Alkali Metal Ion Batteries Research Articles

Realizing High-Performances Sb Anodes for K-Ion Batteries

Alloy anodes have long been considered promising alternatives to carbon counterparts for high-energy K-ion batteries (KIBs) as they could uptake several ions per K atom through alloying reactions, delivering exceptional capacities at low voltage. However, alloy electrodes usually undergo severe volume expansion upon large K ion insertion, which will trigger the pulverization of active particles and the breakage of solid electrolyte interphase (SEI), leading to rapid capacity degradation. Instead of fabricating nanostructured materials, novel electrolyte formulations can be used to realize stable cycling of high-capacity anodes in KIBs. Sb is a promising low-cost anode material for KIBs, possessing a high theoretical capacity of 660 mAh g-1 at average voltage of about 0.5V toward K+/K. However, it shows rapid capacity degradation in conventional carbonate-based electrolytes. To stabilize the Sb anodes, novel ether-based KIB electrolytes are designed to replace the conventional ones, enabling a high reversible capacity over 180 cycles. It is found that a thinner and amorphous SEI, with abundant oligomer-like species, is built in ether base electrolytes. Such SEI is more elastic, and can effectively wrap the Sb particles to accommodate repeated volumetric changes, and preventing copious electrolytes decomposition. These findings allow us to develop crucial fundamental knowledge to design ideal SEIs for stabilizing alloy anodes to boost the energy densities of today’s alkali-metal ion batteries.

Investigation of Heteroatom Doped Graphene Anode for High-Capacity Alkali Metal-Ion Batteries

The drastic growth of Li-ion batteries (LIBs) in global electronic market and low crustal abundance of Li demands for more abundant alternatives such as sodium and potassium having similar electrochemical properties. Sodium-ion battery (SIB) and potassium-ion battery (PIB) can be used “side-by-side” to LIB which can help battery technology progress efficiently. 1Graphite has been a commercial anode in LIB due to its low cost, high abundance, high electrical conductivity, with a theoretical storage capacity (LiC6) of 372 mAh g-1. In contrast the utilization of graphite in SIBs and PIBs is challenging. This is due to the large radius and unstable graphite-intercalation compounds (NaC64) giving very low theoretical capacity of 30 mAh g-1. In PIBs, graphite exhibits a theoretical capacity of 279 mAh g-1 but suffers from poor stability due to huge volume expansion (60%) in fully potassiated state (KC8). Thus, focus is now shifted on to class of amorphous carbon materials such as hard carbon, soft carbon, graphene etc. with variations in micro-structures, larger interlayer spacing, and defect rich sites promoting enhanced capacity and stability even at high current densities. 2 In my presentation I will be discussing about the synthesis of heteroatom doped graphene with high charge storage and stability for LIB, SIB and PIB compared to graphite. The heteroatom doped graphene exhibits nearly 1000 mAh g-1 (LIB), 380 mAh g-1 (SIB) and 379 mAh g-1 (PIB) at a low current density of 25 mAg-1. Additionally, the elastic nature of ultrathin graphene nanosheets aids in attaining long term cyclability at 1 A g-1 with high-capacity retention of 83% for 300 cycles (LIB), 73% for 400 cycles (SIB) and 91% for 600 cycles (PIB). The enhanced stability in case of PIB, is attributed to optimizing solid electrolyte interphase (SEI) components and improving interfacial reaction kinetics at high current densities. Choice of high concentrated electrolyte (HCE) over conventional KPF6 in EC:DEC determines the nature of SEI and thereby helps in achieving cycling stability. The stability in SEI is characterized via voltage profile and understanding chemical composition by ex-situ X-ray photoelectron spectroscopy. Robust SEI in HCE is due to difference in anion structure studied by Raman spectroscopy.Furthermore, the charge-discharge mechanism, alkali ion diffusion kinetics and structure-activity relationship of electrode materials was investigated using various techniques like cyclic voltammetry profiles at different scan rates and Galvanostatic intermittent titration technique (GITT). Additionally, deeper insights into the fundamental understanding of interfacial and bulk behavior were provided with the help of in-situ Raman spectroscopy and in-situ potentiostatic electrochemical impedance spectroscopy (PEIS) analysis. The investigation of peak area and shift in D (defect) and G (graphitic) band analyzed from in-situ Raman studies helped in understanding the evolution and reversibility of alkali ion storage behavior during charging and discharging. PEIS analysis gave us a thorough understanding of the evolution of stable SEI on charging-discharging and after cycling, which helps us to understand the long-term stability in LIB, SIB and PIB.

