Wrinkle Recovery Research Articles

Development of Bed Linen Performance Index

In order to develop the performance of the bed linen index objectively, the first seven properties of the fabric are selected by twenty-four experts subjectively, and these experts also give the weight for each property according to the necessity. These properties are total hand value (THV), moisture management, abrasion resistance, air permeability, wrinkle recovery, thermal resistance, and drape of fabric. After selecting the properties and the weight for each characteristic, an integrated index for bed linen performance value is developed. Before directly using the value of each property into the equation, normalization of data should be done to shrink the range of the data such that the range is fixed between 1 and 5. The correlation between subjective and objective evaluations was very high (r = 0.82). This indicates that the bed linen performance index could be estimated as well.

Dyeing Property Improvement of Madder with Polycarboxylic Acid for Cotton.

Cotton fabrics were dyed with the madder and compounds of citric acid (CA) and dicarboxylic acids [tartaric acid (TTA), malic acid (MLA), succinic acid (SUA)] as cross-linking agents and sodium hypophosphite (SHP) as the catalyst. The molecular structures and crystal structures of the dyed cotton fabrics were analyzed using Fourier-transform infrared spectroscopy (FTIR) and X-ray diffractometry (XRD), respectively. The results showed that the polycarboxylic acids esterified with the hydroxyl groups in the dye and cellulose, respectively, and the reaction mainly occurred in the amorphous region of the cotton fabric. Compared with the direct dyed cotton fabric, the surface color depth (K/S) values of the CA, CA+TTA, CA+MLA, CA+SUA cross-linked dyed cotton fabrics increased by approximately 160%, 190%, 240%, 270%, respectively. The CA+SUA cross-linked dyed cotton fabric achieved the biggest K/S value due to the elimination of the negative effect by α-hydroxyl in TTA and MLA on esterification reaction, and the cross-linked dyed cotton fabrics had great levelness property. The washing and rubbing fastness of the cross-linked cotton fabrics were above four levels. The light resistance stability and the antibacterial property of the cross-linked dyed cotton fabrics was obviously improved. The sum of warp and weft wrinkle recovery angle (WRA) of the CA+SUA cross-linked dyed cotton fabric was 55° higher than that of raw cotton fabric, and its average UV transmittance for UVA was less than 5% and its UPF value was 50+, showing a great anti-wrinkle and anti-ultraviolet properties.

Antibacterial cotton functionalized with olive oil for developing medical textiles

To promote the use of natural antimicrobial agents and to reduce the bad environmental impact caused due to synthetic agents, a novel finishing solution of olive oil along with ethanol has been developed and then applied on cotton fabric at different concentrations by pad-dry-cure method. The finished fabrics are characterized by SEM, FTIR & TGA methods. It is found that olive oil is successfully bonded on the cotton fabric. The antimicrobial property of finished fabric is evaluated by AATCC- 147 method. The treated fabrics show excellent resistance to both E.coli and S.aureus bacteria before and after washing. As the concentration of oil is increased, the antimicrobial efficiency is found to be higher. The whiteness index of treated fabrics is decreased, due to the formation of yellow patches on the fabric surface. Several physical properties, such as mass, tensile strength and wrinkle recovery angle have been analyzed. The results show that, there is an increase in mass and wrinkle recovery angle of finished the fabric. However, there is a reduction in the tensile strength of the cotton fabric. The above findings will promote the use of natural antimicrobial agents for the production of eco –friendly and sustainable antimicrobial textiles.

Screen printing of cellulose electrospun nanofibres with PDA polymer

Herein, the preparation of print paste formulation containing the PDA (Polydiacetylene) polymer has been investigated for the first time. Screen printing method was employed to apply the prepared print paste on cellulose ENMs, and the Electrospinning method was used to fabricate cellulose acetate ENM followed by its deacetylation to prepare CEL ENMs. Distinct blue colour was developed with 254 nm UV-irradiation of printed CEL ENMs. We achieved good colour strength (K/S = 3.1) on printed ENMs, excellent colourfastness to washing (staining on multifibre: rating 5) and colourfastness to light (blue wool scale: rating 1). We found that the printed CEL ENMs can be effectively used as thermochromic sensor as it induced blue-to-red colour transition at 80 °C. Moreover, it has demonstrated solvatochromic property when incubated in NaOH. Mechanical properties (Tensile strength and wrinkle recovery), chemical structure (ATR-FTIR spectroscopy) as well as surface morphology (SEM analysis) of ENMs were also determined.

