Wastewater Discharge Research Articles

A novel ion-responsive hydrogel based on quaternized chitosan and hydroxyethyl cellulose for high efficient chloride ion adsorption

Chloride removal is crucial for industrial wastewater discharge, seawater purification and concrete structure durability. In this study, a novel hydrogel with excellent chloride adsorption property was prepared and the adsorption capacity in relation to external pH and other ions was evaluated. The hydrogel was synthesized using a one-pot method with quaternized chitosan (HACC), hydroxyethyl cellulose (HEC), and carboxymethyl chitosan (CMC) as monomers. By adjusting the material compositions, we effectively modulated the microstructure and charge characteristics of hydrogel, achieving a balanced swelling ratio and optimal adsorption performance. The optimal process conditions were identified as 25 °C and a chloride ion concentration of 40 mmol L−1, achieving a maximum adsorption capacity of 1080 mg g−1. Isotherm modeling showed that the adsorption fits well with the Freundlich isotherm, suggesting multilayer adsorption. The quaternary ammonium groups serve as fixed positive charge sites or active adsorption sites, enabling the hydrogel to efficiently adsorb anions through the synergistic effects of electrostatic interactions, physical adsorption, and amino protonation. The varied adsorption capacities of quaternary ammonium groups for different anions give rise to competitive adsorption phenomena among them. The incorporation of silver ions into the hydrogel greatly enhances its selective adsorption of chloride ions through chemical combination. This work presents a comprehensive strategy for designing a novel hydrogel with exceptional adsorption properties specifically tailored for chloride ions.

Urbanization and greenhouse gas emissions from municipal wastewater in coastal provinces of China: Spatiotemporal patterns, driving factors, and mitigation strategies

Coastal cities, as hubs of social and economic activity, have witnessed rapid urbanization and population growth. This study explores the transformative changes in urban municipal wastewater treatment practices and their profound implications for greenhouse gas (GHG) emissions in Chinese coastal provinces. The approach employed in this study integrates comprehensive data analysis with statistical modeling to elucidate the complex interplay between urbanization, wastewater treatment practices, and GHG emissions. Results reveal a substantial surge in GHG emissions from coastal wastewater treatment, rising from 3367.1 Gg CO2e/yr in 1990–23644.8 Gg CO2e/yr in 2019. Spatially, the top 20 cities contribute 56.0% of emissions, with hotspots in the Bohai Sea Region, Yangtze River Delta, and Pearl River Delta. Initially dominated by emissions from untreated wastewater, post-2004, GHG emissions from treatment processes became the primary source, tied to electricity use. Growing population and urbanization rates escalated wastewater discharge, intensifying GHG emissions. From 1990 to 2019, average GHG intensity ranged between 320.5 and 676.6 g CO2e/m3 wastewater, with an annual increase of 12.3 g CO2e/m3. GHG intensity variations relate to the wastewater treatment rate, impacting CH4, N2O, and CO2 emissions, underscoring the need for targeted strategies to mitigate environmental impact.

Comprehensive recovery of valuable elements from vanadium precipitation liquor using selective impurity removal-reduction precipitation process

The vanadium precipitation liquor produced by the vanadium slag extraction process contains various valuable elements, which are not utilized at high value. In this paper, chromium is recovered through aluminum salt impurity removal - chemical reduction precipitation method. Moreover, the ammonia nitrogen and sodium sulfur in the vanadium precipitation liquor are recovered by stripping and crystallization, thereby achieving comprehensive resource recovery and utilization. The aluminum salt slag removal reduction chemical precipitation method is used to separate Cr from Si, Ca and V impurities. As a result, the obtained Cr2O3 product has a purity of 98.20%, the chromium recovery efficiency is 97.58%, and the silicon removal efficiency reaches 99.66%. The ammonia nitrogen was recovered by stripping, which would be reused to the vanadium precipitation process, with an ammonia nitrogen stripping efficiency of 98%. The purity of NH4Cl is 99.13% and meets the 99-level national standard. The Na2SO4 was recovered by evaporation concentration - crystallization method, which would be reused to the vanadium slag roasting process, with a Na2SO4 recovery efficiency of 88.38%. And the purity of Na2SO4 is 98.85%, which meets the industrial standard for Class II Na2SO4 products. The final solution after comprehensive recovery of valuable elements would be reused to the leaching process, thereby achieving water circulation. This process realizes the high-value utilization of chromium, ammonia, nitrogen, sodium and sulfur, and has no wastewater discharge and is an environment-friendly route.

