Wrinkle Recovery Research Articles

Comparative study of polycarboxylic acids for sustainable crosslinking of silk fabrics: Evaluating flame retardancy and physical performances

For protein fibers, polycarboxylic acids represent a green strategy to enhance durability without using formaldehyde. This study evaluated the physical and flame retardant properties of silk fabrics treated with three formaldehyde-free crosslinkers: citric acid (CA), 1,2,3,4-butanetetracarboxylic acid (BTCA), and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA). Results showed that these acids bond with silk protein through esterification and amidation, improving washing durability. Particularly, PBTCA integrates phosphorus into silk, boosting flame retardancy. While BTCA led to the highest weight gain and improved wrinkle recovery, it negatively impacted the tensile strength and softness of silk fabrics. Conversely, PBTCA adeptly balanced enhanced wrinkle resistance with minimal effects on tensile strength and softness, and least affected the silk fabrics' whiteness, thus preserving its aesthetic appeal. All crosslinkers improved flame retardancy, but PBTCA displayed superior performance, achieving a limiting oxygen index of 32.4 % at an 80 g/L concentration. In vertical burning tests, PBTCA treated silk fabrics showed reductions in damage length and demonstrated self-extinguishing properties, qualifying them for a higher flame retardant grade. Phosphorus in PBTCA promotes char formation during combustion, essential for effective flame retardation and smoke reduction. This research highlights the exceptional potential of silk treated with PBTCA, showcasing its suitability for demanding applications.

Effect of in-situ deposition of nano-calcium carbonate on the properties of anti-creasing cotton fabrics

Cotton fabrics exhibit excellent moisture absorption and breathability, which makes them comfortable to wear. However, they lack natural wrinkle resistance due to their poor anti-creasing performance and shape retention. Currently, anti-creasing finishing is widely applied to cotton fabrics; however, a contradiction exists between the anti-creasing effect and strength loss. To overcome this trade-off, a chemical deposition method was used to generate in-situ nano-calcium carbonate particles on anti-creasing cotton fibers. These particles effectively fill the micropores and microcracks in the anti-creasing cotton fibers, thereby improving the strength of the fabric. Scanning electron microscopy, wrinkle recovery angle, Fourier transform infrared spectroscopy and X-ray diffraction, and contact angle were used to characterize and analyze the changes in surface morphology, wrinkle resistance, chemical structure, and hydrophilicity of anti-creasing cotton fabrics before and after deposition treatment, respectively. Following nanoparticle deposition, the breaking strength of the anti-creasing cotton fabrics increased by approximately 11–14 %, whereas no significant changes were observed in their wrinkle recovery angle, chemical structure, and hydrophilicity. In addition, the crystallinity index increased after treatment and the washing durability of the deposited nanoparticles was excellent. This study demonstrates a method for overcoming the long-standing trade-off between the anti-creasing effect and strength loss and fills the gap in the field of non-destructive strength repair of anti-creasing cotton fabrics. The study findings provide important data for improving the strength of anti-creasing cotton fabrics. The proposed treatment method is inexpensive, simple, highly efficient, and harmless, and is expected to have bright prospects in future industrial applications.

Surface Modification of Viscose Fabric with Silane Coupling Agents ‐ An Aspect of Comfort Properties

AbstractThe surface of viscose fabric was successfully functionalized with 3‐aminopropyltriethoxysilane (APS) and 3‐methacryloxypropyl‐trimethoxysilane (MPS) in order to optimize its physicochemical characteristics and textile performances. The functionalization was optimized with silane monomer concentrations of 600 and 300 %, ethanol‐water ratios of 60 : 40 and 80 : 20, pH 3.5 and 5, and reaction time of 90 and 60 min at 30 °C, for MPS and APS, respectively. The modified viscose fabric was characterized by FTIR, TGA, DTG, SEM, and EDX. The FTIR spectra of the MPS and APS‐modified fabrics showed additional peaks at 825 cm−1 for Si−CH2 group and 1208 cm−1 Si−O−CH3, respectively, indicating the incorporation of silane coupling agents. The degradation temperatures of MPS and APS‐modified fibres were 342 °C and 328 °C, respectively, while the value for untreated viscose fibre was 319 °C. The elemental percentage of silicone on viscose fibre after modification was 2.6 and 4.2 for MPS and APS respectively. The silane‐modified viscose fibre shown enhanced tensile strength, water repellency, thermal stability, wrinkle recovery, and improved colour fastness quality. These improvements were due to the flexibility of Si−O bond and the fibre matrix interfacial strength properties. Hence, the modification somewhat enhances the physico‐chemical characteristics of viscose fibre.

