Array Of Atoms Research Articles

Quantum Slush State in Rydberg Atom Arrays.

In this Letter, we propose an exotic quantum state that does not order at zero temperature in a Rydberg atom array with antiblockade mechanism. By performing an unbiased large-scale quantum MonteCarlo simulation, we investigate a minimal model with facilitated excitation in a disorder-free system. At zero temperature, this model exhibits a heterogeneous structure of liquid and glass mixture. This state, dubbed quantum slush state, features a quasi-long-range order with an algebraic decay for its correlation function, and is different from most well-established quantum phases of matter.

Theory of cascade correlated emission from atom arrays

Theory of cascade correlated emission from atom arrays

On the structure factor of jammed particle configurations on the one-dimensional lattice

A broad class of blocked or jammed configurations of particles on the one-dimensional lattice can be characterized in terms of local rules involving only the lengths of clusters of particles (occupied sites) and of holes (empty sites). Examples of physical relevance include the metastable states reached by the zero-temperature dynamics of kinetically constrained spin chains, the attractors of totally irreversible processes such as random sequential adsorption, and arrays of Rydberg atoms in the blockade regime. The configurational entropy of ensembles of such blocked configurations has been investigated recently by means of an approach inspired from the theory of stochastic renewal processes. This approach provides a valuable alternative to the more traditional transfer-matrix formalism. We show that the renewal approach is also an efficient tool to investigate a range of observables in uniform ensembles of blocked configurations, besides their configurational entropy. The main emphasis is on their structure factor and correlation function.

Variational manifolds for ground states and scarred dynamics of blockade-constrained spin models on two- and three-dimensional lattices

We introduce a variational manifold of simple tensor network states for the study of a family of constrained models that describe spin-12 systems as realized by Rydberg atom arrays. Our manifold permits analytical calculation via perturbative expansion of one- and two-point functions in arbitrary spatial dimensions and allows for efficient computation of the matrix elements required for variational energy minimization and variational time evolution in up to three dimensions. We apply this framework to the PXP model on the hypercubic lattice in one, two, and three dimensions and show that, in each case, it exhibits quantum phase transitions breaking the sublattice symmetry in equilibrium, and hosts quantum many-body scars out of equilibrium. We demonstrate that our variational ansatz qualitatively captures all these phenomena and predicts key quantities with an accuracy that increases with the dimensionality of the lattice, and conclude that our method can be interpreted as a generalization of mean-field theory to constrained spin models. Published by the American Physical Society 2024

Universal Approach for Quantum Interfaces with Atomic Arrays

We develop a general framework for the analysis of two-sided quantum interfaces, composed of collections of atoms interacting with paraxial light. Accounting for photon-mediated dipole-dipole interactions, our approach is based on the mapping of collective atom-photon interfaces onto a generic one-dimensional model of light scattering, characterized by a reflectivity parameter r0. This entails two key practical advantages: (i) the efficiency of the quantum interface in performing various quantum tasks, such as quantum memory or entanglement generation, is universally given by r0 and is hence reduced to a measurement or classical calculation of a reflectivity; (ii) the efficiency can be greatly enhanced by a properly designed photon mode that spatially matches a collective-dipole eigenmode of the atoms. We demonstrate our approach for realistic cases of finite-size atomic arrays, partially filled arrays, and circular arrays. This provides a unified approach for treating collective light-matter coupling in various platforms, such as optical lattices and optical tweezers. Published by the American Physical Society 2024

Oxygen Radical Coupling on Short-Range Ordered Ru Atom Arrays Enables Exceptional Activity and Stability for Acidic Water Oxidation.