A cleaner production process for high performance cotton fabrics

High performance cotton fabrics with color, luster and wrinkle resistance are manufactured by three steps. The coloration, wrinkle resistance and luster finishing consume a large number of resources, and generate a huge amount of colored wastewater. The present research reports a cleaner process for dyeing, wrinkle resistance and luster finishing of cotton fabrics. Cotton fabrics were dyed at 35 °C for 15 h with multifunctional reactive dye solutions of high concentrations. Scanning electron microscope images show the fiber cross sections became circular like the mercerized cotton fibers, and the fabrics exhibited nice luster and wrinkle resistant ability. For fabrics with light and middle color, a certain amount of 1,3,5-triacryloyhexahydro-1,3,5-triazine was added into the dye liquor to make the fiber cross section become circular and to make the wrinkle recovery angle reach more than 260° to obtain good wrinkle resistant ability. When the padded fabrics were steamed at 102 °C for 3 min instead of fixing at 35 °C for 15 h, the wrinkle recovery angle also reached 266°. The breaking strength of dyed fabrics decreased with increasing the dye and 1,3,5-triacryloyhexahydro-1,3,5-triazine concentrations. The enhancement of wrinkle resistance of dyed fabrics is due to the crosslink effect of the dye molecules with cellulose macromolecules. This one-step process will save a significant amount of energy and water, and reduce the effluent discharged.

Study on the Development of Antiviral Spandex Fabric Coated with Poly(hexamethylene biguanide) Hydrochloride (PHMB).

The spread of COVID-19 has brought about huge losses around the world. This study aims to investigate the applicability of PHMB used for developing antiviral spandex clothing against coronavirus. PHMB was qualitatively determined on the surface of spandex fabrics by using BPB. The antiviral analysis shows that the PHMB-treated spandex fabric can kill 99% of the coronavirus within 2 h of contact, which suggests that the spandex fabric treated with PHMB could be used for developing antiviral clothing against coronaviruses for containing the transmission of COVID-19 in high-risk places. Furthermore, PHMB-treated spandex fabrics were shown excellent antibacterial activity against gram-positive S. aureus and gram-negative K. pneumoniae. The hand feel properties of Spandex fabric were not significantly affected by the PHMB coating in addition to the wrinkle recovery, which was obviously improved after PHMB coating.

Improving the Dyeability and Anti-Wrinkle Properties of Cotton Fabric via Oxidized Raffinose

In the anti-wrinkle finishing of cotton fabrics, the decreased dyeability of the finished fabrics has always been a difficult problem. A new anti-wrinkle finishing mode was developed to solve this problem by changing the finishing sequence of fabric dyeing and anti-wrinkle. In this research, the partial oxidization of raffinose with sodium periodate generated multiple aldehydes, which acted as multifunctional cross-linkers and endowed cotton fabrics with anti-wrinkle and hydrophilic properties. The structural characteristics of oxyRa were analyzed by FTIR and 13C-NMR. Through response surface methodology (RSM), the finishing model of oxyRa was established from the influencing factors of catalyst concentration, pH, curing temperature and time, and the optimized finishing process: the catalyst concentration was 20.12 g/L, pH was 4.32, curing temperature was 150 °C and curing time was 120 s. Under this condition, the predicted wrinkle recovery angle (WRA) of the finished fabric was up to 249.76°, Tensile strength (TS) was 75.62%, Whiteness index (WI) was 70.69. Importantly, comparing the anti-wrinkle and dyeing performance of the fabric with anti-wrinkle and then dyeing and anti-wrinkle after dyeing, the oxyRa-treated fabrics showed better dyeing properties compared with previously reported dimethyldihydroxyethylene urea (DMDHEU), glutaraldehyde (GA), and 1,2,3,4-butanetetracarboxylic acid (BTCA). Analysis of the combined mechanism of different finishing agents and cellulose, demonstrated the reason why oxyRa can be used to change the order of dyeing and anti-wrinkle finishing.

