Apparent Heat Research Articles

Analysis of the Properties and Thermal Behavior of Low-Temperature Phase Change Materials (PCMs) That Can Be Applied in Heating and Ventilation Systems

This article analyses the use of low-temperature PCMs in devices supplementing a room ventilation system to prevent the overcooling effect. In this study, the phase change is numerically simulated in an axisymmetric system consisting of two tubes. One is filled with RT11HC with an initial temperature of 0 °C, while air with an inlet temperature of 20 °C flows through the other, heating the PCM and causing it to melt. Calculations are performed using commercial software with the apparent heat method for a system of given dimensions. Spatial distributions of the system temperature and liquid volume fraction at different time moments (from 0 to 120 min) are determined. It is found that the results depended mainly on the method of determining the latent heat. For the beginning of the charging process (t < 40 min), the values of the liquid phase fraction determined by the H and S methods are similar, while the one determined by the G method is definitely higher (even three times at t = 10 min). In turn, the outlet air temperature determined by the S method is lower than that determined by the other methods. The size and shape of the mesh have no significant effect on the results.

Enzyme stabilisation due to incorporation of a fluorinated non-natural amino acid at the protein surface.

We have previously engineered E. coli transketolase (TK) enzyme variants that accept new substrates such as aliphatic or aromatic aldehydes, and also with improved thermal stability. Irreversible aggregation is the primary mechanism of deactivation for TK in the buffers used for biocatalysis, and so we were interested in determining the extent to which this remains true in more complex media, crude cell lysates or even in vivo. Such understanding would better guide future protein engineering efforts. NMR offers a potential approach to probe protein structure changes, aggregation, and diffusion, and19F-labelled amino acids are a useful NMR probe for complex systems with little or no background signal from the rest of the protein or their environment. Here we labelled E. coli TK with two different19F probes, trifluoromethyl-L-phenylalanine (tfm-Phe), and 4-fluoro phenylalanine (4F-Phe), through site specific non-natural amino acid incorporation. We targeted them to residue K316, a highly solvent exposed site located at the furthest point from the enzyme active sites. Characterisation of the19F-labelled TK variants revealed surprising effects of these mutations on stability, and to some extent on activity. While variant TK-tfm-Phe led to a 7.5°C increase in the thermal transition midpoint (Tm) for denaturation, the TK-4F-Phe variant largely abolished the aggregation of the enzyme when incubated at 50°C19. F-NMR revealed different behaviours in response to temperature increases for the two TK variants, displaying opposite temperature gradient chemical shifts, and diverging motion regimes, suggesting that the mutations affected differently both the local environment at this site, and its temperature-induced dynamics. A similar incubation of TK at 40-55°C is also known to induce higher cofactor-binding affinities, leading to an apparent heat activation under low cofactor concentration conditions. We have hypothesised previously that a heat-inducible conformational change in TK leads to this effect1. H-NMR revealed a temperature-dependent re-structuring of methyl groups, also at 30-50°C, which may be linked to the heat activation. While our kinetic studies were not expected to observe the heat activation event due to the high cofactor concentrations used, this was not the case for TK-4F-Phe, which did appear to heat activate slightly at 45°C. This implied that the mutations at K316 could influence cofactor-binding, despite their location at 47 Å from either active site. Such long-distance effects of mutations are not unprecedented, and indeed we have previously shown how distant mutations can influence active-site loop stability and function in TK, mediated via dynamically coupled networks of residues. Molecular dynamics simulations of the two19F containing variants similarly revealed networks of residues that could couple the changes in dynamics at residue K316, through to changes in active site dynamics. These results independently highlight the sensitivity of active-site function to distant mutations coupled through correlated dynamic networks of residues. They also highlight the potential influence of surface-incorporated probes on protein stability and function, and the need to characterise them well prior to further studies.

