Optical engine investigation of ammonia combustion enhancement with polyoxymethylene dimethyl ethers (PODE₃) as pilot fuel

Abstract

Ammonia, gaining attention as a carbon-free fuel amid declining fossil fuel reserves, faces challenges like combustion instability and misfiring in its application in internal combustion engines. In this study, polyoxymethylene dimethyl ethers (PODE3), a clean, renewable, and electrically synthesized fuel with high cetane number and oxygen content, is evaluated as a pilot fuel for ammonia in dual-fuel engines. The study, performed in a dual-fuel optical engine, investigates the use of PODE₃ compared to diesel as direct injection fuels for ammonia combustion, focusing on the impact of PODE3 injection timing and dwell (the interval between dual-stage injections) on the ignition characteristics of ammonia. The results demonstrate that, compared to diesel, using PODE3 enhances ammonia combustion in dual-fuel engines. This is evident from increased in-cylinder pressure, higher apparent heat release rate (AHRR), advanced combustion phases, and improved indicated mean effective pressure (IMEP), enhancing overall stability. PODE3 also effectively minimizes soot generation, evidenced by a 71.5 % reduction in spatially integrated natural luminosity (SINL), accompanied by a 16.9 % increase in peak flame area. Adjusting PODE3 injection timing is crucial; initial retardation improves combustion performance, marked by higher in-cylinder pressure and AHRR, as well as expanded flame area. However, over-delaying injection timing reduces these gains. The optimal performance is achieved under the SOI-25 condition, balancing combustion and flame development, though some areas remain unburnt. In a dual-stage injection strategy using PODE3, where the second injection timing remains fixed at −25 °CA ATDC, the critical adjustment of advancing the first injection timing to −35 °CA ATDC markedly enhances combustion performance compared to a single injection condition. This setting reduces ignition delays, increases peak in-cylinder pressures, and improves stability, which collectively contribute to a significant 20.4 % increase in the peak flame area, particularly between adjacent fuel jets. Expanding upon this, advancing the first injection timing further to −45 °CA ATDC leads to a decrease in peak in-cylinder pressure and AHRR, accompanied by a notable 40.3 % reduction in the peak flame area. This research affirms the advantages of PODE3 over diesel in ammonia-powered dual-fuel engines, markedly enhancing combustion performance and environmental sustainability, where the injection strategy of PODE3 emerges as a crucial element.