Discharge Voltage Research Articles

A difunctional electrolyte boosting the electrochemical performance of the primary Li/CFx batteries

Lithium/carbon fluorides (Li/CFx) batteries have received widespread attention because of the advantages of high energy density, low environmental pollution, and low self-discharge. However, less attention has been paid to electrolytes which also significantly affect the electrochemical performance of Li/CFx batteries. Herein, we develop a novel electrolyte for Li/CFx batteries, a mixture of lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI) and lithium difluoro(oxalate) borate (LiODFB) with different ratios dissolving in propylene carbonate (PC)/methyl butyrate (MB). Interestingly, the LiODFB not only boosts the specific capacity exceeding the theoretical value (865 mAh−1) by introducing extra capacity via its ring opening reaction with Li+ during the discharge process, but also enhances the discharge voltage and rate capability at varying temperature. As expected, the Li/CFx batteries with electrolyte of 1 M LiODFB in PC/MB delivers an ultrahigh specific capacity of 1169.84 mAh g−1 and energy density of 2646.93 Wh kg−1 at 30 °C and 10 mA g−1, and 966.9 mAh g−1 and 2232.8 Wh kg−1 at 70 ℃ and 500 mA g−1, respectively. These findings provide new ideas on designing Li/CFx batteries with high capacity and high energy density.

Argon admixture-driven enhanced ionization and performance of a 5 kW Hall thruster on krypton

Utilizing alternative propellants has been recognized as a strategy to reduce the total cost of propellants in electric propulsion-based missions. The aim of this study is to quantify the Hall effect thruster (HET) performance and operating characteristics using a Kr–Ar mixture to enable mission designers to evaluate the impact on mission and spacecraft design. We present the performance and plume plasma properties of the P5 5 kW-class HET operated with a Kr–Ar mixture with Ar volumetric flow rate fractions from 0 to 100%. The thruster is characterized at discharge power levels of 2.6 kW and 4.1 kW at constant discharge current and voltage over the range of Ar fractions. Despite higher ionization energy and lower mass of Ar, the thruster exhibited a similar level of thrust within 2% when comparing the pure Kr and 26%-Ar mixture cases. The derived ion energy distribution functions and analytical modeling suggest that the characteristic length for the ionization region is extended as the Ar fraction increases. The increased residence time of Kr at the extended ionization region and background energetic electrons from the ionized Ar neutrals are considered to cause this enhanced ionization of the injected Kr neutrals. This leads to a 6% higher Kr ion density at the 26%-Ar case even at the 16% less injected Kr neutral density than in the pure Kr case. The enhanced Kr ionization and generated Ar ions in the 26%-Ar case consequently led to a comparable thrust with that of the pure Kr case. The study indicates that mixing Ar with approximately 26% volumetrically with Kr can provide a similar or even higher thrust performance at the same discharge power. This will be particularly advantageous for various space missions that require high impulses by reducing the total cost of the propellant.

Destruction of n-hexane from the air stream by pulsed discharge plasma: Modelling and key process parameters optimization by CCD-RSM

In this study, a Dielectric-Barrier Discharge (DBD) plasma reactor was used for the degradation of n-hexane from an air stream. a Central Composite Design (CCD) based Response Surface Methodology (RSM), (CCD-RSM) was utilized to explore the effects of experimental parameters including discharge voltage, initial concentration, gas flow rate, relative humidity and their interactions on the reactor performance. The proposed optimization model showed a satisfactory correlation between the predicted and actual results. According to the results, discharge voltage was the most significant parameter affecting the removal efficiency, CO2 selectivity and the level of O3 and NOx formation, whereas energy yield was mainly influenced by gas flow rate and initial concentration. At optimized conditions (discharge voltage of 8.5 kV, inlet concentration of 94.3 ppm, relative humidity of 55 % and gas flow rate of 733.16 ml/min with combined desirability of 0.921), removal efficiency of 92.57 %, CO2 selectivity of 58.87 %, energy efficiency of 0.25 g/kWh, O3 formation of 140.88 mg/m3 and NOx formation of 122.46 ppm were obtained. Water vapour significantly increased the removal efficiency and CO2 selectivity as well as reduced O3 and NOx. The results revealed that the CCD-RSM provided the optimum process parameters for the Non-Thermal Plasma (NTP) system.