Thermodynamically Traceable Calorimetric Results for Aqueous Sodium Chloride Solutions from T = (273.15 to 373.15) K up to the Saturated Solutions: Part 2 —The Quantities Associated with the Partial Molar Heat Capacity

AbstractIn previous articles (Partanen and Partanen in J. Chem. Eng. Data 65: 5226 − 5239 (2020), J. Solution Chem. 52: 1352 − 1385 (2023)), we presented a traceable and transparent three-parameter model for thermodynamic activity and enthalpy quantities in aqueous NaCl solutions. The model is based on extended Hückel equations with parameters B, b1, and b2 and it applies from T = 273.15 to 373.15 K up to the saturated solutions. These studies demonstrate that the model explains the literature data of almost all thermodynamic quantities including apparent and partial molar enthalpies within experimental error. In the model, the ion-size parameter in the Debye–Hückel equation, B, is regarded as a constant while the parameters of the coefficients of the linear and quadratic molality terms, b1 and b2, respectively, possess quadratic temperature dependences. In this study, the results obtained for the heat capacity quantities of NaCl(aq) are considered. We show that the available heat capacity literature for these solutions can be predicted at least satisfactorily up to the saturated solutions with our new model. Following this success, we supplement the existing thermodynamic tables with the new values for the relative apparent and partial molar heat capacities for NaCl solutions. It is likely that the new tables contain the most reliable values determined so far even though no calorimetric data were used in the parameter estimation of our model. Graphical Abstract

Heat capacities and thermodynamic properties of urea phosphate and its aqueous solutions at various temperatures

Urea phosphate was produced through a complexation reaction of phosphoric acid and urea and subsequent cooling crystallization. The elemental composition analysis, XRD, and FTIR all confirmed that the prepared urea phosphate had high purity and good crystallinity, and showed a clear onset melting temperature of 118.12℃ and corresponding enthalpy change of 222.10 J∙g−1 in TG/DSC measurement. Meanwhile, the heat capacities of urea phosphate and its aqueous solution were carefully measured using microcalorimetry with an expanded relative uncertainty better than 2 %. The experimental results revealed that the heat capacity of urea phosphate rises rapidly with temperature, with an increase of 41 % from −20 to 100℃. The experimental heat capacity data were correlated with semi-empirical models of Maier-Kelley equation, Khodakovsky equation and Debye-Einstein equation which all give excellent reproduction of the measured data with very close average deviation around 0.5 %. The enthalpy, entropy, and Gibbs free energy of solid urea phosphate were estimated at various temperatures by integrating heat capacity against temperature with Maier-Kelley equation and the results confirmed urea phosphate is thermally quite stable below 100℃. The heat capacity of urea phosphate aqueous solution increases with concentration and temperature, and there is a strong linear relationship between the solution’s heat capacity and temperature when the composition remains constant. The apparent molar heat capacity of urea phosphate in solution is positive and increases with concentration and temperature. The extrapolated partial molal heat capacity of urea phosphate is temperature independent and shows an average value of −709.4 J·K−1·mol−1. Due to the partial dissociation and partial ionization of urea phosphate in solution, the excess molar heat capacities show positive deviation from that of ideal solution, which also increases with the increase of concentration and temperature.

Study on the Influence of Laser Power on the Heat–Flow Multi-Field Coupling of Laser Cladding Incoloy 926 on Stainless Steel Surface

In order to explore the influence of laser power on the evolution of molten pool and convective heat transfer of laser cladding Incoloy 926 on stainless steel surface, a three-dimensional thermal fluid multi-field coupled laser cladding numerical model was established in this paper. The variation of latent heat during solid-liquid phase transformation was treated by apparent heat capacity method. The change in the gas–liquid interface was tracked using the mesh growth method in real time. The instantaneous evolution of temperature field and velocity flow field of laser cladding Incoloy 926 on a stainless steel surface under different laser power was discussed. The solidification characteristic parameters of the cladding layer were calculated based on the temperature-time variation curves at different nodes. The mechanism of the impact of laser power on the microstructure of the cladding layer was revealed. The experiment of laser cladding Incoloy 926 on 316L surface was carried out under different laser power. Combined with the numerical simulation results, the effects of laser power on the geometrical morphology, microstructure and element distribution of the cladding layer were compared and analyzed. The results show that with the increase in laser power, the peak temperature and flow velocity of the molten pool surface both increase significantly. The thermal influence of the molten pool center on the edge is enhanced. The temperature gradient, solidification rate, and cooling rate increased gradually. The microstructure parameters (G/R) are relatively small when the laser power is 1000 W. In the experimental range, the dilution rate and wetting angle of the cladding layer both increase with the increase in laser power. When the laser power is 1000 W, the alloying elements of the cladding layer are more evenly distributed and the microstructure is finer. The experimental results are in good agreement with the simulation results.