The discovery of efficient and stable electrocatalysts for oxygen evolution reaction (OER) in acid is vital for the commercialization of the proton-exchange membrane water electrolyzer. In this work, we demonstrate that short-range Ru atom arrays with near-ideal Ru-Ru interatomic distances and a unique Ru-O hybridization state can trigger direct O*-O* radical coupling to form an intermediate O*-O*-Ru configuration during acidic OER without generating OOH* species. Further, the Ru atom arrays suppress the participation of lattice oxygen in the OER and the dissolution of active Ru. Benefiting from these advantages, the as-designed Ru array-Co3O4 electrocatalyst breaks the activity/stability trade-off that plagues RuO2-based electrocatalysts, delivering an excellent OER overpotential of only 160 mV at 10 mA cm-2 in 0.5 M H2SO4 and outstanding durability during 1500 h operation, representing one of the best acid-stable OER electrocatalysts reported to date. 18O-labeled operando spectroscopic measurements together with theoretical investigations revealed that the short-range Ru atom arrays switched on an oxide path mechanism (OPM) during the OER. Our work not only guides the design of improved acidic OER catalysts but also encourages the pursuit of short-range metal atom array-based electrocatalysts for other electrocatalytic reactions.

Integrated molybdenum single atom array sensors with multichannels for nitrite detection in foods

Nitrite (NO2−) is present in a variety of foods, but the excessive intake of NO2− can indirectly lead to carcinogenic, teratogenic, mutagenicity and other risks to the human body. Therefore, the detection of NO2− is crucial for maintaining human health. In this study, an integrated array sensor for NO2− detection is developed based on molybdenum single atom material (IMSMo-SAC) using high-resolution electrohydrodynamic (EHD) printing technology. The sensor comprises three components: a printed electrode array, multichannels designed on polydimethylsiloxane (PDMS) and an electronic signal process device with bluetooth. By utilizing Mo-SAC to facilitate electron transfer during the redox reaction, rapid and efficient detection of NO2− can be achieved. The sensor has a wide linear range of 0.1 μM–107.8 mM, a low detection limit of 33 nM and a high sensitivity of 0.637 mA−1mM−1 cm−2. Furthermore, employing this portable array sensor allows simultaneously measurements of NO2− concentrations in six different foods samples with acceptable recovery rates. This array sensor holds great potential for detecting of small molecules in various fields.

A Strontium Quantum-Gas Microscope

The development of quantum-gas microscopes has brought novel ways of probing quantum degenerate many-body systems at the single-atom level. Until now, most of these setups have focused on alkali atoms. Expanding quantum-gas microscopy to alkaline-earth elements will provide new tools, such as SU(N)-symmetric fermionic isotopes or ultranarrow optical transitions, to the field of quantum simulation. Here we demonstrate the site-resolved imaging of a 84Sr bosonic quantum gas in a Hubbard-regime optical lattice. The quantum gas is confined by a two-dimensional in-plane lattice and a light-sheet potential, which operate at the strontium clock-magic wavelength of 813.4 nm. We realize fluorescence imaging using the broad 461-nm transition, which provides high spatial resolution. Simultaneously, we perform attractive Sisyphus cooling with the narrow 689-nm intercombination line. We reconstruct the atomic occupation from the fluorescence images, obtaining imaging fidelities above 94%. Finally, we realize a 84Sr superfluid in the Bose-Hubbard regime. We observe its interference pattern upon expansion, a probe of phase coherence, with single-atom resolution. Our strontium quantum-gas microscope provides a new platform to study dissipative Hubbard models, quantum optics in atomic arrays, and SU(N) fermions at the microscopic level. Published by the American Physical Society 2024

Strongly Interacting Photons in 2D Waveguide QED.

One-dimensional confinement in waveguide quantum electrodynamics (QED) plays a crucial role to enhance light-matter interactions and to induce a strong quantum nonlinear optical response. In two or higher-dimensional settings, this response is reduced since photons can be emitted within a larger phase space, opening the question whether strong photon-photon interaction can be still achieved. In this study, we positively answer this question for the case of a 2D square array of atoms coupled to the light confined into a two-dimensional waveguide. More specifically, we demonstrate the occurrence of long-lived two-photon repulsive and bound states with genuine 2D features. Furthermore, we observe signatures of these effects also in free-space atomic arrays in the form of weakly subradiant in-band scattering resonances. Our findings provide a paradigmatic signature of the presence of strong photon-photon interactions in 2D waveguide QED.