Investigating the biodesulfurization potential of isolated microbial consortia: Impact of sulfide loading, pH and oxidation-reduction potential on sulfur recovery

Acid rain is regarded as one of the major concerns due to the release of sulfur-containing wastewaters from petrochemical and other allied industries. Biological desulfurization, an ecofriendly process offers no secondary pollution and allows for the recovery of elemental sulfur as a valuable product in a useable form as fertilizer and can be used as raw material in various industries. Therefore, this work explores the bio desulfurization potential of mixed microbial consortia that was isolated from various sources for the removal of sulfur containing compounds from synthetic wastewater at varying influent sulfide loading rate. Further, this study focused on optimizing the critical process parameters such as influent sulfide loading rate, ORP and pH to achieve maximum sulfur recovery. The experiments were performed at varying sulfide loading of 3000, 4000, 5000 and 6000 mg/L using the isolated mixed consortia at an ORP of −300 ± 20 mV and −360 ± 20 mV for an incubation period of 70 h. Results revealed that the isolated microbial consortia belong to the genera 73% Pseudomonas, 24% Alishewanella and 3% Zobellella. The maximum sulfide conversion efficiency to sulfite 309 mg/L, elemental sulfur 1152 mg/L and sulfate 1813 mg/L was exhibited by microbial consortia at an initial sulfide load of 6000 mg/L and ORP of −360 ± 20 mV.

Estimating Biogeochemical Rates Using a Computationally Efficient Lagrangian Approach

Nutrient concentrations in many estuaries have increased over the past century due to increases in wastewater discharge and increased agricultural intensity, contributing to multiple environmental problems. Numerous biogeochemical and physical processes in estuaries influence nutrient concentrations during transport, resulting in complex spatial and temporal variability and challenges identifying predominant processes and their rates. Mechanistic models which require these rates to quantify biogeochemical processes become complex and difficult to calibrate as the number of processes and parameters grows, owing to the high dimensionality of the parameter space and the computational cost of simultaneously modeling the transport and transformations of constituents. We developed a modeling approach that decouples transport from transformations, enabling fast, data-driven exploration of the parameter space. The approach extracted information including water age, cumulative exposure to specific habitats, and mean water depth exposure from a hydrodynamic model. Using this information, a biogeochemical model was implemented to predict ammonium and nitrate concentrations in a Lagrangian frame. The model performed each simulation in milliseconds on a laptop computer, allowing the fitting of rate parameters for key transformations by optimization. The optimization used fixed station nitrate observations and the model was then validated against high-resolution mapping observations of ammonium and nitrate. The results suggest that the observed spatial and temporal variation can be largely represented with five transformation processes and their associated rates. Dissolved inorganic nitrogen (DIN) losses occurred only in shallow vegetated areas in the model, highlighting that biogeochemical processes in these areas should be included in DIN models.