의류관리기 내 직물거동이 구김 제거에 미치는 영향

의류관리기 내 직물거동이 구김 제거에 미치는 영향

New Method to Evaluate the Crosslinking Degree of Resin Finishing Agent with Cellulose Using Kjeldahl Method and Arrhenius Formula

In anti-wrinkle finishing, the crosslinking degree of fabric is mainly determined by wrinkle recovery angle, stiffness, and viscosity, these indicators can only reflect the finishing effect from a macro perspective, which cannot reflect whether the crosslinking is sufficient, and it is difficult to quantify the crosslinking degree. In this paper, we combined the Kjeldahl method with the Arrhenius formula and proposed a method to analyze the crosslinking degree of dimethyloldihydroxyethyleneurea (two-dimensional (2D) resin) with cotton cellulose during delayed-cure finishing for the first time. The nitrogen content of completed fabrics during storage was measured by the Kjeldahl method, and the reaction rate equation of the 2D resin and cellulose under normal temperature conditions was calculated. The results show that the nitrogen content is more suitable to indicate the crosslinking degree, and the apparent activation energy was 28.271 kJ/mol and the pre-finger factor was 0.622, which indicated that the 2D resin was prone to cross-linking with cotton fabrics during storage. During long-term storage, the relative errors between the calculated and measured values of the nitrogen content were within ±5%, and the accuracy was higher than the traditional evaluation method. The stability of 2D resins during the storage of delayed-curing finishing was also analyzed through this method.

Preparation of Ag NPs and Its Multifunctional Finishing for Cotton Fabric.

To explore the combination of silver nanoparticles (Ag NPs) prepared in a green manner with cotton fabrics and the washing durability of the fabric after the combination. In this paper, the natural material, honeysuckle extract, was used as a reducing agent to prepare the Ag NPs’ solution. The structure and size of Ag NPs were analyzed using ultraviolet–visible spectrophotometry (UV–vis), transmission electron microscopy (TEM), dynamic light scattering (DLS), X-ray powder diffraction (XRD), and Fourier transform infrared (FT-IR) spectroscopy characterization. The results showed that Ag+ was successfully reduced to Ag0 by the honeysuckle extract, the particle size was about 10.59 nm, and the potential was −42.9 mV, so it had strong electrostatic repulsion and good stability. Meanwhile, it was found that the synthesized Ag NPs were well coated by the honeysuckle extract, so they would not aggregate. Then, the cotton fabric was finished with Ag NPs’ solution by the dipping method using a complex of polymaleic acid (PMA) and citric acid (CA) as a cross-linking agent to fix Ag NPs on the cotton fabric. The structures of cotton fabrics before and after finishing were characterized using FT-IR, scanning electron microscopy (SEM), XRD, X-ray photoelectron spectroscopy (XPS), and thermogravimetric (TG) analysis, and the multifunctional properties of the finished cotton fabrics were explored by measuring the antibacterial rate, the wrinkle recovery angle (WRA), and the UV protection factor (UPF) value. The results show that Ag NPs were successfully loaded onto cotton fabric, and the PMA + CA compound was successfully cross-linked to the fabric. The cross-linked Ag NPs’ cotton fiber was rougher than that before cross-linking, and its TG stability improved. The PMA + CA compound fixed Ag NPs on the cotton fabric through chemical bonds, so it still had a 99% antibacterial effect against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) after 50 washings. Compared with unfinished cotton fabric, the UPF value and WRA of the cross-linked Ag NPs cotton increased by 34.09 and 98°, respectively, and its color did not change much.