Biphenylite as Anode Materials for Alkali Metal Ion Batteries with Self-Enhanced Storage Mechanism.

In this work, we theoretically investigate the feasibility of biphenylite, the van der Waals layered bulk structure from experimental biphenylene network monolayers, as an anode material for alkali metal ions. The results indicate that the theoretical properties of Li, Na, and K in biphenylite are generally beyond those in graphite. Li-biphenylite exhibits a high specific capacity of 744 mAh·g-1, with a corresponding voltage range of 0.90-0.36 V, low diffusion barrier (<0.30 eV), and small volume change (∼9.9%), far exceeding those of Li-graphite. Moreover, a novel self-enhanced storage mechanism is observed and unveiled, in which the heavy intercalation of Li atoms (i.e., electron doping) induces puckered distortion of the nonhoneycomb carbon frameworks to enhance the intercalation ability and capacity of Li ion via a chemical activation of carbon frameworks. Possessing excellent anode performance beyond graphite, biphenylite is a promising "all-around" anode material candidate for alkali metal ion batteries, especially for lithium ion batteries.

Highly Conductive and Stable Two-Dimensional WC4 Acting as an Efficient Anode Material for Alkali-Metal Ion Batteries: Insight from DFT

Highly Conductive and Stable Two-Dimensional WC₄ Acting as an Efficient Anode Material for Alkali-Metal Ion Batteries: Insight from DFT

Theoretical prediction of stable WB4 monolayer as a high-capacity anode material for alkali-metal ion batteries

As a rapidly evolving 2D monolayer material, tungsten tetraboride MBene exhibits innate advantages in electrochemical applications because of its unique graphene-like structure and metallic properties. In this study, we utilized first-principles calculations to identify the potential applications of WB4 as an anode material in rechargeable alkali-metal-ion batteries. The findings imply that the Li, Na, and K adsorption on the WB4 surface results in exceptionally high conductivity, and the WB4 monolayer can effectively adsorb these ions with significant adsorption energies of −2.516 eV, −2.356 eV, and −2.941 eV for Li, Na, and K ions, respectively. The results indicate that WB4 exhibits excellent stability during lithiation, sodiation, and potassiation. Notably, we propose high storage capacities for LIBs (708mAh/g), SIBs (472mAh/g), and KIBs (177 mAh/g), with maintained structural stability for the adsorption of these metal ions. The measured average open circuit voltages for WB4 were found to be 0.77 V (Li), 0.73 V (Na), and 0.80 V (K), and metallicity remain good maintained within the entire adsorption process. The calculated migration energy barriers for Li, Na, and K were 0.47 eV,0.21 eV and 0.13 eV respectively. The notable properties of WB4 make it an advantageous electrode material for alkali-metal ion batteries.

Long Cycle Life for Rechargeable Lithium Battery using Organic Small Molecule Dihydrodibenzo[c,h][2,6]naphthyridine-5,11-dione as a Cathode after Isoindigo Pigment Isomerization.

Sustainability and adaptability in structural design of the organic cathodes present promises for applications in alkali metal ion batteries. Nevertheless, a formidable challenge lies in their high solubility in organic electrolytes, particularly for small molecular materials, impeding cycling stability and high capacity. This study focuses on the design and synthesis of organic small molecules, the isomers of (E)-5,5'-difluoro-[3,3'-biindolinylidene]-2,2'-dione (EFID) and 3,9-difluoro-6,12-dihydrodibenzo [c, h][2,6]naphthyridine-5,11-dione (FBND). While EFID, characterized by a less π-conjugated structure, exhibits subpar cycling stability in lithium-ion batteries (LIBs), intriguingly, another isomer, FBND, demonstrates exceptional capacity and cycling stability in LIBs. FBND delivers a remarkable capacity of 175mAhg-1 at a current density of 0.05Ag-1 and maintains excellent cycling stability over 2000 cycles, retaining 90% of its initial capacity. Furthermore, an in-depth examination of redox reactions and storage mechanisms of FBND are conducted. The potential of FBND is also explored as an anode in lithium-ion batteries (LIBs) and as a cathode in sodium-ion batteries (SIBs). The FBND framework, featuring extended π-conjugated molecules with an imide structure compared to EFID, proves to be an excellent material template to develop advanced organic small molecular cathode materials for sustainable batteries.

Simultaneous Catalytic Acceleration of White Phosphorus Polymerization and Red Phosphorus Potassiation for High-Performance Potassium-Ion Batteries.