Projektowanie zakładu uzdatniania wody przy wsparciu modeli laboratoryjnych

The subject of the research focused on the possibilities of supporting the design of surface water treatment plants using laboratory models. Within the pilot study, the possibilities of using different water treatment processes in the treatment of water from the water reservoir Nové Mlýny in the Czech Republic were assessed. The planned treatment plant is to supply a future recreational site from a shallow reservoir with significant eutrophication and chemical industry in the drainage basin. Coagulation, sedimentation, dissolved air flotation, membrane filtration processes and adsorption on granular activated carbon were investigated. These processes were identified by the preliminary study as applicable to water treatment and it was necessary to determine which could be applied given the site conditions. Laboratory models for the individual processes were used during the laboratory testing. During the research, problems encountered were debugged and the models were modified and some extensions were added to the original models. The coagulation and sedimentation processes were investigated using conventional jar tests. The dissolved air flotation process was simulated using a modified jar test and a lab scale model. Different types and doses of coagulants, mixing parameters and residence times were investigated in the tests. Turbidity value was used as an optimization parameter due to its rapidity of determination and low cost. For some tests, potassium permanganate oxidizability (also known as the permanganate index) was also used as an evaluation parameter so that different evaluation parameters could be compared. In addition, for the dissolved air flotation process, the parameters of the produced sludge - its quantity, suspended solids content and chemical oxygen demand - were monitored. These parameters are crucial for discharge of waste water into the sewer and its costs. The adsorption tests on granular activated carbon were performed as batch tests. The evaluation parameter was the manganese index. Another possible variant of activated carbon tests is a continuous flow-through column. These columns also allow monitoring of the process of fouling and the evolution of the effluent over time. The pilot project then used the results of the laboratory tests to create a design for a treatment plant in the area of interest and selected parts of the project documentation. The pilot project demonstrated the usefulness of laboratory testing as a tool to support the design of drinking water treatment plants. At the same time, these tests allow for a faster and more certain identification of the appropriate water treatment technology and thus reduce the extent of semi-operational testing at the site, leading to a more efficient use of funds by investors.

Ecological Safety and Regional Cooperation in the Asia-Pacific

On August 24, 2023, the discharge of nuclear-contaminated water from Fukushima into the ocean, an action that has sparked widespread concern and apprehension within the international community, particularly among nations in the Asia-Pacific region. This issue transcends mere environmental concerns, touching upon transnational cooperation and regional policy coordination. The strategic significance of the Asia-Pacific region in international studies is underscored by the concentration of multiple national powers engaging in complex strategic games to achieve their respective national interests and objectives. This paper aims to outline the context of nuclear wastewater discharge, analyze the potential environmental risks, and explore the threats to the marine ecological safety of neighboring countries. It discusses how this decision has become both a challenge and an opportunity for cooperation among Asia-Pacific nations in terms of environmental protection and marine ecological safety. Additionally, the paper employs the Graph Model for Conflict Resolution (GMCR) method, based on existing multilateral cooperation frameworks such as regional marine cooperation organizations and international legal norms, to study the challenges and opportunities for regional cooperation in the context of nuclear wastewater discharge. This research may offer insights and guidance for mitigating current threats to marine ecological safety in the Asia-Pacific, and for constructing a more sustainable and resilient regional marine governance structure.

Research Progress of Chromophoric Dissolved Organic Matter (CDOM) in Landfill Leachate by Electrochemical Method

Over the years, industry, agriculture and other human activities have discharged large amounts of organic pollutants into landfills. Among them, color-resistant dissolved organic pollutants have attracted great attention. In order to achieve the safe discharge of wastewater, a variety of treatment technologies have been used to effectively eliminate CDOM in water. In this paper, the most promising electrochemical oxidation (EO) techniques are reviewed, their basic principles are introduced, and the research progress and application status of electrode materials and electrochemical reactors are introduced. At the same time, the substance composition and detection method of CDOM are discussed. Finally, the performance of EO technology to remove CDOM is summarized. However, we should note that electrode optimization has always been the core of EO technology improvement, and the combination of updated electrode material iteration and treatment process has broad prospects for the wide application of EO technology.

Facilities pond aquaculture system construction and the ecological economy analyzed