The effect of cyclic wrinkling on the durability of waterproof breathable functional outdoor materials for sportswear

The main goal of this article is to analyze the resistance of high-tech sportswear fabrics (especially laminated fabrics with membranes) to moisture management after the simulation of real wear. Therefore, a new device, cyclic wrinkle recovery tester (CWR Tester), was designed and constructed. The device simulates the wrinkling behavior of textiles during wearing by repeated both twisting and compression strain. The nine waterproof materials (five samples of three-layer structure and three samples of two-layer version of waterproof textiles and one softshell) were tested before and after cyclic wrinkling processes in order to find out the level of their hydrostatic resistance (HR) and water vapor resistance (Ret). To find out the performance of these high-tech materials, the range of loading cycles from 1,000 to 20,000 was applied within the tests by CWR Tester. In summary, a significant decrease in the hydrostatic resistance of the tested three-layer and two-layer structure of waterproof textiles (up to 90% from the original level of HR) was shown after cyclic wrinkling. Further, a slight decrease in water vapor resistance was noticed (a maximum of 7%). It may be explained by the fact that the membrane in the tested samples was partially damaged via cycling loading, as having been shown by the scanning electron microscopy images.

Clean dyeing of cotton fabrics by cross-linking reactive dyes with fiber macromolecular chains

Increasing dye utilization, shortening the process and reducing the discharge of colored wastewater are the keys to clean dyeing and finishing of fabrics. In this study, we report a clean dyeing process. The process improved the dye utilization and achieved wrinkle-finishing and dyeing in the same bath by enhancing cross-linking of dyes with fiber macromolecular chains. It was observed by SEM that the cross-section of the dyed fibers showed round or oval shape, and the mid-cavities were reduced or even disappeared. The swelling rate of the fibers and cellulase degradation experiments showed that the dyes formed stable cross-linking structures with the macromolecular chains. Furthermore, differences in the structure of reactive dyes affected the optimal reaction conditions between the dyes and the fibers. Compared to conventional processes, the K/S, color fixation rate, and wrinkle recovery angle of dyed fabrics with different dyes were significantly improved. This illustrated the superiority of this process and the applicability of different structural dyes. Compared to traditional processes, the process saved 29.6 % of dyes and 16.7 % of alkalis. Importantly, the process could save 200 % of water, 9.5 kW h of energy consumption and 61.6 m3 of saturated steam. Ultimately, this process could save 7.22 $ of the cost of dyeing 1 kg of fabric. The concentration of dyes in the dyeing wastewater was significantly reduced. In summary, the clean process has good economic and environmental benefits.

Cotton–Cork Blended Fabric: An Innovative and Sustainable Apparel Textile for the Fashion Industry

Cotton is a preferred textile fiber for apparel textiles and is used primarily for summer wear. However, cotton has drawbacks, such as poor wrinkle resistance, and therefore, blends of cotton with other fibers have gained acceptance in the industry. In this study, a novel 90:10 cotton–cork blended fabric was studied for its physical and performance properties and benchmarked against a 100% cotton fabric. Fabric samples were analyzed to determine the wrinkle recovery angle, tenacity, abrasion resistance, shrinkage, CLO value, moisture absorption, and dyeability. The samples were further analyzed using SEM, DSC, and FTIR. The results showed significant differences between the two fabrics. Cotton–cork blended textile fabric had higher performance properties with the potential to be a viable, sustainable apparel textile.

Multifunctional ammonium polyphosphate coated cotton fabric for flame retardant, anti-wrinkle, ultraviolet protection and anti-bacterial

The multifunctional cotton fabrics, which were expected to become one of the most promising textile materials, gained much attention in the apparel market. In this work, the simultaneous coloration and finishing processes with natural dye were carried out to prepare the multifunctional cotton fabrics. The modification process using ammonium polyphosphate (APP) imparted the cotton fabric with numerous anionic sites along with flame retardant and anti-wrinkle properties. Subsequently, the implementation of coloration with berberine was to render the cotton fabric with elegant shade and anti-bacterial, ultraviolet (UV) protection performances. The obtained results revealed that the cotton fabric treated with APP could obtain deep shade. It was found that the limited oxygen index (LOI), wrinkle recovery angle (WRA), ultraviolet protection factor (UPF) and antibacterial efficiency of treated fabric were 46.4%, 252°, 193 and 99%, respectively. More importantly, the repeated laundering showed negligible influence on the flame retardant and anti-wrinkle performances. In addition, the anti-bacterial and UV protection performance of treated cotton fabric exhibited a slight decline even after 20 cycles of washing. Finally, the washing and rubbing fastness of obtained cotton fabric were also desirable.