Red phosphorus (P) as an anode material of potassium-ion batteries possesses ultra-high theoretical specific capacity (1154mAhg-1 ). However, owing to residual white P during the preparation and sluggish kinetics of K-P alloying limit its practical application. Seeking an efficient catalyst to address the above problems is crucial for the secure preparation of red P anode with high performance. Herein, through the analysis of the activation energies in white P polymerization, it is revealed that the highest occupied molecular orbital energy of I2 (-7.40eV) is in proximity to P4 (-7.25eV), and the lowest unoccupied molecular orbital energy of I2 molecule (-4.20eV) is lower than that of other common non-metallic molecules (N2 , S8 , Se8 , F2 , Cl2 , Br2 ). The introduction of I2 can thus promote the breaking of the P─P bond and accelerate the polymerization of white P molecules. Besides, the ab initio molecular dynamics simulations show that I2 can enhance the kinetics of P-K alloying. The as-obtained red P/C composites with I2 deliver excellent cycling stability (358mAhg-1 after 1200 cycles at 1Ag-1 ). This study establishes catalysis as a promising pathway to tackle the challenges of P anode for alkali metal ion batteries.

Machine learning in metal-ion battery research: Advancing material prediction, characterization, and status evaluation

Metal-ion batteries (MIBs), including alkali metal-ion (Li+, Na+, and K+), multi-valent metal-ion (Zn2+, Mg2+, and Al3+), metal-air, and metal-sulfur batteries, play an indispensable role in electrochemical energy storage. However, the performance of MIBs is significantly influenced by numerous variables, resulting in multi-dimensional and long-term challenges in the field of battery research and performance enhancement. Machine learning (ML), with its capability to solve intricate tasks and perform robust data processing, is now catalyzing a revolutionary transformation in the development of MIB materials and devices. In this review, we summarize the utilization of ML algorithms that have expedited research on MIBs over the past five years. We present an extensive overview of existing algorithms, elucidating their details, advantages, and limitations in various applications, which encompass electrode screening, material property prediction, electrolyte formulation design, electrode material characterization, manufacturing parameter optimization, and real-time battery status monitoring. Finally, we propose potential solutions and future directions for the application of ML in advancing MIB development.

Revealing bimetallic synergy in van der Waals AgInP2Se6 nanosheets for alkali metal ion battery electrodes

We report two-dimensional AgInP2Se6 (AIPSe) bimetallic phosphorus trichalcogenides nanosheets as anodes for advanced alkali metal ion batteries (AMIBs). The intrinsic layered architecture of this compound not only facilitates rapid charge propagation but also accentuates ion storage due to its expansive surface area. The integration of the bimetallic component results in a synergistic enhancement in electronic/ionic conductivity and optimizes the redox dynamics of multi-electronic materials, eventually attaining superior electrochemical characteristics. Moreover, the accompanying deposition of metallic silver during electrochemical processes reduces battery polarization, while the presence of metallic indium acts as an efficacious structural stabilizer, effectively inhibit dendrite proliferation. As an anode electrode coupled with graphite (G) in lithium-ion (LIBs) and potassium-ion batteries (PIBs), AIPSe@G anodes for LIBs achieve 707.8 mA h g−1 at 0.1 A g−1, retain over 900 cycles at 2.0 A g−1, and demonstrate 318.5 mA h g−1 at 3.0 A g−1 rate capability. For PIBs, they reach 480.3 mA h g−1 at 25.0 mA g−1, sustains for 550 cycles at 250 mAg−1, and offers 214.2 mA h g−1 at 3.0 A g−1 rate performance. Comprehensive full cell tests further endure 100 cycles in both LIBs and PIBs under diverse current regimes. Our study pioneers a new direction for AMIB anode materials, emphasizing the advantages of integrating bimetallic features into two-dimensional frameworks to boost electrode dynamics and achieve consistent conversion reactions.

ZnS/SnS2 Heterostructures Encapsulated in N-Doped Carbon Nanofibers for High-Performance Alkali Metal-Ion Batteries.