Pond aquaculture is the main form of aquaculture worldwide. However, there are problems with water quality being difficult to control, discharge pollution, low production quality, etc. Therefore, an efficient, low-carbon, and controllable pond system should be established. In this paper, we introduce two facilities’ pond systems: a segregated pond aquaculture system (SPA) and a batch pond aquaculture system (BPA). In these two systems, we evaluated a rearing period with bream (Megalobrama amblycephala) and detected ecological and economic indexes such as yield, nitrogen and phosphorus conversion efficiency, and energy utilization efficiency in different aquaculture pond systems. The results showed that the yields of the SPA and BPA were 12.81 % and 74.29 %, respectively, greater than those of traditional ponds. The feed conversion ratios (FCRs) of the BPA and SPA were 1.8 and 2.1, respectively, but those of the traditional ponds were 2.3. The proportions of nitrogen converted to fish in the SPA, BPA, and traditional ponds were 29.67 %, 33.45 %, and 26.19 %, respectively, and the percentages of phosphorus converted to fish in the SPA, BPA and traditional ponds were 53.68 %, 63.38 %, and 52.20 %, respectively. With the production of 1 kg of aquatic products, the utilization of solar and feed energy in the SPA, BPA, and traditional ponds was 60.28 ± 1.12 MJ/kg, 66.59 ±0.26 MJ/kg, and 37.05 ±1.33 MJ/kg, respectively. In addition, the SPA and BPA can also use 60 % less water, reduce wastewater discharge by 80 % and use 35 % less land. These results showed that construction facility pond systems could improve pond aquaculture efficiency and have great development potential.

Towards the definition of an antibiotic resistome signature in wastewater and downstream environments

Domestic wastewater is a significant reservoir of antibiotic resistance genes, which pose environmental and public health risks. We aimed to define an antibiotic resistome signature, represented by core genes, i.e., shared by ≥ 90% of the metagenomes of each of three conceptual environmental compartments – wastewater (influent, sludge, effluent), freshwater, and agricultural soil. The definition of resistome signatures would support the proposal of a framework for monitoring treatment efficacy and assessing the impact of treated wastewater discharge into the environment, such as freshwater and agricultural soil.Metagenomic data from 163 samples originating from wastewater (n = 81), freshwater (n = 58), and agricultural soils (n = 24) across different regions (29 countries, 5 continents), were analysed regarding antibiotic resistance diversity, based on annotation against a database that merged CARD and ResFinder databases. The relative abundance of the total antibiotic resistance genes (corresponding to the ratio between the antibiotic resistance genes and total reads number) was not statistically different between raw and treated wastewater, being significantly higher than in freshwater or agricultural soils. The latter had the significantly lowest relative abundance of antibiotic resistance genes. Genes conferring resistance to aminoglycosides, beta-lactams, and tetracyclines were among the most abundant in wastewater environments, while multidrug resistance was equally distributed across all environments. The wastewater resistome signature included 27 antibiotic resistance genes that were detected in at least 90% of the wastewater resistomes, and that were not frequent in freshwater or agricultural soil resistomes. Among these were genes responsible for resistance to tetracyclines (n = 8), macrolide-lincosamide-streptogramin B (n = 7), aminoglycosides (n = 4), beta-lactams (n = 3), multidrug (n = 2), sulphonamides (n = 2), and polypeptides (n = 1). This comprehensive assessment provides valuable insights into the dynamics of antibiotic resistance in urban wastewater systems and their potential ecological implications in diverse environmental settings. Furthermore, provides guidance for the implementation of One Health monitoring approaches.

Interaction and selective treatment of lead-zinc flotation wastewater for wastewater recycling using ectrocatalytic internal micro-electrolysis

Lead-zinc flotation wastewater discharge poses a growing risk to environmental safety, and efficient treatment is challenging due to large quantities of water, combined pollution, and the limitations of current approaches. This study discussed the removal differences, available treatment approach, interaction characteristics, and mechanisms of heavy metals (Pb2+ and Zn2+), flotation reagents (butyl xanthate (BX), and dianilino dithiophosphoric acid (DDA)) in single and composite systems using electrocatalytic internal micro-electrolysis (ECIME). Density functional theory (DFT), solubility, and UV spectrum analyses revealed that the high chemical potential of the (BX)2M, (DDA)2M complexes in lead-zinc flotation wastewater played key roles for the solubility and ECIME removal of these pollutants. The complexes significantly inhibited activated carbon (AC) interface adsorption, as well as DDA and (DDA)2M degradation and Fe(II)–Fe(III)–OH flocculation. Prolonging the treatment times for Pb2+, Zn2+, BX, and (BX)2M effectively alleviated the inhibitory effect. However, cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS) analysis also highlighted the difficulty of the electrochemical reduction deposition of the Pb2+ and Zn2+ reactions. Comparatively, the DDA and (DDA)2M in composite systems showed higher electrochemical stability, while degradation was highly dependent on high voltage and exhibited temporal hysteresis in the ECIME system. The DDA removal rate only reached 60% after ECIME treatment at 45 V for 90 min, while the values of Pb2+ and Zn2+ (9 V, 30 min) and BX (18 V, 70 min) exceeded 90% and exhibited significantly disadvantage effect when voltage was larger than 18 V. Based on the their distinguishing characteristics of ECIME removal and flotation beneficiation effect, an alternative suggested removing of Pb2+, Zn2+ and BX while preserving DDA and (DDA)2Pb in lead-zinc flotation wastewater could be achieved by regulating the reaction potential and time. By adjusting the ECIME settings to a voltage of 15.2 V, a period of 45 min, and a pH of 5.5, a comprehensive removal rate of 97.59% was achieved. Additionally, recycling wastewater at proportions of 50–70% will not lead to confusion in the selection of lead-zinc ore. The results demonstrated the feasibility and economic efficiency of selective removal and reuse, showing considerable potential for practical application.