Stochastic series expansion quantum Monte Carlo for Rydberg arrays

Arrays of Rydberg atoms are a powerful platform to realize strongly-interacting quantum many-body systems. A common Rydberg Hamiltonian is free of the sign problem, meaning that its equilibrium properties are amenable to efficient simulation by quantum Monte Carlo (QMC). In this paper, we develop a Stochastic Series Expansion QMC algorithm for Rydberg atoms interacting on arbitrary lattices. We describe a cluster update that allows for the efficient sampling and calculation of physical observables for typical experimental parameters, and show that the algorithm can reproduce experimental results on large Rydberg arrays in one and two dimensions.

Symmetry breaking in an extended O(2) model

Motivated by attempts to quantum simulate lattice models with continuous Abelian symmetries using discrete approximations, we study an extended-O(2) model in two dimensions that differs from the ordinary O(2) model by the addition of an explicit symmetry breaking term −hqcos(qφ). Its coupling hq allows to smoothly interpolate between the O(2) model (hq=0) and a q-state clock model (hq→∞). In the latter case, a q-state clock model can also be defined for noninteger values of q. Thus, such a limit can also be considered as an analytic continuation of an ordinary q-state clock model to noninteger q. In previous work, we established the phase diagram for noninteger q in the infinite coupling limit (hq→∞). We showed that there is a second-order phase transition at low temperature and a crossover at high temperature. In this work, we seek to establish the phase diagram at finite values of the coupling using Monte Carlo and tensor methods. We show that for noninteger q, the second-order phase transition at low temperature and crossover at high temperature persist to finite coupling. For integer q=2, 3, 4, we know there is a second-order phase transition at infinite coupling (i.e. the well-known clock models). At finite coupling, we find that the critical exponents for q=3, 4 vary with the coupling, and for q=4 the transition may turn into a Berezinskii-Kosterlitz-Thouless transition at small coupling. We comment on the similarities and differences of the phase diagrams with those of quantum simulators of the Abelian-Higgs model based on ladder-shaped arrays of Rydberg atoms. Published by the American Physical Society 2024

Atomic excitation trapping in dissimilar chirally coupled atomic arrays

An atomic array coupled to a one-dimensional nanophotonic waveguide allows photon-mediated dipole-dipole interactions and nonreciprocal decay channels. Such an array possesses many intriguing quantum phenomena due to its distinctive and emergent quantum correlations. In this atom-waveguide quantum system, we theoretically investigate the atomic excitation dynamics and its transport property, specifically at an interface of dissimilar atomic arrays with different interparticle distances. We find that the atomic excitation dynamics is highly dependent on the interparticle distances of dissimilar arrays and the directionality of nonreciprocal couplings. By tuning these parameters, a dominant excitation reflection can be achieved at the interface of the arrays in the single excitation case. We further study two effects on the transport property—of external drive and of single excitation delocalization over multiple atoms—where we manifest a rich interplay between multisite excitation and the relative phase in determining the transport properties. Finally, we present an intriguing trapping effect of atomic excitation by designing multiple zones of dissimilar arrays. Similar to the single excitations, multiple excitations are reflected from the array interfaces and trapped as well, although complete trapping of many excitations together is relatively challenging at long time due to a faster combined decay rate. Our results can provide insights into nonequilibrium quantum dynamics in dissimilar arrays, and they can shed light on confining and controlling quantum registers useful for quantum information processing. Published by the American Physical Society 2024