Synthesis of castor oil/PEG as textile softener

New castor oil/polyethylene glycol (CAO/PEG) hybrids were synthesized by reacting of CAO with PEG 300, 600, 1000, 2000 or 4000, in presence of ammonium per sulfate (APS) as an initiator. The optimum conditions to synthesis such hybrids are: PEG/CAO weight ratio, 35%; APS/PEG weight ratio, 15%; reaction temperature, 80 °C; and reaction time, 60 min. Only the hybrids based on PEG 1000 and 2000 formed oil in water stable emulsions. Treating cotton fabric samples with easy care finishing formulation containing 40 g/L of the synthesized hybrids emulsions results in an enhancement in softness, tensile strength, whiteness index, and stiffness along with a reduction in nitrogen content, wrinkle recovery angle, and wettability properties of treated fabric, compared to that sample finished in absence of that emulsions. The chemical structure of the synthesized CAO/PEG1000 hybrid was confirmed via the FTIR and 1HNMRanalysis whereas the TEM analysis showed that the particles size of that hybrid emulsion is in the range of 27–105 nm. Moreover, such hybrid emulsion treated fabric surface was characterized via SEM and EDX analysis. Furthermore, treating dyed samples with the nominated hybrid emulsion improves the color strength of that samples but keeps the washing fastness, wet rubbing fastness as well as alkaline perspiration fastness of the dyed/finished samples unchanged. The wet rubbing fastness and alkaline perspiration fastness of all the dyed/finished samples were enhanced while the light fastness of such samples decreased.

Preparation of multifunctional cellulose macromolecule blended fabrics through internal and external synergy by N1, N6-bis (ethylene oxide-2-ylmethyl) hexane-1,6-diamine

With the diversification of people's demand for textile functions, the preparation of multifunctional fabrics is still a current research hotspot. In this study, the water-soluble epoxy compound N1, N6-bis(oxiran-2-ylmethyl) hexane-1,6-diamine (EH) was introduced into cellulose macromolecule blended fabrics (cotton/modal) by two-phase vaporization technique, resulting in excellent wrinkle, hydrophobicity, and certain UV protection effects. It could be observed by electron microscopy that EH formed a polymer film on the fiber surface. In addition, the results of EDS scans and fiber swelling rate tests showed that EH was uniformly distributed and formed a cross-linked structure in the amorphous zones inside the fibers. Compared with the control fabrics, the wrinkle recovery angle of the EH-treated fabric was increased by 39.7 %. The fabrics could reach a contact angle of 136.9°, providing excellent hydrophobic effect. In addition, the fabrics achieved certain UV protection effects (UPF of 50+). The EH-treated fabrics were less stabilized in strong acid and alkali conditions, but exhibited greater durability in other environments. In summary, the internal and external synergistic effects of EH in forming polymer films on the fibers surface and internal cross-linking structures provided a cleaner, simple, and feasible method for the preparation of multifunctional cellulose macromolecule fibers textiles.

PHYSICAL PROPERTIES CORRESPONDING TO COMFORT FEEL OF BEDDING FABRICS

The market for bedding products in Thailand now offers a wide range of physical attributes (fiber types, structures, fabric densities, thicknesses, and weights) that produce a variety of tactile sensations and comfort qualities. This study investigated the comfort properties of bedding fabrics in Thailand. Twenty-one bedding fabric samples were collected and measured for their mechanical and surface properties based on the Kawabata evaluation system for fabric (KES-F) as well as the horizontal wicking test and abrasion resistance, air permeability, wrinkle recovery, and thermal resistance (Qmax). The primary hand value (HV) and total hand value (THV) were calculated using the Kawabata hand evaluation equation KN-201-LDY describing women's thin dress fabric, using 5 different properties from the KES-F (tensile, shear, bending, compression, and surface friction). The principle component analysis (PCA) and cluster analysis of the physical properties of fabric samples showed that the samples could be placed in 4 groups. The first group was mostly cotton woven samples. The second group consisted of 2 samples that were both knitted, while the third group was mostly mixed (M) fabric samples. The last group contained cotton and M cotton samples. The first cluster was considered to provide the best hand-feel characteristics of all 4 clusters, while the second cluster was considered the least desirable based on hand-feel. The findings of this study should assist the bedding textile sector in developing new products.