Highly enhanced chloramphenicol adsorption performance of MIL-53-NH2(Al)-derived porous carbons modified with tannic acid

The worldwide demand for antibiotics has experienced a notable surge, propelled by the repercussions of the COVID-19 pandemic and advancements in the global healthcare sector. A prominent challenge confronting humanity is the unregulated release of antibiotic-laden wastewater into the environment, posing significant threats to public health. The adoption of affordable carbon-based adsorbents emerges as a promising strategy for mitigating the contamination of antibiotic wastewater. Here, we report the synthesis of novel porous carbons (MPC) through a direct pyrolysis of MIL-53-NH2(Al) and tannic acid (TANA) under N2 atmosphere at 800 °C for 4 h. The effect of TANA amount ratios (0%–20%, wt wt−1) on porous carbon structure and adsorption performance was investigated. Results showed that TANA modification resulted in decreased surface area (1,600 m2 g−1–949 m2 g−1) and pore volume (2.3 cm3 g−1–1.7 cm3 g−1), but supplied hydroxyl functional groups. Adsorption kinetic, intraparticle diffusion, and isotherm were examined, indicating the best fit of Elovich and Langmuir models. 10%-TANA-MPC obtained an ultrahigh adsorption capacity of 564.4 mg g−1, which was approximately 2.1 times higher than that of unmodified porous carbon. 10%-TANA-MPC could be easily recycled up to 5 times, and after reuse, this adsorbent still remained highly stable in morphology and surface area. The contribution of H bonding, pore-filling, electrostatic and π–π interactions to chloramphenicol adsorption was clarified. It is recommended that TANA-modified MIL-53-NH2(Al)-derived porous carbons act as a potential adsorbent for removal of pollutants effectively.

Hydrophobic silicone modified membranes for efficient oil/water separation: Synthesis, fabrication and application

Oil leakage and discharge of organic wastewater have not only threatened the ecosystem, but also greatly aggravated water scarcity. Efficient separation of oil–water mixture has become a global challenge. To solve this issue, various hydrophobic membranes with special wettability have been developed in past decades. Among them, the hydrophobic silicone-modified membranes have attracted much attention due to their low cost, easy processing and large-scale production. Herein, recent progresses of hydrophobic silicone-modified membranes for oil–water separation are reviewed. Basic mechanisms and principles for efficient oil–water separation are presented as a starting point for the discussion. Then, according to the modified silicone polymers or molecules, we give a detail description of their synthesis and briefly introduce the main reactions with the substrate, the typical grafting strategy and fabricating methods. Subsequently, the performance and oil–water application of various hydrophobic membranes modified silicone are introduced. Finally, some problems and challenges faced by silicone modification are summarized and present, and their future development is also prospected.

Macroplastic and Microparticle Pollution in Beach Sediments from Urias Coastal Lagoon (Northwest Mexico).