Heterogeneous composite ZnS/SnS2 is designed to meet various requirements for alkali metal-ion batteries. The composite is prepared using an electrostatic spinning method and encapsulated in N-doped carbon fibers after high-temperature vulcanization. The special structure of the composite provides a dependable interconnection and fast conductive network for alkali metal ions. The conductive carbon network shortens the diffusion path and greatly improves the migration efficiency of the alkali metal ions in the electrode. As expected, when the current density is 0.1 A g-1, the ZnS/SnS2@NCNFs maintain a high discharge capacity of more than 1437.5, 1321.2, and 861.6 mA h g-1 for lithium-ion, sodium-ion, and potassium-ion batteries, respectively. What is more, a full cell using a prelithiated composite anode and a LiFePO4 cathode is tested and shows excellent electrochemical performance. This work provides new perspectives for the development of novel anodes that can efficiently store alkali metal ions, as well as for the fine-structure design of materials.

Design and Construction of Carbon-Coated Fe3 O4 /Cr2 O3 Heterostructures Nanoparticles as High-Performance Anodes for Lithium Storage.

Transition metal oxides, highly motivated anodes for lithium-ion batteries due to high theoretical capacity, typically afflict by inferior conductivity and significant volume variation. Architecting heterogeneous structures with distinctive interfacial features can effectively regulate the electronic structure to favor electrochemical properties. Herein, an engineered carbon-coated nanosized Fe3 O4 /Cr2 O3 heterostructure with multiple interfaces is synthesized by a facile sol-gel method and subsequent heat treatment. Such ingenious components and structural design deliver rapid Li+ migration and facilitate charge transfer at the heterogeneous interface. Simultaneously, the strong coupling synergistic interactions between Fe3 O4 , Cr2 O3 , and carbon layers establish multiple interface structures and built-in electric fields, which accelerate ion/electron transport and effectively eliminate volume expansion. As a result, the multi-interface heterostructure, as a lithium-ion battery anode, exhibits superior cycling stability maintaining a reversible capacity of 651.2 mAh g-1 for 600 cycles at 2 C. The density functionaltheorycalculations not only unravel the electronic structure of the modulation but also illustrate favorable lithium-ion adsorption kinetics. This multi-interface heterostructure strategy offers a pathway for the development of advanced alkali metal-ion batteries.

Magnesium ion-doped layered oxide cathodes for alkali-metal ion batteries: Recent research progress and outlook

With the widespread application of electrical energy storage technology, it is particularly essential to develop a new generation of rechargeable batteries with low cost, high capacity, and long cycle life. Alkali-metal ion batteries (AIBs) have attracted great attention in the field of secondary batteries due to their high capacity and impressive rate and cycle performance. As a typical class of AIB cathode material, transition metal (TM) layered oxides have been widely studied and applied by virtue of their unique structure and excellent tunability, but there are still some limitations such as poor capacity retention and inferior structural stability. To date, various modification strategies have been investigated to address these issues. In particular, heteroatom doping is considered to be an effective strategy to modify the lattice architecture of cathode materials. This review summarizes the effect of magnesium ion doping on the structure and performance of AIBs, including alkali metal site doping and TM site doping. Specifically, Mg doping can stabilize the structure, eliminate the order, increase conductivity, and enhance the kinetics, which are beneficial to improve the performance of AIBs. Moreover, some typical materials synthesis methods and in-situ characterization techniques for mechanistic studies are also discussed. Finally, the future development trend of electrode doping strategies for advanced AIBs is analyzed.

Graphene-like AlP3 monolayer: A high-performance anode material for Li/Na/K-ion batteries

The rational design of anode materials with high capacity, good stability, and fast diffusion rate are crucial demands for rechargeable alkali metal ion batteries (AMIBs). Herein, the density functional theory calculations have been carried out to investigate the feasibility of an AlP3 monolayer with folded graphene-like structure as an anode material for AMIBs. The results indicated that the alkali metal atoms (AM = Li, Na, and K) can be stably adsorbed on the AlP3 monolayer surface and further enhance the conductivity of the system. The average open-circuit voltages are only 0.70 V, 0.28 V, and 0.37 V for Li, Na, and K storages, respectively. The diffusion energy barriers of Li, Na, and K atoms are 0.56 eV, 0.41 eV, and 0.20 eV, respectively. Furthermore, the AlP3 monolayer possesses a high theoretical specific capacity of 447 mAh g−1, 894 mAh g−1, and 1565 mAh g−1 for Li, Na, and K-ion batteries, respectively. Overall, the AlP3 monolayer is an excellent anode material for AMIBs, especially for K-ion batteries.

Metal Phosphorous Chalcogenide: A Promising Material for Advanced Energy Storage Systems.