Effect of extraction method on properties of feather keratin grafted modified cotton nonwoven fabric for biomedical applications

This study offers a new wound dressing by immobilization of amino acid residues on partially carboxymethylated cotton nonwoven fabrics (CM-CN). To improve the absence of capacity to protect the open wound from infection, firstly, a usual cotton nonwoven fabric was chemically modified by utilizing a pad-dry-cure technique including a carboxymethylation procedure. Subsequently, the chicken feather wastes as a natural source were used for the cationization of CM-CN by the same method. Keratin successfully was extracted from chicken feathers using both chemical and enzymatic processes. Physicochemical and biological properties of the prepared samples were evaluated by FTIR, SEM, mechanical properties such as tensile, bending test and wrinkle recovery, biodegradation, permeability (air and water vapor), and MTT assay for cell viability and proliferation. The tensile strength increased to 200%, the air permeability almost doubled, and the greatest cell growth was observed for modified samples. According to the obtained results, enzymatic extraction was influential and the samples coated with enzyme-extracted keratin showed enhanced properties suitable for wound dressing applications.

Evaluation of Enhanced UV Protection Property of Dyed Cotton Fabrics Based on Inclusion Complex of β-cyclodextrin with Natural Coumarin Extracted from Cortex fraxini

Inclusion complex formed between β-cyclodextrin (β-CD) and natural coumarins extracted from Cortex fraxini were utilized to dye and enhancing the UV protection properties of cotton fabric. Natural coumarins were extracted from Cortex fraxini and the total amount of natural coumarins was evaluated. The inclusion complex of natural coumarins with β-CD were formed and analyzed by ultraviolet-visible spectrum, fluorescence spectroscopy, FTIR and TGA. The obtained results showed that a stoichiometry of 1:1 inclusion complex was formed and the fluorescence intensities and ultraviolet absorption of the natural coumarins were both enhanced by incorporating into β-CD. β-CD was grafted onto cotton fabric based on esterification of citric acid with cellulose and cyclodextrin in the presence of sodium hypophosphite. The grafted cotton fabric was then dyed with natural coumarins extraction of Cortex fraxini as natural ultraviolet absorbent to form stable inclusion complex. UV protection factor (UPF), UVA transmittance (TUVA) and UVB transmittance (TUVB), wrinkle recovery and tensile strength of dyed fabrics were evaluated and demonstrated that graft modification of fabrics with β-CD resulted enhancement in UV protection property and durability accompanied with increasing in wrinkle recovery properties and decreasing in tensile strength. Furthermore, apparent morphology, FTIR and TGA analysis of inclusion complexes loaded cotton fabrics and the relationship between structure and properties were investigated.

Antibacterial Finishing of Linen Fabrics by Combination with Nano-Aluminum Oxide and Crosslinking Agent

Linen is an important natural fiber in cellulosic structure and different chemical processes can be applied on the linen based textile materials. In this study, a concept constituted of different finishing processes was presented. Crease recovery and meanwhile anti-bacterial properties were carried out simultaneously. For crease recovery; modified glyoxylic resin containing catalyst and for gaining antibacterial efficiency; nano-aluminum oxide were used in combination. Then, the amount of the nano-aluminum oxide in the recipe was analyzed in terms of crease resistance efficiencies, and anti-bacterial efficiencies against two different bacteria E. coli and S. aureus. It was observed that the addition of the nano-aluminum oxide to the recipe of the crease resistant process has a positive effect on the wrinkle recovery performances. Moreover, above the concentration of 103 ppm nano-aluminum oxide in the recipe, the anti-bacterial activity against S. aureus was started to occur. However if the concentration become to 5×104 ppm, both in E. coli and S. aureus bacteria solution a significant bacterial reduction appeared. Moreover the durability of the obtained features was tested and it was observed that the obtained features were durable for the 5 cycle of washings as well.

Soil biodegradation of cotton fabrics treated with common finishes

Cotton is one of the most widely used natural fibers available. However, to overcome some of its shortcomings, manufacturers have placed various finishes on cotton fabrics to improve wrinkle recovery, flame retardancy, anti-microbial behavior, water repellency, etc. This study measures the impact of common finishes on the biodegradability of 100% cotton fabrics in a soil laboratory environment. Under a controlled laboratory environment, cotton fabrics treated with 9 different finishing chemicals or chemical combinations were tested according to the standard test method, ASTM D5988-12, for up to 154 days. Results indicate crosslinked fibers show better protection from biodegradation when compared to the control fabric and non-crosslinked fabrics. The production of carbon dioxide (CO2) as a function of time was measured to determine the degree of biodegradation. Untreated cotton samples produced 2500 mg of CO2 after 154 days, approximately 40% more than that of the crosslinked treated fabric. Weightless studies showed the untreated fabrics and non-crosslinked finished having 40–60% weight loss after 154 days, while the crosslinked fabrics had unless than 20% weight loss over the same time period. Scanning electron microscope (SEM) images were used to observe the visual degradation level for each sample showed certain treated fabrics showed a less evidence of cracking on the fiber surface along with less microorganism growth. Fourier-transform infrared spectroscopy (FTIR) analysis showed that in general, treated fabrics with higher CO2 production and higher weight loss showed greater evidence of microorganism growth when analyzing peak bands typically associated with microorganism growth irreversibly bonded to the fibers.