Experimental study on the effects of n-butanol and n-propanol on the spray and combustion characteristics of diesel/biodiesel blends in a constant volume combustion chamber

The depletion of fossil fuel resources and the escalating environmental impact of greenhouse gas emissions have intensified the global exploration of renewable and sustainable energy sources. Biodiesel produced from vegetable oils and animal fats has become a promising alternative to conventional diesel fuel due to its renewability and lower carbon emission. This study investigates the differences in spray, combustion and flame characteristics between soybean-based biodiesel blended with propanol and butanol at various ratios. The results indicate that the liquid spray penetration length of biodiesel mixed with propanol and butanol exceeds that of soybean-based biodiesel. And the increase of spray penetration is accompanied by a longer flame lift-off length, which indicates the improvement of spray characteristics. Regarding combustion, alcohol-fuel blends exhibit a reduction in peak combustion pressure but an increase in peak apparent heat release rate. Additionally, these fuels show a shorter ignition delay and combustion duration. The peak natural flame luminosity is lower for alcohol fuels, suggesting their potential to reduce carbon soot production and support low-carbon combustion. These experimental results contribute to advancing research on cleaner, more efficient and renewable fuels, thereby reducing reliance on conventional fossil fuels.

Investigations on the heat transfer performance of phase change material (PCM)-based heat sink with triply periodic minimal surfaces (TPMS)

During the operational process of electronic components, excessive heat generation results in significant temperature elevation. This elevated temperature poses a significant risk to their service life. Regarding the issue of efficient thermal management of electronic devices in enclosed spaces experiencing high heat flow, a thermal management scheme for electronic equipment using TPMS and a PCM-based heat sink is proposed. The apparent heat capacity method is employed to simulate the melting process of the PCM-based heat sink. The effects of structural parameters w1, w3, and C of TPMS structures on the heat transfer characteristics (including base temperature, liquid fraction, average cell temperature, and average heat transfer coefficient) of the PCM-based heat sink during the melting process are discussed. A temperature testing platform is established. Experimental research is performed to investigate the effect of TPMS structures with two different printing prototypes (Sample 1, and Sample 2) on the heat sink during the intermittent cycle. The results indicate that increasing the parameters C and w1 significantly improves the average heat transfer coefficient (HTC) of the heat sink. When C increases from 0.3 to 0.7, the average HTC increases from 307 W/(m2·K) to 358 W/(m2·K). When w1 increases from 1 to 3, the average HTC increases from 284.5 W/(m2·K) to 321.3 W/(m2·K). Sample 1, possessing superior thermal conductivity, exhibits better heat transfer performance. When the temperature achieves a stable periodic variation, the base temperature of Sample 1 stabilizes within the range of 310 K-340 K. And Sample 2 stabilizes within the range of 315 K-350 K.

Impact of the thermal contrast between the Arabian Sea and the Iranian Plateau on the interannual variability of the East Asian summer monsoon

Abstract The land–sea thermal contrast is known to have a significant impact on the atmospheric circulation. We investigated the influence of the thermal contrast between the Arabian Sea (AS) and the Iranian Plateau (IP) on the interannual variability of the East Asian summer monsoon (EASM). It is found that the thermal distribution of AS–IP exhibits a fixed dipole mode. When the apparent heat over AS (IP) is higher (lower) than normal, summer rainfall is abundant over the mid- and lower reaches of the Yangtze River and Japan with the adjacent maritime regions. By contrast, there is lower rainfall in North China and the coastal regions of South China. We attribute this phenomenon to the propagation of mid-latitude Rossby waves, which play a crucial role in regulating the atmospheric circulations on East Asia and the Northwest Pacific. Significant anomalies in the transport of water vapor were seen in our statistical analyses and were partly reproduced by the Linear Baroclinic Model and Weather Research and Forecasting model experiments. The anticipated outcomes of this research will help to identify another factor related to the variability of the EASM, and provide a scientific basis for understanding the distribution and interaction of thermal anomalies on the plateau system and the Indian Ocean.