The Intersection of Computational Design and Wearable‐Optimized Electrospun Structural Nanohybrids for Electromagnetic Absorption

AbstractBy leveraging the principles of electromagnetic theory and materials science, the characteristics of dielectric polymer composites can be optimized, eliminating repetitive trial‐and‐error in their application as electromagnetic absorbers (EMAs). Herein, a systematic framework for optimizing the thickness and composition of double‐layer EMAs is proposed, using a combination of transmission line, Debye relaxation, and Maxwell–Garnett theories. Following theoretical optimization, a double‐layered electrospun EMA is fabricated, which comprises a ≈1.17 mm thick matrix of styrene–butadiene–styrene (SBS) decorated with MXene on its fibrous structure. The second SBS layer, with a thickness of ≈0.52 mm, incorporates a hybrid of MXene and graphene nanoribbons (GNR) as conductive additives. The EMA exhibits durable electrical performance after 2000 tensile cycles, owing to the surface chemistry engineering and the novel in situ assembly technique. It is capable of shielding 99.9% of the incident wave and >80% absorptivity (A) over almost the entire Ku‐band. The EMA also exhibits desirable mechanical characteristics, such as >300% stretchability and full twist and wrinkle recoveries, making it an excellent choice for protective attire applications. Additionally, the introduced approach provides solutions for the advancement of tailorable polymer composite EMAs, with respect to specific criteria of the target wave frequency, effective absorption bandwidth, and absorption levels.

Investigating Wrinkle Resistance of Cotton and Cotton Blended Fabrics in Relation to a Non-Formaldehyde Durable Press Finish

This study investigated cotton fabric’s wrinkle resistance with a durable press finish, compared to 100% cotton and cotton blended fabrics. Wrinkle resistance of cotton fabrics can be achieved by using chemical resin finishes or blending with polyester, nylon, or spandex. Most of wrinkle resistance finishes contain harmful chemicals such as formaldehyde. However, a durable press finish through pad, dry, and cure fabric application process is treated with crosslinking resins, and it improves wrinkle resistance and is formaldehyde-free, making it a prime alternative to the wrinkle resistance finishes with formaldehyde. Eight different cotton and cotton-blended fabric samples were tested in relation to a non-formaldehyde durable press finish. The fabric samples were tested using AATCC 128 Wrinkle Recovery of Fabrics: Appearance Method. One-way between groups ANOVAs were conducted to examine how wrinkle resistance differs among the fabric samples, depending on fiber type, wrinkle resistant finishes, and non-formaldehyde durable press finish. Post-hoc comparisons using the Bonferroni test were also conducted. Results indicate that there were significant differences on wrinkle resistance by the different fiber contents and wrinkle resistance finishes. The 100% cotton fabric with the nonformaldehyde durable press finish showed greater wrinkle resistance than the other fabrics. The non-formaldehyde durable press finish also has other properties such as abrasion resistance, shape retention, pilling resistance, etc. Further research on these properties is needed to explore characteristics of the non-formaldehyde durable press finish, compared to other wrinkle resistant fabrics.

Highly efficient cross-linking of reactive dyes in the amorphous zones of cotton fabric to simultaneously improve color and wrinkle properties

Dyeing and wrinkle-finishing of cotton fabric is generally achieved through two steps, which consumes a lot of energy and generates a lot of colored wastewaters. In this study, we report an energy-saving and cost-reducing dyeing process that enhanced the cross-linking degree of double reactive group dye in the amorphous zone of cotton fabric, which in turn improved the wrinkle resistance of cotton fabric as well as the utilization of the dye. Compared with the traditional dyeing processes, the method could improve K/S values by 69.7%, dye fixation by 22.4%, and wrinkle recovery angle by 21.5% for dyed cotton fabric. The wrinkle recovery angle of the dyed cotton fabric increased with the increase of cross-linking degree. The cross-section of cotton fibers changed from a flattened girdle shape to an elliptical or rounded shape, and the mid-cavity structure became smaller or even disappeared. In addition, the cross-linked structures could hinder the degradation of fiber macromolecular chains by cellulases. This meant that the better the wrinkle resistance of the dyed cotton fabric, the lower the glucose content in the degradation solution. Compared with the conventional dyeing processes, this dyeing method could be saved 36.5% of dyes and 28.4% of alkali for per 1 kg of cotton fabric, and the cost could be saved by 56.1%. The dye concentration in the waste water was reduced by 43.2%. This method had certain advantages in terms of economic and environmental.