Effect of Silane Coupling Agents on Cotton Fibre Finishing

ABSTRACT Five different silane coupling agents such as vinyltrimethoxysilane (VTMS), vinyltriethoxysilane (VTES), trimethoxysilylpropylmethacrylate (TSPM), glycidoxypropyltriethoxysilane (GPTES) and aminopropyltriethoxysilane (APTES) were used for the surface finishing of cotton fiber by condensation polymerization in ethanol/water medium. The finished cotton fiber showed improved textile properties like tensile strength, wear comfortness, moisture absorption and wrinkle recovery, but decreased swelling in aqueous solution. The finished cotton fibers were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Energy Dispersive X-ray (EDX), thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG). Attachment of silane coupling agents was confirmed and the finished cotton fiber showed increased thermal stability than the unfinished cotton. The finished cotton fiber showed higher reactive dye exhaustion due to silane coupling agent imparts new reactive sites for dye molecule on cotton fiber. The finished cotton fiber showed excellent fastness properties like washing, sunlight and chemical fastness properties. Improved textile properties of the silane finished cotton fiber with higher flexibility due to the presence of Si-O bond between the silane coupling agents and the cotton fiber, causes increased wear comfortness. Possible applications include use of the finished fibers as textile materials and garments.

Development of non-formaldehyde wrinkle resistant finish for cotton using carboxylic acids

A study has been conducted to develop a wrinke resistant cotton fabric using three carboxylic acids combination along with initiator and catalyst, at various pH and concentration, and to determine the effects of treatment on wrinkle recovery angle, wrinkle recovery appearance rating, and carboxyl group content of the treated fabrics. The amount of carboxylic acids on the fabric is determined by % weight gain of treated samples, carboxyl ‘n’ group content, wrinkle recovery angle and wrinkle recovery appearance rating. Furthermore, FTIR spectroscopic analysis has been conducted to study the attachment of acid groups for reducing the available free OH groups on the cotton cellulosic chains. The results show significant wrinkle resistance of treated samples. In order to evaluate the wash durability of the finish applied, the treated sample is laundered for 20 cycles and it is found that the wrinkle recovery property significantly persist even after washing.

The Changes of Appearance Formability of Hanji Blended Fabrics after Fusing

In order to examine the changes in the appearance properties and the post-adhesion appearance properties of Hanji yarn blended fabrics : 100% Hanji yarn fabric, two kinds of cotton / Hanji yarn blended fabrics and 100% cotton fabric, were selected and fused with three kinds of interlinings. After fusing, changes of standardized KES values were examined.<br/>1. W/T, B/W of Hanji yarn blended fabrics was higher than that cotton fabric. WC/W, 2HB/W, 2HB/B, and 2HG/G values of Hanji yarn blended fabrics are lower than cotton fabric. This means that the Hanji yarn was mixed, shape retention, wrinkle recovery was improved, and the drape property was lowered. 2. After fusing, W/T, shape retention, wrinkle recovery of Hanji yarn blended fabrics increased, and WC/W values of Hanji yarn blended fabrics decreased. The wrinkle recovery property of Hanji yarn blended fabrics were improved; however, the 2HG/G value of Hanji yarn fabric increased due to fusing, and the wrinkle recovery property of Hanji yarn fabric decreased. 3. In the selection of adhesive core, I1 adhesive core is excellent in terms of shape stability and wrinkle recovery; however, an I3 adhesive core is recommended for drape and silhouette formation. When the fabric of the adhesive core was PET, it was found to penetrate better between the fabrics during adhesion than the case of cotton fabrics.