This study investigates the occurrence and characteristics of macroplastic and polymer microparticles in the Urias coastal lagoon's beach sediments, in northwest Mexico. Coastal lagoons, productive and vulnerable ecosystems, are impacted significantly by anthropogenic activities, leadings to their pollution by various contaminants, including plastics. Our research involved sampling sediments from four sites within the lagoon that were influenced by different human activities such as fishing, aquaculture, thermoelectric power plant operations, industrial operations, and domestic wastewater discharge. Our methodology included collecting macroplastics and beach sediment samples, followed by laboratory analyses to identify the plastic debris' size, shape, color, and chemical composition. The results indicated a notable presence of macroplastic items (144), predominantly bags, styrofoam, and caps made of polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET). The polymer microparticles were mainly fibers, with cotton and polyester as the most common polymers, suggesting a significant contribution from clothing-related waste. The dominant colors of the microparticles were blue and transparent. High densities were observed in areas with slower water exchange. Our findings highlight the urgent need for better waste management practices to mitigate plastic pollution in coastal lagoons, preserving their ecological and economic functions.

Research on the Granger Causality Experiment of Fukushima Nuclear Wastewater Discharge on Changes in Oil Market Prices

Research on the Granger Causality Experiment of Fukushima Nuclear Wastewater Discharge on Changes in Oil Market Prices

Photoelectrocatalysis degradation of P-aminophenol using PbO2-TiO2 heterojunction electrode: Catalytic, theoretical calculating and mechanism

To lengthen the lifetime and extend the potential commercial applications of lead dioxide electrode. Herein, PbO2–TiO2 heterostructured electrodes were fabricated via direct current electrodeposition and the surface of the electrode was characterized by electron microscopy (EDS), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The PbO2–TiO2 heterostructure electrode could produce an obvious photocurrent under UV irradiation, indicating a photoelectrocatalytic reaction. The PbO2–TiO2 heterostructured electrode was examined using density functional theory calculations(DFT). Work function(WF) confirmed that the applied electric field is conducive to the movement of photoelectrons, which promotes the photoelectrocatalysis effect. The nudged elastic band(NEB) results showed that the PbO2–TiO2 heterostructure electrode can promote the formation of •OH by reducing the activation barrier. The PbO2–TiO2 electrode was used as an anode to treat P-aminophenol (PAP) wastewater simulated wastewater and real PAP wastewater via photoelectrocatalytic degradation. The PbO2–TiO2 electrode effectively removes chemical oxygen demand (COD) from actual wastewater was 54.93 %,The after-treated Pb2+ concentration (0.037 mg·L−1) was lower than China’s wastewater discharge standard (1 mg·L−1). Finally, the degradation pathway of PAP was determined based on the intermediates detected using gas chromatography–mass spectrometry and the reactive sites of PAP were predicted using the Fukui function.These results suggest that the photoelectrocatalysis degradation of PAP using electrodes is feasible.

Evaluation of water resources carrying capacity in China based on entropy weight TOPSIS model

Water resources carrying capacity refers to the ability of the water resources ecosystem to continuously carry the coordination relationship between human society and economy in the normal development process of a country or a region. Its self-sustaining ability, self-regulation and self-development potential often hinder sustainable development in water shortage areas. Research on water resources’ carrying capacity is a meaningful way to support regional water resources security and realize harmonious development of society, economy, and ecological environment. Correct assessment of water carrying capacity and response to government policies will contribute to improved water use and sustainable economic and social development. This study first sorts out the relevant questionnaires of water resources carrying capacity level evaluation, proposes the evaluation indicators of water resources carrying capacity level, collects and standardizes the required data, and calculates the weight of each evaluation index by entropy weight method. Then, it calculates the comprehensive evaluation value of China’s water resources carrying capacity from 2012 to 2022 in the TOPSIS model. The results show that the total afforestation area, total investment in environmental pollution control, and total industrial wastewater discharge are the third most important factors in improving the carrying capacity of water resources. From 2003 to 2010, China’s water resources carrying capacity improved year by year. From 2011 to 2021, China’s water resources carrying capacity remained stable year by year. The continuous adjustment of China’s industrial structure and strengthening environmental pollution control are inevitable measures to improve the carrying capacity of China’s water resources. This study provides a scientific basis for exploring the changing trend of China’s water resources carrying capacity and formulating reasonable optimal allocation of water resources. It also has great significance for promoting China’s water resources’ carrying capacity and sustainable development of the social economy and ecological environment.