Development and Investigation of Hybrid Knitted Structures for Sensorial Comfort Properties. Part I - Tuck Stitches

ABSTRACT Sensorial evaluation plays an important role in the identification of materials in addition to technical specifications for the wearer. The current study focuses on the development of different hybrid knitted structures with different percentages of knit stitches and tuck. Hundred percent cotton was used to develop unique structures on the 4-cam track single jersey knitting machine. A total of 15 hybrid weft knitted structures are developed with different combinations of knit and tuck stitch percentages. The effects of different amount of knit and tuck stitches on physical parameters, e.g. area density, stitch density, and thickness, were characterized. Sensorial comfort, e.g. resilience, softness, smoothness, drape, and wrinkle recovery rate, were evaluated with the standard test method. After testing and data analysis, it was concluded that percentages of stitch types have a significant effect on the physical parameters and sensorial comfort properties of the fabrics.

Determining optimal drying conditions through analysis of the sample movement in a heat pump dryer

This study analyzes the effect of sample movement on the drying performance based on the drying conditions in a heat pump dryer. The sample movement changes are analyzed by controlling hot air flow into the drum and the mechanical force caused by drum rotation. A drying program is then developed for controlling the drying conditions. Considering the sample movement in the heat pump dryer, for the drum rotating at 50 rpm along with hot air flow, the sample mainly moves at the center of the drum, resulting in more changes in the local movement of the sample than those when only hot air is introduced, or only drum rotation is operated. Moreover, for the abovementioned condition, the drying period was the lowest and the wrinkle recovery is excellent, but the shrinkage increases. Therefore, by identifying the sample movements affecting the drying performance, the drying period decreases as the sample moves, occupying the entire space including the center of the drum. The shrinkage increases when the sample is at the center of the drum. However, it is advantageous for wrinkle recovery when the sample is in the first quadrant and tumbles. On this basis, the drying process is classified into three stages. Hot air flow, drum rotation speed, and drum rotation direction conditions are combined, resulting in efficient wrinkle recovery and shrinkage reduction simultaneously.

Structure and Properties of Natural Dye-Sensitized Nano-TiO2 Photocatalytic Self-Cleaning Cotton Fabrics

In this study the three natural dyes of madder, curcumin and gardenia blue were used as sensitizers to treat the nano-TiO2 which was prepared with the sol-gel method improved by plant honeysuckle extract, and then oxalic acid (OA) and citric acid (CA) were compounded as crosslinkers to modify the cotton fabric, The carboxyl groups on the modified cotton fabric can anchor the dye-sensitized nano-TiO2 to give it self-cleaning performance. Fourier Transform Infrared (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) showed that the dye-sensitized nano-TiO2 was successfully loaded on the surface of the cotton fabrics, and basically did not change their crystalline structure. UV-Visible diffuse reflectance spectra (UV-Vis-DRS) and Photoluminescence Spectroscopy (PL) spectra showed that, compared with nano-TiO2 photocatalytic cotton fabrics, the photocatalytic cotton fabric prepared from our dye-sensitized nano-TiO2 had a narrower band gap energy and a decrease in the recombination rate of electron-hole pairs. The cross-linked cotton fabric treated with dye-sensitized nano-TiO2 had excellent photocatalytic performance and washing resistance. In addition, the cross-linking treatment greatly improved the wrinkle recovery of the cotton fabrics, and the load of dye-sensitized nano-TiO2 endowed the fabric with excellent hydrophilic properties. but it also led to a certain degree of decrease in its breaking strength.

Cetylpyridinium chloride cationic finishing improves the dyeing and antibacterial properties of madder dyed cotton

AbstractIn this work, after cationic pretreatment of cotton fabric with cetylpyridinium chloride (CPC), the compound of citric acid (CA) and succinic acid (SUA) were used as crosslinking agents to dye cotton fabrics with natural madder dye to improve the dyeing and antibacterial properties and realise the multifunctional finishing of cotton fabric. The effects of mordant dyeing, CA + SUA crosslinked dyeing, and CPC/CA + SUA crosslinked dyeing on the microstructure and properties of cotton fabrics were compared. The dyeing by the three processes occurred primarily in the amorphous zone of the fibres, and all kept the original crystalline form of the cotton. CA + SUA crosslinked dyeing and CPC/CA + SUA crosslinked dyeing increased the thermal stability of the cotton fabric. CPC/CA + SUA crosslinked dyed cotton obtained excellent dyeing results with the colour depth value (K/S) of 12.3 and rubbing fastness and washing fastness of levels 4–5, and the levelness and dye permeability were acceptable. Furthermore, the antibacterial rate against Escherichia coli and Staphylococcus aureus reached 99.99%, and the ultraviolet protection factor (UPF) reached 50+. Moreover, the wrinkle recovery angle (WRA) increased by 55% compared with raw cotton. This showed that CPC/CA + SUA crosslinked dyed cotton had excellent antibacterial, anti‐ultraviolet, and anti‐wrinkle performances.

