOF spraying. The purpose of this study was to compare the microstructure, porosity, surface roughness and microhardness of HVOF sprayed WC–Co, Cr 3C 2–NiCr coatings deposited on boiler steels. The paper will also investigate if there is an application of the deposit in energy generation plants with a view to enhance the life of the component and reduce tube failures in such power plants.