Thermal modeling of porous medium integrated in PCM and its application in passive thermal management of electric vehicle battery pack

The integration of a composite of porous medium with phase change material (PCM) offers significant advantages in thermal management systems, enhancing heat transfer efficiency and addressing various thermal regulation challenges. This approach utilizes the PCM's latent heat absorption and the enhanced thermal conductivity provided by the porous medium, resulting in optimized system performance. Its applicability spans across electronics cooling and building insulation systems. However, predicting the thermal behavior of this composite material is challenging, necessitating computational tools to anticipate its response under different conditions and evaluate its influence on cooling strategies. The objective of this study is to create a computational tool specifically tailored to evaluate constitutive parameters of this composite material, thereby providing a comprehensive description of its thermal behavior. To achieve this goal, the multiscale homogenization principle is employed to assess the composite's effective thermophysical material properties using the representative volume element approach. The repeating unit cell of the aluminum lattice is incorporated into the PCM to define a representative volume element. The finite element method (FEM) is utilized to solve the three-dimensional homogenization problem, yielding an orthotropic effective thermal conductivity due to the inherent symmetry of the repeating material cell. Moreover, the study leverages the apparent heat capacity method to effectively manage the phase transitions within the PCM domain, utilizing smooth and temperature-dependent functions to accurately describe the thermophysical properties of the PCM. Integrating the composite into battery pack thermal management, this study thoroughly examines thermal dynamics by comparing outcomes with and without PCM integration. The transient thermal problem is accurately tackled using the FEM, employing the evaluated effective constitutive parameters of the homogenized composite to minimize computational effort. The results indicate a notable decline in the highest temperatures of the battery pack, leading to a reduction of about 14 °C at the specific moment when the phase change material fully transitions into its liquid form. The obtained results emphasize the effectiveness and practical feasibility of the proposed thermal management strategy. The modeling approach presented provides a robust tool with significant efficiency in reducing computational time for analyzing the thermal behavior of large models, as the utilization of the homogenization technique notably decreases the computational time.

The role of charge reactivity in ammonia/diesel dual fuel combustion in compression ignition engine

This study investigates the combustion characteristics of diesel–NH3–air mixture in compression ignition engine. Three different levels of ammonia energy ration (AER) were used for the investigation: 0 % AER (pure diesel), 30 % AER, and 50 % AER. Increasing AER leads to a rise in the initial peak of apparent heat release rate and promotes the prevalence of premixed combustion. Numerical simulations effectively capture the abrupt increase in maximum cylinder pressure (Pmax) from 7.4 to 7.9 MPa as AER increases from 0 to 30 %. Additionally, raising AER from 0 to 30 % extends a high-temperature region externally in the squish zone, attributed to the higher knocking propensity of the 30 % AER premixed charge. The ammonia-assisted diesel accomplish advanced diesel direct injection timing (SOID) at both heavy and medium load conditions. Under light load conditions, an increase in ITE is observed for AER = 50 % as SOID varies from −4 °CA to −10 °CA (ATDC). For medium and high load conditions, ITE monotonically increases with advancing SOID. The maximum ITE of 44.5 % is achieved at SOID = −12 °CA (ATDC) and AER = 30 %.

Experimental and numerical investigations on the intermittent heat transfer performance of phase change material (PCM)-based heat sink with triply periodic minimal surfaces (TPMS)

The excessive heat generated during the operation of electronic components leads to significant temperature increases, posing a significant risk to their service life. For the problem of efficient thermal management of electronic devices in confined spaces experiencing high heat flow, a scheme using triply periodic minimal surfaces and a phase change material-based active–passive cooling heat sink is proposed to control the temperature of electronic equipment. The apparent heat capacity method is employed to simulate the intermittent process of the phase change material-based heat sink. The optimization based on Box-Behnken Design and Nondominated Sorting Genetic Algorithm II is analyzed to obtain an improved triply periodic minimal surface structure. The effect of thermal performance (including base temperature, liquid fraction, and Grashof number) of an intermittent heat sink based on an improved structure is discussed. Visualization and temperature testing platforms are established. Through visualization experiments, the internal temperature and liquid fraction distribution of the heat sink are obtained, and the simulation results are in good agreement with the test results. The results show that the base temperature, liquid fraction, and Grashof number achieve a steady periodic variation during the intermittent process. Specifically, the base temperature remains stable in the range of 314 K to 340 K, the liquid fraction stabilizes between 0.8 and 1.0, and the Grashof number stabilizes between 100 and 1000. At the heating power of 30 W or below, the base temperature of the heat sink exhibits a steady periodic variation. At the heating power of 40 W, the maximum base temperature of the heat sink exceeds 370 K.