Optical pumping of 5s4d1D2 strontium atoms for laser cooling and imaging

We present a faster repumping scheme for strontium magneto-optical traps operating on the broad 5s21S0−5s5p1P1 laser cooling transition. Contrary to existing repumping schemes, we directly address lost atoms that spontaneously decayed to the 5s4d1D2 state, sending them back into the laser cooling cycle by optical pumping on the 5s4d1D2−5s8p1P1 transition. We thus avoid the ∼100µs-slow decay path from 5s4d1D2 to the 5s5p3P1,2 states that is part of other repumping schemes. Using one low-cost external-cavity diode laser emitting at 448nm, we show our scheme increases the flux out of a 2D magneto-optical trap by 60% compared to without repumping. Furthermore, we perform spectroscopy on the 5s4d1D2−5s8p1P1 transition and measure its frequency νSr88=(668917515.3±4.0±25)MHz. We also measure the frequency shifts between the four stable isotopes of strontium and infer the specific mass and field shift factors, δνSMS88,86=−267(45)MHz and δνFS88,86=2(42)MHz. Finally, we measure the hyperfine splitting of the 5s8p1P1 state in fermionic strontium and deduce the magnetic dipole and electric quadrupole coupling coefficients A=−4(5)MHz and B=5(35)MHz. Our experimental demonstration shows that this simple and very fast scheme could improve the laser cooling and imaging performance of cold strontium atom devices, such as quantum computers based on strontium atoms in arrays of optical tweezers. Published by the American Physical Society 2024

Coherent Spin-Phonon Scattering in Facilitated Rydberg Lattices.

We investigate the dynamics of a one-dimensional spin system with facilitation constraint that can be studied using Rydberg atoms in arrays of optical tweezer traps. The elementary degrees of freedom of the system are domains of Rydberg excitations that expand ballistically through the lattice. Because of mechanical forces, Rydberg excited atoms are coupled to vibrations within their traps. At zero temperature and large trap depth, it is known that virtually excited lattice vibrations only renormalize the timescale of the ballistic propagation. However, when vibrational excitations are initially present-i.e., when the external motion of the atoms is prepared in an excited Fock state, coherent state or thermal state-resonant scattering between spin domain walls and phonons takes place. This coherent and deterministic process, which is free from disorder, leads to a reduction of the power-law exponent characterizing the expansion of spin domains. Furthermore, the spin domain dynamics is sensitive to the coherence properties of the atoms' vibrational state, such as the relative phase of coherently superimposed Fock states. Even for a translationally invariant initial state the latter manifests macroscopically in a phase-sensitive asymmetric expansion.

“Invisible” radioactive cesium atoms revealed: Pollucite inclusion in cesium-rich microparticles (CsMPs) from the Fukushima Daiichi Nuclear Power Plant

Understanding radioactive Cs contamination has been a central issue at Fukushima Daiichi and other nuclear legacy sites; however, atomic-scale characterization of radioactive Cs in environmental samples has never been achieved. Here we report, for the first time, the direct imaging of radioactive Cs atoms using high-resolution high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). In Cs-rich microparticles collected from Japan, we document inclusions that contain 27 – 36 wt% of Cs (reported as Cs2O) in a zeolite: pollucite. The compositions of three pollucite inclusions are (Cs1.86K0.11Rb0.19Ba0.22)2.4(Fe0.85Zn0.84X0.31)2.0Si4.1O12, (Cs1.19K0.05Rb0.19Ba0.22)1.7(Fe0.66Zn0.32X0.41)1.4Si4.6O12, and (Cs1.27K0.21Rb0.29Ba0.15)1.9(Fe0.60Zn0.32X0.69)1.6Si4.4O12 (X includes other cations). HAADF-STEM imaging of pollucite, viewed along the [111] zone axis, revealed an array of Cs atoms, which is consistent with a simulated image using the multi-slice method. The occurrence of pollucite indicates that locally enriched Cs reacted with siliceous substances during the Fukushima meltdowns, presumably through volatilization and condensation. Beta radiation doses from the incorporated Cs are estimated to reach 106 – 107 Gy, which is more than three orders of magnitude less than typical amorphization dose of zeolite. The atomic-resolution imaging of radioactive Cs is an important advance for better understanding the fate of radioactive Cs inside and outside of nuclear reactors damaged by meltdown events.

Coherent interface between optical and microwave photons on an integrated superconducting atom chip

Sub-wavelength arrays of atoms exhibit remarkable optical properties, analogous to those of phased array antennas, such as collimated directional emission or nearly perfect reflection of light near the collective resonance frequency. We propose to use a single-sheet sub-wavelength array of atoms as a switchable mirror to achieve a coherent interface between propagating optical photons and microwave photons in a superconducting coplanar waveguide resonator. In the proposed setup, the atomic array is located near the surface of the integrated superconducting chip containing the microwave cavity and optical waveguide. A driving laser couples the excited atomic state to Rydberg states with strong microwave transition. Then the presence or absence of a microwave photon in the superconducting cavity makes the atomic array transparent or reflective to the incoming optical pulses of proper frequency and finite bandwidth.