Spatiotemporal characteristics and potential pollution factors of water quality in the eastern route of the South-to-North Water Diversion Project in China

The eastern route of the South-to-North Water Diversion Project (SNWDP-ER) in China, an open-channel cross-basin project, is exposed to multiple potential pollution sources and has changing hydrodynamic conditions between diversion and non-diversion periods. After a decade of pollution control efforts, it is imperative to perceive the water quality conditions and identify potential pollution factors for further maintenance. Combining the water quality identification index (WQII) and multivariate statistical techniques (MSTs), this study conducted an exploratory analysis in SNWDP-ER, based on the monitoring data in 2020–2021. The monitoring and WQII results show that the overall water quality in SNWDP-ER is satisfactory and meets the Class III requirements in China Environmental Quality Standard for Surface Water, except for total nitrogen (TN) which falls into Class V or even worse. The periodic alternations of flow direction between diversion and non-diversion periods tend to deteriorate water quality, particularly in the initial stage of alternations. Water quality appears more stable during the diversion period, and impounding lakes along the project are crucial to water environment restoration in this period. Due to the positive influence brought by the self-purification and environmental carrying in the Luoma Lake, Nansi Lake, and Dongping Lake, water quality exhibits an enhancing trend from upstream to downstream in the Lianghu and Jiaodong reaches. Besides, the monitoring stations in Shandong reach exhibit significant divisional heterogeneity under hierarchical cluster analysis (HCA) with the Nansi Lake and Dongping Lake as the demarcation points, and the results of factor analysis/principal component analysis (FA/PCA) further identified the contributions of mining, shipping, and land use to each section. Based on the findings, the study recommends implementing wastewater discharge control, abandoned mines remediation, and continued water quality monitoring for further maintenance and improvement in SNWDP-ER.

TECHNOLOGICAL ADVANCEMENT IN REMOVING HEAVY METALS FROM INDUSTRIAL WASTE WATER

Fluorides are important contaminants found in effluents from a variety of industries, including electroplating and glass. These are extremely harmful to living things and have a negative impact on their health. Thus, removing fluoride with biosorbents is an important step toward environmental conservation. The untreated discharge of industrial waste water into the environment has long had an impact on human, plant, and animal health. These effluents contain harmful compounds that are not degradable through chemical or microbiological processes. However, they are most likely to accumulate in soil, aquatic environments, and plant organs. The present work investigated the elimination of fluoride utilizing an aquatic plant species, Eichhornia Crassipes (Water Hyacinth) by the method of phytoremediation.

WATER RESOURCES OF THE KHOROSTKIV TERRITORIAL COMMUNITY: ECOLOGICAL STATUS, WATER USE PROBLEMS, OPTIMISATION MEASURES

The article analyses the ecological state of surface water resources of the Khorostkiv territorial community (ТС). According to the results of laboratory tests, pathogenic microorganisms, bacteriological indicators exceeding the regulatory requirements, faecal contamination and high content of organic matter were detected in the surface water bodies of the Khorostkiv TC. In addition to the pollution of surface water bodies in the Khorostkiv TC, an important environmental problem worth paying attention to is the lack of sanitary protection and water protection zones for rivers and ponds, as well as the littering of the coastal strip. It was found that the water supply network of the Khorostkiv territorial community includes only the water supply network of the town of Khorostkiv (30 km, unsatisfactory condition), since there are no centralised water supply systems in rural settlements. In the sources of centralised water supply in Khorostkiv, the levels of ammonium nitrogen and colour are exceeded. Hydrochemical analysis of water samples from private wells in Khorostkiv and the villages of Peremyliv and Khlopivka confirmed compliance with the requirements of SanR&R № 400. The volume of daily water consumption and water disposal was analysed. The main sources of pollution of the community's water resources and the volume of wastewater discharges were identified. Priority areas for improving the ecological state of water resources of the Khorostkiv community are substantiated. Keywords: surface water, groundwater, pollutants, water supply, water disposal, territorial community (ТС).