Transient thermal 2D FEM analysis of SiC MOSFET in short-circuit operation including high-temperature material laws and phase transition of aluminum source electrode

Understanding the electrothermal behavior of SiC MOSFET power devices under extreme operation conditions, such as short circuits, is crucial for their application certification. However, simulating short circuits in electronic components is challenging due to the necessity of a comprehensive thermal and electrical Multiphysics model that incorporates material laws and respects elevated temperatures with broad ranges. It is also needed to model the melting of the topside Al electrode. The paper presents for the first time a 2D electrothermal FEM that simulates the thermodynamic behavior of SiC MOSFET at high temperatures transistors under short-circuit conditions, including wide-range temperature-dependent material property laws. This work models the Al phase transition by considering the apparent heat capacity method and including the latent heat absorbed during the Al solid-liquid phase change (PC). The geometric accuracy of this study provides significant added values compared to existing 1D models. It was deduced that including the temperature-dependent material laws highly impacted the results. The rise in SiC junction temperature led to a delay in the onset of Al melting. It also impacted the progression manner of the Al melting process after the formation of new melting fronts.

Level-set topology optimization of heat sinks with phase-change material

Phase-change materials (PCMs) excel in storing significant thermal energy through the latent heat of fusion during phase changes. However, they often suffer from low thermal conductivity, requiring the incorporation of materials with higher thermal conductivity to overcome this limitation. In this study, we employ the level-set method to topologically optimize the distribution of both PCM and high thermal conductivity materials within heat sinks.The heat transfer process is modeled as an unsteady diffusion problem, with PCM integrated using the apparent heat capacity method. The finite element method, implemented using FEniCS, is utilized to compute the temperature distribution at each time step. The optimization problem is solved using ParaLeSTO, a modular topology optimization software written in C++, seamlessly interfacing with FEniCS through its Python interface.To compute boundary point sensitivities for level-set topology optimization, the discrete adjoint method is employed, combining a perturbation scheme with automatic differentiation. The proposed methodology is first applied to a two-dimensional example of temperature oscillation minimization with a heat flux boundary condition, drawn from existing literature. Subsequently, a two-dimensional example with multiple volumetric heat sources is studied, followed by an extension to a three-dimensional design domain.Comparisons with optimized designs without PCM, serving as a reference, highlight the superior thermal performance of heat sink designs with PCM. The results showcase a maximum temperature reduction of up to 42%, a mean temperature reduction of up to 42%, and a temperature variance reduction of up to 94%. This research contributes to heat sink design by offering discrete solutions that significantly improve thermal performance as compared to designs without PCM. Its impact extends to addressing crucial challenges in thermal management across various applications, including automotive cooling systems, aerospace components, and consumer electronics.

Cellulose-Based Polyurethane Foams of Low Flammability.

Decreasing oil resources creates the need to search for raw materials in the biosphere, which can be converted into polyols suitable for obtaining polyurethane foams (PUF). One such low-cost and reproducible biopolymer is cellulose. There are not many examples of cellulose-derived polyols due to the sluggish reactivity of cellulose itself. Recently, cellulose and its hydroxypropyl derivatives were applied as source materials to obtain polyols, further converted into biodegradable rigid polyurethane foams (PUFs). Those PUFs were flammable. Here, we describe our efforts to modify such PUFs in order to decrease their flammability. We obtained an ester from diethylene glycol and phosphoric(III) acid and used it as a reactive flame retardant in the synthesis of polyol-containing hydroxypropyl derivative of cellulose. The cellulose-based polyol was characterized by infrared spectra (IR) and proton nuclear magnetic resonance (1H-NMR) methods. Its properties, such as density, viscosity, surface tension, and hydroxyl numbers, were determined. Melamine was also added to the foamed composition as an additive flame retardant, obtaining PUFs, which were characterized by apparent density, water uptake, dimension stability, heat conductance, compressive strength, and heat resistance at 150 and 175 °C. Obtained rigid PUFs were tested for flammability by determining oxygen index, horizontal flammability test, and calorimetric analysis. Obtained rigid PUFs showed improved flammability resistance in comparison with non-modified PUFs and classic PUFs.