Electromagnetically induced transparency and quantum enhancement of transmission via dressed bloch photons in an array of three-level Λ-type atoms.

We investigate the interactions between an array of three-level atoms and two photon fields with distinct frequencies employing quantum electrodynamics (QED). The control beam, as expected, has a considerably higher intensity than the probe beam, and the probe photon's eigenstate notably then appears as a distinctive dressed Bloch wave. We calculate the dispersion relation and quantum amplitude of the probe photons for their transmission. At positions predicting electromagnetically induced transparency (EIT) phenomena, we unveil remarkable enhancements in the transmission of the probe beam. Crucially, these enhancements are intricately linked to the unique characteristics of the dressed Bloch wave eigenstate. Moreover, we demonstrate that modulating frequency and intensity of the control beam and the lattice constant would further tune these enhancements. Our study highlights the crucial role of the dressed Bloch wave eigenstate in substantially amplifying targeted light beams, thereby significantly enhancing the detection sensitivity for minute electromagnetic signals and emphasizing its pivotal role in unveiling intriguing phenomena.

Circumventing superexponential runtimes for hard instances of quantum adiabatic optimization

Classical optimization problems can be solved by adiabatically preparing the ground state of a quantum Hamiltonian that encodes the problem. The performance of this approach is determined by the smallest gap encountered during the evolution. Here, we consider the maximum independent set problem, which can be efficiently encoded in the Hamiltonian describing a Rydberg atom array. We present a general construction of instances of the problem for which the minimum gap decays superexponentially with system size, implying a superexponentially large time to solution via adiabatic evolution. The small gap arises from locally independent choices which cause the system to initially evolve and localize into a configuration far from the solution in terms of Hamming distance. We investigate remedies to this problem. Specifically, we show that quantum quenches in these models can exhibit signatures of quantum many-body scars, which in turn, can circumvent the superexponential gaps. By quenching from a suboptimal configuration, states with a larger ground-state overlap can be prepared, illustrating the utility of quantum quenches as an algorithmic tool. Published by the American Physical Society 2024

Variational Monte Carlo with large patched transformers

Large language models, like transformers, have recently demonstrated immense powers in text and image generation. This success is driven by the ability to capture long-range correlations between elements in a sequence. The same feature makes the transformer a powerful wavefunction ansatz that addresses the challenge of describing correlations in simulations of qubit systems. Here we consider two-dimensional Rydberg atom arrays to demonstrate that transformers reach higher accuracies than conventional recurrent neural networks for variational ground state searches. We further introduce large, patched transformer models, which consider a sequence of large atom patches, and show that this architecture significantly accelerates the simulations. The proposed architectures reconstruct ground states with accuracies beyond state-of-the-art quantum Monte Carlo methods, allowing for the study of large Rydberg systems in different phases of matter and at phase transitions. Our high-accuracy ground state representations at reasonable computational costs promise new insights into general large-scale quantum many-body systems.

Extreme single-excitation subradiance from two-band Bloch oscillations in atomic arrays

Atomic arrays provide an important quantum optical platform with photon-mediated dipole–dipole interactions that can be engineered to realize key applications in quantum information processing. A major obstacle for such applications is the fast decay of the excited states. By controlling two-band Bloch oscillations of single excitation in an atomic array under an external magnetic field, here we show that exotic subradiance can be realized and maintained with orders of magnitude longer than the spontaneous decay time in atomic arrays with the finite size. The key finding is to show a way for preventing the wavepacket of excited states scattering into the dissipative zone inside the free space light cone, which therefore leads to the excitation staying at a subradiant state for an extremely long decay time. We show that such operation can be achieved by introducing a spatially linear potential from the external magnetic field in the atomic arrays and then manipulating interconnected two-band Bloch oscillations along opposite directions. Our results also point out the possibility of controllable switching between superradiant and subradiant states, which leads to potential applications in quantum storage.