Three‐dimensional interconnected graphene network‐based high‐performance air electrode for rechargeable zinc‒air batteries

AbstractAlthough zinc‒air batteries (ZABs) are regarded as one of the most prospective energy storage devices, their practical application has been restricted by poor air electrode performance. Herein, we developed a free‐standing air electrode that is fabricated on the basis of a multifunctional three‐dimensional interconnected graphene network. Specifically, a three‐dimensional interconnected graphene network with fast mass and electron transport ability, prepared by catalyzing growth of graphene foam on nickel foam and then filling reduced graphene oxide into the pores of graphene foam, is used to anchor iron phthalocyanine molecules with atomic Fe‒N4 sites for boosting the oxygen reduction during discharging and nanosized FeNi hydroxides for accelerating the oxygen evolution during charging. As a result, the obtained air electrode exhibited an ultra‐small electrocatalytic overpotential of 0.603 V for oxygen reactions, a high peak power density of 220.2 mW cm‒2, and a small and stable charge‒discharge voltage gap of 0.70 V at 10 mA cm‒2 after 1136 cycles. Furthermore, in situ Raman spectroscopy together with theoretical calculations confirmed that phase transformation of FeNi hydroxides takes place from α‐Ni(OH)x to β‐Ni(OH)x to γ‐Ni(3+δ)+OOH for the oxygen evolution reaction and Ni is the active center while Fe enhances the activity of Ni active sites.

Electrical arc discharge in air between Pt-coated NEMS electrodes at nanoscale separation

A thorough understanding of arc discharge mechanism as well as determination of arc discharge voltage at the nanometer scale remains challenging due to the complexities associated with electrode preparation and precisely maintaining nanoscale separations in experiments. This work addresses this challenge through a novel approach by accurately measuring electric breakdown/discharge voltages between Pt-coated Si electrodes with separations ranging from ∼5 nm to 370 nm using a combination of fixed and flexible nano-electrodes while inherently creating an ideal environment to mitigate the effect of mechanical vibrations on the measurement results. For separations of 10, 100, and 300 nm, the corresponding discharge voltages are ∼15, 75, and 160 V, respectively, with the apparent electric field for the 10 nm separation exceeding 1.5 GV m−1. The results acquired from the investigated electrode configuration closely resembling the laterally actuated nanoelectromechanical system (NEMS) cantilever relays reveals strong agreement with NEMS relay breakdown characteristics, emphasizing the importance of arc discharge considerations while designing micro/nano electromechanical devices. Furthermore, deliberately applied arc discharge is shown to provide electrode nano-welding for realization of configurable NEMS circuits.

Natural low corrosive phytic acid electrolytes enable green, ultrafast, stable and high-voltage aqueous proton battery

Proton is a promising charge carrier for aqueous rechargeable batteries due to its small ionic radius, fast diffusion kinetics and great abundance in nature. However, commonly-used proton battery electrolytes are strong acids, such as sulfuric acid, phosphoric acid, etc., which always leads to the notorious rapid corrosion of electrode and metal components, and thus the poor cyclability, the limited materials option and high maintenance cost. Here, we reported a new-type high-concentration phytic acid (PA) electrolytes, which exhibits marvellous superiorities including environmental friendliness, low corrosiveness, high ionic conductivity (133.3 mS cm−1) and wide working potential window (∼2.9 V) in contrast to conventional acid electrolytes. The experimental and calculation results indicated that the scarcity of free water in high-concentration PA electrolytes and the desolvation effect of the preferentially absorbed PA interfacial layer on the electrode surface work in synergy to inhibit the water activity and thus prevent electrode dissolution and side reactions. Benefiting from this, the assembled K0.2VO0.6[Fe(CN)6]0.8•6H2O (VHCF)//MoO3 button-type proton battery shows an average discharge voltage of 0.7 V with a pair of well-defined redox peak at about 1.4 V, great rate performance, excellent cycling stability (87.9% capacity retention after 1000 cycles at 5 A g−1) and superb coulombic efficiency at various current densities (1 A g−1–50 A g−1). Attributed to good anti-freezing properties of the electrolytes, the proton battery can also run normally at -60 °C and exhibit competent performance (a capacity retention of 45 mAh g−1 at 0.1 A g−1 after 540 cycles). Such green low corrosive electrolyte will be fully compatible with conventional battery fabrication process, and open brand new avenue for the development of aqueous proton battery.