Eco-dyeing with biocolorant from spent coffee ground on low molecular weight chitosan crosslinked cotton

Growing concern about the environmental effects of synthetic dyes is encouraging the use of natural dyes. Spent coffee ground (SCG), a potential renewable source of natural dye, was investigated as a biocolorant for dyeing of cotton. SCG contains the brown pigment melanoidin. Low molecular weight chitosan (LMWCTS) was used to introduce amino groups, with citric acid (CA) as a crosslinker. LMWCTS was applied to cotton at various concentrations using a simple pad-dry-cure technique, followed by dyeing with SCG extract using an exhaustion process. Fourier transform infrared spectrometry analysis confirmed the formation of ester linkages between the citric acid and cellulose or chitosan. The dyed fabrics were also evaluated for color properties using CIELAB (L*, a* and b*) and K/S values, color fastness, and whiteness index, for physical properties (wrinkle recovery angle, drape coefficient, and tensile strength), and for surface morphology. The combination of chitosan and citric acid provided fabrics with a rich natural brown shade. The samples showed the increase in color strength and wrinkle resistance compared with untreated and alum-mordanted samples. Fabrics treated with CA/LMWCTS had the ability to retain drape and exhibited good wrinkle resistance through 20 wash cycles. Color fastness to washing and rubbing was good.

Multifunctional Finishing of Cotton with Compounds Derived from MCT-β-CD and Quantification of Effects Using MLR Statistical Analysis.

Multifunctionalization of cotton using a single product has not been made until now. Such a product was synthesized using compounds with multiple functions (glyoxal, ethylenediamine (ED) and monochlorotriazinyl-β–cyclodextrin (MCT-β-CD)), under different mass ratios. Obtaining this multifunctional derivative has been confirmed by spectroscopic analyses (1H-NMR and FTIR) and a scanning electron microscope (SEM). Treatment of cotton with the MCT-β-CD derivative (D-CD) has been realized with the pad dry-cure technology. The presence of this multifunctional derivative on cotton was highlighted with spectroscopic (FTIR, EDAX, XRD) and thermoanalytical (DSC) methods. The objective of treating cotton with D-CD was to achieve four simultaneous effects: large wrinkle recovery angle (WRA), hydrophilicity, antibacterial capacity and a good breaking resistance. This objective has been achieved, so the garments that will be manufactured with such multifunctional cotton will be more comfortable. The efficiency of treatments with D-CD was marked out by multiple linear regression (MLR) and certain quality indices. Using MLR, the behavior of the treated cotton was mathematically modeled and the stationary/optimal points corresponding to each effect were calculated. Quality indices have been calculated and all final samples had values higher than 1, which confirmed the positive effects exerted by D-CDs on cotton.

Eco-friendly and efficient flame-retardant cotton fabric based on a multi-hydroxyl hyperbranched phosphoramidate

A kind of multi-hydroxyl containing hyperbranched phosphoramidate (HPAE) was successfully synthesized and characterized by FT-IR, 1H-NMR, 31P-NMR, and GPC. With the crosslinking of butane tetracarboxylic acid (BTCA), the flame-retardant cotton fabrics were prepared, and the combustion behavior and thermal degradation properties were investigated by limiting oxygen index (LOI), vertical flammability test, cone calorimetry test and thermogravimetric analysis. After treating with 300 g/L HPAE, good flame retardancy was obtained with LOI value of 29.0% and treated cotton fabrics can pass the vertical flammability test without afterflame and afterglow. The peak heat release rate was decreased from 255 to 93 kW/m2 and the total heat release after treatment was reduced by 37%. The thermal stability was greatly improved and over 40% of char residues maintained at 800 °C in N2. The washing durability of HPAE-BTCA treated cotton fabrics was also investigated and LOI value decreased from 29.0 to 25.2% after 25 washing cycles. Besides, the tensile strength, wrinkle recovery angle, and whiteness of cotton fabric after treatment were examined. Overall, our research provides a facile and effective approach to prepare durable flame-retardant cotton fabric, which has great potential in friendly flame-retardant textiles.