Effect of the direct introduction of disulfide groups with 2-iminothiolane hydrochloride on wrinkle recovery of natural protein fibers

To develop environmentally friendly natural protein fibers with good wrinkle recovery without changing their excellent physical properties, thiol groups were directly introduced into silk and wool fibers by chemical modification using 2-iminothiolane hydrochloride. Thereafter, disulfide (–SS–) groups were introduced by oxidative cross-linking. The wrinkle recovery of the wool fabrics improved with the increase in 2-iminothiolane hydrochloride concentration. In particular, introducing the reduction process between the 2-iminothiolane hydrochloride treatment and the oxidation process improved the wrinkle recovery of wool fabrics. In contrast, the silk fabrics treated with 0.04 wt% 2-iminothiolane hydrochloride exhibited good wrinkle recovery. In addition, combustion-ion chromatography revealed that sulfur was introduced into the silk fabrics by oxidation after 2-iminothiolane hydrochloride treatment. According to these experiments, directly introducing –SS– groups using 2-iminothiolane hydrochloride into silk and wool fibers effectively improves wrinkle recovery without changing the physical properties of natural protein fabrics.

A sustainable blend of Tencel/jute fibers as an alternative to cotton/polyester for clothing

The increasing concern about the environment has enhanced the utilization of sustainable products in every field of life, from common household items to fabrics. Although cotton is a plant-based fiber, its cultivation requires large amounts of water and pesticides. Therefore, the future of product development demands environmental friendliness. To overcome the problems of cotton related to the environment, a novel sustainable fabric was developed by using Tencel and jute fiber for the apparel industry to reduce the usage of cotton. In this current study, six blended yarns of two counts (10 & 20 Ne) of Tencel and jute (90:10, 80:20, and 70:30) were developed by ring spinning to weave fabric in two weave designs (Plain & Twill). These developed fabrics were assessed for mechanical, comfort, and hand properties. The results revealed that the blended fabric with a high content of Tencel is good in terms of mechanical, comfort, and hand properties, except for stiffness, pilling resistance, resilience, and drapeability. Additionally, fabric woven with a fine yarn count is also good in the above-stated properties, except for stiffness, resilience, and wrinkle recovery. However, fabrics woven with a twill weave design have good comfort and hand properties, except for smoothness and drapability. On the other hand, fabric with a plain weave design is good in terms of mechanical properties, except for tear strength. The comparison of TJ blended fabric with PC blended fabric shows that the tensile strength, air permeability and OMMC of JT blended fabric is 8.31%, 96%, and 29.46% higher than PC blended fabric but tear strength is 99% less. Furthermore, statistical analysis was performed to check the effect of the input variables on the response factors, and it was found that the effect of yarn count on all output responses is statistically the most significant.

Vinylated Modification of Biophytic Acid and Flame-Retardant/Crease-Proofing Finishing of Cotton Fabrics via In Situ Copolymerization

The vinyl phytic acid (GPA) was prepared using biophytic acid (PA) and glycidyl methacrylate (GMA), in which double bonds were introduced into the phytic acid molecule to increase the active groups in the phytic acid molecule. Furthermore, itaconic acid (IA) containing two unsaturated double bonds and GPA was polymerized in situ and crosslinked on the surface of cotton fabrics, and flame retardant and crease-proofed fabrics were obtained. The effects of GPA, IA, and the initiator on the flame-retardant and crease-proofing properties of the fabrics were analyzed by a single-factor and double-dip double-nip experiment. A flame-retardant and wrinkle-resistant fabric was obtained when the limiting oxygen index (LOI) and wrinkle recovery angle (WRA) were 28% and 270°, respectively. During combustion, the thermal properties of the fabrics changed; typically, the extrapolated initial temperature (Te) decreased, and moisture release increased. After burning, the fabrics had good shape retention, and the carbon residue content increased to 48%, which effectively inhibited or slowed down the combustion and heat release of the textiles. However, the whiteness, mechanical properties, and washability of the products need to be further improved.