Combustion characteristics of RP-3 aviation kerosene/n-butanol blended fuel in a compression ignition engine

In order to meet the requirements of Sustainable Aviation Fuel (SAF) to achieve the imperatives of energy conservation and emission reduction. This paper compares the combustion characteristics of diesel, RP-3/n-butanol blends in terms of heat release rate, in-cylinder pressure, temperature and fuel economy in a compression ignition engine, taking into account the advantages of lightweight structure, low fuel consumption and wide range of applications of aviation piston engines. The results certified the viability of applying RP-3 and RP-3/n-butanol blends in diesel engines. Adding n-butanol prolonged the ignition delay and shorten the combustion duration. Moreover, the peak of the pressure, temperature and apparent heat release rate (AHRR) increased. In addition, the blended fuel showed obvious diffusion combustion characteristics at high load. With the n-butanol increased, the combustion instability of the blended fuels decreased significantly, at low load. At n = 2400r/min, pme = 0.53 MPa, compared with diesel, the maximum heat release rate (MHRR) of R70B30 increased by 76.6 %, improving the combustion characteristics of the blended fuel. Moreover, the equivalent specific fuel consumption (ESFC) of RP-3 is 5.56–14.83 % lower than that of diesel, and the effective thermal efficiency (ETE) of RP-3 is 2.8–13.46 % higher than that of diesel under most working conditions.

Optical engine investigation of ammonia combustion enhancement with polyoxymethylene dimethyl ethers (PODE₃) as pilot fuel

Ammonia, gaining attention as a carbon-free fuel amid declining fossil fuel reserves, faces challenges like combustion instability and misfiring in its application in internal combustion engines. In this study, polyoxymethylene dimethyl ethers (PODE3), a clean, renewable, and electrically synthesized fuel with high cetane number and oxygen content, is evaluated as a pilot fuel for ammonia in dual-fuel engines. The study, performed in a dual-fuel optical engine, investigates the use of PODE₃ compared to diesel as direct injection fuels for ammonia combustion, focusing on the impact of PODE3 injection timing and dwell (the interval between dual-stage injections) on the ignition characteristics of ammonia. The results demonstrate that, compared to diesel, using PODE3 enhances ammonia combustion in dual-fuel engines. This is evident from increased in-cylinder pressure, higher apparent heat release rate (AHRR), advanced combustion phases, and improved indicated mean effective pressure (IMEP), enhancing overall stability. PODE3 also effectively minimizes soot generation, evidenced by a 71.5 % reduction in spatially integrated natural luminosity (SINL), accompanied by a 16.9 % increase in peak flame area. Adjusting PODE3 injection timing is crucial; initial retardation improves combustion performance, marked by higher in-cylinder pressure and AHRR, as well as expanded flame area. However, over-delaying injection timing reduces these gains. The optimal performance is achieved under the SOI-25 condition, balancing combustion and flame development, though some areas remain unburnt. In a dual-stage injection strategy using PODE3, where the second injection timing remains fixed at −25 °CA ATDC, the critical adjustment of advancing the first injection timing to −35 °CA ATDC markedly enhances combustion performance compared to a single injection condition. This setting reduces ignition delays, increases peak in-cylinder pressures, and improves stability, which collectively contribute to a significant 20.4 % increase in the peak flame area, particularly between adjacent fuel jets. Expanding upon this, advancing the first injection timing further to −45 °CA ATDC leads to a decrease in peak in-cylinder pressure and AHRR, accompanied by a notable 40.3 % reduction in the peak flame area. This research affirms the advantages of PODE3 over diesel in ammonia-powered dual-fuel engines, markedly enhancing combustion performance and environmental sustainability, where the injection strategy of PODE3 emerges as a crucial element.

Investigation on self-excited thermoacoustic instability and emission characteristics of premixed CH4/NH3/air flame