Numerical modeling and performance analysis of anode with porous structure for aluminum-air batteries

Aluminium-air batteries have been considered as one of the most promising next-generation energy storage devices. In this work, based on COMSOL Multiphysics, we firstly explored the effect of 3D pore size structure change on the permeation performance of the solution. The results showed that enhancing the permeation stroke of permeable solutions was beneficial to expanding the electrode reaction contact area, but it would reduce the permeation and corrosion resistance effects. For this reason, we further carried out a secondary study of TPMS structure on fluid permeation and its electrochemical performance based on the TPMS structure modelling mechanism. The results showed that the TPMS structure possessed both good solution permeation reaction rate and good corrosion resistance. Additionally, in order to further verify the validity of the simulation data, we carried out the validation of the self-corrosion rate, discharge properties, and electrochemical properties. From the final data, the discharge voltage of the TPMS structure was only 1.43 V, but its corrosion current and polarisation impedance were 2.207 × 10−2 A/cm2 and 2.2 Ω∙cm2, respectively. At the same time, the structure also had good solution permeability. Therefore the porous anode structure design for aluminium-air batteries in three-dimensional state is preferred.

Electrical Discharge-Assisted Turning for UD CFRP Under Low Voltage Condition

The demand for carbon fiber reinforced plastics (CFRP), classified as functional resins, has increased for micromachined products that are manufactured using lathes and used in the medical field. However, the problems with machining CFRP include the occurrence of burrs and deterioration of the finished dimensions owing to the significant tool wear caused by the carbon fiber. To turn CFRP and maintain high dimensional accuracy, the authors proposed a novel combination of conventional turning and electrical discharge-assisted turning (EDAT). In this study, the capability to control the machinability of EDAT under low-voltage conditions was experimentally investigated. The relationship between the discharge voltage, frequency, and depth of discharge influence of the carbon fibers was clarified.

Unravelling K intercalation on graphene and its variants through two-dimensional cluster expansion modeling

In this study, we investigate K ordering and its impact on K intercalation and storage capacity in graphite, bilayer and single-layer graphene through two-dimensional cluster expansion implemented in first-principles calculations with van der Waals corrections. For graphite, similar to the Li counterpart, K intercalation exhibits a multistage feature as the K concentration increases from C2 to KC8. However, beyond KC8, K atoms become crowded in graphite, resulting in a negative discharge voltage. For bilayer and single-layer graphene, a noticeable displacement of K from original hexagonal sites occurs at higher K concentrations compared to graphite. K intercalation in graphite after the initial segment (from C2 to KC8) leads to an increase in interlayer distance, while in bilayer graphene causes much larger elongation in interlayer distance. The calculated overpotential for K intercalation on bilayer and single-layer graphene is found to be 0.17 and 0.13 V, respectively, which is lower than the overpotential (0.86 V) observed on graphite. The charge redistribution between K and carbon layers indicates that bilayer and single-layer graphene offer pseudo-capacitance, facilitating faster charge transfer and higher K capacity. The above observation suggests the graphene structures have a superior K-storage capacity compared to graphite.

Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries

The high redox potential of Zn0/2+ leads to low voltage of Zn batteries and therefore low energy density, plaguing deployment of Zn batteries in many energy-demanding applications. Though employing high-voltage cathode like spinel LiNi0.5Mn1.5O4 can increase the voltages of Zn batteries, Zn2+ ions will be immobilized in LiNi0.5Mn1.5O4 once intercalated, resulting in irreversibility. Here, we design a polymer hetero-electrolyte consisting of an anode layer with Zn2+ ions as charge carriers and a cathode layer that blocks the Zn2+ ion shuttle, which allows separated Zn and Li reversibility. As such, the Zn‖LNMO cell exhibits up to 2.4 V discharge voltage and 450 stable cycles with high reversible capacity, which are also attained in a scale-up pouch cell. The pouch cell shows a low self-discharge after resting for 28 days. The designed electrolyte paves the way to develop high-voltage Zn batteries based on reversible lithiated cathodes.

Flexible Aluminum-Air Battery Based on High-Performance Three-Dimensional Dual-Network PVA/KC/KOH Composite Gel Polymer Electrolyte.