The development of efficient and affordable electrode materials is crucial for clean energy storage systems, which are considered a promising strategy for addressing energy crises and environmental issues. Metal phosphorous chalcogenides (MPX3 ) are a fascinating class of two-dimensional materials with a tunable layered structure and high ion conductivity, making them particularly attractive for energy storage applications. This review article aims to comprehensively summarize the latest research progress on MPX3 materials, with a focus on their preparation methods and modulation strategies. Additionally, the diverse applications of these novel materials in alkali metal ion batteries, metal-air batteries, and all-solid-state batteries are highlighted. Finally, the challenges and opportunities of MPX3 materials are presented to inspire their better potential in energy storage applications. This review provides valuable insights into the promising future of MPX3 materials in clean energy storage systems.

Synergisticγ-In2 Se3 @rGO Nanocomposites with Beneficial Crystal Transformation Behavior for High-Performance Sodium-Ion Batteries.

Crystal transformation of metal compound cathodes during charge/discharge processes in alkali metal-ion batteries usually generates profound impact on structural stability and electrochemical performance, while the theme in anode materials, which always occurs and completes during the first redox cycle, is rarely explored probably due to the fast transformation dynamics. Herein, for the first time, a unique crystal transformation behavior with slow dynamics in anode of sodium-ion batteries (SIBs) is reported, which further promotes electrochemical performance. Specifically, irreversible γ → β crystal transformation of In2 Se3 is observed, induced by the persistent size degradation of In2 Se3 particles during repeated sodiation/desodiation, supported by a series of ex situ characterizations, such as HRTEM, XRD, and XPS of γ-In2 Se3 /reduced graphene oxide (γ-In2 Se3 @rGO) nanocomposite. The hybrid electrode shows ultrahigh long-term cycling stability (378mA h g-1 at 1.0 A g-1 after 1000 cycles) and excellent rate capability (272mA h g-1 at 20.0 A g-1 ). Full battery with Na3 V2 (PO4 )3 cathode also manifests superior performance, promising β-In2 Se3 dominated electrode materials in high-power and long-life SIBs. The first-principle calculations suggest the crystal transformation enhances electric conductivity of β-In2 Se3 and facilitates its accessibility to sodium. In combination with the synergistic effect between rGO matrix, substantially enhanced electrochemical performance is realized.

Colossal Stability of SiB11 (BO)12 - : An Implication as Potential Electrolyte in High-Voltage Alkali-ion Battery.

High-voltage alkali metal-ion batteries (AMIBs) require a non-hazardous, low-cost, and highly stable electrolyte with a large operating potential and rapid ion conductivity. Here, we have reported a halogen-free high-voltage electrolyte based on SiB11 (BO)12 - . Because of the weak π-orbital interaction of -BO as well as the mixed covalent and ionic interaction between SiB11 -cage and -BO ligand, SiB11 (BO)12 - has colossal stability. SiB11 (BO)12 - possesses extremely high vertical detachment energy (9.95 eV), anodic voltage limit (∼10.05 V), and electrochemical stability window (∼9.95 V). Furthermore, SiB11 (BO)12 - is thermodynamically stable at high temperatures, and its large size allows for faster cation movement. The alkali salts MSiB11 (BO)12 (M=Li, Na, and K) are easily dissociated into ionic components. Electrolytes based on SiB11 (BO)12 - greatly outperform commercial electrolytes. In short, SiB11 (BO)12 - -based compound is demonstrated to be a high-voltage electrolyte for AMIBs.

Solution-based self-assembly synthesis of two-dimensional-ordered mesoporous conducting polymer nanosheets with versatile properties.

Conducting polymers with conjugated backbones have been widely used in electrochemical energy storage, catalysts, gas sensors and biomedical devices. In particular, two-dimensional (2D) mesoporous conducting polymers combine the advantages of mesoporous structure and 2D nanosheet morphology with the inherent properties of conducting polymers, thus exhibiting improved electrochemical performance. Despite the use of bottom-up self-assembly approaches for the fabrication of a variety of mesoporous materials over the past decades, the synchronous control of the dimensionalities and mesoporous architectures for conducting polymer nanomaterials remains a challenge. Here, we detail a simple, general and robust route for the preparation of a series of 2D mesoporous conducting polymer nanosheets with adjustable pore size (5-20 nm) and thickness (13-45 nm) and controllable morphology and composition via solution-based self-assembly. The synthesis conditions and preparation procedures are detailed to ensure the reproducibility of the experiments. We describe the fabrication of over ten high-quality 2D-ordered mesoporous conducting polymers and sandwich-structured hybrids, with tunable thickness, porosity and large specific surface area, which can serve as potential candidates for high-performance electrode materials used in supercapacitors and alkali metal ion batteries, and so on. The preparation time of the 2D-ordered mesoporous conducting polymer is usually no more than 12 h. The subsequent supercapacitor testing takes ~24 h and the Na ion battery testing takes ~72 h. The procedure is suitable for users with expertise in physics, chemistry, materials and other related disciplines.

