As the semiconductor industry drives to more functionality in smaller and lighter devices, it requires new materials to meet the changing requirements of new and more advanced chip designs and packaging solutions. Photoimagable polymeric dielectric materials are a key building block for wafer level packaging (WLP); these include polyimide (PI), polybenzoxazole (PBO), acrylics, silicones, epoxy-phenolics and benzocyclobutene (BCB). Because of low copper diffusion, low temperature curing, high reliability and low moisture adsorption, BCB was the platform chosen for modification. In this work, we will focus on the development of self priming, low stress, aqueous developable version of BCB, known as AD-BCB. This new photodielectric material has improved mechanical properties of <25MPa film stress value and >28% elongation while maintaining good post develop and post cure adhesion on various substrates including silicon, silicon oxide, silicon nitride, copper, aluminum and epoxy molding compound. Elongation is significantly increased for this positive tone, aqueous developable, photodielectric materials, while film stress and wafer bow are significantly reduced. In addition, this new formulation is self priming and does not require a spin-on adhesion promoter. The material can be cured at as low as 200 °C with lithographic feature size of <10 μm and dielectric constant of 3.0.