With a large theoretical capacity and high energy density, aluminum-air batteries are a promising energy storage device. However, the rigid structure and liquid electrolyte of a traditional aluminum-air battery limit its application potential in the field of flexible electronics, and the irreversible corrosion of its anode greatly reduces the battery life. To solve the above problems, a PVA/KC/KOH (2 M) composite gel polymer electrolyte (GPE) with a three-dimensional dual-network structure consisting of polyvinyl alcohol (PVA), kappa-carrageenan (KC), and potassium hydroxide was prepared in this paper by a simple two-step method and applied in aluminum-air batteries. At room temperature, the ionic conductivity of the PVA/KC/KOH (2 M) composite GPE was found to be up to 6.50 × 10-3 S cm-1. By utilizing this composite GPE, a single flexible aluminum-air battery was assembled and achieved a maximum discharge voltage of 1.2 V at 5 mA cm-2, with discharge time exceeding 3 h. Moreover, the single flexible aluminum-air battery maintains good electrochemical performance under various deformation modes, and the output voltage of the battery remains at about 99% after 300 cycles. The construction of flexible aluminum-air batteries based on a three-dimensional dual-network PVA/KC/KOH composite GPE provides excellent safety and high-multiplication capabilities for aluminum-air batteries, making them potential candidates for various flexible device applications.

A bithiophene-substituted porphyrin displaying multi-electron redox processes as a cathode for lithium organic batteries

A non-metallated porphyrin, 5,15-di([2,2′-bithiophen]-5-yl)-10,20-diphenylporphyrin (BTPP) has been synthesized and utilized as an electrode material for lithium organic batteries (LOBs). Benefiting from the bipolar characteristics of the porphyrin core and extended [Formula: see text]-conjugation with bithiophene units, BTPP displayed as cathode material a discharge capacity of 128 mAh. g[Formula: see text] at a current density of 0.2 A. g[Formula: see text], with an average discharge voltage of 3.2 V and showed a good rate capability. At a high current density of 10 A. g[Formula: see text], it delivered a discharge capacity of 32 mAh. g[Formula: see text].

A Remaining Useful Life Indirect Prediction Method for Lithium-Ion Batteries Based on SA-DBN

To solve the issue that the battery capacity cannot be directly measured in practice, a more practical indirect remaining useful life (RUL) prediction method is proposed. First, the battery state characteristic parameters are analyzed and the time interval of equal discharge voltage drop (TIE-DVD) is selected as the indirect health factor. Second, the degradation relationship model is established by using back propagation (BP) neural network. Then, the deep belief network (DBN) model is used to establish the indirect health factor prediction model. Finally, to verify the adaptability of the proposed method to different types of batteries with different aging levels, both datasets from our own laboratory and the datasets from NASA Ames Research Center are used for experimental validations. The comparative experiments demonstrate that the proposed RUL prediction method is simple, accurate, and practical.

Determining the effect of laboratory testing conditions on working parameters of the ST-25 hall thruster

The object of this study is the ST-25 Hall thruster with limited discharge power, no more than 200 W, designed by Flight Control LLC (Ukraine). The problem that was solved in the current paper was to determine the effect of residual gas pressure in vacuum chambers on the operating parameters of the Hall thruster. To solve this task, the operating parameters of the ST-25 thruster were determined, which was tested in three vacuum chambers with different sizes of residual pressure. As a result of the laboratory study into the operating parameters of the ST-25 thruster, the volt-ampere characteristics of the engine discharge at fixed values of the working gas (xenon) flow rate were obtained. The dependences of the engine thrust on the mass flow rate of the working gas at fixed values of the discharge voltage were derived. Based on the experimental data, the dependences of the specific impulse of the engine anode unit on the discharge voltage, as well as the dependence of efficiency of the engine anode unit on the discharge voltage were calculated. The studies showed that when the residual pressure in the vacuum chamber is reduced by 2–3 times, the operating parameters of the engine increase by 15–20 %. Such a reduction in residual pressure increases thrust by 25–40 %. Special feature of the results is the determination of threshold values of residual gas pressure in vacuum chambers during experimental studies, in which the operating parameters of the Hall thruster are similar to its operating parameters under space conditions. This work’s findings could be used in practice when conducting experimental studies of electric rocket engines, when it is necessary to estimate the operating parameters of Hall thrusters that will be obtained under actual space conditions