High-Performance Alkali Metal Ion Storage in Bi2Se3 Enabled by Suppression of Polyselenide Shuttling Through Intrinsic Sb-Substitution Engineering.

Bismuth selenide holds great promise as a kind of conversion-alloying-type anode material for alkali metal ion storage because of its layered structure with large interlayer spacing and high theoretical specific capacity. Nonetheless, its commercial development has been significantly hammered by the poor kinetics, severe pulverization, and polyselenide shuttle during the charge/discharge process. Herein, Sb-substitution and carbon encapsulation strategies are simultaneously employed to synthesize SbxBi2-xSe3 nanoparticles decorated on Ti3C2Tx MXene with encapsulation of N-doped carbon (SbxBi2-xSe3/MX⊂NC) as anodes for alkali metal ion storage. The superb electrochemical performances could be assigned to the cationic displacement of Sb3+ that effectively inhibits the shuttling effect of soluble polyselenides and the confinement engineering that alleviates the volume change during the sodiation/desodiation process. When used as anodes for sodium- and lithium-ion batteries, the Sb0.4Bi1.6Se3/MX⊂NC composite exhibits superior electrochemical performances. This work offers valuable guidance to suppress the shuttling of polyselenides/polysulfides in high-performance alkali metal ion batteries with conversion/alloying-type transition metal sulfide/selenide anode materials.

Recent Progress of Self-Supported Metal Oxide Nano-Porous Arrays in Energy Storage Applications.

The demand for high-performance and cost-effective energy storage solutions for mobile electronic devices and electric vehicles has been a driving force for technological advancements. Among the various options available, transitional metal oxides (TMOs) have emerged as a promising candidates due to their exceptional energy storage capabilities and affordability. In particular, TMO nanoporous arrays fabricated by electrochemical anodization technique demonstrate unrivaled advantages including large specific surface area, short ion transport paths, hollow structures that reduce bulk expansion of materials, and so on, which have garnered significant research attention in recent decades. However, there is a lack of comprehensive reviews that discuss the progress of anodized TMO nanoporous arrays and their applications in energy storage. Therefore, this review aims to provide a systematic detailed overview of recent advancements in understanding the ion storage mechanisms and behavior of self-organized anodic TMO nanoporous arrays in various energy storage devices, including alkali metal ion batteries, Mg/Al-ion batteries, Li/Na metal batteries, and supercapacitors. This review also explores modification strategies, redox mechanisms, and outlines future prospects for TMO nanoporous arrays in energy storage.

In-situ-grown multidimensional Cu-doped Co1-xS2@MoS2 on N-doped carbon nanofibers as anode materials for high-performance alkali metal ion batteries

Transition metal sulfides with the high theoretical capacity and low cost have been considered as advanced anode candidate for alkali metal ion batteries, but suffered from unsatisfactory electrical conductivity and huge volume expansion. Herein, a multidimensional structure Cu-doped Co1-xS2@MoS2 in-situ-grown on N-doped carbon nanofibers (denoted as Cu-Co1-xS2@MoS2 NCNFs) have been elaborately constructed for the first time. The bimetallic zeolitic imidazolate framework CuCo-ZIFs were encapsulated in the one-dimensional (1D) NCNFs through an electrospinning route and then on which the two-dimensional (2D) MoS2 nanosheets were in-situ grown via a hydrothermal process. The architecture of 1D NCNFs can effectively shorten ion diffusion path and enhance electrical conductivity. Besides, the formed heterointerface between MOF-derived binary metal sulfides and MoS2 can provide extra active centers and accelerate reaction kinetics, which guarantee a superior reversibility. As expected, the resulting Cu-Co1-xS2@MoS2 NCNFs electrode delivers excellent specific capacity of Na-ion batteries (845.6 mAh/g at 0.1 A/g), Li-ion batteries (1145.7 mAh/g at 0.1 A/g), and K-ion batteries (474.3 mAh/g at 0.1 A/g). Therefore, this innovative design strategy will bring a meaningful prospect for developing high-performance multi-component metal sulfides electrode for alkali metal ion batteries.