The temperature dependences of emission characteristics are investigated for laser diodes based on asymmetric separate-confinement heterostructures with a broadened waveguide. It is established that an increase in the charge-carrier concentration in the waveguide layer is the basic mechanism of saturation in the light-current characteristic with increasing temperature in the CW mode. It is experimentally shown that the temperature delocalization of charge carriers leads to increasing internal optical losses and decreasing external differential quantum efficiency. It is shown that the degree of delocalization of charge carriers depends on the charge-carrier temperature distribution, the threshold concentration, and the quantum-well depth. The effect of thickness and energy depth of the quantum well on the temperature sensitivity of the threshold current and output optical power is considered.