Разработка и исследование имитационной модели мультикамерного разрядника для грозозащитного троса

Optical fiber overhead ground wire (OPGW) is an effective solution for laying mainline digital communications along high-voltage power lines. It allows you to use the existing infrastructure of the power grid and ensure the transfer of a large amount of data. The flow of lightning currents and short-circuit currents can cause a violation of the thermal resistance of the fiber and a deterioration of its performance. When the OPGW is insulated through an insulator shunted by a spark gap, during operation it is possible to change the distance in the discharge gap due to the displacement of the electrodes in the plane. Also, when the short circuit location is close, multiple overlaps will occur and as a result, short circuit current will flow through the OPGW. Thus, the article considers the possibility to use a device with a multielectrode system developed on the principle of a multichamber spark gap as a replacement of the spark gap to increase the reliability of the unit with an isolated OPGW suspension. Modeling of the device has been carried out in the ANSYS Maxwell software package, the mathematical apparatus of which is based on the use of Maxwell's differential equations and the finite element method, which allows performing numerical modeling with sufficiently high accuracy. A simulation model of a multichamber spark gap has been developed in the ANSYS Maxwell software package and calculations of electrical characteristics have been performed. For the electrode system of a multi-chamber arrester, an uneven distribution of the applied voltage across the spark discharge gaps of the chambers is determined. It is shown that when a voltage is applied to a spark gap, the highest electric field strength occurs between the first and second electrodes, and then a cascade of discharge gaps occurs, which provides the required low discharge voltages of the spark gap as a whole. The developed simplified simulation model of a multi-chamber arrester has shown all the necessary conditions for cascade imaging of the voltage distribution and the electric-field strength of various electrode options. Based on the research conducted electrodes geometry is identified for smart prototype development and ongoing multi-chamber arrester research.

Identification of the effect of electric pulse discharges on the recycling of household glass

The work was devoted to the study of the recycling of household glass waste by the electric pulse method. Cullet and glass containers were considered as the object of research. Cullet and used glass containers are considered suitable for recycling among solid household waste. The treatment of solid household waste was carried out with the formation of electrical discharges in an inhomogeneous environment (glass fragments and glass products in an aqueous environment). The experiments were carried out at different values of pulse discharge voltage (from 12 kV to 37 kV), capacitor bank capacity (from 0.4 to 1.2 µF), number of pulse discharges (from 250 to 1,000) and frequency (from 0.3 Hz to 2 Hz). The dependence of the output of the finished product on the parameters of electric pulse discharges has been revealed from the research results. According to the main results of the research work, it was found that as the parameters of electric pulse discharges increase, the yield of the finished product increases. The data made it possible to assign effective parameters for processing cullet and glass products using the electric pulse method. The granulometric composition of the powder material obtained by this method has been determined. A product with a diameter of the largest fraction of 5-8 mm and a diameter of a small fraction of 0.4 mm and 0.7 mm was obtained. The results of the experiment can be used in research on saving natural resources, energy conservation and solving environmental problems of solid waste recycling. Powdered glass is used as a thermal insulator and decorative material in construction. In addition, crushed glass is used in the production of concrete as an additional raw material.

Comparative Study of Joint Estimation of State of Charge (SOC) and State of Health (SOH) of Lithium-ion Batteries Based on Different Tree Models

The realization of accurate State of Health (SOH) and State of Charge (SOC) estimation is a prerequisite to ensure the safe use of energy storage batteries, which helps to further improve the energy utilization efficiency effectively. Data-driven methods are efficient, accurate, and do not rely on accurate battery models, which is a hot direction in battery state estimation research. However, the relationships between variables in the lithium-ion battery dataset are mostly nonlinear, which largely affects the prediction of the model. In addition, the model also has a series of defects, such as large computation, strong data dependence, and long consumption time. In this paper, a joint online estimation method of battery SOC-SOH based on tree modeling algorithm is proposed to solve the above problems. Based on NASA battery sample data, this study explores the changing law between SOC and discharge voltage and temperature under different State of Health (SOH). Subsequently, a combination of RFR, GBDT and XGBoost tree modeling algorithms are used for battery SOC-SOH estimation based on the above variation rules. The experimental results show that the R<sup>2</sup> scores of the XGBoost algorithm in predicting both SOC and SOH are more than 0.995, indicating its good adaptability and feasibility.