Ammonia is one of the promising carbon-free alternative fuels for low-carbon power generation. This study investigated the self-excited thermoacoustic instability of premixed CH4/NH3/air flame in a swirl burner. The work aims to determine the effects of ammonia mole fraction (χNH3), equivalence ratio (Ф) and combustion chamber length (CL) on flame morphology and self-excited flame dynamics. In addition, the emission characteristics of CH4/NH3/air flame were also investigated. Results show that the thermoacoustic instability of the 1/4 wave mode is excited when 0.8≤Ф≤1.2 and χNH3 ≤ 0.3. There are apparent pressure fluctuations and heat release fluctuations in the combustion chamber. The fluctuating frequency decreases with increasing CL. The maximum fluctuating frequency and oscillation intensity appear near Ф=1.0. When χNH3 increases, the amplitude of fluctuating pressure and heat release rate decrease obviously, and the instability range narrows to Ф=1.0–1.1 simultaneously. The low-order acoustic network model successfully predicted the instability transition and frequency decreasing trend caused by increasing ammonia. The increase in the convective time delay is responsible for this transition. Emission analysis indicates that NOx emission can be controlled within 100 ppm under fuel-rich conditions, but the CO emission increases sharply. Thermoacoustic instability and nitrogen oxides can be simultaneously controlled under fuel-rich conditions when χNH3>0.3. However, this will be limited by unburned reactants.

Growth, survival, digestive activity and respiratory metabolism of Octopus maya juveniles fed with prepared diets.

The effects of two prepared feeds were tested on growth, survival, enzymatic activity, nutritive reserves in the digestive gland and oxygen consumption of Octopus maya juveniles. For the first time, a semihumid paste (HD, control) and a dry diet, in pelleted form (PD, experimental) with the same formulation were used for this species. The experiment lasted for 42 days. Results indicate that growth rates were similar for both diets (p > 0.05); however, survival (70%) was higher with the PD compared to the HD (48%) (p < 0.05). The performance index was higher for octopuses fed the PD (p < 0.05). No differences in acid proteases activity were observed. However, a higher activity of alkaline proteases in the octopuses fed the PD was observed (p < 0.05). Ingestion rate was higher for octopuses fed the PD. Routine energy inversion was similar in both treatments (p > 0.05). A greater energy inversion was observed in octopuses fed the PD, whose active metabolism was double compared to the octopuses fed the HD. Results showed that the PD promoted similar growth compared to the HD diet but favored survival, and a greater investment in the active metabolism, reflected in the apparent heat increase.

Direct Numerical Simulation of single bubble dynamics in nucleate pool boiling with micro-region modeling and thermal coupling to a solid wall

In this study, we conduct two-dimensional, axisymmetric simulations to investigate the growth and departure of a single bubble, with a particular focus on the conjugate heat transfer between the fluid and the heating wall. A multiscale modeling approach is employed to account for nanoscale effects near the liquid-vapor-solid triple contact line (CL). At the macro (bubble size) scale, the interface dynamics is captured with the front-tracking method by using the open-source code TRUST/TrioCFD. The macro scale algorithm is coupled with a sub-grid micro-region model. It is driven by the wall superheating at the CL as input, and predicts the macroscopic apparent contact angle and heat fluxes. To validate our modeling approach, we first conduct quantitative comparisons using the data on the bubble growth experiment RUBI and its simulations. Next, an investigation of the case of water under atmospheric pressure and gravity is performed. Notably, we observe a significant spatial variation in temperature near the nucleation site during the expansion and contraction of the bubble base. This variation greatly affects the thermal boundary layers in the fluid and solid domains and the bubble growth, demonstrating the need to resolve the conjugate heat transfer in the considered cases.

Heat transfer performance of supercritical CO2 in a vertical U-tube

Supercritical carbon dioxide (sCO2) is taken as an excellent working medium for efficient and compact energy conversion devices. However, heat transfer performance (HTP) of sCO2 in a vertical U-tube is intricate owing to dramatic variation of its temperature-dependent thermophysical properties. In this study, flow and heat transfer performance (FHTP) of sCO2 in a vertical U-tube is studied with an improved shear stress transfer model. Additionally, the impacts of operational parameters (heat flux q, mass flux G and pressure P), flow directions and bending diameters (dbend) of U-tube on FHTP are investigated. In both directions, the differences in local pressure drop caused by buoyancy effect and thermal expansion are analyzed deeply. The results demonstrate that the bend section can disturb flow and vortexes persist in downstream, thus improve the HTP. However, an apparent heat transfer deterioration zone can be observed in the ascending section. Under both directions, the average heat transfer coefficient (havg) raises with the growing G and P and decreasing q and dbend, while the total pressure drop (ΔPtotal) rises with the raising G and q as well as decreasing P. Moreover, the U-tube with down-up direction obtains higher havg and lower ΔPtotal than up-down.