High-Current Density Performance of a Magnetically Shielded Hall Thruster

The performance of a magnetically shielded Hall thruster operating on xenon and krypton is characterized at discharge current densities up to 10 times greater than its nominal level. A thrust stand and far-field probe suite are employed to evaluate operation at 300 V discharge voltage and discharge currents from 15 to 125 A (xenon) and from 15 to 150 A (krypton). The thrust, specific impulse, and anode efficiency at the highest currents are found to be 1650±30 mN, 2309±56 s, and 52.8±2.0% respectively for xenon, and 1839±18 mN, 2567±48 s, and 55.0±1.6% for krypton. The thrust density at the highest conditions are shown to be six (xenon) and eight (krypton) times higher than the lowest current condition. A maximum in anode efficiency as a function of discharge current is observed for both gases. This is attributed to a trade between mass utilization, which increases to unity with current, and beam utilization, which gradually decreases with current. The dependence of these efficiency modes on current is discussed in the context of a series of first-principles scaling laws. The observation that efficiency only moderately decreases with current density is examined in the context of high-power electric propulsion development.

High-Voltage Discharge Optimization of a Hybrid-Wall Hall Thruster

A segmented discharge channel is generally adopted in a hybrid-wall Hall thruster. A metallic wall is situated in the upstream portion of the channel, while a boron nitride ceramic wall is retained in the downstream portion of the channel. This hybrid-wall design avoids the disadvantages of the mechanical properties of boron nitride ceramic. Moreover, the channel can be widened by reducing the thickness of the metallic wall upstream of the channel. In this study, the width and configuration of a discharge channel based on a hybrid-wall Hall thruster are investigated, and a convergent channel configuration is adopted. The experimental results show that the configuration of the channel significantly affects the discharge process, and the ionization and acceleration efficiency of the HEP-100HW are substantially improved using the convergent hybrid channel. The specific impulse and efficiency of the HEP-100HW with the optimal convergent hybrid channel are 210 s/2.5% and 270 s/6% higher than those of the HEP-100HW with a straight hybrid channel and the HEP-100 with a straight-configuration ceramic channel at the discharge voltage of 900 V, respectively. Furthermore, from experiments and supporting simulations, it was found that the convergent hybrid-wall design resulted in an increase in the number of ions created further upstream in the channel compared to a conventional design. This led to more efficient acceleration and ejection of the ions out of the channel, resulting in the observed performance improvement. The results from this study provide valuable guidance for the design of high-power and high-voltage Hall thrusters.

Dual-ion regulation of coordination chemistry for high-voltage stabilized P2-type cathode

P2-Na2/3Ni1/3Mn2/3O2 has shown great potential as cathode material for sodium-ion batteries with its high theoretical capacity and energy density. However, severe structural changes are induced by charging P2-Na2/3Ni1/3Mn2/3O2 above 4.2 V, resulting in rapid capacity decay and poor kinetic capability. In this study, we propose a Zn/Ti synergistic modification strategy to stabilize the P2-type cathode under high voltage. It is found that the P2-O2 phase transition with large volume change is replaced by a milder P2-Z phase transition with the noteworthy improvement in structural stability and Na+ diffusion kinetics, due to the disordered Na+/vacancy and the suppressed of the sliding of transition metal layers, as disclosed by density functional theory calculations and in-situ X-ray diffraction. Concurrently, The phenomenon of Ni and O reductive coupling is inhibited by regulating local O coordination owing to the incorporation of a strong Ti−O covalence bond, leading to the more reversible charge compensation mechanism and the inhibited lattice O evolution, as clearly revealed by ex-situ X-ray absorption spectroscopy and Differential Electrochemical Mass Spectrometry. Consequently, we obtained a stable P2-Na0.67Zn0.05Ni0.28Mn0.52Ti0.15O2 cathode, achieving an average discharge voltage of 3.62 V at 0.1 C and a capacity retention of 80% after 500 cycles at 2 C. This research provides valuable insights into the enhancement of sodium-ion battery cathode materials by utilizing different functional ions in synergy.